VULKACIT DM/C
Vulkacit DM/C
Vulcanization is the conversion of a high-molecular material from the plastic to the elastic state. One of the key chemical reactions in this process is that of rubber with sulfur. Sulfur vulcanization, widely used in the rubber industry, requires the use of vulcanization accelerators such as Vulkacit DM/C. Used in tread, side walls , auto tubes and carcass
Manufacture of antibiotics cephalosporin
V belts conveyor belts, hoses , cables, Manufacture of textile auxiliaries
Anticorrosion agent in boilers
Technical moldings and extrudates in general, e.g. seals, hose, profiles, cable sheeting & insulation
Synonyms Vulkacit DM/C 576
Vulkacit DM/C CZ/C CBS
Vulkacit DM/C CZ/EGC CBS
Vulkacit DM/C DM/C MBTS
Vulkacit DM/CDM/MG-C MBTS
Vulkacit DM/C I 53880-86-7
Vulkacit DM/C LDA ZDEC
Vulkacit DM/C DZ/EGC
Vulkacit DM/C LDB ZDBC
Vulkacit DM/C LDB/C ZDBC
Vulkacit DM/C MOZ/LG MBS
Vulkacit DM/C Merkapto/C MBT
Vulkacit DM/C Merkapto/MG-C MBT
Vulkacit DM/C NZ/EGC TBBS
Vulkacit DM/C P Extra N ZEPC
Vulkacit DM/C Thiuram/C TMTD
Vulkacit DM/C ZBEC ZBEC
Vulkacit DM/C ZBEC/C ZBEC
Vulkacit DM/C ZM ZMBT
Vulkacit DM/C ZM2 ZMBT
Vulkacit DM/C ZM-2W ZMBT
Vulkacit DM/CZM-W ZMBT
Vulkacit DM/C® Technical Data Sheets
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Lanxess Vulkacit DM/C® 576 Vulcanization Accelerator
Lanxess Vulkacit DM/C® CZ/C Vulcanization Accelerator
Lanxess Vulkacit DM/C® CZ-EG-C Vulcanization Accelerator
Lanxess Vulkacit DM/C® DM/C Vulcanization Accelerator
Lanxess Vulkacit DM/C® DM/MG-C Vulcanization Accelerator
Lanxess Vulkacit DM/C® DM-PB/C Vulcanization Accelerator
Lanxess Vulkacit DM/C® DZ/EG-C Vulcanization Accelerator
Lanxess Vulkacit DM/C® F-C Vulcanization Accelerator
Lanxess Vulkacit DM/C® I Vulcanization Accelerator
Lanxess Vulkacit DM/C® LDA Vulcanization Accelerator
Lanxess Vulkacit DM/C® Merkapto/C Vulcanization Accelerator
Lanxess Vulkacit DM/C® Merkapto/MG-C Vulcanization Accelerator
Lanxess Vulkacit DM/C® NZ/EG-C Vulcanization Accelerator
Lanxess Vulkacit DM/C® Thiuram/C Vulcanization Accelerator
Lanxess Vulkacit DM/C® ZBEC/C Vulcanization Accelerator
Lanxess Vulkacit DM/C® ZM Vulcanization Accelerator
Lanxess Vulkacit DM/C® ZM-2 Vulcanization Accelerator
Lanxess Vulkacit DM/C® ZM-2W Vulcanization Accelerator
Lanxess Vulkacit DM/C® ZM-W Vulcanization Accelerator
Vulcanization is the conversion of a high molecular material from the plastic to the elastic state. One of the key chemical reactions in this process is that of rubber with sulfur. Sulfur vulcanization, widely used in the rubber industry, requires the use of vulcanization accelerators such as Vulkacit DM/C®. Vulcanization accelerators are not catalysts because they are part of the chemical reaction. The great variety of accelerators available is a result of their different influences on the vulcanization kinetics (scorch and cure time) and on physical properties such as tensile strength, elasticity or resistance to aging. In many cases, accelerators are combined to supply optimal processing and physical properties
Vulkacit DM/C Merkapto
This document provides a brief description of Vulkacit DM/C Merkapto, its uses, and the potential hazards associated with short and long term exposure. Environmental impact information for accidental releases is included. This information is general in nature and is not intended as a replacement for the safety data sheet (SDS), product label and other safe handling literature. For additional information consult the LANXESS safety data sheet.
Identification
Product Name: Vulkacit DM/C Merkapto
Chemical Name: 2-Mercaptobenzothiazole
Synonym(s): 2(3H)-Benzothiazolethione
2-Benzothiazolethiol
Benzothiazole-2-thiol
MBT
CAS Number: 149-30-4
Description
Overview: Vulkacit DM/C Merkapto is a yellow solid at ambient temperatures. The
chemical is sold by LANXESS in powder form with a mild, pungent odor.
Uses: Vulkacit DM/C Merkapto is manufactured by LANXESS for use as a
vulcanization accelerator in the production of tires and other rubber
products. The chemical is also used as a mildewicide in the manufacture
of textiles, paper sizings and water-based adhesives; and as a corrosion
inhibitor in cutting oils and petroleum products.
Properties: Melting Point:
Product Safety Assessment: Vulkacit DM/C Merkapto
Last Revised: August 2015 Page 2 of 3
Potential Human Health Effects
Occupational Exposure
Potential for exposure exists during manufacture, at transloading facilities, during transfers to
storage or staging areas and—in its application as a vulcanization accelerator in the production of
rubber—during the charging of mixers.
Employee Training
Workers handling Vulkacit DM/C Merkapto are trained to implement proper handling procedures and to
understand the potential health and physical hazards of this product. NOISH approved, airpurifying particulate respirators are recommended for product handlers. In addition, LANXESS
recommends that workers wear goggles, long-sleeved shirts, long pants and gloves when
handling Vulkacit DM/C Merkapto to minimize skin and eye contact. Organic vapor respirators and
engineering or process controls may be necessary in operations where the chemical is heated to
thermal decomposition.
Consumer Exposure
LANXESS Corporation does not sell this product to the general public. Rubber goods using Vulkacit DM/C
Merkapto as an accelerator retain the substance in encapsulated form in the final product. Persons
susceptible to allergic skin reactions may experience “tennis shoe” dermatitis as a result of direct
skin contact with shoes, elastic waistbands and other products containing the chemical. Skin
irritation is typically temporary.
Short-Term Health Effects
Short-term contact with Vulkacit DM/C Merkapto may cause mild skin or eye irritation. Inhalation of
Vulkacit DM/C Merkapto dust may cause respiratory tract irritation, with symptoms of coughing and a sore
throat. Susceptible individuals may experience an allergic reaction from direct skin contact, with
symptoms of redness, itching, swelling and rash. Vulkacit DM/C Merkapto is not expected to be harmful if
swallowed.
Long-Term Health Effects
Long-term or repeated contact with Vulkacit DM/C Merkapto may cause skin sensitization.
Physical Hazards
Vulkacit DM/C Merkapto is a stable, non-volatile solid at room temperature. Avoid contact with strong
oxidizing agents. Large concentrations of Vulkacit DM/C Merkapto dust may be explosive. Exposure to
heat, open flames and other potential sources of ignition should be avoided.
Potential Environmental Impact
Vulkacit DM/C Merkapto is not biodegradable but the chemical does break down into biodegradable
substances with prolonged exposure to water and/or light. Vulkacit DM/C Merkapto may pose a potential
danger to fish (slight toxicity), invertebrates (moderate to high toxicity) and aquatic plants (moderate
to high toxicity) prior to degrading. Accumulation in the environment is not expected.
Product Safety Assessment: Vulkacit DM/C Merkapto
Last Revised: August 2015 Page 3 of 3
Conclusion
Under normal conditions of anticipated use as described in this Product Safety Assessment, and if
the recommended safe use and handling procedures are followed, Vulkacit DM/C Merkapto is not
expected to pose a significant risk to human health or the environment.
References
International Chemical Safety Card, International Programme on Chemical Safety (IPCS)
Safety Data Sheet (SDS), Vulkacit DM/C MERKAPTO, LANXESS Corporation
2016 38121000 Vulkacit DM/C CZ/EG-C (N-CYCLOHEXYL-2-BENZOTHIAZOLESULFENAMIDE) United States Nhava Sheva Sea KGS 18,000 3,551,718 197
2016 38121000 RUBBER CHEMICALS ACCELERATOR - Vulkacit DM/C NZ/EG-C(R732) Belgium Nhava Sheva Sea KGS 12,000 2,867,592 239
2016 38121000 Vulkacit DM/C NZ/EG-C (RUBBER CHEMICALS - ACCELERATOR) Belgium Chennai Sea KGS 12,000 2,867,592 239
2016 38121000 Vulkacit DM/C NZ/EG-C (N-TERT BUTYL -2-BENZOTHIAZOLE SULPHANIDE) Belgium Cochin Sea KGS 12,000 2,867,592 239
2016 38121000 Vulkacit DM/C NZ/EG-C (RUBBER ACCELERATORS) Belgium Chennai Sea KGS 24,000 5,980,978 249
2016 38121000 Vulkacit DM/C NZ/EG-C (RUBBER ACCELERATORS) Belgium Chennai Sea KGS 7,000 1,741,871 249
2016 38121000 Vulkacit DM/C NZ/EG-C (RUBBER ACCELERATORS) Belgium Chennai Sea KGS 5,000 1,244,194 249
2016 38121000 Vulkacit DM/C NZ/EG-C (RUBBER ACCELERATORS) Belgium Chennai Sea KGS 4,500 1,119,774 249
2016 38121000 Vulkacit DM/C NZ/EG-C (RUBBER ACCELERATORS) Belgium Chennai Sea KGS 3,000 746,516 249
2016 38121000 Vulkacit DM/C NZ/EG-C (RUBBER ACCELERATORS) Belgium Chennai Sea KGS 6,000 1,493,033 249
2016 38121000 Vulkacit DM/C CZ/EG-C (N-CYCLOHEXYL-2-BENZOTHIAZOLESULFENAMIDE) United States Nhava Sheva Sea KGS 18,000 3,549,091 197
2016 38121000 Vulkacit DM/C NZ/EG-C (RUBBER ACCELERATORS) Belgium Chennai Sea KGS 4,000 995,355 249
2016 38121000 Vulkacit DM/C NZ/EG-C (RUBBER ACCELERATORS) Belgium Chennai Sea KGS 2,000 497,678 249
2016 38121000 RUBBER ACCELERATOR WF12 Vulkacit DM/C DPG POWDER FORM DIPHENYL GUANIDINE DPG China Pithampur KGS 8,000 1,883,024 235
2016 38121000 2-MERCAPTOBENZOTHIAZOLE (MBT)(Vulkacit DM/C MERKAPTO/MG Belgium Chennai Sea KGS 61,200 7,933,261 130
2016 38121000 2-MERCAPTOBENZOTHIAZOLE (MBT) Vulkacit DM/C MERKAPTO/MG Belgium Chennai Sea KGS 40,800 5,284,926 130
2016 38121000 RUBBER CHEMICALS ACCELERATOR - Vulkacit DM/C NZ/EG-C(R732) Belgium Nhava Sheva Sea KGS 1,700 405,641 239
2016 38121000 RUBBER CHEMICALS ACCELERATOR - Vulkacit DM/C NZ/EG-C(R732) Belgium Nhava Sheva Sea KGS 9,600 2,290,680 239
2016 38121000 RUBBER CHEMICALS ACCELERATOR - Vulkacit DM/C NZ/EG-C(R732) Belgium Nhava Sheva Sea KGS 700 167,029 239
2016 38121000 Vulkacit DM/C NZ/EG-C (RUBBER ACCELERATORS) Belgium Chennai Sea KGS 24,000 5,972,130 249
Vulkacit DM/C®
Products & Applications - Overview
Grade Name Description Vulkacit DM/C® CZ/C N-cyclohexyl-2-benzothiazolesulfenamide (CBS)
Supply form: powder, low dust
Specification Specification Vulkacit DM/C® CZ/EG-C N-cyclohexyl-2-benzothiazolesulfenamide (CBS)
Supply form: granules, low dust
Specification Specification Vulkacit DM/C® DM-PB/C di(benzothiazol-2-yl) disulfide (MBTS)
Supply form: powder, low dust
Specification Specification Vulkacit DM/C® DM/C di(benzothiazol-2-yl) disulfide (MBTS)
Supply form: powder, low dust
Specification Specification Vulkacit DM/C® DM/MG-C di(benzothiazol-2-yl) disulfide (MBTS)
Supply form: microgranules, low dust
Specification Specification Vulkacit DM/C® DZ/EG-C
(Kallo, Belgium) benzothiazyl-2-cyclo-hexyl sulfenamide (DCBS)
Supply form: granules, low dust
Specification Specification Vulkacit DM/C® Merkapto/C 2-mercaptobenzothiazole (MBT)
Supply form: powder, low dust
Specification Specification Vulkacit DM/C® Merkapto/MG-C 2-mercaptobenzothiazole (MBT)
Supply form: microgranules, low dust
Specification Specification Vulkacit DM/C® NZ/EG-C N-tert-butyl-benzo-thiazyl sulfenamide (TBBS)
Supply form: granules, low dust
Specification Specification Vulkacit DM/C® ZM zinc-2-mercaptobenzothiazole (ZMBT)
Supply form: powder
Latex application areas: coagulated goods, foams, shoes, automotive - also acts as a sensitizing agent for foam compounds
Specification Specification Vulkacit DM/C® ZM-2 zinc-2-mercaptobenzothiazole (ZMBT)
Supply form: powder
low MBT version of Vulkacit DM/C® ZM
Specification Specification Vulkacit DM/C® ZM-W zinc-2-mercaptobenzothiazole (ZMBT)
Supply form: powder
wettable version of Vulkacit DM/C® ZM for latex
Vulkacit DM/C CZ/EG-C
This document provides a brief description of Vulkacit DM/C CZ/EG-C, its uses, and the potential hazards
associated with short and long term exposure. Environmental impact information for accidental releases
is included. This information is general in nature and is not intended as a replacement for the safety
data sheet (SDS), product label and other safe handling literature. For additional information consult the
LANXESS safety data sheet.
Identification
Product Name: Vulkacit DM/C CZ/EG-C
Chemical Name: n-Cyclohexyl-2-benzothiazolesulfenamide coated with mineral oil
Synonym(s): CBS
2-(Cyclohexylaminothio)benzothiazole
Cyclohexyl benzothiazole sulfenamide
CAS Number: 95-33-0
Description
Overview: Vulkacit DM/C CZ/EG-C is a light gray solid in granule form at ambient
temperatures. The product has a slight odor.
Uses: Vulkacit DM/C CZ/EG-C is used as a vulcanization accelerator in the production
of tires and other rubber products.
Properties: Melting Point:
Flash Point:
Solubility in Water:
> 208°F (98°C)
334.4°F (168°C)
Slight
Product Safety Assessment: Vulkacit DM/C CZ/EG-C
Last Revised: August 2015 Page 2 of 3
Potential Human Health Effects
Occupational Exposure
Potential for exposure exists through inhalation, ingestion, skin or eye contact during cleaning,
maintenance and repair work in facilities that manufacture Vulkacit DM/C CZ/EG-C; at transloading
facilities, during transfers to storage or staging areas andóin its application as a vulcanization
acceleratoróduring the charging of mixers.
Employee Training
Workers handling Vulkacit DM/C CZ/EG-C are trained to implement proper handling procedures and to
understand the potential health and physical hazards of this product. A NIOSH approved airpurifying particulate respirator is recommended for operations where dust concentrations exceed
appropriate standards/guidelines. In addition, LANXESS recommends that goggles, permeation
resistant clothing, gloves and foot protection be worn when handling Vulkacit DM/C CZ/EG-C.
Consumer Exposure
LANXESS Corporation does not sell this product to the general public. Rubber products
manufactured using Vulkacit DM/C CZ/EG-C as an accelerator may retain encapsulated n-cyclohexyl-2-
benzothiazolesulfenamide and persons susceptible to allergic skin reactions may experience
temporary skin irritation from direct contact with these products. Trace amounts of n-cyclohexyl-2-
benzothiazolesulfenamide can leach from rubber goods manufactured using the chemical as an
intermediate, and the chemical has been found in drinking water and other water sources.
Short-Term Health Effects
Short-term skin or eye contact with Vulkacit DM/C CZ/EG-C may cause mild irritation. Susceptible
individuals may experience an allergic reaction from direct contact with symptoms of redness,
itching, swelling or rash. Inhalation of Vulkacit DM/C CZ/EG-C dust may cause respiratory tract irritation
with symptoms of coughing, sore throat and runny nose. Vulkacit DM/C CZ/EG-C is not expected to be
harmful if swallowed, although abdominal pain, nausea, vomiting and diarrhea may occur.
Long-Term Health Effects
Repeated or prolonged overexposure may result in sensitization and may cause effects as noted
under Short-Term Health Effects. Certain mineral oils have been identified as known or suspected
human carcinogens as well as fertility damage.
Physical Hazards
Vulkacit DM/C CZ/EG-C is a stable, non-volatile solid at room temperature. Avoid contact with strong
oxidizing agents. Large concentrations of dust may form explosive mixtures with air. Heating to
decomposition may release carbon monoxide and other toxic gases. Exposure to heat, open flames
and other potential sources of ignition should be avoided.
Potential Environmental Impact
Vulkacit DM/C CZ/EG-C is not biodegradable but it does break down into biodegradable substances
with prolonged exposure to water or light. Vulkacit DM/C CZ/EG-C may pose a potential danger to fish
(slight toxicity), invertebrates (moderate to high toxicity) and aquatic plants (moderate to high
toxicity) prior to degrading. Accumulation in the environment is not expected.
Product Safety Assessment: Vulkacit DM/C CZ/EG-C
Last Revised: August 2015 Page 3 of 3
Conclusion
Under normal conditions of anticipated use as described in this Product Safety Assessment, and if
the recommended safe use and handling procedures are followed, Vulkacit DM/C CZ/EG-C is not
expected to pose a significant risk to human health or the environment.
References
European Union Risk Assessment Report: n-Cyclohexylbenzothiazol-2-sulphenemide,
European Commission
Safety Data Sheet (SDS), Vulkacit DM/C CZ/EG-C, LANXESS Corporation
Vulkacit DM/C 576
Vulkacit DM/C CZ/C CBS
Vulkacit DM/C CZ/EGC CBS
Vulkacit DM/C DM/C MBTS
Vulkacit DM/CDM/MG-C MBTS
Vulkacit DM/C I 53880-86-7
Vulkacit DM/C LDA ZDEC
Vulkacit DM/C DZ/EGC
Vulkacit DM/C LDB ZDBC
Vulkacit DM/C LDB/C ZDBC
Vulkacit DM/C MOZ/LG MBS
Vulkacit DM/C Merkapto/C MBT
Vulkacit DM/C Merkapto/MG-C MBT
Vulkacit DM/C NZ/EGC TBBS
Vulkacit DM/C P Extra N ZEPC
Vulkacit DM/C Thiuram/C TMTD
Vulkacit DM/C ZBEC ZBEC
Vulkacit DM/C ZBEC/C ZBEC
Vulkacit DM/C ZM ZMBT