Textile, Leather, Paper and Industrial Chemicals

Tartrate de calcium ( Calcium tartarate ; Calcium tartrate)
cas no 1934-21-0 4,5-dihydro-5-oxo-1-(4-sulfophenyl)-4-[(4-sulfophenyl)azo]-1H-Pyrazole-3-carboxylic acid, trisodium salt; Dihydro-5-oxo-1-(4-sulfophenyl)- 4-((4-sulfophenyl)azo)-1H- pyrazole-3- carboxylic acid, trisodium salt; Filter Yellow; Pyrazole-3-carboxylic acid, 4,5-dihydro-5-oxo-1-(4- sulfophenyl)- 4-((4-sulfophenyl)azo)-, trisodium salt; Tartrazine C; Trisodium 1-(4-sulfonatophenyl)-4-(4-sulfonatophenylazo)-5- pyrazolone-3- carboxylate; Trisodium 1-(4-sulfophenyl)-4-((4-sulfophenyl)azo) -1H-pyrazole-3-carboxylate;
TARTRAZINE
SYNONYMS Acid Yellow 23; C.I. 19140; C.I. Acid Yellow 23 trisodium salt; C.I. Food Yellow 4; D&C Yellow 5; Hydrazine Yellow; Lemon Yellow A; Zlut kysela 23; 4,5-dihydro-5-oxo-1-(4-sulfophenyl)-4-[(4-sulfophenyl)azo]-1H-Pyrazole-3-carboxylic acid, trisodium salt; Dihydro-5-oxo-1-(4-sulfophenyl)- 4-((4-sulfophenyl)azo)-1H- pyrazole-3- carboxylic acid, trisodium salt; Filter Yellow; Pyrazole-3-carboxylic acid, 4,5-dihydro-5-oxo-1-(4- sulfophenyl)- 4-((4-sulfophenyl)azo)-, trisodium salt; Tartrazine C; Trisodium 1-(4-sulfonatophenyl)-4-(4-sulfonatophenylazo)-5- pyrazolone-3- carboxylate; Trisodium 1-(4-sulfophenyl)-4-((4-sulfophenyl)azo) -1H-pyrazole-3-carboxylate; FD & C Yellow No.5; CAS NO. 1934-21-0
TARTRAZINE E 102
Tartrazine E 102 is known as azo dye or azorecolors.
Tartrazine E 102 is an additive used to give yellow color to food and beverages .


CAS Number: 1934-21-0
EC Number: 217-699-5
E number: E102 (colours)
Chemical formula: C16H9N4Na3O9S2



Trisodium 5-hydroxy-1-(4-sulfonatophenyl)-4-[(E)-(4-sulfonatophenyl)diazenyl]-1H-pyrazole-3-carboxylate, FD&C Yellow 5, Trisodium 5-oxo-1-(4-sulfonatophenyl)-4-[(E)-(4-sulfonatophenyl)diazenyl]-2,5-dihydro-1H-pyrazole-3-carboxylate, 1310yellow, c.i.640, 1H-Pyrazole-3-carboxylic acid, 2,5-dihydro-5-oxo-1-(4-sulfophenyl)-4-[(E)-2-(4-sulfophenyl)diazenyl]-, sodium salt (1:3), EINECS 217-699-5, 1H-Pyrazole-3-carboxylic acid, 4,5-dihydro-5-oxo-1-(4-sulfophenyl)-4-[(4-sulfophenyl)azo]-, trisodium salt, C16H9N4Na3O9S2, YELLOW 5, Tartrazin, TARTRAZINE, FD & C Yellow 5, y-4, 3-carboxy-5-hydroxy-1-para-sulfophenyl-4-para-sulfophenylazopyrazole trisodium salt, 69850, FD & C Yellow No. 5, Food Yellow No. 4, TARTAZINE, tartarazine, E102, MFCD00148908, FD and C Yellow No. 5, Acid Yellow 23, 1H-pyrazole-3-carboxylic acid, 2,5-dihydro-5-oxo-1-(4-sulfophenyl)-4-[(E)-(4-sulfophenyl)azo]-, trisodium salt, l-gelb2, Filter Yellow, Acid Yellow 23 and Food Yellow 4



Tartrazine E 102 has the ability to dissolve in water.
Tartrazine E 102 is known with the code E102 among food dyes.
Tartrazine E 102 is a synthetic food coloring.


Tartrazine E 102 is used as a colorant in the production of liquid and solid substances in the food industry.
Tartrazine E 102 gives yellow color to the products it is used in.
The chemical formula of Tartrazine E 102 looks like this: C16H9N4Na3O9S2


Tartrazine E 102 is known as azo dye or azorecolors.
Tartrazine E 102, a synthetic colorant, is not found in the natural environment.
Tartrazine E 102 is a water-soluble powder in physical form.


The color of Tartrazine E 102 is golden yellow.
Tartrazine E 102, known with the code E102, may appear as powder granules or aqueous solution.
Tartrazine E 102 is added to food products to increase their appeal and give them a pleasant lemon yellow hue.


Products that are attractive when viewed from the outside will be naturally perceived by people subconsciously, so manufacturers try to influence consumers in this way.
Many foods contain Tartrazine E 102 in varying amounts depending on the manufacturer or person preparing the food.


However, the latest trend is to replace Tartrazine E 102 with a non-synthetic coloring agent such as annatto, malt color or beta-carotene.
Many food products vary in Tartrazine E 102 content depending on the food preparer or manufacturer, and the latest trend is to replace non-synthetic coloring agents such as malt color, annatto or beta-carotene.


When Tartrazine E 102 is found in packaged foods, it is usually designated as “color,” “tartrazine,” or “E102,” depending on the jurisdiction and applicable labeling laws.
When Tartrazine E 102 is in foods, it is typically labeled as “color,” “tartrazine,” or “E102,” depending on the jurisdiction and applicable labeling laws.


Tartrazine E 102 is acid yellow 23 colorant.
Tartrazine E 102 is suitable for shampoos, shower & bubble baths, deodorants and toothpaste.
Tartrazine E 102 is also known as E number E102.


In cosmetics Tartrazine E 102 is usually labelled as CI 19140 or FD&C Yellow 5.
Tartrazine E 102 (also known as E102 or FD&C Yellow 5) is a synthetic yellow dye used mainly for food coloring.
Tartrazine E 102 is produced from benzene – and is little more technically than brightly colored industrial waste.


Tartrazine E 102's also one of the world's most widely used color additives – although there are natural and less damaging alternatives available, such as beta carotene, turmeric and annatto.
Tartrazine E 102, also known as 5, is known as the second most widely used food coloring.


Tartrazine E 102's chemical formula is C 16 H 9 N 4 Na 3 O 9 S 2 . Contains pyrazoline ring.
Tartrazine E 102 is among the azo dyes because it contains the -N=N- group.
In fact, Tartrazine E 102 is the most commonly used synthetic dye with monoazo structure among azo dyes.


Tartrazine E 102's color varies between orange and yellow.
Tartrazine E 102 is in powder form.
Tartrazine E 102 also dissolves easily in water.


Tartrazine E 102 is a food coloring of synthetic origin.
Tartrazine E 102 is not found in nature in its pure form.
Tartrazine E 102 is extracted from coal tar, a manufacturing waste product.


By its physical form, Tartrazine E 102 is a water-soluble powder of yellow color with a golden tint.
Under the influence of sunlight, the Tartrazine E 102 can disintegrate into simpler compounds.
The chemical formula of Tartrazine E 102: C16H9N4Na3O9S2.


Tartrazine E 102 is a synthetic lemon yellow azo dye primarily used as a food coloring.
Tartrazine E 102 is also known as E number E102, FD&C Yellow 5, Yellow 5 Lake, Acid Yellow 23, Food Yellow 4, and trisodium 1-(4-sulfonatophenyl)-4-(4-sulfonatophenylazo)-5-pyrazolone-3-carboxylate).


Tartrazine E 102 is a synthetic water soluble dye.
Tartrazine E 102 exhibits good light.
Tartrazine E 102 is designed for use in bar soap, bath & shower, liquid and skincare products.



USES and APPLICATIONS of TARTRAZINE E 102:
Tartrazine E 102 is used as a colorant in ice cream, pasta and confectionery factories.
In addition, Tartrazine E 102 can be easily used in the production of foods such as soft drinks, puddings, powdered drink mixes, breakfast cereals, jams, almond pastes, yoghurts and pickles.


Products containing Tartrazine E 102 are commonly processed commercial foods that have an artificial yellow or green color, or that consumers expect to appear brown or creamy.
The bright yellow color imitation "lemon" in baked goods has often been used.


The following is a list of foods that may contain Tartrazine E 102:
Desserts and confections : ice cream , ice pops and candy , fudge and hard candy ( jelly bear , "Check!" candies, marshmallows , etc.), cotton candy , puddings and gelatin (such as Jelly-O), cake mixes, pastries, custard powder, marzipan , biscuits and cookies. [one]


Beverages: soft drinks ( like Mountain Dew ), energy and sports drinks, powdered drink mix (like Kool-Aid), fruit-infused drinks, and flavored/mixed alcoholic beverages.
Snacks: Flavored corn chips such as Doritos , nachos , gum , popcorn ( both microwave and movie theater popcorn), and potato chips


Condiments and spreads: jam , jelly (including mint jelly), marmalade , mustard, horseradish, pickles (other products containing pickles, such as tartar sauce and dill pickles), and processed sauces.
Other processed foods: cereal ( like cornflakes , muesli ), instant or "cubed" soup), rice , rices like risotto , noodles (some varieties like Kraft Meals), pureed fruit and pickled peppers, light green seaweed salad like Wakame .


It is common for commercially processed foods to have an artificial green or yellow color, or for foods containing Tartrazine E 102 that consumers expect to appear brown or creamy.
Tartrazine E 102 is included in products such as ice creams, various desserts and candies, custard powder, ice pops and sugar, puddings, confectionery and hard candy, soft candies, cotton candy, gelatin, pastries, cake mixes, marzipan, biscuits and cookies.


In the beverage section; Tartrazine E 102 is found in soft drinks, energy and sports drinks, powdered drink mixes (such as Kool-Aid), fruit-infused drinks, and flavored, mixed alcoholic beverages.
Products falling into the snack category: nachos, flavored corn chips such as Doritos, chewing gum and popcorn (both popcorn at home and popcorn at the cinema contain Tartrazine E 102)


In the condiment and spread category of Tartrazine E 102: jam, jelly (including mint jelly), marmalade, horseradish, mustard, pickles (other products containing pickles, such as tartar sauce and dill pickles), and processed sauces.
Tartrazine E 102 is included in various food products: cereals (breakfast cereals such as corn flakes and muesli), rice such as risotto, noodles (such as some types of Kraft Meals), rice, pureed fruit and pickled peppers, light green seaweed salad.


Tartrazine E 102 is preferred in some personal care and cosmetic products.
Tartrazine E 102 is used Liquid and bar soaps, green hand soap remover, moisturizers and lotions, mouth washes, perfumes, shampoos and toothpastes, conditioners and other hair products.


Tartrazine E 102 is used Cosmetic products such as eye shadow, blush and lipstick, especially those that are pink or purple.
Tartrazine E 102 is often used for makeup products, manufacturers use different labels for all shades in the product line.
Tartrazine E 102 is used Nail polish, temporary tattoos, nail polish remover and tanning lotions.


Areas of Use of Tartrazine E 102: Desserts and candies, ice creams, soft drinks, energy and sports drinks, fruit liqueurs, cookies, corn chips, popcorn, potato chips, condiments, pastes, sauces, shampoo, bath foams, shower gel, liquid soaps, toothpastes.
Tartrazine E 102 is used in household cleaning products.


Tartrazine E 102 is used as a coloring agent in pasta, confectionery and ice cream.
At the same time, Tartrazine E 102 will be possible to see foods such as puddings, powdered drink mixes, soft drinks, jams, breakfast cereals, yoghurts, almond pastes, and pickles among the foods we see used.


Tartrazine E 102 is widely used because of its low cost. The E102 additive is one of the cheapest synthetic colorants.
Tartrazine E 102 is used in the food industry to give products a yellow color.
Tartrazine E 102 is often mixed with other colorants to give products a certain color and tint.


Tartrazine E 102 is a food additive in the category of synthetic azo colorants.
Tartrazine E 102 gives a yellow color and it is allowed to be used in any type of food (alcoholic and non-alcoholic beverages, meat products, milk, eggs, vegetables, fruits, cereals, sweets etc.), except those meant for infants and young children.


Tartrazine E 102 can be used on its own or in combination with other colorants.
Tartrazine E 102 is a synthetic lemon yellow azo dye primarily used as a food colouring.
Tartrazine E 102an be used to colour bath salts, bath bombs, melt and pour soap and lip balms.


Tartrazine E 102 is not suitable for cold process soap manufacture or gel candles.
Tartrazine E 102 is used for the production of azo dyes in the following chemicals: Sodium hydroxide, phenylhydrazine-p-sulfonic acid, and diethyl oxaloacetate.


Tartrazine E 102 is an additive used to give yellow color to food and beverages .
Soft drinks, ice cream , candies , pudding and spaghetti are the main foods Tartrazine E 102 is found in.
You can find Tartrazine E 102 in a large range of this food medicine product.


For example: Food Products confectionery soft drinks energy drinks instant puddings flavored corn chips breakfast cereals cake mixes pastries icing powder yellow popcornsoups (especially instant or "cube" soup) sauces some Rice (paella, such as risotto, etc.) powdered drink mixes sports drinks ice cream gum marzipan jam and marmalade mustard and radish yoghurt jelly noodles pickles and other pickled products fruit cordial potato chips biscuits lemon products honey products and many prepared foods Non-Food Products soap cosmetics shampoo and other hair productsmoisturizers hand santiser nail polish crayons tools and stamp paints you can also use ink to write medications vitamins antacids medical capsules some prescription drugs.


Tartrazine E 102 is used for coloring purposes in the production of products such as ice cream, confectionery, soft drinks, desserts, candies, flavored corn chips, energy drinks, sauces, pastries, spaghetti and pudding.
The use of Tartrazine E 102 in food products has been approved in EU countries, USA, Russia, Canada, Ukraine and Belarus.


The use of Tartrazine E 102 was previously banned in some European countries.
However, the European Union directive 94 / 36 / EC has allowed the use of Tartrazine E 102 by stipulating that the relevant information must be included in the package.


Tartrazine E 102 is a commonly used color all over the world, mainly for yellow, and can also be used with brilliant blue FCF (FD&C Blue 1, E133) or green S (E142) to produce various green shades.
Tartrazine E 102 serves as a dye for wool and silks, a colorant in food, drugs and cosmetics and an adsorption-elution indicator for chloride estimations in biochemistry.


Other products: Other products, such as household cleaning products, paper plates, pet foods, crayons, inks for writing instruments, stamp dyes, face paints, envelope glues, and deodorants, may also contain Tartrazine E 102.
3D printing: Tartrazine E 102 has been used as a biocompatible photoblocker for generating transparent hydrogels with complex inner structures.



PRODUCTS CONTAINING TARTRAZINE E 102:
-Foods:
Many foods contain Tartrazine E 102 in varying proportions, depending on the manufacturer or person preparing the food.
When in food, tartrazine is typically labelled as "color", "tartrazine", or "E102", depending on the jurisdiction, and the applicable labeling laws.

Products containing tartrazine commonly include processed commercial foods that have an artificial yellow or green color, or that consumers expect to be brown or creamy looking.
Tartrazine E 102 has been frequently used in the bright yellow coloring of imitation lemon filling in baked goods.
The following is a list of foods that may contain tartrazine:


*Desserts and confectionery:
ice cream, ice pops and popsicles, confectionery and hard candy (such as gummy bears, Peeps marshmallow treats, etc.), cotton candy, instant puddings and gelatin (such as Jell-O), cake mixes, pastries (such as Pillsbury pastries), custard powder, marzipan, biscuits, and cookies.


*Beverages:
soft drinks (such as Mountain Dew), energy and sports drinks, powdered drink mixes (such as Kool-Aid), fruit cordials, and flavored/mixed alcoholic beverages.


*Snacks:
flavored corn chips (such as Doritos, nachos, etc.), chewing gum, popcorn (both microwave and cinema-popped), and potato chips.


*Condiments and spreads:
jam, jelly (including mint jelly), marmalade, mustard, horseradish, pickles (and other products containing pickles such as tartar sauce and dill pickle dip), and processed sauces.


*Other processed foods:
cereal (such as corn flakes, muesli, etc.), instant or "cube" soups, rices (like paella, risotto, etc.), noodles (such as some varieties of Kraft Dinner), pureed fruit and pickled peppers, bright-green-colored seaweed salad.



PERSONAL CARE AND COSMETICS PRODUCTS USES OF TARTRAZINE E 102:
A number of personal care and cosmetics products may contain Tartrazine E 102, usually labelled as CI 19140 or FD&C Yellow 5, including:
Liquid and bar soaps, green hand sanitizer, moisturizers and lotions, mouth washes, perfumes, toothpastes, and shampoos, conditioners and other hair products.

Cosmetics, such as eyeshadow, blush, face powder and foundation, lipstick, etc. – even those that are primarily pink or purple. (Usually make-up manufacturers use one label for all shades in a product line, placing the phrase "may contain" ahead of all colors that are used in that line, not necessarily that specific shade.)
Nail polish, nail polish remover, temporary tattoos, and tanning lotions.



MEDICATIONS OF TARTRAZINE E 102:
Various types of medications include Tartrazine E 102 to give a yellow, orange or green hue to a liquid, capsule, pill, lotion, or gel, primarily for easy identification.

Types of pharmaceutical products that may contain Tartrazine E 102 include vitamins, antacids, cold medications (including cough drops and throat lozenges), lotions and prescription drugs.
Most, if not all, medication data sheets are required to contain a list of all ingredients, including Tartrazine E 102.
Some include Tartrazine E 102 in the allergens alert section.



WATER SOLUBLE FOOD COLORANT USES OF TARTRAZINE E 102:
Tartrazine E 102 is among the E-100 group food colorants.
Tartrazine E 102 is a synthetic additive with high water solubility.
Tartrazine E 102 is mostly used as a colorant in cheese, cake, gum, pudding, ice cream, pasta and confectionery manufacturing.
Although Tartrazine E 102 is a harmless additive for human health, its daily use; per kg of the user.



WHAT DOES TARTRAZINE E 102 DO?
The chemical structure of Tartrazine E 102 is similar to aspirin.
So asthmatics and others with aspirin sensitivity are particularly prone to side effects for products containing Tartrazine E 102.
In addition, Tartrazine E 102 has been linked to quite a list of harmful and unpleasant reactions, including: anxiety migraines OCD (obsessive compulsive disorder)



CHEMISTRY OF TARTRAZINE E 102:
Tartrazine E 102 is water-soluble and has a maximum absorbance in an aqueous solution at 425 nm.
Tartrazine E 102 is one of the oldest known members of the pyrazolone family of dyes.



TARTRAZINE E 102 SOURCE:
Tartrazine E 102, which is in the E 102 group colorant category, is a water-soluble colorant.
Tartrazine E 102 has a suitable location for use in many different food production and can be used in a wide range of production areas.
Tartrazine E 102 is a synthetic food dye with high water solubility.



FUNCTIONS AND PROPERTIES OF TARTRAZINE E 102:
*Tartrazine E 102 contains components that are not harmful to human health.
*Tartrazine E 102 has a wide range of uses in the food field.
*This coloring substance, Tartrazine E 102, which can be transferred into produced foods without any problems, is a yellow food dye.



WHAT FOODS CONTAIN TARTRAZINE E 102?
Tartrazine E 102 is used in many food products.
Foods containing E102;
*Soda,
*Wine,
*Non-alcoholic flavored drinks,
*Fruit and vegetable candies,
*red fruits,
*Decorating and covering materials,
*bakery products,
*sauces,
*flavored cheeses,
*Some aquatic products,
*cookies,
*preserves,
*ice creams,
*Chewing gum,
*Jam,
*Jelly and puddings,
*Cream powders and instant soups,
*Additional liquid and solid foods



WHAT IS THE TARTRAZINE E 102 PRESERVATIVE MADE OF?
Coal tar is processed to produce Tartrazine E 102.
Tartrazine E 102 is a waste product produced during coal mining.
In addition, the raw materials required for the production of Tartrazine E 102 are peat, shale and hydrocarbons remaining during the processing of oil.

These items include;
· toluenes
· xiols
· phenols
· benzenes
· anthracenes



HOW TO OBTAIN TARTRAZINE E 102?
Tartrazine E 102 is a synthetic product formed as a result of the condensation of phenylhydrazine-p-sulfonic acid and oxaloacetic acid.
Tartrazine E 102 in the reaction combines with sulfanilic acid containing nitrogen.

Afterwards, an ester is formed.
Tartrazine E 102 is formed by hydrolysis of the resulting ester and sodium hydroxide.
Tartrazine E 102 is also formed as a result of the condensation of two moles of Phenylhydrazine-p-sulfonic acid and one mole of dihydroxytartaric acid.



SOURCE OF TARTRAZINE E 102:
Tartrazine E 102 is a water-soluble colorant. It is in the E 102 group colorants category.
Tartrazine E 102 is a synthetic food dye with high water solubility.
Tartrazine E 102 is also suitable for use in different food productions and it is possible to transfer it to production areas in a wide structure.



SPECIAL STORAGE/USE CONDITIONS OF TARTRAZINE E 102:
Store Tartrazine E 102 in a cool and dry place, free from moisture, in its original packaging.
Protect Tartrazine E 102 from heat and light.



PHYSICAL and CHEMICAL PROPERTIES of TARTRAZINE E 102:
Chemical formula: C16H9N4Na3O9S2
Molar mass: 534.36 g·mol−1
Solubility in water: 20 g/100 mL
Solubility: 18 g/100 mL in glycerol, negligible in ethanol
Physical state: solid
Color: No data available
Odor: No data available
Melting point/freezing point: No data available
Initial boiling point and boiling range: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Flash point: No data available

Autoignition temperature: No data available
Decomposition temperature: No data available
pH: No data available
Viscosity
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Water solubility No data available
Partition coefficient:
n-octanol/water: No data available
Vapor pressure: No data available
Density: No data available
Relative density: No data available
Relative vapor density: No data available

Particle characteristics: No data available
Explosive properties: No data available
Oxidizing properties: No data available
Other safety information No data available
Appearance/Structure: Yellow, powder
Solubility: Water-soluble
E Code: E102
Melting Point 300ºC
Boiling Point N/A
Flash Point N/A
Molecular Formula: C16H9N4Na3O9S2
Molecular Weight: 534.36
Density: 1.93 g/cm3 (20ºC)



FIRST AID MEASURES of TARTRAZINE E 102:
-Description of first-aid measures:
*If inhaled:
After inhalation:
Fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
*In case of eye contact:
After eye contact: rinse out with plenty of water.
Remove contact lenses.
*If swallowed:
After swallowing:
Make victim drink water (two glasses at most).
Consult doctor if feeling unwell.
-Indication of any immediate medical attention and special treatment needed:
No data available



ACCIDENTAL RELEASE MEASURES of TARTRAZINE E 102:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up dry.
Dispose of properly.
Clean up affected area



FIRE FIGHTING MEASURES of TARTRAZINE E 102:
-Extinguishing media:
*Suitable extinguishing media:
Water
Foam
Carbon dioxide (CO2)
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Suppress (knock down) gases/vapors/mists with a water spray jet.
Prevent fire extinguishing water from contaminating surface water or the ground water system.



EXPOSURE CONTROLS/PERSONAL PROTECTION of TARTRAZINE E 102:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Safety glasses
*Skin protection:
Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Splash contact:
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
*Respiratory protection:
Recommended Filter type: Filter type P1
-Control of environmental exposure
Do not let product enter drains.



HANDLING and STORAGE of TARTRAZINE E 102:
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Dry.
Keep in a dry place.



STABILITY and REACTIVITY of TARTRAZINE E 102:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .
-Conditions to avoid:
no information available
-Incompatible materials:
No data available



TARTRAZINE FOOD GRADE
Tartrazine Food Grade is a common color around the world, primarily yellow, but can also be used with Brilliant Blue FCF (FD u0026 C Blue 1, E133) or Green S (E142) to produce a variety of green hues.
Tartrazine, also known as E 102, is a synthetic lemon yellow azo dye used as a food coloring.
Tartrazine Food Grade is also used in pharmaceuticals and cosmetics.

CAS Number: 1934-21-0
Molecular Formula: C16H13N4NaO9S2
Molecular Weight: 492.41
EINECS Number: 217-699-5

Synonyms: Tartrazine, 1934-21-0, Acid yellow 23, Yellow 5, Food Yellow 4, Aizen tartrazine, FD&C Yellow No. 5, Tartraphenine, Tartran Yellow, FD & C Yellow no. 5, Amacid Yellow T, Cilefa Yellow T, 1342-47-8, trisodium salt, C.I. ACID YELLOW 23, A.F. Yellow No. 4, C.I. 19140, Tartrazine FD&C Yellow #5, Atul Tartrazine, Erio Tartrazine, Kako Tartrazine, Tartrazine Lake, Tartrazine B, Tartrazine C, Tartrazine G, Tartrazine M, Tartrazine N, Tartrazine O, Tartrazine T, CI 19140, HD Tartrazine, Hydrazine Yellow, Lake Yellow, Sugai Tartrazine, Tartrazine FQ, Tartrazine NS, Tartrazine XX, Tartrazol Yellow, Tartrazine XXX, Tartrazine MCGL, Tartrazol BPC, Dye Yellow Lake, Fenazo Yellow T, Kayaku Tartrazine, Mitsui Tartrazine, Oxanal Yellow T, Tartar Yellow N, Tartar Yellow S, Tartrazine Yellow, Kiton Yellow T, Lemon Yellow A, Acid Yellow T, Bucacid tartrazine, Dolkwal tartrazine, Hexacol Tartrazine, Hidazid Tartrazine, Acilan Yellow GG, Egg Yellow A, San-ei Tartrazine, Tartar Yellow FS, Tartar Yellow PF, Airedale Yellow T, Canacert tartrazine, Food Yellow 5, Neklacid Yellow T, Tartrine Yellow O, Eurocert Tartrazine, Vondacid Tartrazine, Hydroxine Yellow L, Tartrazine C Extra, Calcocid Yellow XX, KCA Tartrazine PF, Yellow Lake 69, Naphtocard Yellow O, Tartrazine A Export, HD Tartrazine Supra, Calcocid Yellow MCG, Tartrazine Yellow 5, Yellow No. 5, Tartrazine A expo T, Tartrazine B.P.C., D&C Yellow 5, Food Yellow No. 4, Lemon Yellow A Geigy, Schultz No. 737, Maple Tartrazol Yellow, Acid Leather Yellow T, C.I. 640, Unitertracid Yellow TE, Yellow No. 5 FDC, Curon Fast Yellow 5G, FD And C Yellow 5, 1310 Yellow, 1409 Yellow, Xylene Fast Yellow GT, Hispacid Fast Yellow T, Usacert Yellow No. 5, C.I. Food Yellow 4, Hexacert Yellow No. 5, trisodium 5-oxo-1-(4-sulfonatophenyl)-4-(4-sulfonatophenyl)diazenyl-4H-pyrazole-3-carboxylate, CHEBI:9405, FD&G Yellow No. 5, Tartrazine Extra Pure A, L Yellow Z 1020, Tartrazine Lake Yellow N, 12225-21-7, Edicol Supra Tartrazine N, D and C Yellow No. 5, KCA Foodcol Tartrazine PF, Certicol Tartrazol Yellow S, Tartrazine O Specially Pure, Tartrazine XX Specially Pure, Dye FD and C Yellow No. 5, Tartrazine FD & C Yellow #5, E102, Kayaku Food Colour Yellow No. 4, C.I. Acid Yellow 23, trisodium salt, trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4H-pyrazole-3-carboxylate, m-8847, Yellow 5 Lake, NSC4760, Zlut kysela 23, 4,5-Dihydro-5-oxo-1-(4-sulfophenyl)-4-((4-sulfophenyl)azo)-1H-pyrazole-3-carboxylic acid, trisodium salt, Sodium 5-oxo-1-(4-sulfonatophenyl)-4-((4-sulfonatophenyl)diazenyl)-4,5-dihydro-1H-pyrazole-3-carboxylate, Trisodium 5-oxo-1-(4-sulfonatophenyl)-4-[(E)-(4-sulfonatophenyl)diazenyl]-4,5-dihydro-1H-pyrazole-3-carboxylate, Zlut potravinarska 4,3-Carboxy-5-hydroxy-1-p-sulfophenyl-4-p-sulfophenylazopyrazole trisodium salt, L-Gelb 2, L-Gelb 2 [German], Zlut kysela 23 [Czech], UNII-I753WB2F1M, Zlut potravinarska 4 [Czech], tri sodium salt, CCRIS 2656, HSDB 7216, FD & C Yellow No. 5 tartrazine, NSC 4760, Food yellow No.4, EINECS 217-699-5, E 102, Epitope ID:124945, Tartrazine, analytical standard, Acid Yellow 23 Aluminium lake, UJMBCXLDXJUMFB-UHFFFAOYSA-K, Tartrazine, p.a., 95-105%, Tartrazine, Dye content >=85 %, AMY22425, Trisodium salt of 3-carboxy-5-hydroxy-1-sulfophenylazopyrazole, Tartrazine, for microscopy (Hist.), 1-(4-Sulfophenyl)-4-((4-sulfophenyl)azo)-1H-pyrazole-3-carboxylic, MFCD00148908, AKOS015903034, AKOS016010270, Trisodium 3-carboxy-5-hydroxy-1-p-sulfophenyl-4-p-sulfophenylazopyrazole, Trisodium 5-hydroxy-1-(4-sulphophenyl)-4-(4-sulphophenylazo)pyrazole-3-carboxylate, BP-31013, Trisodium 4,5-dihydro-5-oxo-1-(4-sulfophenyl)-4-((4-sulfophenyl)azo)-1H-pyrazole-3-carboxylate, Y-4, FT-0621860, C.I. Acid Yellow 23, trisodium salt (VAN), C07574, D90635, Q407158, W-107716, 4,5-Dihydro-5-oxo-1-(4-sulfophenyl)-4-((4-sulfophenyl)azo)-1H-pyrazole-3-carboxylic acid, 5-oxo-1-(4-sulfophenyl)-4-[(E)-(4-sulfophenyl)azo]-4H-pyrazole-3-carboxylic acid, 1H-Pyrazole-3-carboxylic acid, 4,5-dihydro-5-oxo-1-(4-sulfophenyl)-4-(2-(4-sulfophenyl)diazenyl)-, sodium salt (1:3), 4,5-dihydro-5-oxo-1-(4-sulfophenyl)-4-(4-sulfophenyl)azo-1H-Pyrazole-3-carboxylic acid trisodium salt, Pyrazole-3-carboxylic acid, 5-hydroxy-1-(p-sulfophenyl)-4-(p-sulfophenyl)azo-, trisodium salt, sodium (E)-5-oxo-1-(4-sulfonatophenyl)-4-((4-sulfonatophenyl)diazenyl)-4,5-dihydro-1H-pyrazole-3-carboxylate.

Tartrazine Food Grade can be synthesized by the reaction of sulfanilic acid with 3-carboxy-l-(4-sulfophenyl)-5-pyrazolone.
Soluble in water for yellow, slightly soluble in ethanol and soluble fiber.
Tartrazine Food Grade, insoluble in other organic solvents.

An organic sodium salt which is the trisodium salt of Tartrazine Food Grade acid.
Tartrazine Food Grade is a coloring additive of the nitric type (called azoic), with a citric yellow hue,authorized for use in the food industry.
Tartrazine Food Grade is obtained synthetically by azo coupling of diazotized sulfanilic acid.

The strong sulfuric acid for yellow, yellow solution diluted; In nitric acid solution for yellow.
Tartrazine Food Grade is used for wool, silk, vinegar, polyamide fiber dyeing and printing directly.
Tartrazine Food Grade is a synthetic azo dye, commonly found in drugs, food products and cosmetics.

Tartrazine Food Grade is primarily used to add color to a variety of food and beverage products.
The Barium salt also used for paper, leather, soap, drug, plastic, aluminium surface shading, can also be used in cosmetics and food coloring.
The prevalence of Tartrazine Food Grade intolerance is estimated at 360,000 U.S. Citizens affected, less than 0.12% of the general population.

According to the FDA, Tartrazine Food Grade causes hives in fewer than 1 in 10,000 people, or 0.01%.
It is not clear how many individuals are sensitive or intolerant to Tartrazine Food Grade, but the University of Guelph estimates that it is 1 to 10 out of every ten thousand people (0.01% to 0.1% of the population).
There is much controversy about whether Tartrazine Food Grade has ill effects on individuals who are not clearly intolerant.

Total avoidance is the most common way to deal with Tartrazine Food Grade sensitivity, but progress has been made in reducing people's Tartrazine Food Grade sensitivity in a study of people who are simultaneously sensitive to both aspirin and tartrazine.
Tartrazine Food Grade is a food coloring of synthetic origin.
Tartrazine Food Grade is not found in nature in its pure form.

The E102 colorant is extracted from coal tar, a manufacturing waste product.
By its physical form, Tartrazine Food Grade is a water-soluble powder of yellow color with a golden tint.
Under the influence of sunlight, the Tartrazine Food Grade additive can disintegrate into simpler compounds. The chemical formula of tartrazine: C16H9N4Na3O9S2.

Tartrazine Food Grade is widely used because of its low cost.
Tartrazine Food Grade additive is one of the cheapest synthetic colorants.
Tartrazine Food Grade colorant is used in the food industry to give products a yellow color.

Tartrazine Food Grade is often mixed with other colorants to give products a certain color and tint.
Tartrazine Food Grade is a synthetic lemon yellow azo dye commonly used as a food colouring and is water soluble.
Tartrazine Food Grade can be used with Brilliant Blue FCF or Green S to produce various green shades.

Tartrazine Food Grade and (E 102a) are additives used to give yellow color to foods and beverages.
Soft drinks, ice cream , candies , pudding and spaghetti are the main foods.
They cause skin rashes and asthma attacks.

Tartrazine Food Grade is an organic compound classified as an azo dye.
Tartrazine Food Grade is chemical name is 5-(4-sulfophenyl)-4-(4-sulfophenylazo)-3H-1,2,4-triazol-3-one.
Tartrazine Food Grade provides a bright, lemon yellow color to food and beverages.

Tartrazine Food Grade is water-soluble and stable under various conditions, making it suitable for a wide range of products.
The use of tartrazine as a food additive is regulated by food safety authorities in different countries.
Some individuals may experience hypersensitivity or allergic reactions to Tartrazine Food Grade, and there have been anecdotal reports linking it to conditions such as asthma and hyperactivity in children.

However, scientific studies have not consistently supported these claims.
Regulatory bodies carefully evaluate the safety of food additives, including tartrazine, and establish acceptable daily intake levels.
In many countries, food products containing Tartrazine Food Grade are required to list it on the ingredient label.

This allows consumers with sensitivities or allergies to avoid products containing this additive.
Due to concerns about artificial food colorings, some food manufacturers and consumers prefer natural alternatives.
Turmeric, saffron, and annatto are examples of natural colorings that can be used as substitutes for synthetic dyes like tartrazine.

Tartrazine Food Grade is an azo dye, also known as FD&C Yellow No. 5 and is commonly used as a pharmaceutical colorant.
Tartrazine Food Grade has been FDA-approved as a drug colorant for internal consumption, external use and around the eye area.
In addition to use in pharmaceuticals as a dye, Tartrazine Food Grade is used as a food and cosmetic colorant.

FD&C colors are the colors certified for use by the U.S. FDA, in the drug, food and cosmetic industry.
Over-the-counter and prescription drugs that contain Tartrazine Food Grade shall bear statements on the label stating that the product contains FD&C Yellow No. 5 (tartrazine) as a color additive or contains color additives including Tartrazine Food Grade.
They may also state that Tartrazine Food Grade may cause allergic-type reactions (including bronchial asthma) in certain susceptible persons.

Although the overall incidence of Tartrazine Food Grade sensitivity in the general population is low, it is frequently seen in patients who also have aspirin hypersensitivity.
This warning statement shall appear in the "Precautions" section of the labeling.
Tartrazine Food Grade is an azoic food additive with dye function, internationally labeled as INS102 and in Europe with the number E102.

Tartrazine Food Grade is a pyrazolone derivative and is used in various food, cosmetic, and pharmaceutical products to impart a bright yellow color.
Tartrazine Food Grade hypersensitivity reactions include headaches, asthma attacks, itching or hives, insomnia, and hyperactivity.
Tartrazine Food Grade is often associated with allergies and hypersensitivity reactions, particularly in patients with asthma or aspirin intolerance.

Tartrazine Food Grade hypersensitivity reactions include headaches, asthma attacks, itching or hives, insomnia, and hyperactivity.
The avoidance of Tartrazine Food Grade to prevent allergic asthma in these patients is controversial.
A Cochrane Review from 2006 suggests that exclusion of tartrazine from the diets of patients with asthma does not worsen or improve asthma symptoms.

Tartrazine Food Grade is a synthetic lemon yellow azo dye used primarily as a food coloring.
Tartrazine Food Grade is also known as E number E102, CI. FD u0026 C Yellow 5, Acid Yellow 23, Food Yellow 4, and Trisodium 1-(4- sulfonatophenyl)-4-(4-sulfonatophenylazo)-5-pyrazolone-3-carboxylate).
Tartrazine Food Grade is a synthetic organic chemical.

Tartrazine Food Grade is soluble in water and has a maximum absorbance in an aqueous solution at 427 ± 2 nm.
Tartrazine Food Grade (otherwise known as E102 or FD&C Yellow 5) is a synthetic lemon yellow azo dye used as a food coloring.
Tartrazine Food Grade is derived from coal tar.

Tartrazine Food Grade is water solubleand has a max absorbance in an aqueous solution at 427±2 nm.
Tartrazine Food Grade says it has no side effects by world organizations and is accepted by all religious organizations.
Tartrazine Food Grade is known as azo dye or azocolors.

Asthma, blurred vision, skin disease can cause allergic reactions.
In Germany, after, Tartrazine Food Grade is stipulated that Tartrazine can reduce and affect children's activity and attention.
Tartrazine Food Grade is recommended to stay away from those who are allergic to (E 210) or Aspirin.

Tartrazine Food Grade can be of vegetable or animal origin.
Tartrazine Food Grade by Sensient Cosmetic Technologies is a synthetic water soluble dye.
Tartrazine Food Grade exhibits good light fastness.

Tartrazine Food Grade is designed for use in bar soap, bath & shower, liquid and skincare products.
Tartrazine Food Grade is a synthetic lemon yellow azo dye primarily used as a food colouring.
Can be used to colour bath salts, bath bombs, melt and pour soap and lip balms.

Tartrazine Food Grade appears to cause the most allergic and/or intolerance reactions of all the azo dyes, particularly amongst those with an aspirin intolerance and asthmatics.
Other reactions can include migraine, blurred vision, itching, rhinitis and purple skin patches, (because of this more use is now being made of Annatto (E160b).
In conjunction with Benzoic acid (E210) Tartrazine Food Grade appears to create an over-activity in children.

Tartrazine Food Grade is a dye.
Tartrazine Food Grade is found in confectionery, cotton candy, soft drinks, instant puddings, flavored chips (Doritos, Nachos), cereals (corn flakes, muesli), cake mixes, pastries, custard powder, soups (particularly instant or "cube" soups), sauces, some rices (paella, risotto, etc.), Kool-Aid, Mountain Dew, Gatorade, ice cream, ice pops, candy, chewing gum, marzipan, jam, jelly, gelatins, marmalade, mustard, horseradish, yogurt, noodles, pickles and other pickled products, certain brands of fruit squash, fruit cordial, chips, biscuits, and many convenience foods together with glycerin, lemon, and honey products.

Tartrazine Food Grade is also found in soaps, cosmetics, shampoos and other hair products, moisturizers, crayons, and stamp dyes.
The pharmaceutical industry uses this in vitamins, antacids, and prescription drugs.
Tartrazine Food Grade is a synthetic yellow dye used mainly for food coloring.

Tartrazine Food Grade is produced from benzene - and is technically little more than brightly colored industrial waste.
Tartrazine Food Grade also one of the most used color additives in the world – although there are natural and less harmful alternatives available as beta carotene, turmeric and annatto.

Food Products confectionery soft drinks (Mountain Dew is a well-known culprit) energy drinks instant puddings flavored corn chips breakfast cereals cake mixes pastries cream
powder yellow popcorn soups (especially instant or "cubed" soups) sauces some Rice (such as paella, risotto, etc.) powder drink mixes sports drinks ice cream gum marzipan jam and marmalad mustard and radish yogurt jelly noodles pickles and other pickled products fruit cordial potato chips biscuits lemon products honey products and many prepared foods.
Non-Food Products soap cosmetics shampoo and other hair products emollients hand santiser nail polish pens can also use ink to write tools and stamp paints.

Tartrazine Food Grade is in the category of E 102 group colorants.
Tartrazine Food Grade is a synthetic food dye with high water solubility.
Tartrazine Food Grade is in a suitable position to be evaluated in different food productions and it is possible to transfer it to production areas in a large structure.

Contains substances that do not harm human health.
Tartrazine Food Grade is a synthetic lemon yellow azo dye commonly used as a food colouring and is water soluble.
Tartrazine Food Grade can be used with Brilliant Blue FCF or Green S to produce various green shades.

Tartrazine Food Grade also has a structure suitable for over-evaluation in the food sector.
The colorant is a yellow food dye and it is possible to transfer it into the food produced without any problems.
Tartrazine Food Grade is used as a colorant in ice cream, pasta and confectionery factories.

In addition, Tartrazine Food Grade is easily used in the production of soft drinks, puddings, powdered drink mixes, breakfast cereals, jams, marzipan, yoghurts and pickles.
Tartrazine Food Grade, also referred to as FD&C yellow #5, is an artificial (synthetic) food dye.
Tartrazine Food Grade is a food colour you might find in a variety of foods – everything from soft drink to snack foods and bread.

This artificial food colour may be linked to hyperactivity, skin rashes, migraines, behavioural problems and asthmatic attacks.
Tartrazine Food Grade is one of several azo food dyes that are made from petroleum products.
Artificial food dyes are used to make foods more aesthetically appealing from a visual standpoint.

These dyes can be used to create colors not possible with natural products as well as to reinstate the original appearance of a food which may be lost in the production process.
Artificial food dyes are also often cheaper and more accessible than natural food dyes.
Tartrazine Food Grade is a synthetic azo dye (artificial color) used to achieve the lemon-like yellow coloring in the food and other products to make it all more visually appealing cheaply.

Tartrazine Food Grade, commonly known as FD&C Yellow 5 in the United States in the European Union, is a bright yellow azo dye that is one of the most common yellow food colorants.
Tartrazine Food Grade is an odorless yellow solid compound, soluble in water and glycols.
Some sources claim its color is either yellow-orange or (dark) orange, even red, though this is most likely from air oxidation or other impurities.

Tartrazine Food Grade's maximum absorbance in aqueous solution is 425 nm.
Tartrazine Food Grade is typically synthesized from petroleum-derived chemicals.
The production process involves the reaction of aromatic amines with diazonium salts.

One of the reasons for the widespread use of tartrazine is its water solubility.
This property allows Tartrazine Food Grade to be easily incorporated into various food and beverage formulations.
Tartrazine Food Grade can exhibit different colors at different pH levels.

In acidic environments, Tartrazine Food Grade appears as a yellow color, but it can shift to orange or red in alkaline conditions.
This pH sensitivity can be advantageous in certain food applications.
Food colorings, including Tartrazine Food Grade, are subject to strict regulations and safety assessments in various countries.

Regulatory agencies evaluate their potential impact on health and set permissible levels to ensure consumer safety.
Tartrazine Food Grade is a synthetic lemon yellow azo dye primarily used as a food coloring.
Tartrazine Food Grade is also known as E number E102, C.I. 19140, FD&C Yellow 5, Yellow 5 Lake, Acid Yellow 23, Food Yellow 4, and trisodium 1-(4-sulfonatophenyl)-4-(4-sulfonatophenylazo)-5-pyrazolone-3-carboxylate).

Tartrazine Food Grade is a commonly used color all over the world, mainly for yellow, and can also be used with brilliant blue FCF (FD&C Blue 1, E133) or green S (E142) to produce various green shades.
Tartrazine Food Grade serves as a dye for wool and silks, a colorant in food, drugs and cosmetics and an adsorption-elution indicator for chloride estimations in biochemistry.
Tartrazine Food Grade, or as it is called Yellow No.5 (E102) on commercial labels, is an artificial azo food coloring that gives a yellow or orange color.

Tartrazine Food Grade intended use is to make foods, especially highly processed foods such as confectionery, carbonated drinks and breakfast cereals, look fresher, tastier and more appetizing, and become aesthetically appealing.
Artificial food dyes are cheaper and more accessible than natural food dyes.
Tartrazine Food Grade is an azo compound with the formula C16H9N4Na3O9S2 obtained from petroleum products.

Carbon, hydrogen , which is generally found in natural food dyesand in addition to nitrogen, Tartrazine Food Grade also contains sodium, oxygen and sulfur.
These are all naturally occurring elements, but natural dyes are not as stable as Tartrazine Food Grade, which is made from petroleum by-products.
Many foods contain Tartrazine Food Grade in varying proportions, depending on the manufacturer or person preparing the food.

When in food, tartrazine is typically labelled as "color", "tartrazine", or "E102", depending on the jurisdiction, and the applicable labeling laws (see Regulation below).
Products containing tartrazine commonly include processed commercial foods that have an artificial yellow or green color, or that consumers expect to be brown or creamy looking.
Tartrazine Food Grade has been frequently used in the bright yellow coloring of imitation lemon filling in baked goods.

Tartrazine Food Grade appears to cause the most allergic and intolerance reactions of all the azo dyes, particularly among asthmatics and those with an aspirin intolerance.
Symptoms from tartrazine sensitivity can occur by either ingestion or cutaneous exposure to a substance containing Tartrazine Food Grade.
Symptoms appear after periods of time ranging from minutes up to 14 hours.

Tartrazine Food Grade is one of the most widely used artificial colorants in the food industry.
Tartrazine Food Grade is often found in products such as candies, soft drinks, cereals, sauces, and desserts.
The colorant is a yellow-orange powder that dissolves in water to give a solution golden yellow at neutrality and in acid.

When dissolved in concentrated sulfuric acid, Tartrazine Food Grade yields an orange-yellow solution that turns yellow when diluted with water
Tartrazine Food Grade a synthetic lemon yellow azo dye used as a food colouring.
Tartrazine Food Grade is water solution with hydrochloric acid discoloration; Add sodium hydroxide is red light deepened.

Melting point: 300 °C
Boiling point: 909.54℃[at 101 325 Pa]
Density: 2.121[at 20℃]
vapor pressure: 0Pa at 25℃
storage temp.: room temp
solubility: DMSO (Sparingly, Heated), Water (Slightly)
Colour Index: 19140
form: Powder
color: Orange
Water Solubility: 260 g/L (30 ºC)
Sensitive: Hygroscopic
Merck: 14,9072
BRN: 69850
Stability: Stable. Hygroscopic. Incompatible with strong oxidizing agents.
Biological Applications Treating hepatitis,periodontal disease,psoriasis
LogP: -1.572 at 20℃

Tartrazine Food Grade is one of various food colors said to cause food intolerance and ADHD-like behavior in children, evidence for this claim is lacking.
Tartrazine Food Grade is possible that certain food colorings may act as a trigger in those who are genetically predisposed, but the evidence for this effect is weak.
Medications prescribed for nausea including pregnancy, painkillers etc. they contain these or other additives, preservatives and colorants.

All foods, beverages, and even medicines that are dyed yellow contain Tartrazine Food Grade.
Although some drugs are dyed in different colors, you can read that they contain Tartrazine Food Grade, E-102a in the package insert.
Tartrazine Food Grade addition, it is not written on many products sold in the markets that they contain tatrazine.

Tartrazine Food Grade is listed as a permitted food coloring in Canada.[24] The majority of pre-packaged foods are required to list all ingredients, including all food additives such as color; however section B.01.010 (3)(b) of the Regulations provide food manufacturers with the choice of declaring added color(s) by either their common name or simply as "colour".
In February 2010, Health Canada consulted the public and manufacturers on their plans to change the labelling requirements.
Tartrazine Food Grade is a cost-effective and stable coloring agent, making it a popular choice for manufacturers.

Tartrazine Food Grade is commonly used in soft drinks, energy drinks, flavored beverages, and powdered drink mixes to enhance the visual appeal of the products.
Regulatory bodies, such as the Joint FAO/WHO Expert Committee on Food Additives (JECFA) and the U.S. FDA, have established acceptable daily intake (ADI) levels for Tartrazine Food Grade.
These levels are set to ensure that the intake of the additive does not pose a risk to human health under normal conditions of use.

Tartrazine Food Grade is sometimes used in combination with other food colorings to achieve specific shades.
This blending of colors can create a broader spectrum of hues in the final product.
Tartrazine Food Grade is relatively stable under heat and light conditions, which contributes to its suitability for a variety of food processing methods and storage conditions.

Unlike some natural food colorings derived from plants, fruits, or vegetables, Tartrazine Food Grade is a synthetic dye and does not occur naturally.
Apart from its use in the food industry, Tartrazine Food Grade is also employed in cosmetics, pharmaceuticals, and personal care products for coloring purposes.
Health Canada felt that Tartrazine Food Grade might be prudent to require the identification of specific colors on food labels, to allow consumers to make better informed choices.

The results of the consultation supported increased transparency.
Some respondents proposed banning the use of synthetic food colors, however Health Canada found that existing scientific literature does not demonstrate that synthetic food coloring is unsafe in the general population; they are instead considering more transparent labelling to allow those with sensitivities to food color to make informed choices.
The relevant proposed regulatory changes will be developed and published for consultation in Part I of the Canada Gazette, the official newsletter of the Government of Canada.

Tartrazine Food Grade was banned in Austria[36] and Germany, before European Parliament and Council Directive 94/36/EC lifted the ban.
Tartrazine Food Grade is a synthetic yellow food dye. It is also called FD&C yellow #5.
Tartrazine Food Grade is one of several azo food dyes made from petroleum products, and among several dyes and food additives studied for potential health impacts.

Many foods contain Tartrazine Food Grade in varying proportions depending on the manufacturer or the person preparing the food; however, the latest trend is to replace a non-synthetic coloring agent such as annatto, malt color or beta-carotene.
When tartrazine is in food, it is typically labeled "color", "tartrazine" or "E102" depending on jurisdiction and applicable labeling laws.
Tartrazine Food Grade-containing products are commonly processed commercial foods that have an artificial yellow or green color, or consumers expect them to appear brown or creamy.

The bright yellow color was often used to imitate the "lemon" in baked goods.
The following is a list of foods that may contain Tartrazine Food Grade; Desserts and confectionery : ice cream , ice pops and candy , fudge and hard candy, cotton candy, puddings and gelatin (such as Jelly-O), cake mixes, pastries, custard powder, marzipan , biscuits and cookies.
Soft drinks ( such as Mountain Dew ), energy and sports drinks, powdered beverage mix (such as Kool-Aid), fruit-based beverages, and flavored/mixed spirits.

Flavored corn chips like Doritos, nachos, chewing gum, popcorn (both microwave and movie theater popcorn), and potato chips.
Condiments and spreads: jam, jelly (including mint jelly), marmalade , mustard, horseradish, pickles (other products that contain pickles, such as tartar sauce and dill pickles), and processed sauces.
Other processed foods: cereal ( like cereal , muesli ), instant or "cubed" soup), rice, rice like risotto, noodles (like some types of Kraft Dishes), mashed fruit and pickled peppers, light green seaweed salad Wakame.

A number of personal care and cosmetic products may contain Tartrazine Food Grade, often labeled as CI 19140.
Liquid and bar soaps, green soap remover, moisturizers and lotions, mouth washes, perfumes, toothpastes and shampoos, creams and other hair products.
Cosmetics such as eye shadow, blush, face powder and foundation, lipstick - mainly pink or purple ones.

Often makeup manufacturers use a label for all the shades in the product line.
Nail polish, nail polish remover, temporary tattoos and tanning lotions.
Tartrazine Food Grade is a food additive approved by the European Union (EU).

Tartrazine Food Grade is used as a synthetic colouring agent in food products.
The common name for Tartrazine Food Grade is Tartrazine.
Tartrazine Food Grade gives a yellow colour to food products and is very soluble in water.

The colouring is derived from coal tar.
The colouring Tartrazine Food Grade has been thought to worsen some symptoms of asthma and bring about allergic reactions in many people, such as migraines and skin irritation.
Tartrazine Food Grade has also been known to cause hyperactivity and is banned in Norway and Austria.

The liqueur Galliano uses it for its bright yellow colour.
Mushy peas (a UK ‘delicacy’ that often accompanies fish and chips) are bright green as a result of a mixture of tartrazine and another colouring agent (Brilliant Blue FCF, E133).
The drink Mountain Dew also contains it, as do many breakfast cereals, such as Life Quaker Oats, processed cheese, pasta, sweets and candies, jams, jellies, mustard, and even bread.

Tartrazine Food Grade is also found in cosmetics such as lipsticks, toothpaste, mouthwash, shampoos and detergents, and many other common products.
Even some medications, such as vitamin pills, throat lozenges, and indigestion tablets may contain tartrazine to give their coatings distinctive, easily identifiable colours.
In people sensitive to benzoic acids, salicylic acid and silicates, Tartrazine Food Grade can cause adverse reactions.

Tartrazine Food Grade can cause allergic reactions with the effects of recurrent hives and asthma in a number of susceptible people.
Tartrazine Food Grade can make a pre-existing neurodermatitis worse.
Tartrazine Food Grade is also related to certain cases of hyperactivity in children.

Tartrazine Food Grade appears to cause the most allergic and intolerance reactions of all the azo dyes, particularly among those with an aspirin intolerance and asthmatics.
The mechanism of sensitivity is obscure and has been called pseudoallergic.
The prevalence of Tartrazine Food Grade intolerance is estimated at roughly 360,000 Americans affected, about 0.12% of the general population.

According to the FDA, Tartrazine Food Grade causes hives in fewer than 1 in 10,000 people, or 0.01%.
Symptoms from Tartrazine Food Grade sensitivity can occur by either ingestion or cutaneous exposure to a substance containing tartrazine.
Reactions can include anxiety, migraines, clinical depression, blurred vision, itching, general weakness, heatwaves, feeling of suffocation, purple skin patches, and sleep disturbance.

In rare cases, the symptoms of Tartrazine Food Grade sensitivity can be felt even at extremely small doses and can last up to 72 hours after exposure.
Some researchers have linked Tartrazine Food Grade to childhood Obsessive-compulsive disorder and hyperactivity.
A study commissioned by the UK's Food Standards Agency found that when used in a mixture of other preservatives, increased levels of hyperactivity in children were observed.

Organic foods typically use betacarotene as an additive when yellow color is desired and more use has been made of Annatto (E160b) for non-organic foods.
Tartrazine Food Grade is a monoazo dyes that occurs as a yellow-orange powder or granules.
Tartrazine Food Grade is principally the trisodium salt of 4,5-dihydro-5-oxo-1-(4-sulfophenyl) -4- [4-sulfophenyl-azo] -1H-pyrazole -3-carboxylic acid and may be converted to the corresponding aluminum lake.

Tartrazine Food Grade is a water-soluble yellow dye that is commonly used in the food industry to add color to a variety of products, including candy, soft drinks, baked goods, and snacks.
Tartrazine Food Grade is also used in cosmetics and personal care products, such as shampoos, lotions, and makeup, to add color and vibrancy.
While Tartrazine Food Grade is considered safe for consumption in small amounts, some individuals may experience allergic reactions to the dye, such as skin rashes, hives, or breathing difficulties.

Tartrazine Food Grade is important to read product labels carefully and to be cautious when using products that contain tartrazine, especially if you have a history of allergies or sensitivities.
Overall, Tartrazine is a popular choice for those looking to add color to their food and personal care products, but it is important to be aware of the potential risks and to use caution when using products containing this ingredient.
Tartrazine Food Grade is approved to use as food coloring in EU. In US, it is subject to certification and permanently listed for use in food, drugs and cosmetics, including drugs and cosmetics for eye area.

Tartrazine Food Grade is approved for use in food products in many countries around the world.
However, there are variations in acceptable levels and specific regulations, so it's important for manufacturers to adhere to local guidelines.
Some individuals may be sensitive or allergic to Tartrazine Food Grade, and in rare cases, this can lead to adverse reactions.

Symptoms may include itching, hives, or more severe allergic responses.
Individuals with a known sensitivity to tartrazine may need to avoid products containing this dye.
Tartrazine Food Grade is also used in some pet foods to enhance the appearance of certain treats or kibbles.

Like in human food products, Tartrazine Food Grade is use is regulated in pet food formulations.
In many regions, food manufacturers are required to list tartrazine in the ingredient list on product labels, making it easier for consumers to identify its presence in the food they purchase.
The chemical structure of Tartrazine Food Grade is similar to aspirin.

So asthmatic and others with aspirin sensitivity are particularly prone to side effects for Tartrazine Food Grade containing products.
In addition, Tartrazine Food Grade has been linked to quite a list of harmful and unpleasant reactions, including: anxiety migraine OCD (obsessive compulsive disorder) urticaria asthma attacks sleep disorders/insomnia blurred vision eczema and other skin rashes.
Tartrazine Food Grade is the second most widely used food coloring agent.

Tartrazine Food Grade is added to a broad range of foods such as soft drinks, chips, pudding, honey, pickles, gum, mustard, gelatin, and baked goods.
Tartrazine Food Grade is a bright yellow azo dye that is more stable and a cheaper alternative to natural food dyes.
Tartrazine is known by other names such as FD&C Yellow No. 5 and E 102 Europe.

Tartrazine Food Grade is also found in some cosmetics and personal care products such as liquid soaps, lotions, hand sanitizer, perfumes, nail polish, and shampoos.
Several medications contain Tartrazine Food Grade, which renders a yellow or orange hue to them.
Tartrazine Food Grade is usually added to antacids, vitamins, cough syrups, and lotions.

Tartrazine Food Grade is also used in other products such as inks, crayons, stamp dyes, and glues.
Tartrazine Food Grade allergy refers to intolerance to this additive.
In a relatively small population, Tartrazine Food Grade causes allergic reactions, the mechanism for which is still not clearly understood.

Although several studies indicate that tartrazine and similar additives cause hyperactivity in kids, the FDA rejected these claims for want of sufficient evidence.
Tartrazine Food Grade allergy symptoms usually manifest as an increase in reaction to other allergens rather than as a direct reaction to tartrazine.
Sensitive individuals react to this dye in different ways.

Major symptoms of Tartrazine Food Grade intolerance include skin rashes, hives, and nasal congestion.
Rarely, Tartrazine Food Grade is said to cause asthma in sensitive individuals.
According to studies, adverse reactions to Tartrazine Food Grade may also affect the gastrointestinal tract, central nervous system, and respiratory tract, though many of these effects are rare and unconfirmed. Some studies even claim that tartrazine causes thyroid tumors and lymphomas, but the evidence is not convincing enough.

Available evidence from various studies on the effects of Tartrazine Food Grade intolerance shows that adverse reactions to tartrazine are of a pharmacological nature and not immunological.
Therefore sensitization after ingestion is largely unlikely.
Extensive cross-reactivity of Tartrazine Food Grade with other azo dyes and natural additives further complicates research in this area.

Management of Tartrazine Food Grade allergy is mainly by allergen avoidance.
People who are tartrazine intolerant should avoid foods that contain the additive.
Dietary modification is done in allergic people by educating the parents and carers about the identification and avoidance of additives.

A different study revealed that 83 of 2210 people treated with tartrazine-containing drugs were allergic to Tartrazine Food Grade.
Other Tartrazine Food Grade, such as household cleaning products, paper plates, pet foods, crayons, inks for writing instruments, stamp dyes, face paints, envelope glues, and deodorants, may also contain tartrazine.
Various types of medications include tartrazine to give a yellow, orange or green hue to a liquid, capsule, pill, lotion, or gel, primarily for easy identification.

Types of pharmaceutical products that may contain Tartrazine Food Grade include vitamins, antacids, cold medications (including cough drops and throat lozenges), lotions and prescription drugs.
Most, if not all, medication data sheets are required to contain a list of all ingredients, including Tartrazine Food Grade.

Some include Tartrazine Food Grade in the allergens alert section.
A systematic review of the medical literature concluded that among patients with asthma, research has shown that exposure to tartrazine does not worsen symptoms and avoidance of Tartrazine Food Grade does not improve symptoms; however, "due to the paucity of evidence, it is not possible to provide firm conclusions as to the effects of tartrazine on asthma control".

Uses:
Tartrazine Food Grade is found in confectionery products and drinks of yellow colors of all tints: candies, cakes, carbonated drinks.
Also, Tartrazine Food Grade colorant is often found in canned fruits and vegetables, mustard, soups and yogurts.
Tartrazine Food Grade is sometimes used as a less expensive alternative to saffron to achieve a yellow color in dishes.

However, it's important to note that the flavor profile of saffron cannot be replicated by Tartrazine Food Grade.
In some countries, food products containing Tartrazine Food Grade are required to include it in the list of ingredients on the label.
This is particularly important for individuals who may have sensitivities or allergies to the dye.

Some individuals may be sensitive or allergic to Tartrazine, and in rare cases, consumption may be associated with adverse reactions.
People with a known sensitivity to aspirin may be more prone to a reaction to Tartrazine Food Grade.
There has been occasional public concern and controversy regarding the use of Tartrazine Food Grade and other food colorings, with some studies exploring potential links to
hyperactivity in children.

However, the scientific evidence on this topic is inconclusive, and regulatory bodies generally consider Tartrazine safe when used within established limits.
Tartrazine Food Grade is sometimes used in the pet food industry to add color to pet treats and kibbles.
Tartrazine Food Grade provides a lemon-yellow color and can be used in drugs, cosmetics, and foods, including dietary supplements, beverages, frozen treats, powder mixes, gelatin products, candies, icings, jellies, spices, dressings, sauces, baked goods and dairy products.

Tartrazine Food Grade is used in supplements like One-A-Day Women’s 50+ Complete Multivitamin, One-A-Day For Him VitaCraves Teen Multi, Mason Natural, Women’s Daily Multi Formula, and others.
Never used as the beneficial (active) ingredient.
Tartrazine Food Grade is used in processed foods like marmalade, jelly, mustard, pickles, popcorn, chewing gum, ice cream, energy drinks, corn chips, horseradish, hard candy, puddings, cake mixes, alcoholic beverages, wines, ice pops, cereal, green-colored seaweed salad, potato chips, marzipan, biscuits, pastries, cookies, noodles, cotton candy, soft drinks, drink mixes, fruit cordials, and others.

Tartrazine Food Grade is frequently used in the production of soft drinks and carbonated beverages to provide a vibrant yellow color.
Tartrazine Food Grade contributes to the overall aesthetic appeal of these beverages.
Confectionery and Candies: Many types of candies, including gummies, hard candies, and chewing gum, utilize tartrazine to achieve a yellow coloring.

Tartrazine Food Grade is often part of the formulation to create visually appealing and colorful confectionery products.
Tartrazine Food Grade may be used in the baking industry to color a variety of products such as cakes, cookies, pastries, and bread.
Tartrazine Food Grade helps give a consistent and attractive yellow color to these baked goods.

Tartrazine Food Grade is employed in the production of desserts, puddings, and gelatin-based products to enhance their color and make them more visually appealing.
Some dairy products, including flavored yogurts and ice creams, may contain tartrazine to add a yellow color.
Tartrazine Food Grade can also be found in custards and other dairy-based desserts.

Tartrazine Food Grade is widely used as a food coloring agent to impart a bright yellow color to a variety of products, including beverages, candies, desserts, and baked goods.
Tartrazine Food Grade is frequently used in the production of soft drinks, energy drinks, and fruit-flavored beverages to enhance their visual appeal.
Tartrazine Food Grade is used in the production of candies, gummies, and other confectionery items to give them a vibrant yellow hue.

In the manufacturing of desserts like puddings, custards, and gelatin-based products, Tartrazine Food Grade may be used to add a yellow color.
Some baked goods, such as cakes, cookies, and pastries, may contain Tartrazine Food Grade to achieve a desired yellow color.
Tartrazine Food Grade can be used in certain sauces, dressings, and condiments to enhance the color of the final product.

In some cases, Tartrazine Food Grade may be used in the pharmaceutical industry to color medications, particularly oral tablets and syrups.
Tartrazine Food Grade is sometimes used in cosmetics, such as lipsticks and eyeshadows, to achieve yellow or gold tones.
Tartrazine Food Grade can be sensitive to light, and prolonged exposure to sunlight may result in the degradation of its color.

Manufacturers may use packaging that helps protect the dye from light to maintain the product's color stability.
In certain formulations, interactions with other ingredients may affect the color stability of Tartrazine.
For example, the presence of certain antioxidants may help preserve the color over time.

Tartrazine Food Grade is water-soluble, making it suitable for use in a variety of liquid products such as beverages, syrups, and sauces.
Tartrazine Food Grade is solubility allows for easy incorporation into different recipes.
In the culinary arts, Tartrazine Food Grade is sometimes used by chefs and food stylists to achieve specific color effects in dishes.

Tartrazine Food Grade is vibrant yellow hue can be used creatively to enhance the visual appeal of food presentations.
In certain products like alcoholic beverages, there may be restrictions on the use of Tartrazine.
Some countries have specific regulations regarding its use in alcoholic drinks.

Tartrazine Food Grade is derived from petroleum. While it undergoes extensive purification processes to ensure safety, some individuals may prefer natural alternatives in their food and beverages.
The bioavailability of Tartrazine Food Grade is generally low, meaning that only a small percentage of the ingested dye is absorbed into the bloodstream.
The majority is excreted in the feces.

There have been studies examining the potential health effects of Tartrazine Food Grade, including its impact on individuals with asthma or attention-deficit/hyperactivity disorder (ADHD).
However, the findings are inconclusive, and further research is needed.
In some cases, the color from Tartrazine Food Grade in food packaging materials may migrate into the food product.

Regulations are in place to ensure that any migration remains within safe levels.
Tartrazine Food Grade is produced on a large scale globally to meet the demand from the food and beverage industry.
Tartrazine Food Grade is widespread use and production contribute to its availability and cost-effectiveness.

Tartrazine Food Grade is a synthetic dye, meaning it is chemically manufactured rather than being derived from natural sources.
Tartrazine Food Grade is synthetic nature allows for consistency in color and availability.
Tartrazine Food Grade is generally stable across a range of pH levels, it can be influenced by changes in acidity.

In acidic conditions, Tartrazine Food Grade tends to be more stable, while in alkaline conditions, its color may degrade over time.
Tartrazine Food Grade is known by various names, including FD&C Yellow No. 5 in the United States and CI 19140 in the European Union.
These designations are used in ingredient lists and serve as identifiers for the dye.

Regulatory agencies establish maximum allowable limits for the use of Tartrazine Food Grade in different food categories.
These limits are in place to ensure that the intake of Tartrazine Food Grade remains within safe levels for consumers.
Some food manufacturers may choose to use natural alternatives, such as turmeric extract or saffron, to achieve a yellow color in products.

However, these alternatives may be more expensive than synthetic dyes like Tartrazine.
Apart from its use in the food industry, Tartrazine Food Grade is sometimes employed in the textile industry as a dye for fabrics, although its use for this purpose is less common compared to other applications.
The regulations regarding the use of Tartrazine can vary between countries.

While Tartrazine Food Grade is widely accepted in many regions, some countries may have specific restrictions or different permissible levels.
Tartrazine Food Grade is known for its stability during food processing and storage.
Tartrazine Food Grade can withstand various manufacturing conditions, including heat and light, without significant degradation of its color properties.

In some regions, food products containing Tartrazine Food Grade are required to carry advisory labels indicating the presence of the dye.
This is to inform consumers, especially those with sensitivities or allergies.
Tartrazine Food Grade is one of the most commonly used food colorings globally, and its acceptance is widespread in a variety of food and beverage products.

This colorant is used in: Liquors, spirits, fruit wine, non-alcoholic flavored beverages, soda (powdered), pastries, salty snacks, sweets, desserts, mustard sauce, spiced sauces, processed cheese, fish and crustacean pâté, cheese rind, food supplements, medicines.
Tartrazine Food Grade is approved for use as a food coloring additive by various regulatory authorities, including the U.S. Food and Drug Administration (FDA), the European Food Safety Authority (EFSA), and the World Health Organization (WHO).

Tartrazine Food Grade is known for its good stability in different pH conditions, making it suitable for a wide range of food and beverage applications.
In food formulations, Tartrazine Food Grade is sometimes used in combination with other food colorings to achieve a specific shade or to create a broader color palette.
Tartrazine Food Grade is used as a dye for wool and silks; as colorant in food, drugs, and cosmetics.

In biochemistry as an adsorption-elution indicator for chloride estimations.
Tartrazine Food Grade is a synthetic lemon yellow azo dye used as a food coloring.
Tartrazine Food Grade appears to cause the most allergic and intolerance reactions of all the azo dyes, particularly among as thmatics and those with an aspirin intolerance.

As a dye for wool and silks; as colorant in food, drugs and cosmetics.
In biochemistry as an adsorption-elution indicator for chloride estimations.
Tartrazine Food Grade is a colorant.

Tartrazine Food Grade has good stability to changes in ph, showing no appreciable change at ph 3–8.
Tartrazine Food Grade has excellent solubility in water with a solubility of 20 g in 100 ml at 25°c.
Tartrazine Food Grade has good stability to light and heat, fair stability to oxidation, and shows no appreciable change in 10% sugar systems.

Tartrazine Food Grade has a lemon-yellow hue and has good tinctorial strength.
Tartrazine Food Grade has moderate compatibility with food components and is used in beverages, baked goods, pet foods, desserts, candy, confections, cereal, and ice cream.

Toxicology:
Tartrazine Food Grade is known as the least toxic coloring agent among synthetic coloring chemicals.
The median acute oral lethal dose of Tartrazine Food Grade in mice is 12.17 g/kg.
Beagle dogs received Tartrazine Food Grade as 2% of the diet for two years without adverse effects, with the possible exception of pyloric gastritis in one dog.

Tumor incidence was unchanged relative to controls, in rats receiving Tartrazine Food Grade at 1.5% of the diet for 64 weeks, and in rats administered this dye at 5.0% of the diet for two years.
Human sensitivity to Tartrazine Food Grade has been reported with some frequency and has been estimated to occur in 1/10,000 persons.
Anaphylactic shock, potentially life-threatening, has been reported but symptoms more commonly cited are urticaria (hives), asthma, and purpura (blue or purple spots on the skin or mucous membrane).

This coloring agent is 5-hydroxy-1-p-sulfophenyl-4-(p-sulfophenylazo)- pyrazol-3-carboxylic acid, trisodium salt.
Tartrazine Food Grade is a yellow powder and has been used as food coloring additive since 1916.

Safety Profile:
Tartrazine Food Grade will not penetrate the skin, but it will stain the surface yellow.
Some individuals may be allergic to Tartrazine Food Grade, experiencing symptoms such as hives, itching, swelling, or, in severe cases, anaphylaxis.
People with a known sensitivity to aspirin may be more prone to an allergic reaction to Tartrazine Food Grade.

There is a rare condition known as aspirin-exacerbated respiratory disease (AERD) or Samter's triad, where individuals with aspirin sensitivity may also react to Tartrazine Food Grade.
This can manifest as respiratory symptoms, such as asthma-like symptoms.

Tartrazine Food Grade is safe to handle, though it should not be consumed in macroscopic amounts.
The amounts used in food are very small.


TAURINE
TBHQ, N° CAS : 1948-33-0, Nom INCI : TBHQ, Nom chimique : 1,4-Benzenediol, 2-(1,1-Dimethylethyl)-; 2-tert-Butyl-1,4-dihydroxybenzene; tert-Butyl hydroquinone, N° EINECS/ELINCS : 217-752-2; Ses fonctions (INCI). Antioxydant : Inhibe les réactions favorisées par l'oxygène, évitant ainsi l'oxydation et la rancidité, Agent masquant : Réduit ou inhibe l'odeur ou le goût de base du produit Agent parfumant : Utilisé pour le parfum et les matières premières aromatiques; Noms français : (DIMETHYL-1,1 ETHYL)-2 BENZENEDIOL-1,4; 1,4-BENZENEDIOL, 2-(1,1-DIMETHYLETHYL)- ; TBHQ; Tert-butyl hydroquinone; TERT-BUTYL-2 BENZENEDIOL-1,4; Tert-butyl-2 hydroquinone. Noms anglais : 2-Tert-butyl hydroquinone; Hydroquinone, T-butyl; Hydroquinone, tert-butyl- ; Mono-tert-butylhydroquinone, MONO-TERTIARYBUTYLHYDROQUINONE. Utilisation et sources d'émission: Agent anti-oxydant; 2-tert-butylhydroquinone. CAS names : 1,4-Benzenediol, 2-(1,1-dimethylethyl)-; IUPAC names : 2-(1,1-DIMETHYLETHYL)-1,4-BENZENEDIOL; 2-(1,1-Dimethylethyl)-1,4-benzenediol, tert-Butylhydroquinone; 2-(1,1-dimethylethyl)-1,4benzendiol ; 2-tert-benzene-1,4-diol; 2-tert-Butylbenzene-1,4-diol; 2-tert-butylhydroquinone; mono t-butyl hydroquinone; MTBHQ ; MONO-TERT-BUTYLHYDROQUINONE; Tert Butyl Hydro Quinone; tert-Butylhydroquinone. Trade names :Eastman™ MTBHQ. T.B.H.QM.T.B.H.Q; 1,4-Benzenediol, 2-(1,1-dimethylethyl)- [ACD/Index Name]; 1948-33-0 [RN] 1-t-Butyl-1,4-dihydroxybenzene 2-(1,1-Dimethylethyl)-1,4-benzenediol 2-(1,1-dimethylethyl)benzene-1,4-diol 2-(2-Methyl-2-propanyl)-1,4-benzenediol [ACD/IUPAC Name] 2-(2-Méthyl-2-propanyl)-1,4-benzènediol [French] [ACD/IUPAC Name] 2-(2-Methyl-2-propanyl)-1,4-benzoldiol [German] [ACD/IUPAC Name] 217-752-2 [EINECS] 2-tert-Butyl-1,4-benzenediol 2-tert-Butylbenzene-1,4-diol 2-tert-Butylhydroquinone 2-tertiary-butylhydroquinone Butylhydroquinone, t- Butylhydroquinone, tert- C12674942B Hydroquinone, t-butyl- Hydroquinone, tert-butyl- MTBHQ MX4375000 TBHQ tert-butyl hydroquinone tert-Butylhydroquinone [1948-33-0] 1,4-Benzenediol (1,1-dimethylethyl)- 1,4-Benzenediol, 2- (1, 1-dimethylethyl)- 123477-69-0 [RN] 140627-33-4 [RN] 2-(1,1-Dimethylethyl)-1,4-benzenediol, 9CI 2-(tert-butyl)benzene-1,4-diol 2-(tert-Butyl)hydroquinone, 2-(tert-Butyl)-1,4-dihydroxybenzene 2-(tert-Butyl)hydroquinone; 2-(tert-Butyl)-1,4-dihydroxybenzene 29863-17-0 [RN] 2-t-Butyl-1,4-benzenediol 2-t-Butylhydroquinone 2-tert-Butyl(1,4)hydroquinone 2-tert-Butyl-benzene-1,4-diol 2-tert-Butyl-benzene-1,4-diol(TBHQ) 4-[(2-methylpropan-2-yl)oxy]phenol 68816-56-8 [RN] Banox 20BA C018855 Eastman MTBHQ EINECS 217-752-2 EYK mono-tert-butylhydroquinone monotertiary butyl hydroquinone Mono-tertiarybutylhydroquinone Mono-Tertiarybuytl Hydroquinone NCGC00090788-04 NCI4972 PHENOXY, 2-(1,1-DIMETHYLETHYL)-4-HYDROXY- quinol, t-butyl- SUSTANE Sustane TBHQ T-BHQ tbhq standard tbhq, reagent t-Butyl hydroquinone t-butylhydroquinone t-Butyl-Hydroquinone Tenox 20 Tenox TBHO Tenox TBHQ Tenox TBHQTBHQ tert-Butyl-1,4-benzenediol Tert-butylhydrochinone TERT-BUTYLHYDROQUI tert-butyl-hydroquinone tert-butylhydroquinone (tbhq) tert-butylhydroquinone 97% tert-butylhydroquinone 98% tert-butylhydroquinone, 97% tert-Butylhydroquinone. tertiary-Butylhydroquinone Tert-ブチルヒドロキノン [Japanese] UNII:C12674942B UNII-C12674942B WLN: QR DQ BX1&1&1
TBEP
TRI(BUTOXYETHYL)PHOSPHATE; Tri(butyl cellosolve) phosphate; Tris(2-butoxyethyl) phosphate; 2-Butoxyethanol phosphate; Phosphoric acid tris(2-butoxyethyl)ester; Tributyl cellosolve phosphate; Tri(2-butoxyethanol) phosphate CAS NO: 78-51-3
TBHP (TERT-BUTYL HYDROPEROXIDE)
TBHP (Tert-butyl hydroperoxide) is a clear, colorless liquid at room temperature, with a characteristic pungent odor.
TBHP (Tert-butyl hydroperoxide) is a water-white liquid commonly commercially available as a 70% solution in water; 80% solutions are also available.
TBHP (Tert-butyl hydroperoxide) is a natural product found in Apium graveolens with data available.

CAS Number: 75-91-2
Molecular Formula: C4H10O2
Molecular Weight: 90.12
EINECS Number: 200-915-7

TBHP (Tert-butyl hydroperoxide) is an organic peroxide widely used in a variety of oxidation processes.
TBHP (Tert-butyl hydroperoxide) is used to initiate polymerization reactions and in organic syntheses to introduce peroxy groups into the molecule.

TBHP (Tert-butyl hydroperoxide) vapor can burn in the absence of air and may be flammable at either elevated temperature or at reduced pressure.
Fine mist/spray may be combustible at temperatures below the normal flash point.
When evaporated, the residual liquid will concentrate TBHP (Tert-butyl hydroperoxide) content and may reach an explosive concentration (>90%).

Closed containers may generate internal pressure through the degradation of TBHP (Tert-butyl hydroperoxide) to oxygen .
TBHP (Tert-butyl hydroperoxide) is a highly reactive product.
The three types of significant physical hazards are flammability, thermal, and decomposition due to contamination.

To minimize these hazards, avoid exposure to heat, fire, or any condition that will concentrate the liquid material.
Store away from heat, sparks, open flames, foreign contaminants, combustibles, and reducing agents.
Inspect containers frequently to identify bulges or leaks.

TBHP (Tert-butyl hydroperoxide) is one of the most widely used hydroperoxides in a variety of oxidation processes, for example the Halcon process.
TBHP (Tert-butyl hydroperoxide) is normally supplied as a 69–70% aqueous solution.
Compared to hydrogen peroxide and organic peracids, TBHP (Tert-butyl hydroperoxide) is less reactive.

Overall, TBHP (Tert-butyl hydroperoxide) is renowned for the convenient handling properties of its solutions.
TBHP (Tert-butyl hydroperoxide)'s solutions in organic solvents are highly stable.
TBHP (Tert-butyl hydroperoxide) is an alkyl hydroperoxide in which the alkyl group is tert-butyl.

TBHP (Tert-butyl hydroperoxide) is widely used in a variety of oxidation processes.
TBHP (Tert-butyl hydroperoxide)e has a role as an antibacterial agent.
TBHP (Tert-butyl hydroperoxide) is used as an oxidising agent.

TBHP (Tert-butyl hydroperoxide) is watery colorless liquid.
TBHP (Tert-butyl hydroperoxide) floats on and dissolves slowly in water.

TBHP (Tert-butyl hydroperoxide) is odorless compound.
TBHP (Tert-butyl hydroperoxide), often abbreviated as TBHP, is a chemical compound with the molecular formula C4H10O2.
TBHP (Tert-butyl hydroperoxide) is an organic peroxide, meaning it contains a peroxide group (-O-O-).

TBHP (Tert-butyl hydroperoxide) is a colorless liquid at room temperature and is commonly used as a source of free radicals in various chemical reactions, especially in oxidation reactions.
TBHP (Tert-butyl hydroperoxide) is a powerful oxidizing agent and is often used in laboratory and industrial settings for purposes such as initiating polymerization reactions, oxidizing organic compounds, and as a radical initiator in various chemical processes.
TBHP (Tert-butyl hydroperoxide) is known for its stability and ease of handling compared to some other peroxides.

TBHP (Tert-butyl hydroperoxide) is the organic compound with the formula (CH3)3COOH.
TBHP (Tert-butyl hydroperoxide) is one of the most widely used hydroperoxides in a variety of oxidation processes, for example the Halcon process.
TBHP (Tert-butyl hydroperoxide) is normally supplied as a 69–70% aqueous solution.

Compared to hydrogen peroxide and organic peracids, tert-butyl hydroperoxide is less reactive and more soluble in organic solvents.
Overall, it is renowned for the convenient handling properties of its solutions.
TBHP (Tert-butyl hydroperoxide)s solutions in organic solvents are highly stable.

TBHP (Tert-butyl hydroperoxide) is odorless compound.
The chemical structure of TBHP consists of a tert-butyl (tertiary butyl) group attached to a hydroperoxy (peroxide) group.
TBHP (Tert-butyl hydroperoxide)s molecular formula is C4H10O2, and its chemical formula is often written as (CH3)3COOH.

TBHP (Tert-butyl hydroperoxide) has a relatively high boiling point of around 86-90°C (187-194°F).
TBHP (Tert-butyl hydroperoxide) is a strong oxidizing agent and can readily donate oxygen atoms, making it useful in a variety of chemical reactions where oxidation is required.
TBHP (Tert-butyl hydroperoxide) is widely used in a variety of oxidation processes.

TBHP (Tert-butyl hydroperoxide) is a flammable liquid and a highly reactive oxidizing agent.
TBHP (Tert-butyl hydroperoxide) is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
TBHP (Tert-butyl hydroperoxide) is widely used in a variety of oxidation processes.

TBHP (Tert-butyl hydroperoxide) is used to initiate polymerization reactions and in organic syntheses to introduce peroxy groups into the molecule.
TBHP (Tert-butyl hydroperoxide) is a highly reactive product.
TBHP (Tert-butyl hydroperoxide) is an intermediate.

TBHP (Tert-butyl hydroperoxide) is primarily used as an initiator.
TBHP (Tert-butyl hydroperoxide) is a strong oxidant and reacts violently with combustible and reducing materials, and metallic and sulfur compounds.
TBHP (Tert-butyl hydroperoxide) is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation.

TBHP (Tert-butyl hydroperoxide) plays an important role for the introduction of peroxy groups in organic synthesis.
TBHP (Tert-butyl hydroperoxide) is a flammable liquid and a highly reactive oxidizing agent.
Pure TBHP is shock sensitive and may explode on heating.

Carbon dioxide or dry chemical extinguishers should be used for fires involving TBHP (Tert-butyl hydroperoxide).
TBHP (Tert-butyl hydroperoxide) and concentrated aqueous solutions of TBHP react violently with traces of acid and the salts of certain metals, including, in particular, manganese, iron, and cobalt.
Mixing anhydrous tert-butyl hydroperoxide with organic and readily oxidized substances can cause ignition and explosion.

TBHP (Tert-butyl hydroperoxide) can initiate polymerization of certain olefins.
TBHP (Tert-butyl hydroperoxide) is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
TBHP (Tert-butyl hydroperoxide) is widely used in a variety of oxidation processes.

TBHP (Tert-butyl hydroperoxide) is a water-white liquid commonly commercially available as a 70% solution in water
TBHP (Tert-butyl hydroperoxide) is used to initiate polymerization reactions and in organic syntheses to introduce peroxy groups into the molecule.
TBHP (Tert-butyl hydroperoxide) vapor can burn in the absence of air.

TBHP (Tert-butyl hydroperoxide) may be flammable at either elevated temperature or at reduced pressure.
TBHP (Tert-butyl hydroperoxide) may be combustible at temperatures below the normal flash point.
Closed containers may generate internal pressure through the degradation of TBHP (Tert-butyl hydroperoxide) to oxygen.

TBHP (Tert-butyl hydroperoxide) is a highly reactive product.
TBHP (Tert-butyl hydroperoxide) is an intermediate in the production of propylene oxide and t-butyl alcohol from isobutane and propylene.
TBHP (Tert-butyl hydroperoxide) is primarily used as an initiator and finishing catalyst in the solution and emulsion polymerization methods for polystyrene and polyacrylates.

Other uses are for the polymerization of vinyl chloride and vinyl acetate and as an oxidation and sulfonation catalyst in bleaching and deodorizing operations.
TBHP (Tert-butyl hydroperoxide) is a strong oxidant and reacts violently with combustible and reducing materials, and metallic and sulfur compounds.
TBHP (Tert-butyl hydroperoxide) is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation.

TBHP (Tert-butyl hydroperoxide) is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions.
Furthermore, TBHP (Tert-butyl hydroperoxide) is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes.
TBHP (Tert-butyl hydroperoxide) plays an important role for the introduction of peroxy groups in organic synthesis.

TBHP (Tert-butyl hydroperoxide) provides a readily available and convenient source of active oxygen suitable for diverse oxidation technologies.
Producers of initiators use T-Hydro solution to synthesize many perester, dialkyl peroxide and perketal derivatives. The product itself serves as a free radical initiator for polymerization, copolymerizations, graft polymerizations and curing of polymers.
TBHP (Tert-butyl hydroperoxide) offers advantages of versatility, regioselectivity, stereoselectivity, chemoselectivity and reactivity control with catalyst choice, mild reaction conditions and bulk availability.

TBHP (Tert-butyl hydroperoxide) finds use in preparing speciality chemicals required by fine chemical and performance chemical industries such as pharmaceuticals and agrochemicals.
TBHP (Tert-butyl hydroperoxide) can selectively oxidize hydrocarbons, olefins and alcohols.
Asymmetric epoxidation and kinetic resolution with TBHP (Tert-butyl hydroperoxide) can provide access to complex chiral intermediates.

TBHP (Tert-butyl hydroperoxide) is used as an initiator for radical polymerization and in various oxidation process such as Sharpless epoxidation.
TBHP (Tert-butyl hydroperoxide) is involved in the osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions.
Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes.

TBHP (Tert-butyl hydroperoxide) plays an important role in the introduction of peroxy groups in organic synthesis.
TBHP (Tert-butyl hydroperoxide) Solution is used for the emulsion polymerization of Styrene, Acrylates and Methacrylates and the curing of polyester resins.
Suitable to be used as active peroxide in high-pressure polymerization or as an initiator in oxygen combination of Ethylene.

Common applications are acrylate, vinyl acetate, styrene-butadiene production, curing of styrene - polyester resins, oxidizing agent for hydrocarbons.
Recommended storage temperature is between 0 °C and +30 °C. Keep pails tightly closed.
Store and handle in a dry, well-ventilated place.

Keep away from sources of heat, ignition and direct sunlight in original packaging.
Provide grounding and venting in order to prevent static electricity build-up.
Avoid any contact with Amine and Cobalt Accelerators, acids, alkalis and heavy metal compounds such as driers and metal soaps.

TBHP (Tert-butyl hydroperoxide) finds applications in various industries, including the pharmaceutical, polymer, and chemical manufacturing sectors.
TBHP (Tert-butyl hydroperoxide) is used in the production of a wide range of products, such as pharmaceutical intermediates, plastics, and specialty chemicals.
TBHP (Tert-butyl hydroperoxide) is used as an oxygen transfer agent in certain chemical reactions, allowing the controlled release of oxygen atoms, which can be essential in the oxidation of organic compounds.

TBHP (Tert-butyl hydroperoxide) is soluble in many organic solvents, making it versatile for use in a variety of reaction conditions.
Common solvents used in conjunction with TBHP include acetone, dichloromethane, and toluene.
TBHP (Tert-butyl hydroperoxide) is commercially available in various concentrations, typically ranging from 70% to 98%.

The choice of concentration depends on the specific application and reaction requirements.
When using TBHP (Tert-butyl hydroperoxide) in a chemical reaction, reaction conditions such as temperature, time, and stoichiometry must be carefully controlled to achieve the desired outcome.
Reaction kinetics and selectivity can be influenced by these factors.

The decomposition of TBHP (Tert-butyl hydroperoxide) can produce oxygen gas and tert-butyl alcohol (TBA).
These decomposition products should be considered when planning and monitoring reactions involving TBHP (Tert-butyl hydroperoxide).
TBHP (Tert-butyl hydroperoxide) is considered harmful if ingested, inhaled, or absorbed through the skin.

TBHP (Tert-butyl hydroperoxide) can irritate the respiratory system, skin, and eyes.
Appropriate personal protective equipment (PPE) should be worn when handling TBHP to prevent contact.
In the event of a spill or accidental exposure to TBHP (Tert-butyl hydroperoxide), emergency procedures outlined in the safety data sheet should be followed.

This may include actions like rinsing affected areas with water and seeking medical attention if necessary.
Disposal of TBHP (Tert-butyl hydroperoxide) and its waste should be done in accordance with local, state, and federal regulations.
Depending on the concentration and volume, it may be necessary to consult with hazardous waste disposal experts.

When using TBHP (Tert-butyl hydroperoxide) in a laboratory or industrial setting, conducting a thorough risk assessment and implementing appropriate safety measures, including engineering controls and emergency response plans, is crucial to mitigate potential hazards.
Compatibility testing should be conducted when planning to use TBHP (Tert-butyl hydroperoxide) with other chemicals to ensure that no unexpected reactions or hazards arise from their interaction.

Melting point: -2.8 °C
Boiling point: 37 °C (15 mmHg)
Density: 0.937 g/mL at 20 °C
vapor pressure: 62 mmHg at 45 °C
refractive index: n20/D 1.403
Flash point: 85 °F
storage temp.: 2-8°C
pka: pK1: 12.80 (25°C)
form: Liquid
color: Clear colorless
Water Solubility: Miscible
Merck: 14,1570
BRN: 1098280
Exposure limits No exposure limit is set. On the basis of its irritant properties a ceiling limit of 1.2 mg/m3 (0.3 ppm) is recommended.
Stability: Stable, but may explode if heated under confinement. Decomposition may be accelerated by traces of metals, molecular sieve or other contaminants. Incompatible with reducing agents, combustible material, acids.
InChIKey: CIHOLLKRGTVIJN-UHFFFAOYSA-N
LogP: 1.230 (est)

TBHP (Tert-butyl hydroperoxide) is normally supplied as a 69–70% aqueous solution.
TBHP (Tert-butyl hydroperoxide)'s solutions in organic solvents are highly stable.
The general mechanism of transition metal-catalyzed oxidative Mannich reactions of N, N-dialkyl anilines with TBHP (Tert-butyl hydroperoxide) as the oxidant consists of a rate-determining single electron transfer (SET) that is uniform from 4-methoxy- to 4-cyano-N, N-dimethylanilines.

The TBHP (Tert-butyl hydroperoxide) radical is the major oxidant in the rate-determining SET step that is followed by competing backward SET and irreversible heterolytic cleavage of the carbon–hydrogen bond at the α-position to nitrogen.
A second SET completes the conversion of N, N-dimethylaniline to an iminium ion that is subsequently trapped by the nucleophilic solvent or the oxidant prior to the formation of the Mannich adduct.
TBHP (Tert-butyl hydroperoxide) could induce oxidative stress in liver mitochondria at low concentrations.

The damaging effect of low concentrations of TBHP (Tert-butyl hydroperoxide) in the course of pyruvate oxidation in isolated liver mitochondria is caused by the opening of the nonspecific Ca2+-dependent cyclosporin A-sensitive pore in the inner mitochondrial membrane.
TBHP (Tert-butyl hydroperoxide) and concentrated aqueous solutions of TBHP react violently with traces of acid and the salts of certain metals, including, in particular, manganese, iron, and cobalt.
Mixing anhydrous TBHP (Tert-butyl hydroperoxide) with organic and readily oxidized substances can cause ignition and explosion.

TBHP (Tert-butyl hydroperoxide) can initiate polymerization of certain olefins.
In the event of skin contact, immediately wash with soap and water and remove contaminated clothing.
In case of eye contact, promptly wash with copious amounts of water for 15 min (lifting upper and lower lids occasionally) and obtain medical attention.

If TBHP (Tert-butyl hydroperoxide) is inhaled or ingested, obtain medical attention immediately.
In the event of a spill, remove all ignition sources, soak up the TBHP (Tert-butyl hydroperoxide) with a spill pillow or noncombustible absorbent material, place in an appropriate container, and dispose of properly.
Respiratory protection may be necessary in the event of a large spill or release in a confined area.

Cleanup of anhydrous TBHP (Tert-butyl hydroperoxide) and concentrated solutions requires special precautions and should be carried out by trained personnel working from behind a body shield.
TBHP (Tert-butyl hydroperoxide) is expected to have high mobility in soil.
If released to air, Tert-butyl hydroperoxide will exist solely as a vapor in the ambient atmosphere.

In aqueous environments, TBHP (Tert-butyl hydroperoxide) is not expected to adsorb to sediment or suspended solids, and volatilization is expected to be the primary fate process.
The half-lives for this compound in a variety of media allow for some moderate longrange transport, but not incredible distances.
An estimated bioconcentration factor (BCF) of 3 was calculated for TBHP (Tert-butyl hydroperoxide) Syracuse Research Corporation (SRC), using an estimated log Kow of 0.94 and a regression-derived equation.

According to a classification scheme, this BCF suggests the potential for bioconcentration in aquatic organisms is low.
TBHP (Tert-butyl hydroperoxide) is commercially available in various concentrations and forms, including solutions in solvents like water or acetone.
These solutions are often used for ease of handling and dosing in laboratory and industrial applications.

TBHP (Tert-butyl hydroperoxide) is commonly used as an initiator in radical reactions, particularly in the production of various polymers.
TBHP (Tert-butyl hydroperoxide) is added to the reaction mixture to generate free radicals, which initiate the polymerization process.
The radicals react with monomers to form polymer chains.

TBHP (Tert-butyl hydroperoxide) is relatively stable when stored under proper conditions.
TBHP (Tert-butyl hydroperoxide) is typically kept in brown glass containers or opaque bottles to protect it from light, as exposure to ultraviolet (UV) light can initiate decomposition.
When storing and handling TBHP, it's essential to keep it away from heat sources, open flames, and incompatible materials.

TBHP (Tert-butyl hydroperoxide) should be stored in a cool, dry place and away from direct sunlight.
Containers should be tightly sealed to prevent contamination and exposure to air.
TBHP (Tert-butyl hydroperoxide) is stable under normal storage conditions, it can decompose explosively if subjected to heat, friction, or contamination with incompatible materials.

Decomposition can lead to the release of oxygen gas and cause fires or explosions.
TBHP (Tert-butyl hydroperoxide) should not be mixed with reducing agents, flammable materials, strong acids, or bases, as these substances can react with it and potentially lead to hazardous reactions.
Manufacturers provide detailed safety data sheets (SDS) or material safety data sheets (MSDS) for TBHP, which include information on its hazards, safe handling practices, first-aid measures, and emergency procedures.

TBHP (Tert-butyl hydroperoxide) can have adverse environmental effects if released into the environment.
Proper disposal methods should be followed, and any spills should be contained and cleaned up using appropriate techniques and materials.

The handling, storage, and transportation of TBHP (Tert-butyl hydroperoxide) are subject to regulations and guidelines established by government agencies and safety organizations.
In some cases, alternative oxidizing agents may be used in chemical reactions instead of TBHP (Tert-butyl hydroperoxide), depending on the specific requirements of the reaction and safety considerations.

Production Methods Of TBHP (Tert-butyl hydroperoxide):
TBHP (Tert-butyl hydroperoxide) is produced by the liquid-phase reaction of isobutane and molecular oxygen or by mixing equimolar amounts of t-butyl alcohol and 30–50% hydrogen peroxide.
TBHP (Tert-butyl hydroperoxide) can also be prepared from t-butyl alcohol and 30% hydrogen peroxide in the presence of sulfuric acid or by oxidation of tert-butylmagnesium chloride.
The manufacturing process of TBHP is in a closed system.

Uses
TBHP (Tert-butyl hydroperoxide) is an intermediate in the production of propylene oxide and t-butyl alcohol from isobutane and propylene.
TBHP (Tert-butyl hydroperoxide) is primarily used as an initiator and finishing catalyst in the solution and emulsion polymerization methods for polystyrene and polyacrylates.
Other uses are for the polymerization of vinyl chloride and vinyl acetate and as an oxidation and sulfonation catalyst in bleaching and deodorizing operations.

TBHP (Tert-butyl hydroperoxide) is a strong oxidant and reacts violently with combustible and reducing materials, and metallic and sulfur compounds.
TBHP (Tert-butyl hydroperoxide) is used to prepare propylene oxide.
In the Halcon process, molybdenum-based catalysts are used for this reaction:
(CH3)3COOH + CH2=CHCH3 → (CH3)3COH + CH2OCHCH3

The byproduct t-butanol, which can be dehydrated to isobutene and converted to MTBE.
On a much smaller scale, TBHP (Tert-butyl hydroperoxide) is used to produce some fine chemicals by the Sharpless epoxidation.
TBHP (Tert-butyl hydroperoxide) is used as the oxidant for nearly all titanium-catalyzed asymmetric epoxidations.

TBHP (Tert-butyl hydroperoxide)is used as an initiator for radical polymerization.
TBHP (Tert-butyl hydroperoxide) is used as the oxidant for nearly all titanium-catalyzed asymmetric epoxidations.
TBHP (Tert-butyl hydroperoxide) is used as an initiator for radical polymerization.

TBHP (Tert-butyl hydroperoxide) is used in various oxidation process such as sharpless epoxidation.
TBHP (Tert-butyl hydroperoxide) is used in the oxidation of dibenzothiophenes.
TBHP (Tert-butyl hydroperoxide) is an organic peroxide widely used in a variety of oxidation processes, for example Sharpless epoxidation.

TBHP (Tert-butyl hydroperoxide) is used in various oxidation process such as sharpless epoxidation.
TBHP (Tert-butyl hydroperoxide) is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions.
Furthermore, tert-Butyl Hydroperoxide is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary TBHP (Tert-butyl hydroperoxide) is used in the oxidation of dibenzothiophenes.

TBHP (Tert-butyl hydroperoxide) plays an important role for the introduction of peroxy groups in organic synthesis.
TBHP (Tert-butyl hydroperoxide) is commonly employed as an initiator in radical polymerization reactions, helping to start the polymerization process by generating free radicals.
TBHP (Tert-butyl hydroperoxide) is used in organic synthesis for various oxidation reactions, including the conversion of alkenes to epoxides and the oxidation of alcohols to ketones or aldehydes.

TBHP (Tert-butyl hydroperoxide) is also used in the synthesis of various organic compounds, including pharmaceuticals and specialty chemicals.
TBHP (Tert-butyl hydroperoxide) can be used as an oxygen source in certain industrial processes.
TBHP (Tert-butyl hydroperoxide) is an organic peroxide widely used in a variety of oxidation processes, for example Sharpless epoxidation.

TBHP (Tert-butyl hydroperoxide) is normally supplied as a 69–70% aqueous solution.
TBHP (Tert-butyl hydroperoxide) is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
TBHP (Tert-butyl hydroperoxide) is used in the manufacture of adhesives and sealants, where it can act as a curing agent or as an ingredient to improve the properties of the final product.

TBHP (Tert-butyl hydroperoxide) is employed in textile finishing processes to modify the surface properties of textiles, such as enhancing water repellency and durability.
TBHP (Tert-butyl hydroperoxide) can be used in the paper industry as a bleaching agent and a pulp delignification agent, aiding in the production of high-quality paper products.
In water treatment processes, TBHP (Tert-butyl hydroperoxide) is used for the oxidation of organic contaminants, helping to purify water and wastewater.

TBHP (Tert-butyl hydroperoxide) is utilized in analytical chemistry techniques, such as chemiluminescence assays and oxidation reactions, for the detection and quantification of specific compounds.
TBHP (Tert-butyl hydroperoxide) serves as an important intermediate in the synthesis of pharmaceutical compounds, contributing to the production of various drug molecules.
TBHP (Tert-butyl hydroperoxide) can be involved in the synthesis of agrochemicals and pesticides, which are essential for crop protection and agricultural productivity.

TBHP (Tert-butyl hydroperoxide) is considered as an additive for improving the properties of fuels, including octane enhancement in gasoline.
TBHP (Tert-butyl hydroperoxide) is used in the textile industry for the oxidative fixing of dyes onto fabrics during the textile printing process.
TBHP (Tert-butyl hydroperoxide) can be found in cosmetic and personal care formulations as an ingredient to enhance product stability or as an oxidizing agent in hair care products.

TBHP (Tert-butyl hydroperoxide) is used for modifying the surfaces of materials like polymers, metals, and nanoparticles to tailor their properties for specific applications, such as improving adhesion or hydrophobicity.
In chemical research laboratories, TBHP (Tert-butyl hydroperoxide) is employed as a versatile reagent for a wide range of synthetic transformations and oxidative reactions.

TBHP (Tert-butyl hydroperoxide) is widely used in a variety of oxidation processes.
TBHP (Tert-butyl hydroperoxide) is the organic compound with the formula (CH3)3COOH.
TBHP (Tert-butyl hydroperoxide) is one of the most widely used hydroperoxides in a variety of oxidation processes, for example the Halcon process.

TBHP (Tert-butyl hydroperoxide) is normally supplied as a 69–70% aqueous solution.
TBHP (Tert-butyl hydroperoxide) is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation.
TBHP (Tert-butyl hydroperoxide) is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions.

Furthermore, TBHP (Tert-butyl hydroperoxide) is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes.
TBHP (Tert-butyl hydroperoxide) plays an important role for the introduction of peroxy groups in organic synthesis.
TBHP (Tert-butyl hydroperoxide) is used in the following products: polymers.

TBHP (Tert-butyl hydroperoxide) is used in the following areas: formulation of mixtures and/or re-packaging.
TBHP (Tert-butyl hydroperoxide) is used for the manufacture of: chemicals.
Release to the environment of TBHP (Tert-butyl hydroperoxide) can occur from industrial use: as an intermediate step in further manufacturing of another substance (use of intermediates) and as processing aid.

TBHP (Tert-butyl hydroperoxide) may be used in:osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliaryoxidation of dibenzothiophenes.
TBHP (Tert-butyl hydroperoxide) is widely used in a variety of oxidation processes.
TBHP (Tert-butyl hydroperoxide) has a role as an antibacterial agent.

TBHP (Tert-butyl hydroperoxide) is commonly used as an initiator in radical polymerization reactions.
TBHP (Tert-butyl hydroperoxide) generates free radicals that start the polymerization process, allowing the synthesis of various polymers and copolymers.
Polymers produced with TBHP (Tert-butyl hydroperoxide) initiators can find applications in plastics, adhesives, coatings, and more.

TBHP (Tert-butyl hydroperoxide) is employed as an oxidizing agent in organic synthesis to facilitate the oxidation of various compounds.
TBHP (Tert-butyl hydroperoxide) can convert alkenes to epoxides, alcohols to ketones or aldehydes, and other functional group transformations.
These reactions are essential in the production of pharmaceuticals, fine chemicals, and specialty materials.

In some industrial processes, TBHP (Tert-butyl hydroperoxide) is used as a source of oxygen atoms.
TBHP (Tert-butyl hydroperoxide) can release oxygen when needed, making it useful in applications where controlled oxygen transfer is required, such as in the production of chemicals and intermediates.
TBHP (Tert-butyl hydroperoxide) is a key reagent in the synthesis of specialty chemicals and intermediates used in the manufacture of various products, including pharmaceuticals, agrochemicals, and dyes.

TBHP (Tert-butyl hydroperoxide) is employed in the epoxidation of fats and oils, which is an important step in the production of epoxidized vegetable oils used as plasticizers and stabilizers in the polymer industry.
TBHP (Tert-butyl hydroperoxide) is commonly used in research and development laboratories for its versatile applications in organic synthesis and as an initiator in various chemical reactions.

TBHP (Tert-butyl hydroperoxide) has been explored as an energy carrier for fuel cells.
In this context, it can be used as a potential source of energy for various applications.

TBHP (Tert-butyl hydroperoxide) is used as an oxidising agent.
TBHP (Tert-butyl hydroperoxide) is watery colorless liquid.

Safety Profile:
TBHP (Tert-butyl hydroperoxide) moderately toxic by ingestion and inhalation.
TBHP (Tert-butyl hydroperoxide) a severe skin and eye irritant.
TBHP (Tert-butyl hydroperoxide) very dangerous fire hazard when exposed to heat or flame, or by spontaneous chemical reaction such as with reducing materials.

Moderately explosive; may explode during distillation.
Violent reaction with traces of acid.
Concentrated solutions may ignite spontaneously on contact with molecular sieve.

Mixtures with transition metal salts may react vigorously and release oxygen.
Forms an unstable solution with 1,2-dichloroethane. To fight fire, use alcohol foam, CO2, dry chemical.
When heated to decomposition it emits acrid smoke and fumes.

TBHP (Tert-butyl hydroperoxide) is a hazardous chemical and should be handled with care.
TBHP (Tert-butyl hydroperoxide) can decompose explosively under certain conditions, especially when exposed to heat or contamination.
Proper storage in a cool, well-ventilated area away from heat sources and open flames is essential.

Health Hazard:
TBHP (Tert-butyl hydroperoxide) is a strong irritant.
Floyd and Stockinger (1958) observed thatdirect cutaneous application in rats did notcause immediate discomfort, but the delayedaction was severe.
The symptoms were erythemaand edema within 2–3 days.

Storage:
TBHP (Tert-butyl hydroperoxide) should be stored in the dark at room temperature separately from oxidizable compounds, flammable substances, and acids.
Reactions involving TBHP (Tert-butyl hydroperoxide) should be carried out behind a safety shield.

TBHP (Tert-butyl hydroperoxide) should be handled in the laboratory using the "basic prudent practices" described in supplemented by the additional precautions for work with reactive and explosive substances.
In particular, TBHP (Tert-butyl hydroperoxide) should be stored in the dark at room temperature (do not refrigerate) separately from oxidizable compounds, flammable substances, and acids.
Reactions involving TBHP (Tert-butyl hydroperoxide) should be carried out behind a safety shield.

Synonyms
TERT-BUTYL HYDROPEROXIDE
75-91-2
TBHP
T-Butyl hydroperoxide
tert-Butylhydroperoxide
2-Hydroperoxy-2-methylpropane
Perbutyl H
t-Butylhydroperoxide
1,1-Dimethylethyl hydroperoxide
Cadox TBH
Hydroperoxide, 1,1-dimethylethyl
Terc. butylhydroperoxid
tert-Butyl hydrogen peroxide
Hydroperoxyde de butyle tertiaire
Hydroperoxide, tert-butyl
Slimicide DE-488
Tertiary butyl hydroperoxide
Trigonox a-75
Trigonox A-W70
TBHP-70
1,1-Dimethylethylhydroperoxide
Tertiary-butyl hydroperoxide
NSC 672
Caswell No. 130BB
Dimethylethyl hydroperoxide
Perbutyl H 69T
t-BuOOH
Luperox TBH 70X
terc.Butylhydroperoxid
Trigonox A-W 70
tert Butylhydroperoxide
CCRIS 5892
HSDB 837
tert-Butyl-hydroperoxide
Kayabutyl H
T-Hydro
EINECS 200-915-7
DE 488
DE-488
UNII-955VYL842B
BRN 1098280
CHEBI:64090
AI3-50541
NSC-672
955VYL842B
Hydroperoxide, 1,1-dimethylethyl-
KAYABUTYL H 70
DTXSID9024693
EC 200-915-7
TERT-BUTYL HYDROPEROXIDE (II)
TERT-BUTYL HYDROPEROXIDE [II]
Trigonox A-75 [Czech]
tBOOH
t Butylhydroperoxide
terc.Butylhydroperoxid [Czech]
t Butyl Hydroperoxide
t-BHP
terc. Butylhydroperoxid [Czech]
Hydroperoxide, t-Butyl
tert Butyl Hydroperoxide
tertiary Butylhydroperoxide
Trigonox
Hydroperoxyde de butyle tertiaire [French]
tBuOOH
tert-BuOOH
Ethyldiethylperoxide
Perbutyl H 69
Perbutyl H 80
t-butyl-hydroperoxide
terbutyl hydroperoxide
tert-butyhydroperoxide
Terc butylhydroperoxid
tert-C4H9OOH
t-butyl hydrogenperoxide
t-butyl-hydrogenperoxide
tert.-butylhydroperoxide
tert.butyl hydroperoxide
tertiarybutylhydroperoxide
tertbutylhydrogen peroxide
t-butyl hydrogen peroxide
tert.-butyl hydroperoxide
DSSTox_CID_4693
tert-butylhydrogen peroxide
2-methylpropane-2-peroxol
DSSTox_RID_78866
DSSTox_GSID_31209
tertiary butyl hydro peroxide
Hydroperoxide,1-dimethylethyl
Trigonox A-80 (Salt/Mix)
UN 2093 (Salt/Mix)
UN 2094 (Salt/Mix)
USP -800 (Salt/Mix)
CHEMBL348399
DTXCID504693
NSC672
tert-Butyl hydroperoxide (8CI)
tert-Butyl hydroperoxide, >90% with water [Forbidden]
WLN: QOX1&1&1
2-Methyl-prop-2-yl-hydroperoxide
Tox21_200838
Aztec t-butyl Hydroperoxide-70, Aq
MFCD00002130
BUTYL HYDROPEROXIDE (TERTIARY)
TERT-BUTYL HYDROPEROXIDE [MI]
AKOS000121070
TERT-BUTYL HYDROPEROXIDE [HSDB]
NCGC00090725-01
NCGC00090725-02
NCGC00090725-03
NCGC00258392-01
tert-Butyl hydroperoxide aqueous solution
Hydroperoxide, 1,1-dimethylethyl (9CI)
tert-Butyl Hydroperoxide (70% in Water)
tert-Butyl hydroperoxide, >90% with water
B3153
FT-0657109
Q286326
J-509597
F1905-8242
TBHQ ( tert-Butyl hydroquinone)
T-BUTYL ALCOHOL, N° CAS : 75-65-0, Nom INCI : T-BUTYL ALCOHOL, Nom chimique : 2-Methylpropan-2-ol, N° EINECS/ELINCS : 200-889-7, Classification : Alcool: Ses fonctions (INCI) Dénaturant : Rend les cosmétiques désagréables. Principalement ajouté aux cosmétiques contenant de l'alcool éthylique, Solvant : Dissout d'autres substances, Agent parfumant : Utilisé pour le parfum et les matières premières aromatiques
T-BUTYL ALCOHOL
Synonyms: 1,3,5-Trichlorohexahydro-1,3,5-triazine-2,4,6-trione, 1,3,5-Trichloro-1,3,5-triazine-2,4,6-trione, TCCA,Trichloroisocyanuric acid ,Bleaching solution CAS #: 87-90-1
TCD Diamine
octahydro-4,7-methano-1H-indenedimethylamine; 4,7-Methano-1H-indenedimethanamine, octahydro-; Octahydro-4,7-methano-1H-indendimethylamin CAS : 68889-71-4
TCMTB
2,2,2-Trihydroxytriethylamine; TEA; 2,2',2''-Nitrilotriethanol; Triethanolamin; Tris(beta-hydroxyethyl)amine; Trolamine; Daltogen; Nitrilotriethanol; Sterolamide; Tri(hydroxyethyl)amine; Triethanolamin; Tris(2-hydroxyethyl)amine; 2,2',2''-Nitrilotriethanol; 2,2',2''-Nitrilotris(ethanol); Nitrilo-2,2',2"-triethanol; 2,2,2-Nitrilotriethanol; 2,2',2"-Nitrilotriethanol; Nitrilo-2,2',2''-triethanol; 2,2',2''-trihydroxy Triethylamine; Triethylolamine; Trihydroxytriethylamine; Tris(beta-hydroxyethyl)amine cas no: 102-71-6
TCPP
SYNONYMS 1,3-Dichloro-2-propanol phosphate, Phosphoric acid tris(1,3-dichloro-2-propyl ester), Tris(1,3-dichloro-2-propyl) phosphate. CAS:13674-87-8
TEA %99-(TRIETANOLAMIN %99)
TEA-C12-14 ALKYL SULFATE N° CAS : 90583-18-9 Nom INCI : TEA-C12-14 ALKYL SULFATE N° EINECS/ELINCS : 292-216-9 Classification : Sulfate, Règlementé, TEA Restriction en Europe : III/62 Ses fonctions (INCI) Agent nettoyant : Aide à garder une surface propre Agent moussant : Capture des petites bulles d'air ou d'autres gaz dans un petit volume de liquide en modifiant la tension superficielle du liquide Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TEA-C12-14 ALKYL SULFATE
TEA-CARBOMER Nom INCI : TEA-CARBOMER Classification : Règlementé, TEA Restriction en Europe : III/62 Ses fonctions (INCI) Gélifiant : Donne la consistance d'un gel à une préparation liquide Agent de contrôle de la viscosité : Augmente ou diminue la viscosité des cosmétiques
TEA-CARBOMER
TEA-COCOATE N° CAS : 61790-64-5 Nom INCI : TEA-COCOATE N° EINECS/ELINCS : 263-155-5 Classification : Règlementé, TEA Restriction en Europe : III/62 Ses fonctions (INCI) Agent nettoyant : Aide à garder une surface propre Agent émulsifiant : Favorise la formation de mélanges intimes entre des liquides non miscibles en modifiant la tension interfaciale (eau et huile) Agent moussant : Capture des petites bulles d'air ou d'autres gaz dans un petit volume de liquide en modifiant la tension superficielle du liquide Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TEA-COCOATE
TEA-COCOYL ALANINATE Nom INCI : TEA-COCOYL ALANINATE Classification : Règlementé, TEA Restriction en Europe : III/62 Ses fonctions (INCI) Agent nettoyant : Aide à garder une surface propre Conditionneur capillaire : Laisse les cheveux faciles à coiffer, souples, doux et brillants et / ou confèrent volume, légèreté et brillance Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TEA-COCOYL ALANINATE
TEA-COCOYL GLUTAMATE N° CAS : 68187-29-1 "Pas terrible" dans toutes les catégories. Nom INCI : TEA-COCOYL GLUTAMATE N° EINECS/ELINCS : 269-084-6 Classification : Règlementé, TEA Restriction en Europe : III/62 Ses fonctions (INCI) Agent nettoyant : Aide à garder une surface propre Conditionneur capillaire : Laisse les cheveux faciles à coiffer, souples, doux et brillants et / ou confèrent volume, légèreté et brillance Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TEA-COCOYL GLUTAMATE
TEA-HYDROGENATED COCOATE. Nom INCI : TEA-HYDROGENATED COCOATE Classification : Règlementé, TEA, Huile hydrogénée Restriction en Europe : III/62 Ses fonctions (INCI) Agent nettoyant : Aide à garder une surface propre Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TEA-HYDROGENATED COCOATE.
TEA-LACTATE N° CAS : 20475-12-1 Nom INCI : TEA-LACTATE N° EINECS/ELINCS : 243-846-8 Classification : Règlementé, TEA Restriction en Europe : III/62 Ses fonctions (INCI) Humectant : Maintient la teneur en eau d'un cosmétique dans son emballage et sur la peau Agent d'entretien de la peau : Maintient la peau en bon état
TEA-LACTATE
TEA-LAURATE N° CAS : 2224-49-9 Nom INCI : TEA-LAURATE Nom chimique : Lauric acid, compound with 2,2',2''-nitrilotriethanol (1:1) N° EINECS/ELINCS : 218-749-9 Classification : Règlementé, TEA Restriction en Europe : III/62 Ses fonctions (INCI) Agent émulsifiant : Favorise la formation de mélanges intimes entre des liquides non miscibles en modifiant la tension interfaciale (eau et huile) Agent moussant : Capture des petites bulles d'air ou d'autres gaz dans un petit volume de liquide en modifiant la tension superficielle du liquide Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TEA-LAURATE
TEA-LAUROYL SARCOSINATE N° CAS : 16693-53-1 Nom INCI : TEA-LAUROYL SARCOSINATE N° EINECS/ELINCS : 240-736-1 Classification : Règlementé, TEA Restriction en Europe : III/62 Ses fonctions (INCI) Antistatique : Réduit l'électricité statique en neutralisant la charge électrique sur une surface Agent nettoyant : Aide à garder une surface propre Agent moussant : Capture des petites bulles d'air ou d'autres gaz dans un petit volume de liquide en modifiant la tension superficielle du liquide Conditionneur capillaire : Laisse les cheveux faciles à coiffer, souples, doux et brillants et / ou confèrent volume, légèreté et brillance Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TEA-LAUROYL SARCOSINATE
SYNONYMS tris(2-hydroxyethyl)ammonium dodecylsulphate ;TriethanolamineLaurylSulfateSolution;TRIETHANOLAMINELAURYLSULPHATE;TEA-LAURYLSULPHATE;Triethanolaminlaurylsulfat;Dodecyl triethanolamine sulfate;2,2,2-NITRILOETHANOL LAURYLULFATE 40% AQUEOUS SOLN.;Laurylsulfuric acid triethanolamine CAS NO:205-388-7
TEA-LAURYL SULFATE
TEA-OLEATE N° CAS : 2717-15-9 Nom INCI : TEA-OLEATE Nom chimique : Oleic acid, compound with 2,2',2''-nitrilotriethanol (1:1) N° EINECS/ELINCS : 220-311-7 Classification : Règlementé, TEA Restriction en Europe : III/62 Ses fonctions (INCI) Agent nettoyant : Aide à garder une surface propre Agent émulsifiant : Favorise la formation de mélanges intimes entre des liquides non miscibles en modifiant la tension interfaciale (eau et huile) Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TEA-OLEATE
TEA-PALMITATE N° CAS : 49719-60-0 Nom INCI : TEA-PALMITATE N° EINECS/ELINCS : 256-444-2 Classification : Règlementé, TEA Restriction en Europe : III/62 Ses fonctions (INCI) Agent nettoyant : Aide à garder une surface propre Agent émulsifiant : Favorise la formation de mélanges intimes entre des liquides non miscibles en modifiant la tension interfaciale (eau et huile) Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TEA-PALMITATE
TENSIOACTIFS Nom INCI : TENSIOACTIFS Ses fonctions (INCI) Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TECHNOMELT EM 357
Technomelt EM 357 is based on natural raw materials.
Ensures manual cleaning even in case of severe scorching.
Before using Technomelt EM 357, its suitability for varnished and synthetic surfaces must be checked.


Technomelt EM 357 is appropriate safety instructions must be followed when using.
Technomelt EM 357 is based on natural raw materials.
Ensures manual cleaning even in case of severe burnt marks.


Before using Technomelt EM 357, its suitability for varnished and synthetic surfaces must be checked.
All information about areas of application and the resulting properties of Technomelt EM 357 are recommendations and cannot be guaranteed in the specific application due to a large number of additional influencing factors.


Technomelt EM 357 is recommended to carry out tests in advance for the respective intended use.
Technomelt EM 357 is a yellow, transparent hot melt adhesive for bonding plastic labels.
The hot melt adhesive, Technomelt EM 357, is wrapped in a thin foil.


This innovative packaging solution avoids unwanted packaging waste and makes handling easier.
Technomelt EM 357 is a high-quality hotmelt adhesive for labeling, especially for bonding plastic labels.
Technomelt EM 357 is solid and economical hot melt adhesive for standard plastic container labeling requirements.


Technomelt EM 357 is a yellow, transparent.
Working temperature of Technomelt EM 357 is 130 to 150°C.
Technomelt EM 357 has high quality hot melt adhesive on synthetic basis.


Technomelt EM 357 is used for gluing plastic labels.
Technomelt EM 357 is easy handling.
Technomelt EM 357 is a yellow, transparent.


Technomelt EM 357 is a yellow, transparent hotmelt for bonding of plastic labels.
The hotmelt adhesive, Technomelt EM 357, is wrapped in a thin film.
Technomelt EM 357 avoids unwanted packaging waste


Technomelt EM 357 is applied by nozzle or roller
Technomelt EM 357 is easy handling
Technomelt EM 357 is a yellowish-transparent
Technomelt EM 357 is a high-quality hotmelt adhesive for labelling, especially for bonding plastic labels.



USES and APPLICATIONS of TECHNOMELT EM 357:
Technomelt EM 357 is used hot melt adhesive based on synthetic rubber.
Technomelt EM 357 is used for gluing labels (paper, metallized, PP, PS, etc.) on packaging made of glass, tin and synthetic materials (including PET bottles).


Technomelt EM 357 is used for equipment of any type.
Operating temperature of Technomelt EM 357 is 130-150 °C
Technomelt EM 357 is used hot melt adhesive based on synthetic rubber.


Technomelt EM 357 is used for gluing labels (paper, metallized, PP, PS, etc.) on packaging made of glass, tin and synthetic materials (including PET bottles).
Technomelt EM 357 is used for equipment of any type.


Cleaning uses of Technomelt EM 357: For cleaning glue tanks, hoses and application systems, we recommend using HOTMELT CLEANER Q 1924.
Technomelt EM 357 can be used to cold clean the surfaces of gluing equipment, conveyor chains and other machine parts from adhering glue.
Technomelt EM 357 is used high-quality synthetic-based hot melt adhesive for bonding plastic labels


Technomelt EM 357 is used roller or nozzle application.
Technomelt EM 357 is used labeling with plastic label.
Technomelt EM 357 is used nozzle, roll.


Cleaning: For cleaning glue tanks, hoses and application systems, we recommend using Technomelt EM 357.
Technomelt EM 357 can be used to cold clean the surfaces of gluing equipment, conveyor chains and other machine parts from adhering glue.
Application of Technomelt EM 357: Labeling


Technomelt EM 357 is used Labeling, Adhesives for labels on PET bottles, Adhesives for labels on tin cans, and Hot melt adhesive for labeling.
Technomelt EM 357 is used Gluing paper, plastic, PP labels.
Technomelt EM 357 is used the adhesive film is transparent.


Technomelt EM 357 avoids the accumulation of adhesive residues on vacuum drums and other parts of the equipment.
The high elongation index allows you to maintain the bonding strength with an increase in the volume of PET bottles under the action of CO2.
Technomelt EM 357 is used for labeling equipment of any type.


Technomelt EM 357 is used Gluing plastic and paper labels on PET bottles; gluing circular labels.
Method of application of Technomelt EM 357 is nozzle, roller.
Technomelt EM 357 is used gluing plastic and paper labels onto PET bottles; gluing circular labels.


Technomelt EM 357 is used gluing paper, plastic, PP labels
Technomelt EM 357 is used transparent, synthetic polymer hotmelt film used in the bonding of plastic labels.
Technomelt EM 357 is applied either by means of a roller or a nozzle.


Technomelt EM 357 uses elastic transparent film for packaging, which dissolves when heated.
In this way, the technological packaging is combined with the adhesive mass, eliminates unnecessary hassle of disposal, simplifies the unpacking process, and eliminates the loss of material due to sticking to the walls of the container.


Technomelt EM 357 is designed for gluing paper and PP labels to glass, metal, PET containers, including circular ones.
Technomelt EM 357 is suitable for labeling bottles, cans, containers.
Technomelt EM 357 is applied with a nozzle or roller.


Technomelt EM 357 is used solid and economic hotmelt adhesive for standard requirements of plastic container labeling.
Technomelt EM 357 is used roller or nozzle application.
Technomelt EM 357 is used hot melt adhesive based on synthetic rubber.


Technomelt EM 357 is used gluing plastic and paper labels onto PET bottles.
Technomelt EM 357 is used the adhesive film is transparent.
Technomelt EM 357 allows you to avoid the accumulation of adhesive residues on vacuum drums and other parts of equipment.


Technomelt EM 357 is used for any type of labeling equipment.
Technomelt EM 357 is used for Gluing plastic and paper labels onto PET bottles; gluing circular labels.
Technomelt EM 357 is used for Gluing paper, plastic, PP labels


Application area of Technomelt EM 357: Gluing plastic and paper labels onto PET bottles; gluing circular labels.
Technomelt EM 357 is used hot melt adhesive with residual stickiness in “easy melt” packaging for gluing paper and PP labels to PET/PVC bottles on rotary labeling machines.


Technomelt EM 357 is used labeling of PP and PET bottles.
Technomelt EM 357 is used hot-melt flexible adhesive based on synthetic rubber.
Technomelt EM 357 is used labeling with plastic label.


Technomelt EM 357 is used bonding of OPP materials.
Area of ​​application of Technomelt EM 357: Labeling with plastic label.
Area of ​​application of Technomelt EM 357: Gluing plastic and paper labels on PET bottles; gluing circular labels.



PROPERTIES OF TECHNOMELT EM 357:
*The adhesive film is transparent.
*Allows you to avoid the accumulation of adhesive residues on vacuum drums and other parts of equipment.
*The high relative elongation allows maintaining the bonding strength when the volume of PET bottles increases under the influence of CO2.
*For any type of labeling equipment.



ADVANTAGES OF TECHNOMELT EM 357:
*Avoids unwanted packaging waste.
*For gluing plastic labels.
*Easy to use



PROPERTIES OF TECHNOMELT EM 357:
*Technomelt EM 357 is an unfilled hot melt adhesive with a softening point at 61-75 0 C, created on the basis of synthetic rubber.
*Technomelt EM 357 is a transparent yellowish composition with a viscosity of 600-1050 MPA .
*After polymerization, the glue forms a transparent, elastic film that is invisible on the container.
*Technomelt EM 357 demonstrates high adhesion, optimal viscosity, and remains plastic.
*Due to this, Technomelt EM 357 compensates for the stretching of soft containers, this is especially important for bottles (cans) with carbonate drinks.



AMONG THE ABVIOUS ADVANTAGES OF USING TECHNOMELT EM 357:
● economical (glue is classified as the most economical in consumption);
● exceptional adhesion to materials used for the manufacture of packaging and labels;
● ease of processing, due to which there is no risk of adhesive mass accumulation on equipment parts, including on the drum, clogs injectors, does not burn, does not form “threads”;
● lack of sensitivity to freezing : causes ease of transportation and storage;
● Suitable for all types of labeling equipment.



SELECTIONS BY PARAMETERS OF TECHNOMELT EM 357:
*Hot melt adhesive application temperature
*Hot melt adhesives with standard operating temperature (160-180 °C)
*Glue type
*Hot melt adhesive with permanent tack based on synthetic rubber



PROPERTIES OF TECHNOMELT EM 357:
*Technomelt EM 357 is used good adhesion to difficult surfaces, such as plastic labels.
*Technomelt EM 357 has low viscosity.
*Technomelt EM 357 is reliable labeling of plastic containers with paper and plastic labels.
*Technomelt EM 357 works at low temperatures, therefore does not damage etiquette.
*Technomelt EM 357 is excellent heat resistance.
*Technomelt EM 357 is easy to use.
*Technomelt EM 357 is reduced burning.



APPLICATION METHOD OF TECHNOMELT EM 357:
*nozzle,
*roller



PURPOSE OF TECHNOMELT EM 357:
Gluing plastic and paper labels onto PET bottles; gluing circular labels



PROPERTIES OF TECHNOMELT EM 357:
*Good adhesion to difficult surfaces, such as plastic labels.
*Low viscosity.
*Reliable labeling of plastic containers with paper and plastic labels.
*Works at low temperatures, therefore does not damage etiquette.
*Excellent heat resistance.
*Easy to use.
*Reduced burning.



FEATURES OF TECHNOMELT EM 357:
*The adhesive film is transparent.
*Technomelt EM 357 avoids the accumulation of adhesive residues on vacuum drums and other parts of the equipment.
*The high elongation index allows you to maintain the bonding strength while increasing the volume of PET bottles under the act



PROPERTIES OF TECHNOMELT EM 357:
*The adhesive film is transparent.
*Allows you to avoid the accumulation of adhesive residues on vacuum drums and other parts of equipment.
*High relative elongation allows maintaining strength



PHYSICAL and CHEMICAL PROPERTIES of TECHNOMELT EM 357:
VISCOSITY, MPA.S: 600 - 1050
OLD NAME: Euromelt 357 Euromelt 357
Viscosity (mPa*s): 600 — 1050
Operating temperature range: 130-150° С
Chemical basis: Melt glue based on synthetic rubber
VISCOSITY, MPA.S: 600 - 1050
viscosity: 600 - 1,050 mPa.s
softening point: 61-75°C
application temperature 12: 130-150°C
base: synthetic polymer



FIRST AID MEASURES of TECHNOMELT EM 357:
-Description of first-aid measures:
*If inhaled:
If breathed in, move person into fresh air.
*In case of skin contact:
Wash off with soap and plenty of water.
*In case of eye contact:
Flush eyes with water as a precaution.
*If swallowed:
Never give anything by mouth to an unconscious person.
Rinse mouth with water.
-Indication of any immediate medical attention and special treatment needed:
No data available



ACCIDENTAL RELEASE MEASURES of TECHNOMELT EM 357:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Keep in suitable, closed containers for disposal.



FIRE FIGHTING MEASURES of TECHNOMELT EM 357:
-Extinguishing media:
*Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
-Further information:
No data available



EXPOSURE CONTROLS/PERSONAL PROTECTION of TECHNOMELT EM 357:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
*Skin protection:
Handle with gloves.
Wash and dry hands.
*Body Protection:
Impervious clothing
*Respiratory protection:
Respiratory protection not required.
-Control of environmental exposure:
Do not let product enter drains.



HANDLING and STORAGE of TECHNOMELT EM 357:
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Store in cool place.
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.



STABILITY and REACTIVITY of TECHNOMELT EM 357:
-Reactivity:
No data available
-Chemical stability:
Stable under recommended storage conditions.
-Possibility of hazardous reactions:
No data available
-Conditions to avoid:
No data available


TEGO AIREX 931
DESCRIPTION:
TEGO Airex 931 shows high efficiency in combination with good compatibility.
TEGO Airex 931 is the First choice in case of foam stabilization.
TEGO Airex 931 is Suitable for a broad range of coating systems.

TEGO Airex 931 is a 4-Heptanone, 2,6-dimethyl-solution of a fluoro-silicone.
TEGO Airex 931 is universally used in solventborne formulations.

TEGO Airex 931 is also highly effective against macro-foam but still compatible.
TEGO Airex 931 is highly suitable for self-leveling floor coating and compressed air spraying.
TEGO Airex 931 is also suitable for flexo/gravure printing, airless spraying, and brush and roller applications.


BENEFITS OF TEGO AIREX 931:
• Universal use in clear and pigmented formulations
• for solventborne coatings
• highly efficient with good compatibility

TYPICAL APPLICATIONS OF TEGO AIREX 931:
• Wood coatings
• General industrial coatings
• Floor coatings
• Protective coatings

CHEMICAL AND PHYSICAL PROPERTIES OF TEGO AIREX 931:
active matter content: approx. 1 %
appearance: clear liquid
chemical description: solution of a fluorosilicone
solvent: diisobutylketone
Form : Liquid
Colour : yellowish, clear
Odour : aromatic
State of aggregation : Liquid
Melting temperature : not measured
Boiling point : 329 - 338 °F
Vapour pressure : 2 mbar
at 68.00 °F
Density : 0.8097 - 0.81 g/cm3
at 77.00 °F
Weight per volume : 6.74 Lb/Gal
Water solubility : insoluble
Viscosity, dynamic : approx. 3 mPa.s
at 25 °C
Method: DIN 51562
Volatile organic compound : 799.96 g/l
6.68 Lb/Gal
percentage volatile: 98.94 %
Percent Water:0.139 %
percent non-volatile: 1.06 %






SAFETY INFORMATION ABOUT TEGO AIREX 931:
First aid measures:
Description of first aid measures:
General advice:
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Move out of dangerous area:

If inhaled:
If breathed in, move person into fresh air.
If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact:
Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Consult a physician.

In case of eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Continue rinsing eyes during transport to hospital.

If swallowed:
Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.
Rinse mouth with water.
Consult a physician.

Firefighting measures:
Extinguishing media:
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas

Advice for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.
Accidental release measures:
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment.

Avoid breathing vapours, mist or gas.
Evacuate personnel to safe areas.

Environmental precautions:
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up:
Soak up with inert absorbent material and dispose of as hazardous waste.
Keep in suitable, closed containers for disposal.

Handling and storage:
Precautions for safe handling:
Avoid inhalation of vapour or mist.

Conditions for safe storage, including any incompatibilities:
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials

Exposure controls/personal protection:
Control parameters:
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls:
Appropriate engineering controls:
Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.

Personal protective equipment:
Eye/face protection:
Tightly fitting safety goggles.
Faceshield (8-inch minimum).
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection:
Handle with gloves.
Gloves must be inspected prior to use.
Use proper glove
removal technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.

Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
It should not be construed as offering an approval for any specific use scenario.

Body Protection:
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection:
Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.

If the respirator is the sole means of protection, use a full-face supplied air respirator.
Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Stability and reactivity:
Chemical stability:
Stable under recommended storage conditions.
Incompatible materials:
Strong oxidizing agents:
Hazardous decomposition products:
Hazardous decomposition products formed under fire conditions.
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas.

Disposal considerations:
Waste treatment methods:
Product:
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging:
Dispose of as unused product.
TEGO DISPERS 750 W
TEGO Dispers 750 W is a slightly anionic,polymeric wetting and dispersing additive for high-quality waterborne formulations.
Suitable for all kindsof pigments.
With inorganic pigments,outstanding stabilization performance can be observed.

TECHNICAL DATA
Active mattercontent: 33%
Appearance: white liquid
Chemical description: polyurethanepolyol resin
Glasstransitiontemperature: Approx. 129 °C
Hydroxylvalue(assupplied) :approx. 120 mg KOH/g
Solvent: water

Low influence on coatingsproperties, therefore suitable for exterior applications.
Solvent-free.
Very compatible.
TEGO Dispers 750 W is a polymeric high performance wetting and dispersing additive with outstanding pigment stabilization.
TEGO Dispers 750 W is a yellowish clear liquid aqueous solution of a copolymer with groups of high pigment affinity.
TEGO Dispers 750 W wets and stabilizes all types of pigment with good compatibility and hardly affects stability.
TEGO Dispers 750 W is suitable for waterborne, direct grind, resin-free, and resin based pigment concentrates.

Tego Dispers 750 W by Evonik is a solvent-free, label-free, slightly anionic, polymeric wetting and dispersing additive for high-quality waterborne formulations.
TEGO Dispers 750 W is applicable in all kinds of pigments and offers good stabilization with inorganic pigment.
TEGO Dispers 750 W shows good compatibility.
TEGO Dispers 750 W provides a low influence and minimal impact on coatings properties and it is used in exterior applications.
TEGO Dispers 750 W possesses viscosity reduction and color intensity/gloss with organic pigments/carbon blacks and inorganic pigments/filler.
TEGO Dispers 750 W is suitable for direct grind, resin-containing-, resin-free pigment concentrates and universal pastes.
Tego Dispers 750 W is designed for pigment concentrates, transportation- wood coatings and inkjet inks.
Recommended shelf life of 24 months.

Instructions for Use
Add grinding before dispersing.
This product should not be used as the sole wetting and dispersing additive when grinding carbon black pigments.
A resistance test should be done before using unpainted stainless steel as a product for storage and transport.
TEGO WET 270
TEGO Wet 270 shows excellent anti-crater properties with flow promotion in waterborne, solventborne, and radiation-curing coatings.
TEGO Wet 270 is a highly effective substrate wetting additive.
TEGO Wet 270 is a clear liquid polyether siloxane copolymer with excellent anti-crater effect with flow promotion in waterborne, solventborne, and radiation-curing formulations.

TECHNICAL DATA
Active mattercontent: 100 %
Appearance: clear liquid
Chemical description: polyether siloxanecopolymer

TEGO Wet 270 PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Colour : yellowish
Odour : specific to the product
State of aggregation : Liquid
Melting temperature : not measured
Boiling temperature : not measured
Vapour pressure : not measured
Density : 1.00 g/cm3
Weight per volume : 8.30 Lb/Gal
Water solubility : > 100 g/l at 25 °C emulsifiable
pH: not measured
Viscosity, dynamic : 10 - 100 mPa.s at 25 °C
Method: DIN 53015 (Höppler)
Volatile organic compound : 120.87 g/l 1.01 Lb/Gal
percentage volatile: 12.11 %
Percent Water:0.015 %
percent non-volatile: 87.89 %

TEGO Wet 270 is suitable for clear coat, radiation-curing, pigmented, and waterborne systems.
TEGO Wet 270 can be used in both the primer/basecoat and the topcoat for lacquer coats.
TEGO Wet 270 is recommended that the addition of this product to the coating be at the let-down stage and as supplied.
Tego Wet 270 is a substrate wetting agent by Evonik. Designed for water- & solvent-borne, solvent-free and radiation-curing formulations.
Used in automotive coatings, industrial coatings, architectural coatings, decorative coatings, printing inks and varnishes.
Also suitable for wood and furniture coatings, inkjet inks, leather pre-primers, primers and top coats based on polyurethane, acrylic, nitrocellulose and casein binders.
Provides very good anti-crater effect and recoatability.
Tego Wet 270 has a shelf life of 24 months.
A highly active siloxane-based substrate wetting additive with excellent anti-crater property and flow promotion.

• Strong anti-crater effect
• Effective substrate wetting and flow improvement
• Less foam stabilization
• Universal for most of the binder/application

TYPICAL APPLICATIONS
General industrial coatings
High solid industrial coatings
Wood coatings
Architecturalpaints

Synonyms
68938-54-5
117272-76-1
CID 54165714
SCHEMBL402381
[dimethyl(trimethylsilyloxy)silyl]oxy-[3-(2-methoxyethoxy)propyl]-methyl-trimethylsilyloxysilane
TEGOAMIN DMDEE

Tegoamin DMDEE, also known as N,N-Dimethyl-N,N-diethyl-1,3-propanediamine, is a chemical compound used primarily as a catalyst in various industrial processes.
Tegoamin DMDEE belongs to the class of aliphatic amines and is characterized by its ability to promote chemical reactions by facilitating the formation of intermediates or accelerating reaction rates.

CAS Number: 3033-62-3
EC Number: 221-220-5

Synonyms: N,N-Dimethyl-N,N-diethyl-1,3-propanediamine, Tegoamin DMDEE, N,N-Diethyl-N',N'-dimethyl-1,3-propanediamine, Diethyl-dimethylpropanediamine, 1,3-Propanediamine, N,N-diethyl-N'-methyl-, Diethyl-dimethylpropanediamine, 1,3-Propanediamine, N,N-diethyl-N'-methyl-, N,N-Diethyl-N'-methyl-1,3-propanediamine, Diethyl-dimethylpropanediamine, N,N-diethyl-N-methyl-1,3-diaminopropane, N,N-Dimethyl-N,N-diethyltrimethylenediamine, N,N-Diethyl-N-methyltrimethylenediamine, N,N-diethyl-N'-methyltrimethylenediamine, N,N-diethyl-N-methyltrimethylenediamine, N,N-Diethyl-N-methyltrimethylenediamine, N,N-diethyl-N-methyltrimethylenediamine, Diethyltrimethylenediamine, N,N-diethyl-N-methyltrimethylenediamine, N,N-Diethyl-N'-methyltrimethylenediamine, N,N-diethyl-N'-methyltrimethylenediamine, N,N-diethyl-N-methyltrimethylenediamine, N,N-diethyl-N'-methyltrimethylenediamine, N,N-diethyl-N-methyltrimethylenediamine, N,N-diethyl-N'-methyltrimethylenediamine, N,N-diethyl-N-methyltrimethylenediamine, N,N-Diethyl-N-methyltrimethylene diamine, N,N-diethyl-N-methyltrimethylenediamine, N,N-Diethyl-N-methyl-1,3-propanediamine, N,N-Diethyl-N-methyl-1,3-diaminopropane, N,N-diethyl-N-methyl-1,3-diaminopropane, N,N-Diethyl-N-methyltrimethylenediamine, N,N-diethyl-N-methyltrimethylenediamine, N,N-Diethyl-N-methyltrimethylene diamine



APPLICATIONS


Tegoamin DMDEE is widely used as a catalyst in the production of polyurethane foams for various applications, including insulation, cushioning, and packaging.
Tegoamin DMDEE serves as a chain extender or crosslinker in the synthesis of polyurethane elastomers, providing enhanced mechanical properties such as strength, flexibility, and abrasion resistance.
Tegoamin DMDEE is employed in the formulation of polyurethane coatings for surfaces such as floors, walls, and industrial equipment, offering durability and chemical resistance.

This compound acts as a catalyst in the production of polyurethane adhesives, sealants, and caulks, enabling strong and long-lasting bonds between substrates.
Tegoamin DMDEE serves as a reactive intermediate in the synthesis of specialty polyurethane materials, including microcellular foams, integral skin foams, and thermoplastic polyurethanes.

Tegoamin DMDEE is used in the formulation of flexible polyurethane foam mattresses, pillows, and furniture cushions, providing comfort and support.
Tegoamin DMDEE acts as a catalyst in the production of rigid polyurethane foam insulation for buildings, appliances, and refrigeration systems, improving energy efficiency and thermal performance.
Tegoamin DMDEE is employed in the manufacture of polyurethane composite materials for automotive parts, aerospace components, and sporting goods.
This compound serves as a catalyst in the production of polyurethane footwear, including athletic shoes, boots, and sandals, offering comfort and durability.

Tegoamin DMDEE is utilized in the formulation of polyurethane coatings for automotive refinishing, providing protection against corrosion, abrasion, and weathering.
Tegoamin DMDEE acts as a catalyst in the production of polyurethane membranes and films for waterproofing applications in construction, roofing, and civil engineering.

Tegoamin DMDEE is employed in the formulation of polyurethane adhesives for bonding wood, metal, plastics, and composites in construction, furniture, and automotive assembly.
Tegoamin DMDEE is used in the production of polyurethane foam-in-place insulation for appliances, refrigerated transport, and cold storage facilities.

Tegoamin DMDEE serves as a catalyst in the production of polyurethane pipe insulation for plumbing, HVAC, and industrial piping systems, reducing heat loss and energy consumption.
Tegoamin DMDEE is employed in the formulation of polyurethane coatings for marine applications such as boat hulls, decks, and underwater structures, offering resistance to water and corrosion.
Tegoamin DMDEE is utilized in the manufacture of polyurethane gaskets, seals, and O-rings for automotive, machinery, and fluid handling equipment.

Tegoamin DMDEE acts as a catalyst in the production of polyurethane foam-in-place packaging for shipping fragile and sensitive products, providing cushioning and impact protection.
Tegoamin DMDEE is used in the formulation of polyurethane casting resins for mold making, prototyping, and architectural modeling applications.

Tegoamin DMDEE serves as a catalyst in the production of polyurethane coatings for medical devices, prosthetics, and orthopedic implants, offering biocompatibility and sterilizability.
Tegoamin DMDEE is employed in the formulation of polyurethane potting compounds and encapsulants for electronics, electrical insulation, and protection against environmental contaminants.
Tegoamin DMDEE acts as a catalyst in the production of polyurethane foam-in-place insulation for appliances, refrigerated transport, and cold storage facilities.
Tegoamin DMDEE is used in the production of polyurethane sealants and adhesives for construction joints, expansion joints, and concrete repair applications.

Tegoamin DMDEE serves as a catalyst in the production of polyurethane elastomers for industrial rollers, conveyor belts, and seals, offering wear resistance and longevity.
Tegoamin DMDEE is employed in the formulation of polyurethane foam-in-place insulation for appliances, refrigerated transport, and cold storage facilities.
Tegoamin DMDEE is utilized in the formulation of polyurethane coatings for marine applications such as boat hulls, decks, and underwater structures, offering resistance to water and corrosion.

Tegoamin DMDEE is used as a catalyst in the production of polyurethane foam mattresses and pillows for residential, commercial, and hospitality applications.
Tegoamin DMDEE serves as a crosslinking agent in the formulation of polyurethane floor coatings for industrial, commercial, and residential flooring systems.
Tegoamin DMDEE is employed in the manufacture of polyurethane rollers and wheels for material handling, printing, and textile machinery.

Tegoamin DMDEE acts as a catalyst in the production of polyurethane foam insulation panels for modular construction and prefabricated building systems.
Tegoamin DMDEE is used in the formulation of polyurethane potting compounds for encapsulating electrical and electronic components in harsh environments.

Tegoamin DMDEE serves as a catalyst in the production of polyurethane sealants for joint sealing, crack repair, and waterproofing applications.
Tegoamin DMDEE is employed in the manufacture of polyurethane gaskets and seals for automotive, aerospace, and industrial machinery.
Tegoamin DMDEE acts as a chain extender in the synthesis of thermoplastic polyurethanes for applications such as automotive interiors, footwear, and sporting goods.

Tegoamin DMDEE is used as a catalyst in the production of polyurethane elastomers for rollers, bushings, and suspension components in automotive and industrial equipment.
Tegoamin DMDEE serves as a crosslinker in the formulation of polyurethane coatings for corrosion protection in marine, offshore, and chemical processing industries.
Tegoamin DMDEE is employed in the manufacture of polyurethane foam-in-place packaging for electronics, appliances, and consumer goods.
Tegoamin DMDEE acts as a catalyst in the production of polyurethane foam-in-place insulation for residential, commercial, and industrial buildings.

Tegoamin DMDEE is used in the formulation of polyurethane adhesives for bonding substrates such as metals, plastics, and composites.
Tegoamin DMDEE serves as a catalyst in the production of polyurethane composite materials for automotive lightweighting, aerospace structures, and wind turbine blades.
Tegoamin DMDEE is employed in the manufacture of polyurethane membranes for waterproofing foundations, basements, and underground structures.

Tegoamin DMDEE acts as a chain extender in the synthesis of waterborne polyurethane dispersions for coatings, adhesives, and textile finishing.
Tegoamin DMDEE is used as a catalyst in the production of polyurethane foam-in-place gaskets and seals for automotive, appliance, and HVACR applications.
This compound serves as a reactive diluent in the formulation of low-viscosity polyurethane coatings for spray, brush, and dip applications.

Tegoamin DMDEE is employed in the manufacture of polyurethane foam filters for air filtration in HVAC systems, automotive engines, and industrial processes.
Tegoamin DMDEE acts as a catalyst in the production of polyurethane elastomers for medical devices, prosthetics, and orthopedic implants.
Tegoamin DMDEE is used in the formulation of polyurethane casting resins for rapid prototyping, art casting, and architectural modeling.
Tegoamin DMDEE serves as a crosslinking agent in the formulation of polyurethane adhesives for structural bonding in aerospace, transportation, and construction.

Tegoamin DMDEE is employed as a catalyst in the production of polyurethane foam-in-place insulation for refrigerated transport vehicles, cold storage facilities, and HVAC ductwork.
Tegoamin DMDEE acts as a chain extender in the synthesis of high-resilience polyurethane foams for automotive seating, furniture cushions, and bedding.
Tegoamin DMDEE is used in the formulation of polyurethane elastomers for industrial rollers, conveyor belts, and seals, offering wear resistance and durability.

Tegoamin DMDEE is valued for its low toxicity and favorable environmental profile, making it a preferred choice in many industrial applications.
Tegoamin DMDEE undergoes rapid dispersion and mixing in reaction mixtures, ensuring uniform distribution and consistent product quality.

Tegoamin DMDEE is compatible with a wide range of polyols, isocyanates, and other raw materials commonly used in polyurethane formulations.
The precise control over reaction conditions and stoichiometry allows for the customization of polyurethane properties to meet specific application requirements.
Tegoamin DMDEE is often handled with care to prevent spills and accidental exposure, and proper ventilation is recommended during use to minimize inhalation risks.

Tegoamin DMDEE is typically stored in tightly closed containers in a cool, dry, well-ventilated area away from heat sources and incompatible materials.
The chemical stability and compatibility of Tegoamin DMDEE make it suitable for long-term storage and transportation.

Its high reactivity and catalytic activity make it an essential component in the production of high-performance polyurethane materials.
Tegoamin DMDEE is supplied in various concentrations and formulations to meet the specific requirements of different applications.
The versatility and reliability of Tegoamin DMDEE make it a valuable tool for chemical manufacturers, formulators, and end-users alike.

Tegoamin DMDEE plays a critical role in the development of innovative products and materials across numerous industries.
Tegoamin DMDEE is a versatile and efficient catalyst with a wide range of applications, contributing to the advancement of polyurethane technology and beyond.



DESCRIPTION


Tegoamin DMDEE, also known as N,N-Dimethyl-N,N-diethyl-1,3-propanediamine, is a chemical compound used primarily as a catalyst in various industrial processes.
Tegoamin DMDEE belongs to the class of aliphatic amines and is characterized by its ability to promote chemical reactions by facilitating the formation of intermediates or accelerating reaction rates.

Tegoamin DMDEE is often employed as a catalyst in polyurethane production, specifically in the synthesis of polyurethane foams, elastomers, coatings, and adhesives.
Tegoamin DMDEE acts as a chain extender or crosslinker in polyurethane formulations, contributing to the development of desirable properties such as flexibility, strength, and durability.

This chemical compound is also utilized in other applications, including the production of specialty chemicals, pharmaceutical intermediates, and agrochemicals.
Its versatile catalytic properties make it valuable in various organic synthesis processes, where it aids in the formation of complex molecules and intermediates.

Tegoamin DMDEE is typically used in conjunction with other catalysts and additives to optimize reaction conditions and achieve desired product characteristics.
Its effectiveness as a catalyst depends on factors such as concentration, temperature, and reaction time.
Tegoamin DMDEE plays a crucial role in catalyzing chemical reactions in a wide range of industrial applications, contributing to the production of diverse products and materials.

Tegoamin DMDEE is a clear, colorless liquid with a characteristic amine odor.
Tegoamin DMDEE possesses a molecular formula of C7H18N2 and a molecular weight of approximately 130.23 g/mol.
Tegoamin DMDEE is soluble in water and many organic solvents, enhancing its versatility in various applications.
Tegoamin DMDEE is characterized by its high purity and low viscosity, facilitating easy handling and dispersion.
Tegoamin DMDEE exhibits excellent stability under normal storage and handling conditions, with no known hazards of polymerization or decomposition.
The chemical structure of Tegoamin DMDEE features two ethyl groups and one dimethylamino group attached to a central propane backbone.
Tegoamin DMDEE is commonly used as a catalyst in polyurethane production, where it facilitates the formation of urethane linkages in polymeric materials.
Tegoamin DMDEE acts as a chain extender or crosslinker in polyurethane formulations, contributing to the development of desired properties such as flexibility and resilience.
Tegoamin DMDEE is known for its fast reaction kinetics and high catalytic efficiency, making it suitable for use in high-throughput manufacturing processes.
Tegoamin DMDEE is employed in the production of polyurethane foams, elastomers, coatings, adhesives, and sealants.
Tegoamin DMDEE serves as a reactive intermediate in the synthesis of specialty chemicals, pharmaceuticals, and agrochemicals.
The amine functionality of Tegoamin DMDEE enables it to participate in various organic reactions, including amidation, alkylation, and condensation.
Tegoamin DMDEE is often used in conjunction with other catalysts and additives to optimize reaction conditions and achieve desired product characteristics.



PROPERTIES


Physical Properties:

Molecular formula: C7H18N2
Molecular weight: Approximately 130.23 g/mol
Appearance: Clear, colorless liquid
Odor: Characteristic amine odor
Melting point: Approximately -65°C (-85°F)
Boiling point: Approximately 155-160°C (311-320°F) at 760 mmHg
Density: Approximately 0.79 g/cm³ at 20°C (68°F)
Solubility: Soluble in water and many organic solvents
Vapor pressure: Negligible
Viscosity: Low viscosity


Chemical Properties:

Chemical structure: N,N-Dimethyl-N,N-diethyl-1,3-propanediamine
Functional groups: Two ethyl groups and one dimethylamino group attached to a central propane backbone
pH: Alkaline (basic)
Stability: Stable under normal storage and handling conditions
Reactivity: Reacts with isocyanates to form urethane linkages
Hydrogen bonding: Forms hydrogen bonds with other molecules in solution
Flammability: Not flammable under normal conditions
Oxidation: Stable under oxidizing conditions
Polymerization: Does not undergo spontaneous polymerization
Hazardous decomposition products: May produce nitrogen oxides, carbon oxides, and toxic fumes when heated to decomposition



FIRST AID


Inhalation:

If inhaled, remove the affected person to fresh air immediately.
If the person is not breathing, administer artificial respiration. Seek medical attention promptly.
If breathing is difficult, administer oxygen if trained to do so. Keep the affected person calm and at rest.


Skin Contact:

Remove contaminated clothing and shoes immediately.
Wash the affected area thoroughly with soap and water for at least 15 minutes.
If irritation persists or if skin damage is evident, seek medical attention.
Do not apply ointments or creams unless directed by a medical professional.


Eye Contact:

Rinse the eyes immediately with gently flowing water for at least 15 minutes, holding the eyelids open to ensure thorough rinsing.
Seek immediate medical attention, even if irritation or pain is mild.
Remove contact lenses, if present and easy to do so, after rinsing.
Protect the unaffected eye during rinsing to prevent cross-contamination.


Ingestion:

Do not induce vomiting unless instructed to do so by medical personnel.
Rinse the mouth thoroughly with water and drink plenty of water to dilute the chemical.
Seek medical attention immediately. Provide the medical personnel with information about the ingested amount and any symptoms experienced.


General First Aid:

If a person exposed to Tegoamin DMDEE shows signs of discomfort, seek medical attention promptly.
Keep the affected person calm and reassure them while waiting for medical assistance.
If necessary, provide basic life support measures such as CPR if trained to do so.
Do not administer any medications unless directed by a medical professional.
Provide the medical personnel with the Safety Data Sheet (SDS) or product label information for proper treatment guidance.



HANDLING AND STORAGE


Handling:

Wear appropriate personal protective equipment (PPE), including chemical-resistant gloves, safety goggles or face shield, and protective clothing, to minimize skin and eye contact.
Use Tegoamin DMDEE in a well-ventilated area to minimize inhalation exposure. If ventilation is insufficient, use respiratory protection such as NIOSH-approved respirators.
Avoid direct skin contact with Tegoamin DMDEE. In case of contact, promptly remove contaminated clothing and wash skin with soap and water.
Use suitable engineering controls such as local exhaust ventilation or containment to minimize exposure during handling and transfer operations.
Prevent spills and leaks by handling containers carefully and using appropriate transfer equipment. Have spill control measures and absorbent materials readily available.
Do not eat, drink, or smoke while handling Tegoamin DMDEE, and wash hands thoroughly after handling to prevent accidental ingestion.
Store Tegoamin DMDEE away from incompatible materials, including strong acids, oxidizing agents, and reactive metals.
Follow established procedures for safe handling, transfer, and disposal of Tegoamin DMDEE in accordance with applicable regulations and guidelines.
Train personnel on safe handling practices and emergency procedures in case of spills, leaks, or exposure incidents.
Keep containers tightly closed when not in use to prevent contamination and minimize evaporation.


Storage:

Store Tegoamin DMDEE in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and sources of ignition.
Store containers of Tegoamin DMDEE in a secure manner to prevent tipping, leaking, or damage.
Keep containers tightly closed to prevent contamination and minimize evaporation.
Ensure that storage areas are properly labeled with the appropriate hazard information and emergency contact numbers.
Check containers regularly for signs of damage or deterioration and replace as needed to prevent leaks or spills.
Provide adequate containment measures such as spill trays or secondary containment to prevent environmental contamination in the event of a spill or leak.
Store Tegoamin DMDEE in suitable containers made of compatible materials such as glass, stainless steel, or high-density polyethylene (HDPE).
Keep storage areas clean and free of clutter to facilitate safe handling and emergency response.
Monitor storage conditions regularly to ensure compliance with safety regulations and guidelines.
Keep Tegoamin DMDEE away from sources of heat, sparks, or flames, as it may react violently with oxidizing agents or undergo thermal decomposition.
TEGOSOFT GMC 6 MB (PEG-6 CAPRYLIC/CAPRIC GLYCERIDES)
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is a polyethylene glycol (PEG) derivative of a mixture of mono-, di-, and triglycerides of caprylic and capric acids having an average of 6 moles of ethylene oxide.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is a water-loving, thin, and transparent liquid that is soluble in aqueous surfactant solutions can solubilize oils and oil-soluble ingredients and has a nice skin feel.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is a popular ingredient in micellar cleansing waters.

CAS: 361459-38-3
EINECS: 800-104-3

Synonyms
Glycerides, mixed decanoyl and octanoyl mono-, di- and tri-, ethoxylated

TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is an excellent emollient and a skin-replenishing component.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) are used as an emulsifier, emollient, refatting agent, solubilizer, and wetting agents in cosmetics like creams, lotions, shampoos at a concentration of 0.5–5%.
Skin care: Skin care: TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) works as an emollient and its fatty acid mixture can be used by the skin to replenish its surface and prevent moisture loss.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is well-tolerated by the skin and is gentle on it.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides)s is a non-ionic ingredient providing oil-free moisturizing in skin care products.

TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is an effective emulsifier and emollient in cleansers and micellar waters as it breaks down and removes sebum.
Thus, TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is widely used in many makeup removers
Hair care: TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) works as a non-ionic component providing oil-free moisturizing in hair care products.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) works as a non-sensitizing, gentle cleanser for hair products.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) works as a secondary liquid surfactant in shampoos and adds good foam quality and a silky after-feel.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is a polyethylene glycol derived from a mixture of mono-, di-, and triglycerides of caprylic and capric acids, usually sourced from coconut oil.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is the mixed triester of glycerin and caprylic and capric acids.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is made by first separating the fatty acids and the glycerol in coconut oil.

TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is done by hydrolyzing the coconut oil, which involves applying heat and pressure to the oil to split it apart.
The acids then go through esterification to add back the glycerol.
The resulting oil is called capric or caprylic triglyceride.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is a hydrophilic emollient clearly soluble in aqueous surfactant solutions, solubilizes oils and oil-soluble ingredients.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is stable in medium pH range (app. 5 to 8) and results in surfactant preparations with good foam quality.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) can be used as a superfatting agent in shampoos, shower and bath preparations and solubilizer in skin cleansing preparations, bath oils, facial cleansers and hair rinses.

Derived from coconut oil and glycerin, TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is considered an excellent emollient and skin-replenishing ingredient.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides)’s included in cosmetics due to its mix of fatty acids that skin can use to replenish its surface and resist moisture loss.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) can also function as a thickener, but its chief job is to moisturize and replenish skin.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides)’s value for skin is made greater by the fact that it’s considered gentle.

TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is a non-ionic ingredient providing oil free moisturizing in skin and hair care products.
Derived from coconuts, TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is a non-sensitizing, gentle cleanser for skin, facial and hair products.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides)'s a great secondary liquid surfactant in shampoos, body washes, etc as it adds good foam quality and a silky after-feel.

TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) can also be used as a solubolizer for small amounts of oil in water solutions.
Equal parts of oil and TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) should be mixed together and then added to the water portion.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is an effective emulsifier and emollient in cleansers and micellar waters as it will break down and remove sebum.

TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is a water soluble emollient prepared from derivatized coconut fatty acids.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is nonionic and compatible with other ionic species in formulation.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is used in personal care both as an emulsifying agent with an HLB of 12.5 and as a low irritation secondary surfactant with a moisturizing effect due to its refatting properties.

TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) acts as a surfactant yet has a moisturizing effect due to its refatting properties.
TEGOSOFT GMC 6 MB (PEG-6 Caprylic/Capric Glycerides) is ideally suited for use in hair care and bath products where its luxurious after feel combined with its solubilization and emulsification properties are best employed.
TEGOSTAB B 8523
TEGOSTAB B 8523


Tegostab B 8523 is a surfactant.
Tegostab B 8523 is a non-hydrolyzable polyether polydimethylsiloxane copolymer.
Tegostab B 8523 is rigid polyurethane foams with an open cell structure are important materials for some industries, such as the construction (gap filling) or the automotive industry.



USES and APPLICATIONS of TEGOSTAB B 8523:
Tegostab B 8523 is a silicon-carbon bond, non-hydrolytic type foam stabilizer, it is a surfactant of polysiloxane-polyether copolymer.
Tegostab B 8523 is mainly used for manufacturing polyester polyurethane and polyether polyurethane rigid foam , and is a foam stabilizer for PUR water foaming process.


Tegostab B 8523 is also suitable for the production of various kind of polyester polyols such as terephthalic acid based polyester polyol and adipic acid based polyester polyol.
Tegostab B 8523 is used in the formulation of polyurethane rigid foams.
Tegostab B 8523 is an additive developed for use in rigid foam systems which are formulated for maximum open cell content.


In these types of formulations Tegostab B 8523 effectively supports cell opening.
Tegostab B 8523 is only a weak stabilizer therefore it has to be used in combination with silicone surfactants, e. g. Tegostab B 8871.
In particular, Tegostab B 8523 is the cell opener of choice for systems that are used to manufacture water blown, thermo-formable rigid foams as they are required to make automotive headliners.


However, since the performance of Tegostab B 8523 largely depends on the nature of the formulations it might be considered for other systems that are designed for open cell rigid foams as well.
Tegostab B 8523 is rigid polyurethane foams with an open cell structure are important materials for some industries, such as the construction (gap filling) or the automotive industry.


Tegostab B 8523 is therefore quite common to use water as a chemical blowing agent.
In most low density foam grades an open cell structure is essential to achieve sufficient dimensional stability.
Tegostab B 8526 can be used in combination with more powerful cell openers, like Tegostab B 8523.


Tegostab B 8523 is a cell opener for rigid polyurethane foam systems which must be used together with a silicone stabilizer.
This combination of additives allows to adjust the open cell content of the obtained foam to the requirements of a given application by simply changing the ratio of the two components.


The cell opening efficiency of Tegostab B 8523 strongly depends on the formulation parameters and the foam processing conditions.
Therefore the optimal use level as well as the ratio of Tegostab B 8523 and Tegostab B 8871 should be identified in an initial screening to avoid the formation of a coarser cell structure and to achieve the desired degree of cell opening.


Tegostab B 8523 is rigid foam with an open cell structure is important, e. g. as final or starting products for the packaging or the automotive supply industry.
For this kind of application the excellent temperature insulating properties polyurethane foam is famous for are not of importance.
For those systems it is therefore quite common to use just water for blowing.
As the resulting foams are mostly low density grade ones, an open cell structure is essential to achieve a sufficient dimensional stability.



PHYSICAL and CHEMICAL PROPERTIES of TEGOSTAB B 8523:
Viscosity (25 °C) 150 – 550 mPas
Density (20 °C) 1.015 – 1.025 g/ml
TELLURIUM DIETHYLDITHIOCARBAMATE (TDEC)

Tellurium diethyldithiocarbamate (TDEC) is a chemical compound used as a vulcanization accelerator in the production of rubber.
Its chemical formula is Te(S₂CN(C₂H₅)₂)₂.
Tellurium diethyldithiocarbamate (TDEC) belongs to the class of dithiocarbamate accelerators, which are commonly employed in the rubber industry to hasten the vulcanization process.
Vulcanization is a crucial step in rubber manufacturing that imparts desirable properties such as elasticity, strength, and durability to the final rubber product.

CAS Number: 20941-65-5
EC Number: 244-121-9



APPLICATIONS


Tellurium diethyldithiocarbamate (TDEC) is widely utilized as an accelerator in the vulcanization process of natural rubber (NR).
Tellurium diethyldithiocarbamate (TDEC) finds applications in the production of rubber goods such as tires, conveyor belts, and automotive components.
Tellurium diethyldithiocarbamate (TDEC) is favored for its ability to enhance the vulcanization efficiency of rubber compounds.

In tire manufacturing, TDEC contributes to improved tread properties, wear resistance, and overall tire performance.
Tellurium diethyldithiocarbamate (TDEC) is employed in the production of rubber footwear, imparting desirable properties like flexibility and durability.
Tellurium diethyldithiocarbamate (TDEC) is used in the manufacturing of rubber hoses and seals, ensuring the integrity and longevity of these components.

Tellurium diethyldithiocarbamate (TDEC) plays a crucial role in the production of rubber belts used in various industrial applications.
Tellurium diethyldithiocarbamate (TDEC) is applied in the formulation of rubber compounds for cable insulation and sheathing, enhancing electrical and mechanical properties.

Tellurium diethyldithiocarbamate (TDEC) is utilized in the production of vibration-isolating rubber mounts and dampers.
Tellurium diethyldithiocarbamate (TDEC) contributes to the vulcanization of rubber used in automotive components, including engine mounts and bushings.
In conveyor belt manufacturing, TDEC assists in achieving optimal tensile strength and wear resistance.

Tellurium diethyldithiocarbamate (TDEC) is employed in the production of rubber gaskets and seals for diverse industrial applications.
Tellurium diethyldithiocarbamate (TDEC) enhances the vulcanization kinetics of rubber, leading to reduced processing times in manufacturing.
Tellurium diethyldithiocarbamate (TDEC) is utilized in the production of molded rubber goods for industrial and consumer applications.

Tellurium diethyldithiocarbamate (TDEC) is employed in rubber compound formulations for molded rubber products, ensuring uniform vulcanization.
Tellurium diethyldithiocarbamate (TDEC) is used in the manufacturing of rubber rollers for printing and industrial machinery.
Tellurium diethyldithiocarbamate (TDEC) contributes to the production of rubber sheets with improved mechanical properties.

Tellurium diethyldithiocarbamate (TDEC) is applied in the formulation of rubberized fabrics for various applications, including waterproofing.
Tellurium diethyldithiocarbamate (TDEC) is employed in the vulcanization of rubber used in the production of shoe soles and insoles.
Tellurium diethyldithiocarbamate (TDEC) assists in achieving a balance between hardness and flexibility in vulcanized rubber.
Tellurium diethyldithiocarbamate (TDEC) is utilized in the production of rubberized components for the construction industry.

Tellurium diethyldithiocarbamate (TDEC) contributes to the vulcanization of rubber in the production of sporting goods such as balls and mats.
Tellurium diethyldithiocarbamate (TDEC) is applied in the manufacturing of rubber parts for the aerospace industry, ensuring performance under demanding conditions.
Tellurium diethyldithiocarbamate (TDEC) is crucial in achieving uniform vulcanization in the production of medical-grade rubber products.
Tellurium diethyldithiocarbamate (TDEC) plays a key role in optimizing the vulcanization process across a wide range of rubber applications, ensuring the quality and performance of the final products.

Tellurium diethyldithiocarbamate (TDEC) is instrumental in the vulcanization of rubber used in the production of industrial belts, contributing to their durability and tensile strength.
Tellurium diethyldithiocarbamate (TDEC) is employed in the formulation of rubber compounds for anti-vibration mounts in machinery and automotive applications.
Tellurium diethyldithiocarbamate (TDEC) is crucial in the production of rubber seals and gaskets for use in machinery, providing enhanced sealing properties.

In the automotive sector, TDEC contributes to the vulcanization of rubber components such as engine mounts, ensuring longevity and resilience.
Tellurium diethyldithiocarbamate (TDEC) is utilized in the manufacturing of rubberized components for the construction of vehicles, including trucks and buses.
Tellurium diethyldithiocarbamate (TDEC) aids in achieving optimal vulcanization characteristics in the production of conveyor belts for material handling systems.

Tellurium diethyldithiocarbamate (TDEC) is applied in rubber formulations for cable sheathing, providing insulation for electrical wiring.
Tellurium diethyldithiocarbamate (TDEC) is utilized in the production of rubber-coated fabrics, offering water resistance and durability in applications like rainwear.
Tellurium diethyldithiocarbamate (TDEC) plays a role in formulating rubber compounds for the production of durable and resilient shoe soles and heels.

In the creation of rubberized rollers for printing and industrial machinery, TDEC ensures proper vulcanization and wear resistance.
Tellurium diethyldithiocarbamate (TDEC) is essential in the manufacturing of rubber hoses for various industrial purposes, including fluid transport.
Tellurium diethyldithiocarbamate (TDEC) contributes to the vulcanization of rubber used in the production of inflatable structures, such as rubber balloons.
Tellurium diethyldithiocarbamate (TDEC) is applied in the formulation of rubber compounds for roller coverings, providing grip and wear resistance.

Tellurium diethyldithiocarbamate (TDEC) plays a role in the production of rubberized components for the marine industry, offering resistance to saltwater and environmental conditions.
In the medical field, TDEC is used in the vulcanization of rubber for medical gloves, ensuring elasticity and barrier properties.

Tellurium diethyldithiocarbamate (TDEC) is crucial in achieving uniform vulcanization in the production of rubberized components for the aerospace industry.
Tellurium diethyldithiocarbamate (TDEC) contributes to the production of rubber sheets with enhanced tear resistance and flexibility for various applications.
Tellurium diethyldithiocarbamate (TDEC) is applied in the formulation of rubberized components for agricultural machinery, ensuring resilience in challenging conditions.

In the creation of rubberized components for household appliances, TDEC ensures durability and resistance to environmental factors.
Tellurium diethyldithiocarbamate (TDEC) plays a key role in optimizing the vulcanization process in the production of rubberized parts for consumer electronics.
Tellurium diethyldithiocarbamate (TDEC) contributes to the formulation of rubber compounds for the production of sporting goods like tennis balls and athletic mats.

Tellurium diethyldithiocarbamate (TDEC) is utilized in the production of rubber components for the mining industry, offering wear resistance in harsh environments.
Tellurium diethyldithiocarbamate (TDEC) is applied in rubber formulations for the production of seals and gaskets used in the oil and gas industry.
Tellurium diethyldithiocarbamate (TDEC) contributes to achieving the desired vulcanization characteristics in the production of rubberized components for the railway sector.
In the creation of rubberized parts for the telecommunications industry, TDEC ensures resilience to environmental exposure and wear.

Tellurium diethyldithiocarbamate (TDEC) is extensively employed in the production of high-performance rubber compounds for use in the aerospace sector, ensuring compliance with stringent requirements for durability and temperature resistance.
In the manufacturing of off-road and specialty vehicle tires, TDEC contributes to the vulcanization process, enhancing the ruggedness and longevity of the tires.
Tellurium diethyldithiocarbamate (TDEC) is a key ingredient in the formulation of rubber compounds for industrial and agricultural conveyor belts, providing optimal vulcanization properties.

Tellurium diethyldithiocarbamate (TDEC) plays a crucial role in the creation of rubber linings for chemical processing equipment, offering resistance to corrosive chemicals.
In the automotive industry, TDEC is utilized in the vulcanization of rubber components for suspension systems, ensuring stability and performance.
Tellurium diethyldithiocarbamate (TDEC) finds applications in the production of rubberized components for the marine sector, including boat fenders and dock bumpers, ensuring durability in marine environments.

Tellurium diethyldithiocarbamate (TDEC) is integral in the formulation of rubber compounds for the construction of durable and weather-resistant roofing materials.
Tellurium diethyldithiocarbamate (TDEC) is applied in the manufacturing of rubberized components for the defense industry, providing resistance to extreme environmental conditions.
Tellurium diethyldithiocarbamate (TDEC) contributes to the vulcanization of rubber used in the production of industrial seals and gaskets, ensuring reliable performance in various applications.
Tellurium diethyldithiocarbamate (TDEC) plays a role in optimizing vulcanization processes for the production of rubber components in the renewable energy sector, including wind turbine components.

In the creation of industrial-grade inflatable products such as airbags, TDEC ensures proper vulcanization, contributing to safety and reliability.
Tellurium diethyldithiocarbamate (TDEC) is used in the formulation of rubber compounds for the production of medical equipment components, including rubber seals and tubing.
Tellurium diethyldithiocarbamate (TDEC) is applied in the production of rubberized components for consumer electronics, providing electrical insulation and durability.
Tellurium diethyldithiocarbamate (TDEC) contributes to the vulcanization of rubber used in the manufacturing of specialty gloves, including those used in cleanroom environments.

Tellurium diethyldithiocarbamate (TDEC) is crucial in optimizing vulcanization processes for the production of rubberized components used in the telecommunications industry.
In the production of high-friction rubber materials for use in brake pads and linings, TDEC contributes to the vulcanization process, ensuring performance under varying conditions.
Tellurium diethyldithiocarbamate (TDEC) finds applications in the formulation of rubber compounds for the creation of high-temperature-resistant seals and gaskets used in industrial processes.

Tellurium diethyldithiocarbamate (TDEC) is utilized in the production of rubberized components for the petrochemical industry, including seals and gaskets for pipelines.
Tellurium diethyldithiocarbamate (TDEC) contributes to the vulcanization of rubber used in the production of specialized footwear, including safety boots for industrial applications.
In the creation of rubberized components for the textile industry, TDEC ensures proper vulcanization for enhanced strength and durability.
Tellurium diethyldithiocarbamate (TDEC) plays a role in optimizing vulcanization processes for the production of rubberized components used in water treatment and purification systems.
Tellurium diethyldithiocarbamate (TDEC) is applied in the formulation of rubber compounds for the production of durable and chemical-resistant laboratory equipment components.

Tellurium diethyldithiocarbamate (TDEC) contributes to the vulcanization of rubber used in the production of components for food processing machinery, ensuring compliance with food safety standards.
Tellurium diethyldithiocarbamate (TDEC) finds applications in the creation of rubberized components for the nuclear industry, providing resistance to radiation and harsh environments.
Tellurium diethyldithiocarbamate (TDEC) is used in the formulation of rubber compounds for the production of resilient and chemical-resistant footwear components for laboratory and industrial settings.



DESCRIPTION


Tellurium diethyldithiocarbamate (TDEC) is a chemical compound used as a vulcanization accelerator in the production of rubber.
Its chemical formula is Te(S₂CN(C₂H₅)₂)₂.
Tellurium diethyldithiocarbamate (TDEC) belongs to the class of dithiocarbamate accelerators, which are commonly employed in the rubber industry to hasten the vulcanization process.
Vulcanization is a crucial step in rubber manufacturing that imparts desirable properties such as elasticity, strength, and durability to the final rubber product.

Tellurium diethyldithiocarbamate (TDEC), as a vulcanization accelerator, facilitates the cross-linking of polymer chains in rubber, leading to the formation of a three-dimensional network structure.
This network enhances the mechanical properties and heat resistance of the rubber.
Dithiocarbamate accelerators like Tellurium diethyldithiocarbamate (TDEC) are known for their effectiveness in promoting vulcanization at lower temperatures compared to some other accelerator types.


PROPERTIES


Chemical Formula: Te(S₂CN(C₂H₅)₂)₂
Molecular Weight: Varies based on specific formulation.
Physical Form: Typically a solid or liquid, depending on formulation.
Color: Color can vary, and it may be influenced by impurities or additives.
Odor: May have a characteristic odor, which can vary.
Melting Point: The temperature at which the solid turns into a liquid.
Boiling Point: The temperature at which the substance transitions from a liquid to a gas.
Density: The mass per unit volume, often measured at a specific temperature.
Solubility: The ability of the substance to dissolve in a particular solvent.
Vapor Pressure: Pressure exerted when the substance transitions from a liquid to a vapor.
Flash Point: The lowest temperature at which the substance can ignite.
Autoignition Temperature: The minimum temperature at which the substance can spontaneously ignite.
Explosive Limits: The concentration range at which the substance can form an explosive mixture with air.
Refractive Index: A measure of how much light is bent or refracted when passing through the substance.
pH: The acidity or basicity of the substance.
Hygroscopicity: The tendency of the substance to absorb moisture from the air.



FIRST AID


Inhalation:

Move the affected person to fresh air.
If breathing is difficult, administer oxygen.
Seek medical attention if symptoms persist.


Skin Contact:

Remove contaminated clothing.
Wash affected areas thoroughly with soap and water.
Seek medical attention if irritation or other symptoms develop.


Eye Contact:

Rinse eyes gently with water for at least 15 minutes, holding eyelids open.
Seek immediate medical attention.


Ingestion:

Rinse mouth with water, but do not induce vomiting.
Seek medical attention immediately.



HANDLING AND STORAGE


Handling:

Personal Protection:
Wear appropriate personal protective equipment (PPE), including gloves, goggles, and a lab coat.
Use respiratory protection if there is a risk of inhalation exposure.

Ventilation:
Work in a well-ventilated area or use local exhaust ventilation to control airborne concentrations.

Avoidance:
Avoid direct contact with skin, eyes, and clothing.
Do not ingest or inhale the substance.

Hygiene Practices:
Wash hands thoroughly after handling.
Do not eat, drink, or smoke in areas where the substance is handled.

Storage:
Store in a cool, dry, well-ventilated area away from incompatible materials.
Keep containers tightly closed when not in use.

Segregation:
Separate from incompatible materials, such as strong acids or bases.

Labeling:
Clearly label containers with the product name, hazard symbols, and safety information.


Storage Conditions:

Temperature:
Store at a specific temperature range if recommended in the SDS.

Humidity:
Avoid excessive humidity, as it may affect the stability of the substance.

Light:
Some substances may be sensitive to light, so store in a dark or opaque container if necessary.

Ventilation:
Ensure adequate ventilation to prevent the buildup of vapors or gases.

Incompatible Materials:
Store away from materials that may react adversely with TDEC.

Special Precautions:
Follow any specific precautions mentioned in the SDS, such as avoiding contact with water or certain chemicals.



SYNONYMS


DITIOCARB TELLURIUM
ETHYL TELLURAC [HSDB]
CHEBI:82566
Tellurium bis(diethyldithiocarbamate)
UNII-0653A77079
Carbamodithioic acid, diethyl-, tetrakis(anhydrosulfide) with thiotelluric acid
Diethyldithio carbamic acid tellurium salt
N,N-diethylcarbamodithioate;tellurium(4+)
C19570
Q27156082
TENSIOACTIFS
TENSIOACTIFS AMPHOTERES Tensioactifs Amphotères Nom INCI : TENSIOACTIFS AMPHOTERES Classification : Tensioactif amphotère Ses fonctions (INCI) Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TENSIOACTIFS AMPHOTERES
TENSIOACTIFS ANIONIQUES, Tensioactifs anioniques, Nom INCI : TENSIOACTIFS ANIONIQUES. Classification : Tensioactif anionique. Nous utilisons ce terme lorsque la marque ne précise pas le nom de l'ingrédient. Sur les produits ménagers, vous trouvez aussi assez souvent la désignation "Agent de surface anionique".Les tensioactifs sont des détergents très efficaces utilisés dans les produits lavants cosmétiques et les produits ménagers. Son représentant le plus fréquent est le SLES (Sodium Laureth Sulfate) : Notez que dans les cosmétiques Bio, l'ingrédient est interdit du fait de sa fabrication et de sa très faible biodégradabilité, alors que dans les produits ménagers, le label Ecolabel l'autorise dans les produits certifiés.Ses fonctions (INCI) Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TENSIOACTIFS ANIONIQUES
TENSIOACTIFS CATIONIQUES Nom INCI : TENSIOACTIFS CATIONIQUES Classification : Tensioactif cationique Ses fonctions (INCI) Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TENSIOACTIFS CATIONIQUES
TENSIOACTIFS NON IONIQUES Tensioactifs non ioniques Nom INCI : TENSIOACTIFS NON IONIQUES Classification : Tensioactif non ionique Ses fonctions (INCI) Tensioactif : Réduit la tension superficielle des cosmétiques et contribue à la répartition uniforme du produit lors de son utilisation
TENSIOACTIFS NON IONIQUES
cas no 100-21-0 Benzene-1,4-dicarboxylic acid; p-Dicarboxybenzene; p-Phthalic acid; 1,4-Benzenedicarboxylic acid; Acide terephtalique; Kyselina tereftalova; Tephthol; p-Benzenedicarboxylic acid; p-Carboxybenzoic acid; para-Phthalic acid;
TEP
SYNONYMS Ethyl phosphate;phosphoric acid triethyl ester; TEP; Phosphoric ether; AURORA KA-1638; Phosphoric acid, triethyl ester; Triethylfosfat; ETHYL ACID PHOSPHATE; Triethyl phosphate; diethylphosphoric acid ethyl ester; TRIETHYL PHOSPHAYE; phosphatedetriethyle; CAS:78-40-0
TEPA – Tetraethylenepentamine
SYNONYMS 1,11-Diamino-3,6,9-triazaundecane; TEPA; N-(2-Aminoethyl)-N'-[2-[(2-aminoethyl)amino]ethyl]-1,2-Ethanediamine;1,4,7,10,13-Pentaazatridecane; 3,6,9-Triazaundecamethylenediamine;CAS NO: 112-57-2
Terephthal aldehyde
Terephthalic aldehyde; 1,4-Diformylbenzene; 1,4-Benzenedicarboxaldehyde; Terephthaldicarboxaldehyde; p-Phthalaldehyde; p-Formylbenzaldehyde; 4-Formylbenzaldehyde; Terephthaldialdehyde; Terephtaldehydes; Terephthaldehyde; 1,4-Benzenedialdehyde; 1,4-Benzenedicarbaldehyde; p-Phthaldialdehyde; p-Benzenedialdehyde CAS NO:623-27-8
TEREPHTHALIC ACID
TERPINEOL, N° CAS : 8000-41-7, Nom INCI : TERPINEOL, N° EINECS/ELINCS : 232-268-1. Ses fonctions (INCI) : Agent masquant : Réduit ou inhibe l'odeur ou le goût de base du produit, Agent parfumant : Utilisé pour le parfum et les matières premières aromatiques. Noms français : TERPINEOL; TERPINEOL (MELANGE D'ISOMERES: ALPHA-, BETA-, GAMMA-); TERPINEOLS ; Utilisation et sources d'émission: Fabrication de parfums, agent de saveur. Terpineol IUPAC names 1-hydroperoxy-2,7,7-trimethyl-bicyclo[3.1.1]heptane 1-methyl-4-(propan-2-ylidene)cyclohexan-1-ol; 2-[(1R)-4-methylcyclohex-3-en-1-yl]propan-2-ol; 2-[(1S)-4-methylcyclohex-3-en-1-yl]propan-2-ol 2-(4-Methyl- 1-cyclohex- 3-enyl) propan- 2-ol 2-(4-Methyl-1-cyclohex-3-enyl)propan- 2-ol 2-(4-methyl-1-cyclohex-3-enyl)propan-2-ol 2-(4-Methyl-3-cyclohexen-1-yl)-2-propanol - 4-isopropenyl-1-methylcyclohexanol (1:1) 2-(4-METHYLCYCLOHEX-3-EN-1-YL)PROPAN-2-OL Reaction mass of p-menth-1-en-8-ol and 1-methyl-4-(1-methylethylidene)cyclohexan-1-ol Reaction mass of p-menth-1-en-8-ol and 1-methyl-4-(1-methylvinyl)cyclohexan-1-ol and 1-methyl-4-(1-methylethylidene)cyclohexan-1-ol Reaction mass of p-menth-1-en-8-ol and 1-methyl-4-(1-methylvinyl)cyclohexan-1-ol and 1-methyl-4-(1-methylethylidene)cyclohexan-1-ol and α,α-dimethyl-4-methylenecyclohexanemethanol Reaction mass of α,α-4-trimethyl-(1S)-3-cyclohexene-1-methanol and α,α-4-trimethyl-(1R)-3-cyclohexene-1-methanol and 1-methyl-4-(1-methylethylidene)-cyclohexanol Terpineol; p-Menthenol (mixed isomers)
TEREPHTHALIC ACID
Terephthalic acid is an organic compound with formula C6H4(CO2H)2.
Terephthalic acid is a commodity chemical, used principally as a precursor to the polyester PET, used to make clothing and plastic bottles.
Terephthalic acid is a high-melting, crystalline material forming very strong fibers.

CAS Number: 100-21-0
EC Number: 202-830-0
Chemical Formula: C6H4-1,4-(COOH)2
Molecular Weight: 166.13

TEREPHTHALIC ACID, 100-21-0, p-Phthalic acid, 1,4-Benzenedicarboxylic acid, benzene-1,4-dicarboxylic acid, p-Dicarboxybenzene, p-Benzenedicarboxylic acid, p-Carboxybenzoic acid, Acide terephtalique, 1,4-dicarboxybenzene, Kyselina tereftalova, WR 16262, TA-33MP, NSC 36973, HSDB 834, p-Phthalate, TA 12, UNII-6S7NKZ40BQ, Kyselina terftalova, Benzene-p-dicarboxylic acid, 6S7NKZ40BQ, CHEBI:15702, MFCD00002558, para-Phthalic acid, Tephthol, DSSTox_CID_6080, DSSTox_RID_78007, DSSTox_GSID_26080, Acide terephtalique, Kyselina tereftalova, CAS-100-21-0, CCRIS 2786, 4-Carboxybenzoic Acid, EINECS 202-830-0, BRN 1909333, terephtalic acid, AI3-16108, P-Phthelate, P-Phthelic acid, UB7, p-Benzenedicarboxylate, terephthalsäure, Benzene-p-dicarboxylate, benzene-1,4-dioic acid, WLN: QVR DVQ, Terephthalic acid, 97%, Terephthalic acid, 98%, EC 202-830-0, SCHEMBL1655, para-benzenedicarboxylic acid, Benzene, p-dicarboxylic acid, 4-09-00-03301 (Beilstein Handbook Reference), BIDD:ER0245, tere-Phthalic Acid (Sublimed), CHEMBL1374420, DTXSID6026080, Benzene, 1,4-Dicarboxylic acid, p-Dicarboxybenzene p-Phthalic acid, BCP06429, NSC36973, STR02759, Tox21_201659, Tox21_303229, NSC-36973, s6251, STL281856, ZINC12358714, Terephthalic acid, analytical standard, AKOS000119464, CS-W010814, HY-W010098, MCULE-9289682931, NCGC00091618-01, NCGC00091618-02, NCGC00091618-03, NCGC00257014-01, NCGC00259208-01, AC-10250, BP-21157, FT-0674866, FT-0773240, T0166, C06337, Terephthalic acid, SAJ special grade, >=98.0%, A852800, AE-562/40217759, Q408984, Terephthalic acid, Vetec(TM) reagent grade, 98%, Z57127536, Kyselina terftalova, RARECHEM AL BO 0011, 1,4-phthalicacid, Ecamsule Related Compound C, United States Pharmacopeia (USP) Reference Standard

Several million tonnes are produced annually.
The common name is derived from the turpentine-producing tree Pistacia terebinthus and phthalic acid.

Terephthalic acid (1,4-benzenedicarboxylic acid) is used for the production of polyesters with aliphatic diols as the comonomer.
The polymer is a high-melting, crystalline material forming very strong fibers.

Terephthalic acid is an organic compound with formula C6H4(CO2H)2.
This white solid is a commodity chemical, used principally as a precursor to the polyester PET, used to make clothing and plastic bottles.

Terephthalic acid is the largest volume synthetic fiber and the production of terephthalic acid is the largest scale operated process based on a homogeneous catalyst.
More recently the packaging applications (PET, the recyclable copolymer with ethylene glycol) have also gained importance.

Terephthalic acid is produced from -xylene by oxidation with oxygen.
The reaction is carried out in acetic acid and the catalyst used is cobalt (or manganese) acetate and bromide.

Phthalic anhydride is made from naphthalene or -xylene by air oxidation over a heterogeneous catalyst.
The main application of phthalic anhydride is in the dialkylesters used as plasticizers (softeners) in PVC.
The alcohols used are, for instance, 2-ethylhexanol obtained from butanal, a hydroformylation product.

Terephthalic acid is an industrially important aromatic acid, almost exclusively used as starting material for saturated polyester, mainly poly(ethylene terephthalate) (> 90%).
Terephthalic acid is almost entirely made by oxidation of petro-derived p-xylene.

Pathways toward biobased p-xylene or terephthalic acid mainly focus on carbohydrates such as cellulose or hemicellulose.
Nonetheless, Yan and colleagues were the first to report a three-step process from corn stover lignin to terephthalic acid.

Starting from depolymerized RCF lignin oil, Terephthalic acid includes (i) a Mo on carbon catalyzed demethoxylation, (ii) a carbonylation of the obtained n-alkylphenol with CO by a homogeneous Pd-catalyst, and finally (iii) an oxidation of the 4-n-propylbenzoic acid to terephathalic acid by a Co-Mn-Br catalyst under O2 pressure.
The demethoxylation was performed on crude lignin oil, which was obtained from corn stover by RCF in methanol over a Ru on carbon catalyst.

The 4-n-alkylphenol yield after demethoxylation, starting from a guaiacyl and syringyl monomer mixture, was 65.7 mol% based on the total monomers (16.1 wt% based on lignin content).
Interestingly, they found that the Mo catalyst also removed para-substituted ester group from phenolic monomers in addition to Terephthalic acid demethoxylation activity.

Next, CO was inserted using carbonylation of 4-n-alkylphenols by a homogeneous Pd catalyst.
To increase reactivity, 4-n-alkylphenol triflates were formed prior to carbonylation.

On average, a 75 mol% yield was obtained for all 4-alkylphenols (methyl, ethyl and n-propyl) toward the 4-alkylbenzoic acid.
Finally, the oxidation yield of 4-alkylbenzoic acid mixture toward terephthalic acid was 60 mol%.

Remarkably, terephthalic acid could be obtained from the reaction mixture by simple filtration and washing with water.
Looking at the overall process, the terephthalic acid yield starting from the lignin oil was 30 mol% and corresponds to 15.5 wt% based on corn stover lignin content.

Terephthalic acid is one isomer of the three phthalic acids.
Terephthalic acid finds important use as a commodity chemical, principally as a starting compound for the manufacture of polyester (specifically PET), used in clothing and to make plastic bottles.

Terephthalic acid is also known as 1,4-benzenedicarboxylic acid, and Terephthalic acid has the chemical formula C6H4(COOH)2.
Terephthalic acid has recently become an important component in the development of hybrid framework materials.

Terephthalic acid is a benzenedicarboxylic acid carrying carboxy groups at positions 1 and 4.
One of three possible isomers of benzenedicarboxylic acid, the others being phthalic and isophthalic acids.

Terephthalic acid is a conjugate acid of a terephthalate(1-).
Terephthalic acid is one isomer of the three phthalic acids.

Terephthalic acid finds important use as a commodity chemical, principally as a starting compound for the manufacture of polyester (specifically PET), used in clothing and to make plastic bottles.
Terephthalic acid is also known as 1,4-benzenedicarboxylic acid, and Terephthalic acid has the chemical formula C6H4(COOH)2.

Process for Preparation of Terephthalic Acid:
One of the world’s most widely produced polymers, poly(ethylene terephthalate) (PET), is synthesized via condensation polymerization of ethylene glycol with terephthalic acid and small amounts of isophthalic acid.
Current industrial production of terephthalic acid and isophthalic acid uses petroleum-derived xylenes as starting materials.

The cost and availability of petroleum varies wildly and unpredictably.
In order to stabilize costs associated with the synthesis of terephthalic acid and isophthalic acid, alternative feedstocks must be made available.

A reaction sequence has been elaborated that addresses this need.
The starting materials, acrylic acid and isoprene, are reacted in a solvent-free cycloaddition catalyzed by an inexpensive Lewis acid catalyst.

Vapor phase aromatization of the resulting cycloadducts affords para- and meta-toluic acid, which are oxidized to terephthalic acid and isophthalic acid, respectively.
Both acrylic acid and isoprene are commercially synthesized from petroleum or shale gas but may also be synthesized from biobased feedstocks.

Thus, by diversifying available feedstocks, costs associated with commercial terephthalic acid and isophthalic acid synthesis are stabilized.
Moreover, this reaction sequence is the only one reported in the literature to produce both terephthalic acid and isophthalic acid for the manufacture of PET.

Biodegradation of Terephthalic acid:
In Comamonas thiooxydans strain E6, terephthalic acid is biodegraded by a pathway starting at terephthalate 1,2-dioxygenase into protocatechuic acid, a common natural product.
Combined with the previously known PETase and MHETase, a full pathway for PET plastic degradation can be engineered.

Properties of Terephthalic acid:
Terephthalic acid is almost insoluble in water, alcohol and ether; Terephthalic acid sublimes rather than melting when heated.
This insolubility makes Terephthalic acid relatively awkward to work with, and up until around 1970 much crude terephthalic acid was converted to the dimethyl ester for purification.

Production of Terephthalic acid:
Terephthalic acid can be formed in the laboratory by oxidizing para-diderivatives of benzene, or best by oxidizing caraway oil, a mixture of cymene and cuminol, with chromic acid.

On an industrial scale, terephthalic acid is produced, similar to benzoic acid, by oxidation of p-xylene by oxygen from air.
This is done using acetic acid as solvent, in the presence of a catalyst such as cobalt-manganese, using a bromide promoter.

Alternatively, Terephthalic acid can be made via the Henkel process, which involves the rearrangement of phthalic acid to terephthalic acid via the corresponding potassium salts.
The terephthalic acid is and dimethyl terephthalate, in turn, often used as a monomer component in the production of polymers, principally polyethylene terephthalate (polyester or PET).

World production in 1970 was around 1.75 million tonnes.
By 2006, global PTA demand had substantially exceeded 30 million tonnes.

Pharmacology and Biochemistry of Terephthalic acid:

MeSH Pharmacological Classification:

Free Radical Scavengers:
Substances that eliminate free radicals.
Among other effects, they protect PANCREATIC ISLETS against damage by CYTOKINES and prevent myocardial and pulmonary REPERFUSION INJURY.

Metabolism/Metabolites of Terephthalic acid:
A Rhodococcus species was isolated from soil by enriching for growth with dimethyl terephthalate as the sole carbon source.
The organism degraded dimethyl terephthalate by hydrolysis of ester-bonds to free terephthalic acid which in turn was metabolized through protocatechuate by an ortho-cleavage pathway

Biological Half-Life of Terephthalic acid:
The concentrations of urine terephthalic acid in rats after single oral administration in dose of 100 mg/kg bw were determined by high pressure liquid chromatography.
The results showed that the first-order kinetics and two-compartment model were noted on the elimination of Terephthalic acid.
The main toxicokinetic parameters were as follows: Ka = 0.51/hr, half-life ka = 0.488 hr, half-life alpha = 2.446 hr, time to peak = 2.160 hr, Ku = 0.143/hr, half-life beta = 31.551 hr, Xu(max) = 10.00 mg.

The pharmacokinetics of (14)C labeled terephthalic acid were determined in Fischer 344 rats after iv and oral administration.
After iv injection, the plasma concentration-time data were fitted using a 3-compartment pharmacokinetic model.
The avg terminal half-life in rats was 1.2 hr and the average volume of distribution in the terminal phase was 1.3 L/kg.

Human Metabolite Information of Terephthalic acid:

Tissue Locations:
Fibroblasts
Platelet

Clinical Laboratory Methods of Terephthalic acid:
A procedure for the hydrolysis of phthalate esters and metabolites to free phthalic acid, recovery and esterification of the acid, and gas chromatographic quantification on 10% OV 25 on Gas Chroin Z all relative to an internal standard of 4-chlorophthalate was developed.
The measurement limit is 0.5 nmol of total phthalate/mL of urine, and replicates.

The assay is linear between 0.5 and 50 nmol/mL of urine, which spans of phthalate levels found thus far in human urine samples.
The procedure can also be used to detect levels of isophthalate and terephthalate simultaneously with phthalate.

Synthesis of Terephthalic acid:

Amoco process:
In the Amoco process, which is widely adopted worldwide, terephthalic acid is produced by catalytic oxidation of p-xylene

The process uses a cobalt–manganese–bromide catalyst.
The bromide source can be sodium bromide, hydrogen bromide or tetrabromoethane.

Bromine functions as a regenerative source of free radicals.
Acetic acid is the solvent and compressed air serves as the oxidant.

The combination of bromine and acetic acid is highly corrosive, requiring specialized reactors, such as those lined with titanium.
A mixture of p-xylene, acetic acid, the catalyst system, and compressed air is fed to a reactor.

Mechanism:
The oxidation of p-xylene proceed by a free radical process.
Bromine radicals decompose cobalt and manganese hydroperoxides.

The resulting oxygen-based radicals abstract hydrogen from a methyl group, which have weaker C–H bonds than does the aromatic ring.
Many intermediates have been isolated.

p-xylene is converted to p-toluic acid, which is less reactive than the p-xylene owing to the influence of the electron-withdrawing carboxylic acid group.
Incomplete oxidation produces 4-carboxybenzaldehyde (4-CBA), which is often a problematic impurity.

Challenges:
Approximately 5% of the acetic acid solvent is lost by decomposition or "burning".
Product loss by decarboxylation to benzoic acid is common.

The high temperature diminishes oxygen solubility in an already oxygen-starved system.
Pure oxygen cannot be used in the traditional system due to hazards of flammable organic–O2 mixtures.

Atmospheric air can be used in Terephthalic acid place, but once reacted needs to be purified of toxins and ozone depleters such as methylbromide before being released.
Additionally, the corrosive nature of bromides at high temperatures requires the reaction be run in expensive titanium reactors.

Alternative reaction media:
The use of carbon dioxide overcomes many of the problems with the original industrial process.
Because CO2 is a better flame inhibitor than N2, a CO2 environment allows for the use of pure oxygen directly, instead of air, with reduced flammability hazards.

The solubility of molecular oxygen in solution is also enhanced in the CO2 environment.
Because more oxygen is available to the system, supercritical carbon dioxide (Tc = 31 °C) has more complete oxidation with fewer byproducts, lower carbon monoxide production, less decarboxylation and higher purity than the commercial process.

In supercritical water medium, the oxidation can be effectively catalyzed by MnBr2 with pure O2 in a medium-high temperature.
Use of supercritical water instead of acetic acid as a solvent diminishes environmental impact and offers a cost advantage.
However, the scope of such reaction systems is limited by the even harsher conditions than the industrial process (300−400 °C, >200 bar).

Promotors and additives:
As with any large-scale process, many additives have been investigated for potential beneficial effects.
Promising results have been reported with the following.

Ketones act as promoters for formation of the active cobalt(III) catalyst.
In particular, ketones with a-methylene groups oxidize to hydroperoxides that are known to oxidize cobalt(II).

Butanone is often used.
Zirconium salts enhance the activity of Co-Mn-Br catalysts.

Selectivity is also improved.
N-Hydroxyphthalimide is a potential replacement for bromide, which is highly corrosive.

The phthalimide functions by formation of the oxyl radical.
Guanidine inhibits the oxidation of the first methyl but enhances the usually slow oxidation of the toluic acid.

Alternative routes:
Terephthalic acid can be prepared in the laboratory by oxidizing many para-disubstituted derivatives of benzene, including caraway oil or a mixture of cymene and cuminol with chromic acid.

Although not commercially significant is the so-called "Henkel process" or "Raecke process", named after the company and patent holder, respectively.
This process involves the transfer of carboxylate groups.
For example potassium benzoate disproportionates to potassium terephthalate and potassium phthalate rearranges to potassium terephthalate.

Lummus (now a subsidiary of McDermott International) has reported a route from the dinitrile, which can be obtained by ammoxidation of p-xylene.

Uses of Terephthalic acid:
Used in wool processing and making plastic films and sheets.
Also added to poultry feeds and to certain antibiotics to increase their effectiveness.

Industrial Processes with risk of exposure:
Textiles (Fiber & Fabric Manufacturing)
Farming (Feed Additives)

Terephthalic acid is used almost exclusively to produce saturated polyesters.
Production of linear, crystalline polyester resins, fibers, and films by combination with glycols; reagent for alkali in wool; additive to poultry feeds.

Forms polyesters with glycols which are made into plastic films & sheets; used in analytical chemistry.
Terephthalic acid is an intermediate in the production of oligomeric terephthalic acid esters.

Industry Uses of Terephthalic acid:
Adhesives and sealant chemicals
Intermediates
Investment casting waxes
Lubricants and lubricant additives
Paint additives and coating additives not described by other categories
Plasticizers
Reactant in polymerization process
Solvents (which become part of product formulation or mixture)
monomer for polyester based composites
polyester for composite manufacture
polyester for composite part manufacture

Consumer Uses of Terephthalic acid:
Building/construction materials not covered elsewhere
Food packaging
Intermediates
Investment casting waxes.
Paints and coatings
Plastic and rubber products not covered elsewhere

Methods of Manufacturing of Terephthalic acid:
p-Xylene is the feedstock for all terephthalic acid production.
Oxidation catalysts and conditions have been developed which give nearly quantitative oxidation of the methyl groups, leaving the benzene ring virtually untouched.

These catalysts are combinations of cobalt, manganese, and bromine, or cobalt with a co-oxidant, e.g., acetaldehyde.
Oxygen is the oxidant in all processes.

Acetic acid is the reaction solvent in all but one process.
Given these constant factors, there is only one industrial oxidation process, with different variations, two separate purification processes, and one process which intermixes oxidation and esterification steps.

Produced commercially primarily by the Amoco process.
Inhibition of the oxidation of the second methyl group of p-xylene is suppressed with the aid of added bromine-containing promoters as cocatalysts.
The oxidation takes place in air and produces raw terephthalic acid, which is dissolved at high temperature under pressure in water, hydrated, and thus purified.

Prepared by oxidation of p-methylacetophenone.

(1) Oxidation of para-xylene or of mixed xylenes and other alkyl aromatics (phthalic anhydride); (2) reacting benzene and potassium carbonate over a cadmium catalyst.
Reacting carbon monoxide or methanol with toluene to form various intermediates which, upon oxidation, form terephthalic acid.

General Manufacturing Information of Terephthalic acid:

Industry Processing Sectors:
Adhesive manufacturing
All other basic organic chemical manufacturing
All other chemical product and preparation manufacturing
Construction
Paint and coating manufacturing
Plastic material and resin manufacturing
Plastics product manufacturing
Textiles, apparel, and leather manufacturing

Applications of Terephthalic acid:
Terephthalic acid can be synthesized from bio-based materials for a variety of applications, which include the production of polyester fiber, non-fiber field, PET bottles, synthetic perfumes and medicines.
Terephthalic acid is used as a linker molecule in the preparation of metal organic frameworks (MOFs).

Virtually the entire world's supply of terephthalic acid and dimethyl terephthalate are consumed as precursors to polyethylene terephthalate (PET).
World production in 1970 was around 1.75 million tonnes.

By 2006, global purified terephthalic acid (PTA) demand had exceeded 30 million tonnes.
A smaller, but nevertheless significant, demand for terephthalic acid exists in the production of polybutylene terephthalate and several other engineering polymers.

Other uses of Terephthalic acid:
Polyester fibers based on PTA provide easy fabric care, both alone and in blends with natural and other synthetic fibers.
Polyester films are used widely in audio and video recording tapes, data storage tapes, photographic films, labels and other sheet material requiring both dimensional stability and toughness.

Terephthalic acid is used in paint as a carrier.
Terephthalic acid is used as a raw material to make terephthalate plasticizers such as dioctyl terephthalate and dibutyl terephthalate.

Terephthalic acid is used in the pharmaceutical industry as a raw material for certain drugs.
In addition to these end uses, Terephthalic acid based polyesters and polyamides are also used in hot melt adhesives.

PTA is an important raw material for lower molecular weight saturated polyesters for powder and water-soluble coatings.
In the research laboratory, terephthalic acid has been popularized as a component for the synthesis of metal-organic frameworks.

The analgesic drug oxycodone occasionally comes as a terephthalate salt; however, the more usual salt of oxycodone is the hydrochloride.
Pharmacologically, one milligram of terephthalas oxycodonae is equivalent to 1.13 mg of hydrochloridum oxycodonae.
Terephthalic acid is used as a filler in some military smoke grenades, most notably the American M83 smoke grenade and M90 vehicle-employed smoke grenade, producing a thick white smoke that acts as an obscurant in the visual and near-infrared spectrum when burned.

History of Terephthalic acid:
Terephthalic acid was first isolated (from turpentine) by the French chemist Amédée Cailliot (1805–1884) in 1846.
Terephthalic acid became industrially important after World War II.

Terephthalic acid was produced by oxidation of p-xylene with dilute nitric acid.
Air oxidation of p-xylene gives p-toluic acid, which resists further air-oxidation.

Conversion of p-toluic acid to methyl p-toluate (CH3C6H4CO2CH3) opens the way for further oxidation to monomethyl terephthalate, which is further esterified to dimethyl terephthalate.
In 1955, Mid-Century Corporation and ICI announced the bromide-promoted oxidation of p-toluic acid to teraphthalic acid.

This innovation enabled the conversion of p-xylene to terephthalic acid without the need to isolate intermediates.
Amoco (as Standard Oil of Indiana) purchased the Mid-Century/ICI technology.

Reactivity Profile of Terephthalic acid:
TEREPHTHALIC ACID is a carboxylic acid.
Terephthalic acid donates hydrogen ions if a base is present to accept them.

This "neutralization" generates substantial amounts of heat and produces water plus a salt.
Insoluble in water but even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in Terephthalic acid to corrode or dissolve iron, steel, and aluminum parts and containers.

May react with cyanide salts to generate gaseous hydrogen cyanide.
Will react with solutions of cyanides to cause the release of gaseous hydrogen cyanide.

Flammable and/or toxic gases and heat are generated by reaction with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides.
React with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat.

Reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat.
Can be oxidized by strong oxidizing agents and reduced by strong reducing agents.

These reactions generate heat.
May initiate polymerization reactions; may catalyze (increase the rate of) chemical reactions.

Handling and Storage of Terephthalic acid:

Nonfire Spill Response:
SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with ethanol and transfer the dampened material to a suitable container.
Use absorbent paper dampened with ethanol to pick up any remaining material.

Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal.
Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution.
Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

STORAGE PRECAUTIONS: You should store this material in a refrigerator.

Safe Storage of Terephthalic acid:
Separated from strong oxidants.

Storage Conditions of Terephthalic acid:
Store in detached units of noncombustible construction.

Regulatory Information of Terephthalic acid:

Atmospheric Standards of Terephthalic acid:
This action promulgates standards of performance for equipment leaks of Volatile Organic Compounds (VOC) in the Synthetic Organic Chemical Manufacturing Industry (SOCMI).
The intended effect of these standards is to require all newly constructed, modified, and reconstructed SOCMI process units to use the best demonstrated system of continuous emission reduction for equipment leaks of VOC, considering costs, non air quality health and environmental impact and energy requirements.
Terephthalic acid is produced, as an intermediate or a final product, by process units covered under this subpart.

First Aid of Terephthalic acid:

EYES:
First check the victim for contact lenses and remove if present.
Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.

Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.
IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

SKIN:
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.
Gently wash all affected skin areas thoroughly with soap and water.
If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

INHALATION:
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.
If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital.

Provide proper respiratory protection to rescuers entering an unknown atmosphere.
Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.

INGESTION:
DO NOT INDUCE VOMITING.
If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.

Be prepared to transport the victim to a hospital if advised by a physician.
If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body.

DO NOT INDUCE VOMITING.
IMMEDIATELY transport the victim to a hospital.

Fire Fighting of Terephthalic acid:
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher.

Accidental Release Measures of Terephthalic acid:

Spillage Disposal of Terephthalic acid:

Personal protection:
Particulate filter respirator adapted to the airborne concentration of the substance.
Sweep spilled substance into covered containers.

If appropriate, moisten first to prevent dusting.
Carefully collect remainder.
Then store and dispose of according to local regulations.

Cleanup Methods of Terephthalic acid:
Remove all ignition sources.
Collect powdered material in the most convenient and safe manner and deposit in sealed containers.
Ventilate area after clean up is complete.

Disposal Methods of Terephthalic acid:
The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination.
Recycle any unused portion of the material for Terephthalic acid approved use or return Terephthalic acid to the manufacturer or supplier.

After material has been contained, scoop up contaminated soil and place in impervious containers.
Material may be disposed of in an approved chemical incinerator.

If facilities are not available, material may be disposed of in an approved waste chemical landfill.
When dilute, amenable to biological treatment at a municipal sewage treatment plant.

Preventive Measures of Terephthalic acid:
The scientific literature for the use of contact lenses by industrial workers is inconsistent.
The benefits or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses.

However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye.
In those specific cases, contact lenses should not be worn.

In any event, the usual eye protection equipment should be worn even when contact lenses are in place.
Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing.

Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers.
Contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.

Identifiers of Terephthalic acid:
CAS Number: 100-21-0
3DMet: B00943
Beilstein Reference: 1909333
ChEBI: CHEBI:15702
ChEMBL: ChEMBL1374420
ChemSpider: 7208
ECHA InfoCard: 100.002.573
EC Number: 202-830-0
Gmelin Reference: 50561
KEGG: C06337
PubChem CID: 7489
RTECS number: WZ0875000
UNII: 6S7NKZ40BQ
CompTox Dashboard (EPA): DTXSID6026080
InChI:
InChI=1S/C8H6O4/c9-7(10)5-1-2-6(4-3-5)8(11)12/h1-4H,(H,9,10)(H,11,12) check
Key: KKEYFWRCBNTPAC-UHFFFAOYSA-N check
InChI=1/C8H6O4/c9-7(10)5-1-2-6(4-3-5)8(11)12/h1-4H,(H,9,10)(H,11,12)
Key: KKEYFWRCBNTPAC-UHFFFAOYAF
SMILES: O=C(O)c1ccc(C(O)=O)cc1

Properties of Terephthalic acid:
Chemical formula: C8H6O4
Molar mass: 166.132 g·mol−1
Appearance: White crystals or powder
Density: 1.522 g/cm3
Melting point: 427 °C (801 °F; 700 K) in a sealed tube. Sublimes at standard atmospheric pressure.
Boiling point: Decomposes
Solubility in water: 0.0015 g/100 mL at 20 °C
Solubility: polar organic solvents aqueous base
Acidity (pKa): 3.51, 4.82
Magnetic susceptibility (χ): −83.51×10−6 cm3/mol

Molecular Weight: 166.13
XLogP3: 2
Hydrogen Bond Donor Count: 2
Hydrogen Bond Acceptor Count: 4
Rotatable Bond Count: 2
Exact Mass: 166.02660867
Monoisotopic Mass: 166.02660867
Topological Polar Surface Area: 74.6 Ų
Heavy Atom Count : 12
Complexity: 169
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes

Vapor pressure: <0.01 mmHg ( 20 °C)
Quality Level: 100
Assay: 98%
Form: powder
Autoignition temp.: 925 °F
mp: >300 °C (lit.)
Solubility: water: ~0.017 g/L at 25 °C
Density: 1.58 g/cm3 at 25 °C
Greener alternative category: Enabling
SMILES string: OC(=O)c1ccc(cc1)C(O)=O
InChI: 1S/C8H6O4/c9-7(10)5-1-2-6(4-3-5)8(11)12/h1-4H,(H,9,10)(H,11,12)
InChI key: KKEYFWRCBNTPAC-UHFFFAOYSA-N

Structure of Terephthalic acid:
Dipole moment: 2.6D

Thermochemistry of Terephthalic acid:
Std enthalpy of formation (ΔfH⦵298): 232 kJ/m

Related compounds of Terephthalic acid:
p-Xylene
Polyethylene terephthalate
Dimethyl terephthalate

Related carboxylic acids:
Phthalic acid
Isophthalic acid
Benzoic acid
p-Toluic acid

Names of Terephthalic acid:

Preferred IUPAC name:
Benzene-1,4-dicarboxylic acid

Other names:
Terephthalic acid
para-Phthalic acid
TPA
PTA
BDC
TERGITOL 15-S-40 (70%)
Tergitol 15-S-40 (70%) is a secondary Alcohol Ethoxylate.
Tergitol 15-S-40 (70%) is a 70% aqueous solution of a secondary alcohol ethoxylate with 41 ethylene oxide (EO) units.


CAS Number: 84133-50-6
EC-Number: 617-534-0
Product Type: Wetting Agents / Wet Edge Enhancers > Surfactants
Chemical Composition: Secondary alcohol ethoxylate
Surfactant Type: Nonionic


Tergitol 15-S-40 (70%) is used mulsion stabilizer, provides freeze-thaw and ionic stability.
Tergitol 15-S-40 (70%) is a nonionic surfactant.
Tergitol 15-S-40 (70%) is a secondary Alcohol Ethoxylate.


Tergitol 15-S-40 (70%) is a 70% aqueous solution of a secondary alcohol ethoxylate with 41 ethylene oxide (EO) units.
Tergitol 15-S-40 (70%) is a versatile, high-performance secondary alcohol ethoxylate (SAE).
Tergitol 15-S-40 (70%) acts as a non-ionic surfactant, freeze-thaw controller, dispersing agent, emulsifier.


Tergitol 15-S-40 (70%) offers freeze thaw and ionic stability and good handling properties.
Tergitol 15-S-40 (70%) is not alkyl phenol ethoxylate-based.


Tergitol 15-S-40 (70%) is a readily biodegradable nonionic surfactant with low odor used in applications such as industrial cleaning, household cleaning, textile auxiliaries, leather auxiliaries, and agrochemical auxiliaries.


Tergitol 15-S-40 (70%) is non-APE, fast wetting, low odor, easy biodegradation, not easy to form gel, fast dissolving, easy rinsing, easy to use, suitable for high concentration formula, can effectively remove oily dirt, fast foam breaking, low aquatic toxicity.


Tergitol 15-S-40 (70%) is used industrial cleaners, household cleaners, commercial cleaners, pulp and paper, textile auxiliaries, agrochemical auxiliaries, leather auxiliaries.
Tergitol 15-S-40 (70%) is a biodegradable surfactant and is aligned with the 10th principle of Green Chemistry "Design for Degradation".



USES and APPLICATIONS of TERGITOL 15-S-40 (70%):
Tergitol 15-S-40 (70%) is used mulsion stabilizer, provides freeze-thaw and ionic stability.
Tergitol 15-S-40 (70%) is used emulsion polymerization, paints and coatings, floor waxes, and wax emulsions.
Tergitol 15-S-40 (70%) is used as emulsion polymerization, paints, solid cleaners.


Tergitol 15-S-40 (70%) possesses high HLB emulsifier & dispersant.
Tergitol 15-S-40 (70%) provides an unbeatable combination of performance and cost when used in place of primary alcohol etthoxylates (PAE), nonylphenol ethoxylates (NPE), octylphenol ethoxylates (OPE), and other general purpose surfactants in a wide range of formulating application.


Tergitol 15-S-40 (70%) is used in paint and coatings, floor polish and wax emulsions.
Tergitol 15-S-40 (70%) is used as a surfactant for superior overall cleaning performance, readily biodegradable, and rapid wetting.
Tergitol 15-S-40 (70%) is used Emulsion polymerization, Paints & coatings, and Floor polish & wax emulsions


Tergitol 15-S-40 (70%) is used Hand Dishwashing, Institutional Fabric Care, Metal Cleaning, Bathroom Cleaners, Glass Cleaners, Institutional Hard Surface Care, Kitchen Cleaners, Multipurpose Cleaners, Toilet Cleaners, and Wipes.
Tergitol 15-S-40 (70%) is used in cloud-point extraction technique to extract polycyclic aromatic hydrocarbons from aqueous solutions.


Tergitol 15-S-40 (70%) is non-APE, fast wetting, low odor, easy biodegradation, not easy to form gel, fast dissolving, easy rinsing, easy to use, suitable for high concentration formula, can effectively remove oily dirt, fast foam breaking, low aquatic toxicity.
Tergitol 15-S-40 (70%) is used Industrial, and Other.


Tergitol 15-S-40 (70%) is used Industrial cleaners, household cleaners, commercial cleaners, pulp and paper, textile auxiliaries, agrochemical auxiliaries, leather auxiliaries.
Tergitol 15-S-40 (70%) has been used as a surfactant to study its influence on the formation of multi-phase micro-emulsions.


Tergitol 15-S-40 (70%) is a readily biodegradable nonionic surfactant with low odor used in applications such as industrial cleaning, household cleaning, textile auxiliaries, leather auxiliaries, and agrochemical auxiliaries.
Tergitol 15-S-40 (70%) also has superior wetting ability, quick foam collapse, low aquatic toxicity, and is non-APE based.


Tergitol 15-S-40 (70%) is used Exterior Wall - Facade Paint, Interior Wall Paint, Fabric Sizing, and Fiber and Yarn Lubrication.
Uses of Tergitol 15-S-40 (70%): Industrial cleaning agent Household cleaning agent Commercial cleaning agent.
Tergitol 15-S-40 (70%) is used to study the synergistic effect of Tergitol 15-S-7 and AOT (dioctyl sulfosuccinate) on bacterial oxidation of alkanes in crude oils.


Tergitol 15-S-40 (70%) is used along with MgSO4 in anolyte reservoir for electrokinetic experiments.
Tergitol 15-S-40 (70%) is used Agrochemical auxiliaries, Emulsifier in emulsion polymerization, Household cleaning, Industrial cleaning, Institutional cleaning, Leather auxiliaries, Textile auxiliaries, and Wetting agent in WB coating


-Uses of Tergitol 15-S-40 (70%):
*Exterior Wall - Facade Paint
*High Gloss and Trim
*Interior Wall Paint
*Varnish
*Wood Coatings
*Boiler Systems
*Process Treatments
*Reverse Osmosis


-Application field of Tergitol 15-S-40 (70%):
●Industrial cleaning agent
●Household cleaning agent
●Commercial cleaning agent
●Water-based paint wetting agent
●textile auxiliaries
●Agrochemical auxiliaries
●Emulsion polymerization emulsifier
●Leather additives


-Cosmetic Uses of Tergitol 15-S-40 (70%):
*emulsion stabilisers
*surfactants
*surfactant - emulsifying



BENEFITS OF TERGITOL 15-S-40 (70%):
• Emulsion stabilizer
• Provides freeze/thaw & ionic stability
• Electrolyte solubility
• Good handling properties
• Non-APE
• Concentrates
• Superior wetting
• Low odor
• Rapid dissolution & good rinseability
• Easy handling
• Narrow gel range
• Effective removal of grease
• Readily biodegradable
• Quick foam collapse
• Low aquatic toxicity EC50 > 10 mg/L



SOLUBILITY AND COMPATIBILITY OF TERGITOL 15-S-40 (70%):
● Soluble in water
● Soluble in chlorinated solvents and polar organic solvents
● Chemically stable in the presence of dilute acids, bases and salts
● Compatible with anionic , cationic, and other nonionic surfactants
● In the presence of dilute acid/dilute alkali 1 salt, the chemical performance is stable
● Excellent compatibility with anionic, cationic and nonionic surfactants
● Soluble in chlorinated solvents and most polar organic solvents




BENEFITS OF TERGITOL 15-S-40 (70%):
*Emulsion stabilizer
*Provides freeze/thaw & ionic stability
*Electrolyte solubility
*Good handling properties



FEATURES AND BENEFITS OF TERGITOL 15-S-40 (70%):
Emulsion stabilizer Provides freeze/thaw & ionic stability Electrolyte solubility Good handling properties



PRODUCT TYPE OF TERGITOL 15-S-40 (70%):
*Freeze-thaw Controllers
*Wetting Agents / Wet Edge Enhancers > Surfactants
*Dispersing Agents
*Emulsifiers



KEY FEATURES OF TERGITOL 15-S-40 (70%):
*Non-APE
*Concentrates
*Superior wetting
*Rapid dissolution & good rinseability
*Narrow gel range, Effective removal of grease
*Readily biodegradable



PERFORMANCE ADVANTAGES OF TERGITOL 15-S-40 (70%):
●Non-APE
●Suitable for high concentration formula
●Quick wetting
●Low odor
●Not easy to form gel
●Quick dissolving, easy to rinse
●Easy to use
●Effectively remove oil stains and dirt
●Easily biodegradable
●Quick foam breaking
●Low aquatic toxicity



PHYSICAL and CHEMICAL PROPERTIES of TERGITOL 15-S-40 (70%):
Physical Form: Liquid
Actives, wt%: 70
Diluent: Water
Cloud Point1: <100
HLB2: 18
Moles EO: 41
Pour Point3: 5
Appearance: Pale yellow liquid
Density at 30°C (86°F), g/mL: 1.072
Flash Pt, Closed Cup, ASTM D93: None
Physical state: liquid
Color: yellow
Odor: No data available
Melting point/freezing point: No data available
Initial boiling point and boiling range: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available

Flash point: No data available
Autoignition temperature: No data available
Decomposition temperature: No data available
pH: No data available
Viscosity
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Water solubility: No data available
Partition coefficient: n-octanol/water: No data available
Vapor pressure: No data available
Density: 1,072 g/cm3
Relative density: No data available
Relative vapor density: No data available
Particle characteristics: No data available
Explosive properties: No data available
Oxidizing properties: No data available
Other safety information: No data available

CMC: 1314 ppm (25°C)
concentration: 70% in water
density: 1.072 g/mL at 30 °C
description: non-ionic
form: liquid
grade: laboratory grade
greener alternative category: Aligned
HLB: 18
mol wt: 1,960 g/mol by calculation
Quality Level: 100
solubility: water: freely soluble (some compositions may form gels)
transition temp cloud point: >100 °C (1 wt% actives aq solution), pour point: 5 °C
Density: 1.0720 g/mL
Quantity: 2.5 L
Solubility Information: Solubility aq. soln.: soluble.
Specific Gravity: 1.072
Chemical Name or Material: Tergitol 15-S-40



FIRST AID MEASURES of TERGITOL 15-S-40 (70%):
-Description of first-aid measures:
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
Immediately call in physician.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Immediately call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed:
No data available



ACCIDENTAL RELEASE MEASURES of TERGITOL 15-S-40 (70%):
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up with liquid-absorbent material.
Dispose of properly.
Clean up affected area.



FIRE FIGHTING MEASURES of TERGITOL 15-S-40 (70%):
-Extinguishing media:
*Suitable extinguishing media:
Water
Foam
Carbon dioxide (CO2)
Dry powder
*Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.



EXPOSURE CONTROLS/PERSONAL PROTECTION of TERGITOL 15-S-40 (70%):
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Tightly fitting safety goggles
*Skin protection:
required
*Body Protection:
protective clothing
-Control of environmental exposure:
Do not let product enter drains.



HANDLING and STORAGE of TERGITOL 15-S-40 (70%):
-Precautions for safe handling:
*Hygiene measures:
Immediately change contaminated clothing.
Apply preventive skin protection.
Wash hands and face after working with substance.
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Store under nitrogen.



STABILITY and REACTIVITY of TERGITOL 15-S-40 (70%):
-Reactivity:
No data available
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .
-Possibility of hazardous reactions:
No data available
-Conditions to avoid:
no information available



SYNONYMS:
Secondary alcohol ethoxylate 41 EO



TERGITOL CA-60
Tergitol CA-60 is a new generation of high-performance, readily biodegradable comparable to alkylphenol ethoxylate (APE) surfactants, and better than primary alcohol ethoxylate (PAE) surfactants.


CAS Number: 70750-27-5
Chemical Name:Alcohols, C12-13, ethoxylated propoxylated
Surfactant Type: Nonionic
Molecular Formula:C29H62O2


Tergitol CA-60 is soluble in water.
Tergitol CA-60 is soluble in chlorinated solvents and most polar organic solvents.
Density of Tergitol CA-60 is 5.0 aEUR" 7.5 Gram per litre (g/L).


Tergitol CA-60 is a new generation of high-performance, readily biodegradable comparable to alkylphenol ethoxylate (APE) surfactants, and better than primary alcohol ethoxylate (PAE) surfactants.
Tergitol CA-60 has excellent wetting, excellent formulating, and handling properties, Specially developed for textile softeners.


Tergitol CA-60 is non-APE, fast wetting, low odor, easy biodegradation, not easy to form gel, fast dissolving, easy rinsing, easy to use, suitable for high concentration formula.
Tergitol CA-60 can effectively remove oily dirt, fast foam breaking, low aquatic toxicity.


Tergitol CA-60 is used industrial cleaners, household cleaners, commercial cleaners, pulp and paper, textile auxiliaries, agrochemical auxiliaries, leather auxiliaries



USES and APPLICATIONS of TERGITOL CA-60:
Tergitol CA-60 is used industrial cleaners, household cleaners, commercial cleaners, water-based paint wetting agents, textile auxiliaries, agrochemical auxiliaries, leather auxiliaries.
Tergitol CA-60 is a readily biodegradable nonionic surfactant with low odor used in applications such as industrial cleaning, household cleaning, textile auxiliaries, leather auxiliaries, and agrochemical auxiliaries​​.


Tergitol CA-60 is non-APE, fast wetting, low odor, easy biodegradation, not easy to form gel, fast dissolving, easy rinsing, easy to use, suitable for high concentration formula.
Tergitol CA-60 can effectively remove oily dirt, fast foam breaking, low aquatic toxicity.


Tergitol CA-60 is used industrial cleaners, household cleaners, commercial cleaners, pulp and paper, textile auxiliaries, agrochemical auxiliaries, leather auxiliaries
Tergitol CA-60 also has superior wetting ability, quick foam collapse, low aquatic toxicity, and is non-APE based.


Recommended Applications of Tergitol CA-60: Industrial cleaners, household cleaners, commercial cleaners, water-based paint wetting agents, textile auxiliaries, agrochemical auxiliaries, leather auxiliaries.
Tergitol CA-60 is used in Industrial cleaning, textile auxiliaries, Household cleaning, Agrochemical auxiliaries, Wetting agent in WB coating, and Leather auxiliaries.


Tergitol CA-60 is used Industrial cleaning, Household cleaning, Institutional cleaning, Wetting agent in WB coating, Textile auxiliaries, Agrochemical auxiliaries, and Leather auxiliaries
Tergitol CA-60 is used multi-purpose surfactant.


Recommended Application of Tergitol CA-60: Industrial cleaning agent, household cleaning agent.
Tergitol CA-60 is used Textile auxiliaries, Industrial cleaning, Household cleaning, and Institutional cleaning
Tergitol CA-60 is used Exterior Wall - Facade Paint, Interior Wall Paint, Fabric Sizing, and Fiber and Yarn Lubrication


-Applications of Tergitol CA-60:
• Agrochemical auxiliaries
• Household cleaning
• Industrial cleaning
• Institutional cleaning
• Leather auxiliaries
• Textile auxiliaries
• Wetting agent in WB coating



BENEFITS OF TERGITOL CA-60:
 Non-APE
 Concentrates
 Superior wetting
 Low odor
 Rapid dissolution & good rinseability
 Easy handling
 Narrow gel range
 Effective removal of grease
 Readily biodegradable
 Quick foam collapse
 Low aquatic toxicity EC50 > 10 mg/L



KEY FEATURES OF TERGITOL CA-60:
*Industrial cleaning
*Textile auxiliaries
*Household cleaning
*Institutional cleaning
*Textile auxiliaries



SOLUBILITY AND COMPATIBILITY OF TERGITOL CA-60:
• Soluble in water
• Soluble in chlorinated solvents and most polar organic solvents
• Chemically stable in the presence of dilute acids, bases and salts
• Compatible with anionic, cationic and other nonionic surfactants



PHYSICAL and CHEMICAL PROPERTIES of TERGITOL CA-60:
Cloud Point (1% wt. aq. soln.),: °C 40
Appearance (25°C): Colorless or pale yellow liquid
HLB: 11-12
Surface Tension (25°C, 1% wt. aq. soln.), mN/m: 29.5
Pour Point, °C: 5
Ross Miles Foam Height (0.1% wt. aq. soln., 0 / 5 min): mm 35 / 5
pH (1% wt. aq. soln.): 5.0 – 7.5
Density at 20°C, g/mL: 1.0022
Viscosity at 40°C, cSt: 34
common name: Special Alkoxylates
Appearance: colorless or light yellow liquid



FIRST AID MEASURES of TERGITOL CA-60:
-Description of first-aid measures:
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
Immediately call in physician.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Immediately call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed:
No data available



ACCIDENTAL RELEASE MEASURES of TERGITOL CA-60:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up with liquid-absorbent material.
Dispose of properly.
Clean up affected area.



FIRE FIGHTING MEASURES of TERGITOL CA-60:
-Extinguishing media:
*Suitable extinguishing media:
Water
Foam
Carbon dioxide (CO2)
Dry powder
*Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.



EXPOSURE CONTROLS/PERSONAL PROTECTION of TERGITOL CA-60:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Tightly fitting safety goggles
*Skin protection:
required
*Body Protection:
protective clothing
-Control of environmental exposure:
Do not let product enter drains.



HANDLING and STORAGE of TERGITOL CA-60:
-Precautions for safe handling:
*Hygiene measures:
Immediately change contaminated clothing.
Apply preventive skin protection.
Wash hands and face after working with substance.
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Store under nitrogen.



STABILITY and REACTIVITY of TERGITOL CA-60:
-Reactivity:
No data available
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .
-Possibility of hazardous reactions:
No data available
-Conditions to avoid:
no information available



SYNONYMS:
1-ethoxydodecane
1-propoxydodecane
Alcohols, C12-13, ethoxylated propoxylated
Alkyl-(C12-C13)-alcohol, ethoxylated & propoxylated



TERGITOL CA-90
Tergitol CA-90 is a readily biodegradable nonionic surfactant with low odor used in applications such as industrial cleaning, household cleaning, textile auxiliaries, leather auxiliaries, and agrochemical auxiliaries​​.


CAS Number: 84133-50-6
MDL Number:MFCD00132411
Surfactant Type: Nonionic
Chemical Name:POLYETHYLENE GLYCOL TRIMETHYLNONYL ETHER


Tergitol CA-90 is non-APE, fast wetting, low odor, easy biodegradation, not easy to form gel, fast dissolving, easy rinsing, easy to use, suitable for high concentration formula, can effectively remove oily dirt, fast foam breaking, low aquatic toxicity.
Tergitol CA-90 offers freeze thaw and ionic stability and good handling properties.


Tergitol CA-90 is used industrial cleaners, household cleaners, commercial cleaners, pulp and paper, textile auxiliaries, agrochemical auxiliaries, leather auxiliaries.
Tergitol CA-90 is a biodegradable surfactant and is aligned with the 10th principle of Green Chemistry "Design for Degradation".


Tergitol CA-90 is used mulsion stabilizer, provides freeze-thaw and ionic stability.
Tergitol CA-90 is a nonionic surfactant.
Tergitol CA-90 is a secondary Alcohol Ethoxylate.


Tergitol CA-90 is a 70% aqueous solution of a secondary alcohol ethoxylate with 41 ethylene oxide (EO) units.
Tergitol CA-90 is a versatile, high-performance secondary alcohol ethoxylate (SAE).
Tergitol CA-90 acts as a non-ionic surfactant, freeze-thaw controller, dispersing agent, emulsifier.


Tergitol CA-90 is not alkyl phenol ethoxylate-based.
Tergitol CA-90 is a secondary Alcohol Ethoxylate.
Tergitol CA-90 is a 70% aqueous solution of a secondary alcohol ethoxylate with 41 ethylene oxide (EO) units.



USES and APPLICATIONS of TERGITOL CA-90:
Tergitol CA-90 is non-APE, fast wetting, low odor, easy biodegradation, not easy to form gel, fast dissolving, easy rinsing, easy to use, suitable for high concentration formula, can effectively remove oily dirt, fast foam breaking, low aquatic toxicity.
Tergitol CA-90 is used Industrial, and Other.


Tergitol CA-90 is used Industrial cleaners, household cleaners, commercial cleaners, pulp and paper, textile auxiliaries, agrochemical auxiliaries, leather auxiliaries.
Tergitol CA-90 has been used as a surfactant to study its influence on the formation of multi-phase micro-emulsions.


Tergitol CA-90 is a readily biodegradable nonionic surfactant with low odor used in applications such as industrial cleaning, household cleaning, textile auxiliaries, leather auxiliaries, and agrochemical auxiliaries​​.
Tergitol CA-90 also has superior wetting ability, quick foam collapse, low aquatic toxicity, and is non-APE based.


Tergitol CA-90 is used Exterior Wall - Facade Paint, Interior Wall Paint, Fabric Sizing, and Fiber and Yarn Lubrication.
Uses of Tergitol CA-90: Industrial cleaning agent Household cleaning agent Commercial cleaning agent.
Tergitol CA-90 is used to study the synergistic effect of Tergitol 15-S-7 and AOT (dioctyl sulfosuccinate) on bacterial oxidation of alkanes in crude oils.


Tergitol CA-90 is used in cloud-point extraction technique to extract polycyclic aromatic hydrocarbons from aqueous solutions.
Tergitol CA-90 is used along with MgSO4 in anolyte reservoir for electrokinetic experiments.
Tergitol CA-90 is used Agrochemical auxiliaries, Emulsifier in emulsion polymerization, Household cleaning, Industrial cleaning, Institutional cleaning, Leather auxiliaries, Textile auxiliaries, and Wetting agent in WB coating


Tergitol CA-90 is used mulsion stabilizer, provides freeze-thaw and ionic stability.
Tergitol CA-90 is used emulsion polymerization, paints and coatings, floor waxes, and wax emulsions.
Tergitol CA-90 is used as emulsion polymerization, paints, solid cleaners.


Tergitol CA-90 possesses high HLB emulsifier & dispersant.
Tergitol CA-90 provides an unbeatable combination of performance and cost when used in place of primary alcohol etthoxylates (PAE), nonylphenol ethoxylates (NPE), octylphenol ethoxylates (OPE), and other general purpose surfactants in a wide range of formulating application.


Tergitol CA-90 is used in paint and coatings, floor polish and wax emulsions.
Tergitol CA-90 is used as a surfactant for superior overall cleaning performance, readily biodegradable, and rapid wetting.
Tergitol CA-90 is used Emulsion polymerization, Paints & coatings, and Floor polish & wax emulsions


Tergitol CA-90 is used Hand Dishwashing, Institutional Fabric Care, Metal Cleaning, Bathroom Cleaners, Glass Cleaners, Institutional Hard Surface Care, Kitchen Cleaners, Multipurpose Cleaners, Toilet Cleaners, and Wipes


-Application field of Tergitol CA-90:
●Industrial cleaning agent
●Household cleaning agent
●Commercial cleaning agent
●Water-based paint wetting agent
●textile auxiliaries
●Agrochemical auxiliaries
●Emulsion polymerization emulsifier
●Leather additives


-Cosmetic Uses of Tergitol CA-90:
*emulsion stabilisers
*surfactants
*surfactant - emulsifying


-Uses of Tergitol CA-90:
*Exterior Wall - Facade Paint
*High Gloss and Trim
*Interior Wall Paint
*Varnish
*Wood Coatings
*Boiler Systems
*Process Treatments
*Reverse Osmosis



BENEFITS OF TERGITOL CA-90:
• Non-APE
• Concentrates
• Superior wetting
• Low odor
• Rapid dissolution & good rinseability
• Easy handling
• Narrow gel range
• Effective removal of grease
• Readily biodegradable
• Quick foam collapse
• Low aquatic toxicity EC50 > 10 mg/L
• Emulsion stabilizer
• Provides freeze/thaw & ionic stability
• Electrolyte solubility
• Good handling properties



SOLUBILITY AND COMPATIBILITY OF TERGITOL CA-90:
● Soluble in water
● Soluble in chlorinated solvents and most polar organic solvents
● In the presence of dilute acid/dilute alkali 1 salt, the chemical performance is stable
● Excellent compatibility with anionic, cationic and nonionic surfactants
● Soluble in chlorinated solvents and most polar organic solvents
● Chemically stable in the presence of dilute acids, bases and salts
● Compatible with anionic, cationic and other nonionic surfactants



KEY FEATURES OF TERGITOL CA-90:
*Non-APE
*Concentrates
*Superior wetting
*Rapid dissolution & good rinseability
*Narrow gel range, Effective removal of grease
*Readily biodegradable



PERFORMANCE ADVANTAGES OF TERGITOL CA-90:
●Non-APE
●Suitable for high concentration formula
●Quick wetting
●Low odor
●Not easy to form gel
●Quick dissolving, easy to rinse
●Easy to use
●Effectively remove oil stains and dirt
●Easily biodegradable
●Quick foam breaking
●Low aquatic toxicity



BENEFITS OF TERGITOL CA-90:
*Emulsion stabilizer
*Provides freeze/thaw & ionic stability
*Electrolyte solubility
*Good handling properties



FEATURES AND BENEFITS OF TERGITOL CA-90:
Emulsion stabilizer Provides freeze/thaw & ionic stability Electrolyte solubility Good handling properties



PRODUCT TYPE OF TERGITOL CA-90:
*Freeze-thaw Controllers
*Wetting Agents / Wet Edge Enhancers > Surfactants
*Dispersing Agents
*Emulsifiers



PHYSICAL and CHEMICAL PROPERTIES of TERGITOL CA-90:
Cloud point (1%w% aqueous solution) : 61
Product appearance (25*C) : colorless or light yellow liquid
HLB: 13-14
Surface tension (25*C, 1 wt% aqueous solution), mN/m: 30.5
Pour point (*C): 16
Roche foam height (0.1 wt% aqueous solution, initial/5min), mm: 65/5
pH(1 wt% aqueous solution): 5.0-7.5
Density (20*C g/mL): 1.0237
Kinematic Viscosity (40*C, cSt): 51
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Color: yellow
Evaporation Rate: Calculated 1.93
Flash Point: does not flash
Kinematic Viscosity: Calculated 71 mm2/s @ 25 °C (77 °F)
Non VOC: Calculated 10 %
Odor: pungent
Relative Density: Calculated 1.024 @ 20 °C (68 °F) Reference Material: (water = 1)
Relative Vapor Density: Calculated 4.8
Vapor Pressure: Calculated 15 mmHg @ 20 °C (68 °F)



FIRST AID MEASURES of TERGITOL CA-90:
-Description of first-aid measures:
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
Immediately call in physician.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Immediately call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed:
No data available



ACCIDENTAL RELEASE MEASURES of TERGITOL CA-90:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up with liquid-absorbent material.
Dispose of properly.
Clean up affected area.



FIRE FIGHTING MEASURES of TERGITOL CA-90:
-Extinguishing media:
*Suitable extinguishing media:
Water
Foam
Carbon dioxide (CO2)
Dry powder
*Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.



EXPOSURE CONTROLS/PERSONAL PROTECTION of TERGITOL CA-90:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Tightly fitting safety goggles
*Skin protection:
required
*Body Protection:
protective clothing
-Control of environmental exposure:
Do not let product enter drains.



HANDLING and STORAGE of TERGITOL CA-90:
-Precautions for safe handling:
*Hygiene measures:
Immediately change contaminated clothing.
Apply preventive skin protection.
Wash hands and face after working with substance.
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Store under nitrogen.



STABILITY and REACTIVITY of TERGITOL CA-90:
-Reactivity:
No data available
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .
-Possibility of hazardous reactions:
No data available
-Conditions to avoid:
no information available



SYNONYMS:
TERGITOL(TM) 15-S-7
TERGITOL(TM) 15-S-30
DETERGENT BIOGRAD FL-70
Alcohols, C12-14-secondary, ethoxylated
15-S-9
TERGITOL TMN
C1214 alcohol
TERGITOL TMN-6
TERGITOL(R) TMN 3
TERGITOL(R) TMN 6
DETERGENT BIOGRAD FL-70
TERGITOL(TM) 15-S-30
TERGITOL(TM) 15-S-40
TERGITOL(TM) 15-S-5
TERGITOL(TM) 15-S-7
TERGITOL(TM) 15-S-9
TERGITOL TMN
TERGITOL TMN-6

TERGITOL ECO-20
TERGITOL ECO-20 is a nonionic surfactant known as polyethylene glycol alkyl ethers.
TERGITOL ECO-20 is an oil that is derived from the castor beans that has been polyethoxylated.
TERGITOL ECO-20 reduces the surface tension of water, helping water to interact better with other substances (eg oils, dirt) and increase cleaning efficiency.

CAS Number: 61791-12-6
Molecular formula: C57H104O9(CH2CH2O)n
EINECS no: 500-151-7

TERGITOL ECO-20 comes in various grades, forms and quantities, like most of the chemicals provided by Spectrum.
A colorless oil that has no taste or smell and boils at 313 C, it is used in the production of many products such as lubricants, paints, dyes, waxes, perfumes, pharmaceuticals and plastics.

TERGITOL ECO-20 is a nonionic surfactant manufactured by Dow Inc.
It is part of the TERGITOL ECO-20 series, which focuses on providing sustainable and environmentally friendly surfactant solutions.

TERGITOL ECO-20 has the ability to hold together substances that normally do not mix with each other, such as oil and water, and to obtain a homogeneous mixture.
This property is important for the formation and stabilization of emulsions.

TERGITOL ECO-20 facilitates the diffusion and penetration of liquids onto solid surfaces.
This feature allows for more effective cleaning of surfaces in cleaning products and industrial applications.

TERGITOL ECO-20 ensures homogeneous distribution of liquids in other liquids.
This feature ensures proper mixing and stabilization of ingredients in many formulations.

TERGITOL ECO-20 is a nonionic surfactant, it dissolves well in water and is generally biodegradable.
This contributes to its evaluation as an environmentally friendly surfactant.

TERGITOL ECO-20 is generally chemically stable at different pH levels and temperature ranges, making it easy to use in a variety of formulations.
TERGITOL ECO-20 is commonly used in various industrial and commercial applications as a surfactant, which is a substance that reduces the surface tension between two liquids or between a liquid and a solid.

TERGITOL ECO-20 are widely used in cleaning products, detergents, emulsifiers, and other formulations where their ability to lower surface tension and increase the wetting and spreading properties is valuable.
TERGITOL ECO-20 in the name indicates that TERGITOL ECO-20 is designed with environmental considerations in mind, and it may offer benefits in terms of reduced environmental impact compared to traditional surfactants.

TERGITOL ECO-20 can maintain its chemical and physical properties under high temperature conditions.
This feature provides an advantage in applications that need to be used at high temperatures.
TERGITOL ECO-20 has the ability to control and prevent foam in some applications.

TERGITOL ECO-20 dissolves easily in water and blends well with other ingredients to obtain a homogeneous mixture.
TERGITOL ECO-20 is compatible with ionic substances and can be used in combination with other ionic surfactants or ingredients.
TERGITOL ECO-20 has low foaming properties in some applications, allowing it to be used where foam is not desired.

The cleaning efficiency of TERGITOL ECO-20 offers high performance, especially in dissolving and removing oil, dirt and other tough contaminants.
TERGITOL ECO-20 helps wetting surfaces, which is an important feature in cleaning and coating applications.
TERGITOL ECO-20 help to remove dirt and stains by reducing the surface tension of water and allowing it to penetrate and lift away contaminants.

In industrial settings, TERGITOL ECO-20 aid in the removal of oil, grease, and other contaminants from surfaces and equipment.
TERGITOL ECO-20 can stabilize emulsions, where two immiscible liquids (e.g., oil and water) are mixed together to form a stable and uniform product.
TERGITOL ECO-20 are sometimes used in agricultural formulations to improve the effectiveness of pesticides and herbicides.

TERGITOL ECO-20 are used in shampoos, body washes, and other personal care items for their cleansing and foaming properties.
TERGITOL ECO-20 are involved in the wetting, dyeing, and finishing processes in textile manufacturing.

TERGITOL ECO-20 are a type of nonionic vegetable oil ethoxylate based on castor oil, which is composed of traditional fatty acids.
They have unique physical properties that allow usage as versatile emulsifiers, solubilisers, emollients, dispersants, and lubricants in various market segments including personal care, home care and agrochemicals.

Boiling point: 232.6℃[at 101 325 Pa]
Density: 1.05 g/mL at 20 °C
vapor pressure: 0Pa at 25℃
Flash point: 257℃
storage temp.: REFRIGERATOR (+4C)
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
pka: 0[at 20 ℃]
form: Viscous Liquid
color: Clear yellow
PH: 5.0-7.0 (1g/10 mL in H2O)
Odor: at 100.00?%. bland
Water Solubility: 24.11mg/L at 25℃
Stability: Stable. Incompatible with storng oxidizing agents.
LogP: 4.297 at 25℃

TERGITOL ECO-20, short for surface-active agents, are a class of chemical compounds that have a unique molecular structure.
They consist of a hydrophilic (water-attracting) "head" and a hydrophobic (water-repelling) "tail."
This dual nature allows surfactants to lower the surface tension between two substances, such as water and oil, which otherwise do not mix well.

TERGITOL ECO-20, Surfactant is a Nonylphenol Ethoxylate surfactant.
It is nonionic and provides excellent detergency, outstanding wetting, versatile solubility characteristics and low odor.
TERGITOL ECO-20 is suggested for use in cleaners & degreasers, prewash spotters and oil field chemicals.

TERGITOL ECO-20 have no net electric charge and are compatible with a wide range of pH levels.
They are often used in applications where low foaming and good detergency are required.
TERGITOL ECO-20 have a negatively charged hydrophilic head and are widely used in cleaning products like laundry detergents, dishwashing liquids, and shampoos.

TERGITOL ECO-20 have a positively charged hydrophilic head and are often used in fabric softeners, disinfectants, and hair conditioners.
TERGITOL ECO-20 have both positively and negatively charged groups and can function as both anionic and cationic surfactants, depending on the pH of the solution.
They are commonly used in personal care products.

TERGITOL ECO-20 is a biodegradable surfactant, making it environmentally friendly.
It decomposes more easily in waste water treatment systems and helps reduce negative effects on the environment.

TERGITOL ECO-20 tends to spread easily on the surfaces it is applied to and disperse homogeneously.
This contributes to a more efficient distribution of pesticides and coating products onto the plant or surface.
TERGITOL ECO-20 is well soluble in water, therefore it is preferred as an ideal surfactant for water-based formulations.

TERGITOL ECO-20s generally have low toxicity and show low levels of human and environmental toxicity.
TERGITOL ECO-20 is among such surfactants and is preferred in various industries for its safe use.
TERGITOL ECO-20 is colorless and odorless, therefore it does not change the color or odor of the products it is used with.

TERGITOL ECO-20 is compatible with a variety of chemicals and generally does not cause undesirable reactions when mixed with other ingredients.
TERGITOL ECO-20 may have the ability to provide corrosion inhibition.

This can help protect metal surfaces and prevent oxidation.
Regarding TERGITOL ECO-20 specifically, it is important to note that the properties and uses of surfactants can vary depending on their specific chemical composition and intended applications.

Uses

TERGITOL ECO-20 are commonly used in various cleaning formulations, such as all-purpose cleaners, glass cleaners, and floor cleaners, due to their ability to disperse and remove dirt, grease, and stains.
TERGITOL ECO-20 are found in many personal care items like shampoos, body washes, facial cleansers, and bubble baths.
They contribute to the foaming and cleansing properties of these products.

TERGITOL ECO-20 is used in various cleaning products such as household cleaning products, industrial cleaners, bathroom and floor cleaners.
It improves cleaning efficiency by effectively dissolving oils, dirt and other contaminants.
TERGITOL ECO-20 is effectively used in the application of pesticides.

TERGITOL ECO-20 helps plant protection products to be better distributed on the leaf surface and increases its effectiveness.
TERGITOL ECO-20 used for emulsification, wetting and dispersion in paint and coating products.
This ensures better adhesion of paints and coatings to surfaces.

TERGITOL ECO-20 is used for emulsification, dispersion and wetting in cosmetic products such as shampoo, conditioner, body lotion.
TERGITOL ECO-20 can be used as a cleaner, wetting agent and dispersant in industrial production processes.
It has uses in various industries such as metalworking, pulp production, water treatment.

TERGITOL ECO-20 is used for emulsification and stabilization of agricultural chemical products.
TERGITOL ECO-20 can be used to provide foam control in certain formulations.
It is used in various applications in concrete additives and offers stabilization properties.

TERGITOL ECO-20 can be used for emulsification and dispersion in copier and ink production.
TERGITOL ECO-20 are often used as emulsifiers in various applications, including the formulation of creams, lotions, and oil-in-water or water-in-oil emulsions.

TERGITOL ECO-20 can be utilized in agricultural formulations to improve the efficacy of herbicides, pesticides, and other agrochemicals by enhancing their spread and adhesion on plant surfaces.
TERGITOL ECO-20 may find use in various industrial processes, such as metal cleaning, paint formulation, and polymer production.

TERGITOL ECO-20 can be involved in the wetting, dyeing, and finishing processes in textile manufacturing.
TERGITOL ECO-20 has been used as a detergent to improve the solubility of dye and to increase the transmembrane permeation.
It has been used as a vehicle for drug/stimulant delivery in cells.

TERGITOL ECO-20 used in the metalworking industry for the dispersion of coolants and foam control.
It is also effective in cleaning and degreasing metal surfaces.

TERGITOL ECO-20 can be used for stain removal and dirt removal in carpet and textile cleaning.
TERGITOL ECO-20 is widely used in carpet shampoos and washing detergents.
Preferred for anti-fungal varnishes, paints and coatings because of their emulsification and stabilization properties.

TERGITOL ECO-20 is used in bathroom cleaners to dissolve lime and soap residues and to clean surfaces.
TERGITOL ECO-20 can be used for emulsification and dispersion in textile dyeing and printing processes.
It helps dyes and printing materials to penetrate textile surfaces better.

TERGITOL ECO-20 is used for wetting, dispersing and cleaning properties in surface treatment chemicals.
It is especially preferred for cleaning and coating metal and plastic surfaces.
TERGITOL ECO-20 is used as a surfactant in a variety of applications in oil processing and refining in oil refineries.

TERGITOL ECO-20 is used in plastics production for its wetting and dispersing properties during mold filling and processing of plastics.
TERGITOL ECO-20 used in the formulation of plant protection products, it provides effective dispersion and adhesion to the leaf surface.

TERGITOL ECO-20 is used for emulsification and cleaning in make-up removers, bath foams, liquid soaps and other cosmetic products.
TERGITOL ECO-20 can be used in irrigation water to increase water distribution and penetration. It can help plant roots better penetrate and use water more efficiently.

Health Hazard
TERGITOL ECO-20, in contact with the skin, may cause mild skin irritation in some people.
In case of prolonged or intense contact, effects such as redness, itching and dryness may occur on the skin.

Eye irritation
When in contact with the eyes, TERGITOL ECO-20 may cause redness, burning and irritation of the eyes.
Contact with eyes should be avoided and in case of contact, wash with plenty of water.

Respiratory tract irritation
When dust or vapors are inhaled, TERGITOL ECO-20 may cause respiratory irritation in some people.
If working in dusty environments, adequate ventilation and respiratory protection should be provided.

Risk of swallowing
TERGITOL ECO-20 can cause serious health problems if swallowed.
In case of accidental ingestion seek medical attention immediately.

Allergic reactions
Some people may have allergic reactions to TERGITOL ECO-20 or its ingredients.
If allergy symptoms occur, product use should be stopped immediately and a healthcare professional should be consulted.

Chemical incompatibility
TERGITOL ECO-20 may be incompatible with some other chemicals and serious hazards may arise from mixing or reacting with such chemicals.

Synonyms
TERGITOL ECO-20
RO 40
BY112
BY125
ELH-40
BY 140
RO series
BY series
CREMOPHOREE1
CREMOPHOR EL
EMULSIFIER KS
PEGCASTOROILS
Kolliphor? EL
CreMophor®
Cremophor®
Cremophor? ELP
Kolliphor? ELP
PEG Castor oil
CREMOPHOR(R) EL
Cremophor EL-10
Cremophor EL-12
Cremophor EL-30
Cremophor EL-40
Cremophor EL-60
Cremophor EL-80
Cremophor EL-90
CREMOPHOR EL(R)
PEG-2 CASTOR OIL
PEG-3 CASTOR OIL
PEG-4 CASTOR OIL
PEG-5 CASTOR OIL
PEG-8 CASTOR OIL
PEG-9 CASTOR OIL
PEG-10 CASTOR OIL
PEG-11 CASTOR OIL
PEG-15 CASTOR OIL
PEG-16 CASTOR OIL
PEG-20 CASTOR OIL
PEG-25 CASTOR OIL
PEG-26 CASTOR OIL
PEG-29 CASTOR OIL
PEG-30 CASTOR OIL
PEG-33 CASTOR OIL
PEG-35 CASTOR OIL
PEG-36 CASTOR OIL
PEG-40 CASTOR OIL
PEG-44 CASTOR OIL
PEG-50 CASTOR OIL
PEG-54 CASTOR OIL
PEG-55 CASTOR OIL
PEG-60 CASTOR OIL
PEG-75 CASTOR OIL
PEG-80 CASTOR OIL
Cremophor® EL
EMULSIFIER 1371 B
PEG-100 CASTOR OIL
PEG-200 CASTOR OIL
CASTOROILETHOXYLATE
Emulsifier EL series
Polyoxyl 40 Castor Oil
CREMOPHOR EL(R), USP/NF
CASTOR OIL, ETHOXYLATED
Ricinus oil, ethoxylated
polyethoxylatedcastoroil
Castoroil,polyethoxylated
polyoxyethylene castor oil
Castor oilCremophor®:EL
EthoxylatedNonylphenolPOE30
TERGITOL ECO-36
Tergitol Eco-36 is a kind of surfactant.
Tergitol Eco-36 also known as castor oil ethoxylate.
This is a type of nonionic surfactant created by the reaction of ethylene oxide with oils.

CAS Number: 61791-12-6
EC number: 500-151-7
Molecular Weight: 1113.6
Molecul formula: C57H104O9(CH2CH2O)n

Tergitol Eco-36 is water soluble and compatible with both polar and nonpolar liquids.
Tergitol Eco-36 is a biodegradable surfactant and has a low environmental impact.
Therefore, it is widely used as an environmentally friendly cleaning agent.

Tergitol Eco-36 is a slightly yellow, clear liquid.
Tergitol Eco-36 has no smell and is oily.
It dissolves easily in water and has a boiling point of 268 °C.

Tergitol Eco-36 used in a variety of applications such as agrochemicals, mining, inks, coatings and adhesives, metalworking, lubricants, household cleaning, and industrial cleaning​​.
Tergitol Eco-36 is a chemical compound also known as Nonoxynol-6.
Tergitol Eco-36 belongs to a group of surfactants, also called nonylphenol ethoxylate.

Tergitol Eco-36 is a common chemical compound used in industrial and commercial products, cleaning products, detergents, various industrial applications, and agriculture.
Tergitol Eco-36 is used to help oils and dirt be more easily dissolved by surfactant-containing products.
In this way, it can increase the effectiveness of cleaning products and make cleaning processes easier.

Tergitol Eco-36 can also be used to stabilize emulsions in the formulation of some pesticides and industrial paints and coatings.
Tergitol Eco-36 is a triglyceride fatty acid which has the potential to repel insects and promote plant growth.
Tergitol Eco-36 is an ethoxylated nonionic vegetable oil based on castor oil consisting of traditional fatty acids.

Tergitol Eco-36 acts as emulsifier, solubilizer, anti-static agents and lubricants.
Tergitol Eco-36 is a triglyceride fatty acid with the potential to repel insects and promote plant growth.
Tergitol Eco-36 is a biodegradable surfactant and has a low environmental impact therefore, it is widely used as an environmentally friendly cleaning agent.

Tergitol Eco-36 is a slightly yellow, clear liquid.
It has no smell and is oily. It dissolves easily in water and has a boiling point of 268 °C.
Tergitol Eco-36 is a safe product, but may cause reactions such as skin irritation or eye irritation in some people.

When working with Tergitol Eco-36, it is important to avoid contact with skin and eyes and to wash your hands after use.
Tergitol Eco-36 is a versatile and multifunctional nonionic surfactant.
In addition, Tergitol Eco-36 is used as an odor remover and emulsifier.

Tergitol Eco-36 is an excellent dispersant, cleaner, surfactant (low foam).
Tergitol Eco-36 is even used as a lubricant in some special formulations.
In addition, Tergitol Eco-36 is frequently used in perfume-based formulations, liquid soaps, bubble baths and shampoos.

Tergitol Eco-36 is used in body washes and shower gels, lotions, facial cleansers, cosmetics to dissolve oils and fragrances.
Tergitol Eco-36 is a safe product, but may cause reactions such as skin irritation or eye irritation in some people.
Whether you are looking for a deodorizer - Tergitol Eco-36 is what you are looking for.

Tergitol Eco-36 can also be used in textile cleaning formulations and metalworking formulations.
Tergitol Eco-36 is a surfactant manufactured by the Dow Chemical Company.
This is a type of nonionic surfactant created by the reaction of ethylene oxide with oils.

Tergitol Eco-36 is a surfactant.
Tergitol Eco-36 are molecules that allow different substances such as water and oil to mix together.
Tergitol Eco-36 is a biodegradable surfactant, meaning it can degrade in an environmentally friendly way.

Tergitol Eco-36 is non-ionic.
Tergitol Eco-36 is compatible with non-ionic, anionic and cationic ingredients and products.
In addition, Tergitol Eco-36 is derived from natural plant-derived castor oil.

Tergitol Eco-36 is respectively ethoxylated castor oil.
In addition, Tergitol Eco-36 has excellent emulsifying and diffusing properties.
Tergitol Eco-36 is soluble in water, fatty acid or other organic solvents.

Tergitol Eco-36 can be used as the main ingredient of synthetic fiber spinning oil used in the textile industry.
As an emulsifier in the pharmaceutical industry, for the preparation of pesticide emulsifier, emulsion polymerization emulsifiers water soluble metal cutting fluid.
Tergitol Eco-36 can be used as a primary or secondary emulsifier in both oil-in-water and water-in-oil cosmetic products.

Boiling point: 232.6℃[at 101 325 Pa]
Density: 1.05 g/mL at 20 °C
vapor pressure: 0Pa at 25℃
Flash point: 257℃
storage temp.: REFRIGERATOR (+4C)
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
pka: 0[at 20 ℃]
form: Viscous Liquid
color: Clear yellow
PH: 5.0-7.0 (1g/10 mL in H2O)
Odor: at 100.00?%. bland
Water Solubility: 24.11mg/L at 25℃
Stability: Stable. Incompatible with storng oxidizing agents.
LogP: 4.297 at 25℃

Tergitol Eco-36 is an oil obtained from polyethoxylated castor beans.
Moreover, Tergitol Eco-36 is a colorless oil that boils at 313°C and has no taste or odor.
Tergitol Eco-36 is used in the production of many products such as lubricants, paints, paints, candles, perfumes.

Tergitol Eco-36 can mix immiscible materials such as oil and water.
Also, Tergitol Eco-36 has many uses in various formulations, both in industrial and industrial applications, primarily as non-ionic surfactants.
It has native ethoxylate, Castor oil, Pale yellow viscous liquid in India.

Tergitol Eco-36 is supplied as prescribed and specified by the regulating Pharmacopoeia.
Tergitol Eco-36 (also known as PEG-n-CO) are ethylene oxide condensates of castor oil and hydrogenated castor oil.
The number of moles of Tergitol Eco-36 can vary.

Tergitol Eco-36 is prepared by reacting 35 moles of ethylene oxide with each mole of castor oil.
In addition, the resulting product is a mixture.
The main component of Tergitol Eco-36 is the material that the hydroxyl groups of castor oil triglyceride have.

Tergitol Eco-36 with ethylene oxide to form polyethylene glycol ethers.
Minor components of Tergitol Eco-36 are polyethylene glycol esters of ricinoleic acid, polyethylene glycols and
It is found in polyethylene glycol ethers of glycerol.

Tergitol Eco-36 is a synthetic, nonionic surfactant used to stabilize emulsions of non-polar materials in water.
Tergitol Eco-36 is an excipient or additive in medicines.
Therapeutically, modern drugs are rarely given in pure chemical form, so most of the active ingredients excipients or additives such as Tergitol Eco-36.

Tergitol Eco-36 is a nonionic surfactant belonging to the group of polyoxyethylene fatty acid esters of castor oil.
At room temperature, Tergitol Eco-36 takes the form of a paste or semi-liquid paste with a tendency to delaminate.
However, Tergitol Eco-36 is a ready-to-use homogeneous liquid when heated to 50°C.

Tergitol Eco-36 is a safe product, but may cause reactions such as skin irritation or eye irritation in some people.
When working with Tergitol Eco-36, it is important to avoid contact with skin and eyes and to wash your hands after use.
Tergitol Eco-36 is a versatile surfactant that can be used in a number of different applications.

Tergitol Eco-36 is widely used as an environmentally friendly cleaning agent and is a safe product.
Tergitol Eco-36 is a biodegradable surfactant.
This means that Tergitol Eco-36 can degrade without leaving a harmful residue in the environment.

This makes Tergitol Eco-36 an environmentally friendly cleaning agent and an ideal choice for other applications.
Tergitol Eco-36 is a safe product.
It can cause reactions such as skin irritation or eye irritation in some people, but these are usually mild and short-lived.

Uses
Tergitol Eco-36 is a triglyceride fatty acid with the potential to repel insects and promote plant growth.
Tergitol Eco-36 can be applied to various emulsifiers, especially organic phosphorus emulsifier, where it has a distinctive feature.
Also, Tergitol Eco-36 can be used as industrial emulsifier, penetrating agent, antifoaming agent.

Tergitol Eco-36 is used in water treatment chemicals, biocidal products, lubricant-greases, leather tanning and dyeing.
In addition, Tergitol Eco-36 is used in finishing products, cosmetics-personal care products, emulsifiers, washing-cleaning.
Tergitol Eco-36 is used in hydraulic and heat transfer fluids, mining, non-metal surface treatment products, hydraulic fluids.

Tergitol Eco-36 is used in brightening-waxes, processing aids (i.e. pH regulators, flocculants and precipitants),laboratory chemicals, powder coating/core welding and brazing products.
Also, Tergitol Eco-36 is used to make fine chemicals, plastics and fabricated metal products.
Tergitol Eco-36 is permitted to be used as an inert ingredient in non-food pesticide products.

Tergitol Eco-36 is used in cleaning products by increasing foaming and removing dirt and oil more easily.
Tergitol Eco-36 is used in paints and coatings by mixing water and pigments together.
Tergitol Eco-36 is used in cosmetics to make the skin and hair soft and smooth.

Tergitol Eco-36 is used in medicines by allowing the medicines to be absorbed more easily into the body.
Tergitol Eco-36 is used in agricultural chemicals by making plants grow better and give more yield.
Tergitol Eco-36 is used in metalworking fluids, making it easier to process metals.

Tergitol Eco-36 is used in lubricants by reducing friction and making machines last longer.
Tergitol Eco-36 is used in food additives, making food look better and last longer.
Tergitol Eco-36 was used as a detergent to increase the solubility of the dye.

Tergitol Eco-36 is used to increase transmembrane permeability.
Tergitol Eco-36 has been used as a vehicle for drug/stimulant delivery in cells.
In addition, Tergitol Eco-36 is used to emulsify and dissolve oils and other water-insoluble substances.

Tergitol Eco-36 was originally developed for use as a solvent and emulsifier.
Tergitol Eco-36 is a triglyceride fatty acid with the potential to repel insects and promote plant growth.
Tergitol Eco-36 is used in water treatment chemicals, biocidal products, lubricants-greases, leather tanning.

Tergitol Eco-36 is used in dyeing, finishing products, cosmetics-personal care products, emulsifiers, washing and cleaning products.
Tergitol Eco-36 is used in metal surface treatment products (including those for galvanizing and electroplating), metal.
Also Tergitol Eco-36 is used in processing aids (ie pH regulators, flocculants and precipitators), laboratory chemicals, flux coating/core welding and brazing products.

Tergitol Eco-36 is used to make fine chemicals, plastics and fabricated metal products.
Tergitol Eco-36 is allowed to be used as an inert ingredient in non-food pesticide products.
Tergitol Eco-36 can be used in laundry detergents, dishwashing liquids, liquid soaps and other cleaning products to increase their effectiveness to dissolve oil stains and dirt.

Tergitol Eco-36 can be used in industrial cleaning products and washing chemicals to easily clean oil, dirt and residues.
Tergitol Eco-36 is sometimes used in the formulation of pesticides to stabilize emulsions.
Tergitol Eco-36 can be used to increase the stability of emulsions in paint and coating products.

Tergitol Eco-36 can also be used as a surfactant in other industrial applications.
It can be used in various chemical processes to facilitate the dissolution of oils, dirt and other substances.
Tergitol Eco-36 can be used as additive, foamer, stabilizer, lubricant, solvent.

Tergitol Eco-36 can be used as leveling agent, antistatic agent, washing agent, dispersing agent, separating agent, degreasing agent.
In addition, Tergitol Eco-36 can be used as a plasticizer, thickener, viscosity regulator.
Tergitol Eco-36 can be used as a chemical intermediate.

Tergitol Eco-36 can be used in laundry detergents, dishwashing liquids, liquid soaps and other cleaning products to increase their effectiveness to dissolve oil stains and dirt.
Tergitol Eco-36 can be used in industrial cleaning products and washing chemicals to easily clean oil, dirt and residues.
Tergitol Eco-36 is sometimes used in the formulation of pesticides to stabilize emulsions.

Tergitol Eco-36 can be used to increase the stability of emulsions in paint and coating products.
Tergitol Eco-36 can also be used as a surfactant in other industrial applications.
It can be used in various chemical processes to facilitate the dissolution of oils, dirt and other substances.

Tergitol Eco-36 can be applied to various emulsifiers, especially organophosphorus emulsifiers.
Tergitol Eco-36 can be used as stabilizer, lubricant, solvent and leveling agent.

Also, Tergitol Eco-36 can be used as industrial emulsifier, penetrating agent, antifoaming agent, additive, foamer.
Tergitol Eco-36 can be used as antistatic agent, washing agent, dispersing agent, separating agent, degreasing agent.

Hazards
Tergitol Eco-36 are considered endocrine disruptors potentially acting on the endocrine system.
These substances can affect the functioning of hormones in the endocrine system, which plays an important role in the regulation of hormonal balance.

Environment and Bioaccumulation
Tergitol Eco-36 may degrade slowly in aquatic environments and persist in the environment.
Therefore, it can harm aquatic ecosystems and aquatic organisms.
In addition, these substances can be absorbed by organisms and cause bioaccumulation.

Toxic Effects
Tergitol Eco-36 may contain substances that in some cases may be toxic and cause skin and eye irritation.

Potential Carcinogenicity
Some studies suggest that Tergitol Eco-36 may have some carcinogenic effects.
However, research on this subject is still ongoing and clear results have not been obtained.

Synonyms
Tergitol Eco-36
Cremophor EL
dermowax HC-40
etocas 40
hetoxide C-40
nikkol CO-40
polyethylene glycol (40) castor oil
polyoxyethylene (40) castor oil
stepantex CO-40
toximul 8242
cremophor el
castor oil ethoxylated
polyoxyethylene castor oil
Ethoxylated castor oil
PEG Castor oil
Emulsifier EL series
RO 40
RO series
BY series
Cremophor EL series
Castor Oil Ethoxylate
Emulsifier EL
Castor oil ethoxylates
PEG-35 Castor Oil;
Castor Oil polyoxyethylene ether;
Polyoxyethyleneglycerol Triricino
Polyoxyethylene castor oil ether
Polyoxyethylene Castor oil ethoxylate
cremophor EL
Polyoxyl 35 Castor Oil
6D4M1DAL6O
Emulphor EL620
Etocas 35
PEG-35 Castor oil
PEG-36 Castor oil
ALPICARE CO 36
AQ 250
Actinol CS 40
Alkamuls EL 620
Alkamuls OR 36
Alkasurf CO 10
Alkasurf CO 15
Alkasurf CO 25B
Alkasurf CO 40
Arlatone 285
Arlatone 650
Atlas G 1281
Atlas G 1300
Bio-Soft HR 40
Bio-Soft HR 55
CHEMAX CO-36
Castor oil polyoxyethylene ether
Castor oil, ethylene glycol polymer
Castor oil, ethylene oxide reaction product
Castor oil, polyethoxylated
Cemulsol BR
Chemax CO
Cremaphor
EC 500-151-7
EO 90
ETHOX CO-36
EUMULGIN RO 35
Emanon CH 80
Emulan EL
Emulan ELP
Emulphor EL 620
Emulphor EL 620P
Emulphor EL 719
Emulphor EL 749
Emulphor EL 980
Emulpon EL 40
Emulsogen EL
Emulsogen EL 400
Ethofor RO 40
Ethox CO 25
Ethox CO 30
Ethoxylated castor oil
Etocas 40
Etocas 5
Eumulgin HRE 40
Eumulgin RO 40
Eumulgin RT 40
G 1300
HCO 505
HETOXIDE C-36
Hairikku AQ 250
Heliwet EO 33
Hextoxide C 15
Hextoxide C 25
MERGITAL EL 35
PEG-10 Castor oil
PEG-100 Castor oil
PEG-11 Castor oil
PEG-15 Castor oil
PEG-2 Castor oil
PEG-20 Castor oil
PEG-200 Castor oil
PEG-25 Castor oil
PEG-26 Castor oil
PEG-3 Castor oil
PEG-33 Castor oil
PEG-4 Castor oil
PEG-5 Castor oil
PEG-50 Castor oil
PEG-54 Castor oil
PEG-55 Castor oil
PEG-8 Castor oil
PEG-9 Castor oil
POLYOXYL 35 CASTOR OIL (II)
POLYOXYL 35 CASTOR OIL (MART.)
POLYOXYL 35 CASTOR OIL (USP-RS)
POLYOXYL 36 CASTOR OIL
Polyethylene glycol (100) castor oil
Polyethylene glycol (11) castor oil
Polyethylene glycol (15) castor oil
Polyethylene glycol (25) castor oil
Polyethylene glycol (26) castor oil
Polyethylene glycol (3) castor oil
Polyethylene glycol (30) castor oil
Polyethylene glycol (33) castor oil
Polyethylene glycol (35) castor oil
Polyethylene glycol (5) castor oil
Polyethylene glycol (50) castor oil
Polyethylene glycol (54) castor oil
Polyethylene glycol (55) castor oil
Polyethylene glycol (60) castor oil
Polyethylene glycol 1000 castor oil
Polyethylene glycol 1800 castor oil
Polyethylene glycol 200 castor oil
Polyethylene glycol 2000 castor oil
Polyethylene glycol 400 castor oil
Polyethylene glycol 450 castor oil
Polyethylene glycol 500 castor oil
Polyoxyethylated castor oil
Polyoxyethylene (10) castor oil
Polyoxyethylene (100) castor oil
Polyoxyethylene (11) castor oil
Polyoxyethylene (15) castor oil
Polyoxyethylene (2) castor oil
Polyoxyethylene (20) castor oil
Polyoxyethylene (200) castor oil
Polyoxyethylene (25) castor oil
Polyoxyethylene (26) castor oil
Polyoxyethylene (3) castor oil
Polyoxyethylene (30) castor oil
Polyoxyethylene (33) castor oil
Polyoxyethylene (35) castor oil
Polyoxyethylene (36) castor oil
Polyoxyethylene (4) castor oil
Polyoxyethylene (40) castor oil
Polyoxyethylene (5) castor oil
Polyoxyethylene (50) castor oil
Polyoxyethylene (54) castor oil
Polyoxyethylene (55) castor oil
Polyoxyethylene (60) castor oil
Polyoxyethylene (8) castor oil
Polyoxyethylene (9) castor oil
UNII-4ERD2076EF
UNII-6D4M1DAL6O
UNII-GF873K38RZ
UNII-VXP26NM2XX
UNIPEG-CO-36
Castor oil ethoxylates EL-20
Castor oil ethoxylates EL-32
Castor oil ethoxylates EL-36
Castor oil ethoxylates EL-40
Castor oil ethoxylates EL-60
Castor oil ethoxylates EL-80
TERGITOL ECO-40
TERGITOL ECO-40 are readily biodegradable castor oil alkoxylates with differing degrees of ethoxylation and are recommended non-ionic emulsifiers.
TERGITOL ECO-40 is a type of surfactant produced by the Dow Chemical Company.
TERGITOL ECO-40 also known as castor oil ethoxylate.

CAS Number: 65256-16-8

TERGITOL ECO-40 is a type of nonionic surfactant created by the reaction of ethylene oxide with oils.
Tergitol Eco-40 is water soluble and compatible with both polar and nonpolar liquids.
Tergitol Eco-40 is a biodegradable surfactant and has a low environmental impact.

TERGITOL ECO-40 is widely used as an environmentally friendly cleaning agent.
Tergitol Eco-40 is a slightly yellow, clear liquid.
It has no smell and is oily.

TERGITOL ECO-40 dissolves easily in water and has a boiling point of 268 °C.
Tergitol Eco-40 is a safe product, but may cause reactions such as skin irritation or eye irritation in some people.

TERGITOL ECO-40 is a nonionic surfactant or detergent, also known as polyethylene glycol alkyl ethers.
These types of surfactants are obtained by adding TERGITOL ECO-40 to the molecules of fatty alcohols (for example, aliphatic alcohol) through a chemical process called ethoxylation.
TERGITOL ECO-40 has a certain ethylene oxide chain length in the molecular structure, especially due to the addition of ethylene oxide, which determines its specific properties.

TERGITOL ECO-40 is a surfactant compatible with various organic solvents.
This feature increases its suitability for various formulations in industrial cleaning products and paint/coating applications.

TERGITOL ECO-40 has the ability to penetrate surfaces.
This helps oil and contaminants penetrate porous surfaces effectively and the cleaning reaches the deeper layers.
TERGITOL ECO-40 is known for its softening effect in some applications (eg in the textile industry).

TERGITOL ECO-40 can behave stably at various pH levels and temperatures.
This ensures its use in different conditions and the stability of its performance.

TERGITOL ECO-40 can be used as a corrosion inhibitor in some formulations.
This helps protect metal surfaces and increase their longevity.
TERGITOL ECO-40 is used in household and industrial cleaning products as an agent that effectively dissolves and removes oils and contaminants.

TERGITOL ECO-40 is a biodegradable and environmentally friendly surfactant.
This contributes to wastewater treatment systems and the reduction of negative impacts on the environment.
TERGITOL ECO-40 is a versatile surfactant widely used in various industries.

TERGITOL ECO-40 is used for different purposes in many areas from cosmetics to industrial cleaning, from agriculture to painting and coating.
Depending on the intended use, it can be used with other ingredients in different concentrations and mixtures.
TERGITOL ECO-40 reduces the surface tension of water.

This facilitates the interaction between water and other substances (eg oils or contaminants), thus ensuring an effective cleaning of cleaning products.
TERGITOL ECO-40 has the ability to hold together substances that normally do not mix with each other, such as oil and water, and to obtain a homogeneous mixture.
This property can be used in cosmetics, the paint and coating industry, and many other applications.

TERGITOL ECO-40 has the ability to spread and adhere easily to a surface, thus helping the active ingredient in sprays and pesticides to be evenly dispersed on the plant surface.
TERGITOL ECO-40 can be used for stabilization of foams and other mixtures.

TERGITOL ECO-40 is a nonionic surfactant, it is well soluble in water and generally biodegradable.
This contributes to its evaluation as an environmentally friendly surfactant.
TERGITOL ECO-40 is an effective surfactant widely used in different industries and applications.

TERGITOL ECO-40s and concentrations in which they are used may vary depending on the manufacturers and the field of application.
It is important to always pay attention to the product's instructions for use and safety information.

Tergitol Eco-40 is a surfactant. Surfactants are molecules that allow different substances such as water and oil to mix together.
Tergitol Eco-40 is a biodegradable surfactant, meaning it can degrade in an environmentally friendly way.
Therefore, it is widely used in cleaning products and other applications.

Grade: Technical
Form: Liquid
Color: orange, amber
Flash Point: > 268 °C (> 514 °F)
Odor: fatty odour
pH: 6.5
Relative Density: 1.039 - 1.043 @ 40 °C (104 °F) Reference Material: (water = 1)
Vapor Pressure: < 0.01 mmHg

Tergitol Eco-40 is a safe product, but may cause reactions such as skin irritation or eye irritation in some people.
When working with Tergitol Eco-40, it is important to avoid contact with skin and eyes and to wash your hands after use.
Tergitol Eco-40 is a surfactant.

TERGITOL ECO-40s are molecules that allow different substances such as water and oil to mix together.
Tergitol Eco-40 is a biodegradable surfactant, meaning it can degrade in an environmentally friendly way.
Therefore, it is widely used in cleaning products and other applications.

Uses
Tergitol Eco-40 is used in cleaning products by increasing foaming and removing dirt and oil more easily.
Tergitol Eco-40 is used in paints and coatings by mixing water and pigments together.
Tergitol Eco-40 is used in cosmetics to make the skin and hair soft and smooth.

Tergitol Eco-40 is used in medicines by making the medicines more easily absorbed into the body.
TERGITOL ECO-40 used as a surfactant for household cleaning products, industrial cleaners and general cleaning products.
It is an effective agent for dissolving and cleaning oils and contaminants.

TERGITOL ECO-40 is used in the formulations of agricultural chemicals such as herbicides, insecticides and fungicides.
It helps the active ingredients to be properly distributed on the plant surface and to increase its effectiveness.
TERGITOL ECO-40 is used in paint and coating products for its spreading, wetting and stabilizing properties.

TERGITOL ECO-40 used for emulsification, dispersion and softening during dyeing, printing and textile processing.
It can be used for emulsification, stabilization and cleansing properties in cosmetic products such as shampoo, conditioner, body lotion.
TERGITOL ECO-40 used in the metalworking industry for the dispersion of coolants and foam control.

TERGITOL ECO-40 can be used for its dispersing and wetting properties during pulp and paper production.
TERGITOL ECO-40 can be used for foam control and dispersion in water treatment processes.
It can be used in bath products such as shower gels, bubble baths and soaps.

TERGITOL ECO-40 is effective for emulsification and stabilization of these products.
TERGITOL ECO-40 is widely used in cleaning machines used in homes and industrial areas due to its cleaning and dirt removal effect.
In the application of pesticides, TERGITOL ECO-40 allows the active ingredient to adhere to the leaf surface and penetrate.

TERGITOL ECO-40 is used for cleaning metal surfaces, dissolving oils and dispersing the cleaning solution.
It can be used in construction chemicals and provides stabilization and dispersion properties in the formulation of products such as concrete additives.
TERGITOL ECO-40 can be used for anti-fungal varnishes and paints because of its emulsification and stabilization properties.

In spray formulations, TERGITOL ECO-40 helps to distribute sprays evenly on the surface and ensures effective application of the product.
TERGITOL ECO-40 used in the construction field for its emulsification and dispersion properties in products such as water-based adhesives, sealants and coating materials.
TERGITOL ECO-40 is used for emulsification and dispersion in copier and ink production.

TERGITOL ECO-40 is used as an active ingredient in many cleaning products such as general cleaning products, floor cleaners, glass cleaners and industrial detergents.
It can be used for emulsification and dispersion in wood staining and coating.
TERGITOL ECO-40 can be used as a surfactant in a variety of applications in refinery processes and petrochemical production.

Tergitol Eco-40 is used in agricultural chemicals by enabling plants to grow better and yield more.
Tergitol Eco-40 is used in metalworking fluids, making it easier to process metals.

Tergitol Eco-40 is used in lubricants by reducing friction and making machines last longer.
Tergitol Eco-40 is used in food additives, making food look better and last longer.

Healty Hazard
In contact with the skin, Tergitol Eco-40 may cause mild skin irritation in some people.
Skin irritation may occur, particularly with prolonged contact or exposure to high concentrations.

Eye irritation
In case of eye contact, it may cause redness, burning and irritation of the eyes.
Eye contact should be avoided and in case of contact, wash with plenty of water.

Respiratory Irritation
Inhalation of dust or vapors may cause respiratory tract irritation in some people.
Therefore, if TERGITOL ECO-40 is used in aerosol or powder form, appropriate ventilation and respiratory protection must be provided.

Risk of swallowing
TERGITOL ECO-40 can cause serious health problems if swallowed.
In case of accidental swallowing, seek immediate medical attention.

Allergic reactions
Some people may have allergic reactions to TERGITOL ECO-40 or its ingredients.

Chemical incompatibility
TERGITOL ECO-40 may be incompatible with some other chemicals and serious hazards may arise from mixing or reacting with such chemicals.

Synonyms
TERGITOL ECO-40
Tergitol speedwet
65256-16-8
TERGITOL NP 10
Tergitol NP 10 is a non-ionic surfactant.
Tergitol NP 10 is a nonionic polyglycol ether surfactant.
Tergitol NP 10 Surfactant is a nonylphenol ethoxylate-based surfactant.
Tergitol NP 10 is nonylphenol with 10 moles of ethylene oxide adducts.


CAS Number: 127087-87-0
EC Number: 500-045-0
MDL number: MFCD00132411
Molecular Formula: C17H35O4S.Na


Tergitol NP 10, Surfactant is a Nonylphenol Ethoxylate based surfactant.
Tergitol NP 10 is nonionic and provides excellent detergency, rinse-ability, and low odor.
Tergitol NP 10 is suggested for use in cleaners & degreasers, prewash spotters and metalworking fluids.
This is a Nonylphenol Ethoxylate-based nonionic surfactant that provides excellent detergency, rinse-ability, and low odor.


Tergitol NP 10, Surfactant is a Nonylphenol Ethoxylate based surfactant.
Tergitol NP 10 is nonionic and provides excellent detergency, rinse-ability, and low odor.
Tergitol NP 10 is nonionic surfactant.
Tergitol NP 10 possesses good detergency performance.


Acid value: The acid value of Tergitol NP 10 (General 0713) is not more than 0.2.
Tergitol NP 10 is nonionic and provides excellent detergency, rinse-ability, and low odor.
Tergitol NP 10 or Nonylphenol 10 is nonylphenol ethoxylate-based surfactant.
Tergitol NP 10 is nonionic and provides excellent detergency, rinse-ability, and low odor.


Tergitol NP 10 is a non-ionic surfactant.
Tergitol NP 10 is nonylphenol and ethylene oxide condensation from the anhydrous mixture.
The content of C9H19C6H4(OCH2CH2)2OH (in the formula, the average value of n is 9) should be 90.0% to 110.0%.
Tergitol NP 10 is colorless to light yellow viscous liquid; Odorless; Easy to coagulate below 10°C.


Tergitol NP 10 is easily soluble in ethanol and soluble in water.
Tergitol NP 10 adds 100ml of water to a 250ml beaker, soak the thermometer in the center of the solution, heat the solution in a water bath with constant stirring until the solution is turbid, then raise the temperature to 10°C, and remove the water bath, keep stirring until the solution is clear (the thermometer mercury ball is fully visible), record the temperature at this point, which should be 52-56°C.
Tergitol NP 10 has high emulsifying feature.


Tergitol NP 10 is nonionic surfactant.
Tergitol NP 10 is non-ionic in water, it is no charge.
Due to these properties, Tergitol NP 10 is used in the synthesis of detergents, cleaners, emulsifiers and various other products.
Nonylphenols are compounds in the alkylphenols chemical class.


The structure of NPs can vary.
The nonyl group can be attached to the phenol ring at various positions, often at the 4 or 2 position;
Tergitol NP-10, Surfactant is a Nonylphenol Ethoxylate based surfactant.
Tergitol NP 10 is nonionic and provides excellent detergency, rinse-ability, and low odor.


Tergitol NP 10 can be branched or linear.
Branched nonylphenol, 4-nonylphenol, is the most commonly produced and marketed nonylphenol.
Although pure Tergitol NP 10 is colorless, the mixture of nonylphenol isomers is a light yellow liquid.
Nonylphenols are moderately soluble in water but soluble in alcohol.


Nonylphenol arises from the environmental degradation of Tergitol NP 10s, which are metabolites of commercial detergents called alkylphenol ethoxylates.
Nonyl phenol ethoxylates are clear light orange colored liquids.
Tergitol NP 10 is amphipathic (having both hydrophilic and hydrophobic properties), which allows them to envelop non-polar substances such as oil and grease and isolate them from water.



USES and APPLICATIONS of TERGITOL NP 10:
Tergitol NP 10 is used as cleaners & detergents, degreasers, paper & textile processing, paints, prewash spotters, agrochemicals, metalworking fluids, oil field chemicals.
Tergitol NP 10 is used in open cotton cooking, as a wetting agent in the pre-cleaning of the fiber, in an enzyme desizing bath, and as a leveling agent in dyeing.


Tergitol NP 10 is a nonionic surfactant for used in paints and coatings, paper and textile processing, cleaners and detergents, agrochemicals, and metalworking fluids; with excellent detergency, outstanding wetting, versatile solubility characteristics, and exceptional handling properties.
Tergitol NP 10 can also be used in oilfield drilling and production formulations.


Tergitol NP 10 quickly removes the filth from the fibers and takes the wax and pectin from the fiber in cotton and allows it to be easily removed.
Tergitol NP-10 Surfactant is a Nonylphenol Ethoxylate based surfactant.
Tergitol NP 10 is used as cleaners & detergents, degreasers, paper & textile processing, paints, prewash spotters, agrochemicals, metalworking fluids, oil field chemicals.


Tergitol NP 10 is nonionic and provides excellent detergency, rinse-ability, and low odor.
Tergitol NP 10 is suggested for use in cleaners & degreasers, prewash spotters and metalworking fluids.
Tergitol NP 10 is used as a surfactant cleaner and degreaser in many industrial areas, especially detergents.
Tergitol NP 10 is not affected by hard waters, acidic and basic environments.


Tergitol NP 10, which is easily soluble in hot water, does not form any ions when dissolved in water.
Tergitol NP 10 is suggested for use in cleaners & degreasers, prewash spotters and metalworking fluids.
Tergitol NP 10 is used as an additive in formulations in many sectors, especially shampoo and soap.
Tergitol NP 10 tends to dissolve in both aqueous phase and oil and reduce the surface tension of liquids.


Tergitol NP 10, which is easily soluble in hot water, does not form any ions when dissolved in water.
They foam less compared to anion active substances.
Tergitol NP 10 is used as an additive in the production of pesticides.
Tergitol NP 10 is also works as a detergent and wetting agent.


Tergitol NP 10 is used in cleaners & detergents, paper & textile processing, paints & coatings, agrochemicals, metalworking fluids.
Tergitol NP 10 is used for washing and soaking all natural and synthetic fibers.
Tergitol NP 10 is used in cleaners & detergents, paper & textile processing, paints & coatings, agrochemicals, metalworking fluids.
Tergitol Np-10 is used as a surfactant cleaner and degreaser in many industrial areas, especially detergents.


Tergitol NP 10 is suggested to be used for cleaners & degreasers, prewash spotters, and metalworking fluids.
Tergitol NP 10 is suggested for use in cleaners & degreasers, prewash spotters and metalworking fluids.
Tergitol NP 10 is also works as a detergent and wetting agent.
Tergitol NP 10 and Tergitol NP 10 ethoxylates are only used as components of household detergents.


Tergitol NP 10 is used in cleaners & detergents, paper & textile processing, paints & coatings, agrochemicals, metalworking fluids.
Tergitol NP 10 is suggested for use in cleaners & degreasers, prewash spotters, and metalworking fluids.
Tergitol NP 10 is a nonionic surfactant for used in paints and coatings, paper and textile processing, cleaners and detergents, agrochemicals, and metalworking fluids; with excellent detergency, outstanding wetting, versatile solubility characteristics, and exceptional handling properties.


Tergitol NP 10 can also be used in oilfield drilling and production formulations.
Tergitol NP 10 is used as an additive in formulations in many sectors, mainly shampoo and soap.
Tergitol NP 10 is used as additives in the manufacture of antioxidants, lubricating oil additives, laundry and dishwashing detergents, emulsifiers and solubilizers.


In the agricultural field, Tergitol NP 10 is used together with rosin during adhesive production, as Tergitol NP 10 reduces surface tension and acts as a good wetting agent.
Tergitol NP 10 is a surfactant nonionic nonyl phenol, low odor, water soluble surfactants used in paper & textile and liquid processing metal working.


Tergitol NP 10 is included in the surfactant category and also as an emulsifier (binding agent between oil and water).
Tergitol NP-10 is a non-ionic surfactant.
Tergitol NP 10 is also works as a detergent and wetting agent.
Tergitol NP 10 is also precursors of alkylphenol ethoxylates and nonylphenol ethoxylates, which are commercially important nonionic surfactants used in detergents, paints, pesticides, personal care products and plastics.


Tergitol NP 10 is also used as an emulsifier in some productions.
Tergitol NP 10 is used in the manufacture of personal care products.
Tergitol NP 10 is used for bonding agents with a higher water content than oil.
Tergitol NP 10 is used in the manufacture of antioxidants, lubricating oil additives, laundry and dishwashing detergents, emulsifiers and solubilizers.


Tergitol NP 10 is compatible with dyes, pigments, protective colloids, thickener and other substances with a molar mass in the further range.
Tergitol NP 10 is also not sensitive to molten metal ions, which ensures that their concentration is not too high.
Tergitol NP 10 is used in detergent production, Antioxidants, In lubricant oil additives, In paint production, and Laundry and dishwashing detergents,


Tergitol NP 10 is also often used as an intermediate in the manufacture of non-ionic surfactants nonylphenol exoxylates, which are used in detergents, paints, pesticides, personal care products, and plastics.
Tergitol NP 10 (nonyl phenol 10 moles) is used as emulsifier & detergent for textile, paint, agrochemicals, cleaners formulation.
Tergitol NP 10 is used In insecticides, In plastic, In emulsifiers and solubilizers, Cleaners & degreasers, and Agrochemical


Tergitol NP 10 tends to dissolve in both the aqueous phase and oil and reduce the surface tension of liquids.
Tergitol NP 10 is also used as an emulsifier in some productions.
Tergitol NP 10 is used Oil in water emulsion, Metalworking fluid, Paint & coatings, Surfactant, Detergents, Papers and textiles, Paints, Agrochemicals, Dishwashing liquid, and Other household use.


Tergitol NP 10 for use in paints and coatings, paper and textile processing, cleaners and detergents, agrochemicals, and metalworking fluids; with excellent detergency, outstanding wetting, versatile solubility characteristics, and exceptional handling properties.
Tergitol NP 10 can also be used in oilfield drilling and production formulations.
Tergitol NP-10 is a non-ionic surfactant .


Tergitol NP 10 is also works as a detergent and wetting agent.
In the agricultural field, Tergitol NP 10 is used with colophon resin during the production of spreading adhesive, as Tergitol NP 10 reduces the surface tension and acts as a good wetting agent.
Tergitol NP 10 is used in cleaners & detergents, paper & textile processing, paints & coatings, agrochemicals, metalworking fluids.


Tergitol NP 10 can also be used to produce tris (4-nonyl-phenyl) phosphide (TNPP), an antioxidant used to protect polymers such as rubber, vinyl polymers, polyolefins and polystyrene.
Tergitol NP 10 is used as an additive in the production of pesticides.
Tergitol NP 10 is suggested for use in cleaners & degreasers, prewash spotters and metalworking fluids.


Tergitol NP 10 is used excellent detergency, outstanding wetting, versatile solubility characteristics, soluble in water, Exceptional handling properties, Low odor, Excellent rinseability, Cleaners & detergents, Paper & textile processing, Paints & coatings, Agro-chemicals, and Metalworking fluids


Tergitol NP 10 is used Nonylphenol Ethoxylate, Cleaning product formulations, Paints and coatings, Emulsion polymerization, and anywhere there is a need for increased surface activity
Tergitol NP 10 is used Coating Auxiliary Agents, Leather Auxiliary Agents, Paper Chemicals, and Petrol.


-Uses of Tergitol NP 10:
∞ Cleaners & degreasers
∞ Agrochemical
∞ Oil in water emulsion
∞ Metalworking fluid
∞ Paint & coatings


-Nonyl phenol ethoxylate types are very effective detergents, emulsifiers, wetting agents and dispersing agents.
Tergitol NP 10s main applications are; in detergents and cleaners and in industrial processes where the above properties are important.
-Used for:
*Cleaners & detergents


-Detergent:
Tergitol NP 10 is used as a non-ionic surface active wetting agent or an emulsifier, depending on the additional oxide ratio and order in this sector.
Tergitol NP 10 is also used as an additive and cleaner in dish soap, shampoo, etc. products.


-Textile:
Tergitol NP 10 is used in the printing part of the products produced in this sector.
-Chemistry:
Tergitol NP 10 is used as a stabilizer in the chemical industry.


-Applications of Tergitol NP 10:
Cleaners and Detergents
Paper & Textile processing
Paints & Coatings
Agrochemical
Metalworking fluid


- Tergitol / Nonylphenol Exthoxylate 10 or often called NP-10 Surfactants can be used as:
*Cleaner & Detergent
*Paint & Coating
*Metalworking fluids
*Agrochemicals


-Applications of Tergitol NP 10:
• Cleaners & detergents
• Paper & textile processing
• Paints & coatings
• Agrochemicals
• Metalworking fluids


-Detergent:
In this sector, Tergitol NP 10 is used as a non-ionic surface active wetting agent or an emulsifier, depending on the additional oxide ratio and the order.
Tergitol NP 10 is also used as an additive and cleaner in dish soap, shampoo, etc. products.


-Application of Tergitol NP 10:
*Dishwashing liquid
*other household use


-Uses of Tergitol NP 10:
*Detergents
*Papers and textiles
*Paints
*Agrochemicals


-Textile:
Tergitol NP 10 is used in the printing part of the products produced in this sector.
-Chemistry:
Tergitol NP 10 is used as a stabilizer in the chemical industry.


-Uses of Tergitol NP 10:
*Excellent detergency
*Outstanding wetting
*Versatile solubility characteristics, soluble in water
*Exceptional handling properties
*Low odor
*Excellent rinseability


-Applications of Tergitol NP 10:
• Cleaners & detergents
• Paper & textile processing
• Paints & coatings
• Agro-chemicals
• Metalworking fluids


-Uses of Tergitol NP 10:
*Cleaning product formulations
*Paints and coatings
*Emulsion polymerization
*Anywhere there is a need for increased surface activity



BENEFITS OF TERGITOL NP 10:
• Excellent detergency
• Outstanding wetting
• Versatile solubility characteristics
• Exceptional handling properties
• Low odor
• Excellent rinseability
• Deliver a combination of economy and performance
• Excellent detergency and wetting
• Good solubilization and emulsification



FUNCTIONS OF TERGITOL NP 10:
*Cleaner & Degreaser
*Emulsifier
*Surfactant



USAGE of TERGITOL NP 10:
Tergitol NP 10 is preferably given to baths as 10-15% solutions.
Tergitol NP 10 is used at 0.2-0.7 g/lt ratios in different applications, bathrooms, depending on operating conditions.
Tergitol NP 10 is recommended to use 0.5-2 g/lt Geosol Tergitol NP 10 together with 5 g/lt sodium sulfate for wool washing.
0.5-2 g/lt Geosol Tergitol NP 10 and 3-5 g/lt soda are used for wool washing in alkaline environments.



SOLUBILITY AND COMPATIBILITY OF TERGITOL NP 10:
• Soluble in water
• Soluble in chlorinated solvents and most polar solvents
• Chemically stable in the presence of dilute acids, bases and salts
• Compatible with soaps, anionic and other nonionic surfactants, and many organic solvents



PRODUCTION AND REACTIONS OF TERGITOL NP 10:
Tergitol NP 10 is produced by printing on elastic fabric with certain thinners as a viscosity reducer.
Tergitol NP 10 is effective in creating a sim effect.
Also, a gilding effect is created thanks to Tergitol NP 10.



PHYSICAL and CHEMICAL PROPERTIES of TERGITOL NP 10:
Physical state: liquid
Color: yellow
Odor: mild
Melting point/freezing point:
Freezing point: 3,8 °C
Initial boiling point and boiling range > 250 °C
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Flash point 247 °C - closed cup - ASTM D 93
Autoignition temperature: No data available
Decomposition temperature: No data available
pH: No data available

Viscosity
Viscosity, kinematic: 237 mm2/s at 25 °C
Viscosity, dynamic: No data available
Water solubility: completely soluble
Partition coefficient: n-octanol/water: log Pow: 2,1 - 3,4
Vapor pressure: < 0,01 hPa at 20 °C
Density: No data available
Relative density: No data available
Relative vapor density: No data available
Particle characteristics: No data available
Explosive properties: No data available
Oxidizing properties: No data available
Other safety information: No data available

Molecular Formula: C17H35O4S.Na
Molar Mass: 765.285
Density: 1.00
Melting Point: 57-58℃
Boling Point: 30℃
Flash Point: >150℃
Water Solubility: 1g/L
Solubility: Miscible with water, with ethanol (96 per cent) and with vegetable oils.
Vapor Presure: 0 Pa at 25℃
Appearance: powder to lump to clear liquid
Color: Almost colorless liquid
Merck: 14,6677
Storage Condition: Sealed in dry,Room Temperature
Refractive Index: 1.4950-1.4990

Appearance: Pale Yellow Liquid
Chemical Composition: Nonylphenol Ethoxylate
Density: 1.060 g/ml
Solubility: Soluble
Viscosity: 237 cPs
pH Value: 6
Appearance Form: liquid
Color: yellow
Odor: mild
Odor Threshold: No data available
pH: No data available
Melting point/freezing point:
Freezing point: 3,8 °C
Initial boiling point and boiling range: > 250 °C
Flash point: 247 °C - closed cup - ASTM D 93
Evaporation rate: No data available
Flammability (solid, gas): No data available

Upper/lower flammability or explosive limits: No data available
Vapor pressure: < 0,01 hPa at 20 °C
Vapor density: No data available
Density: No data available
Relative density: No data available
Water solubility: completely soluble
Partition coefficient: n-octanol/water
log Pow: 2,1 - 3,4
Autoignition temperature: No data available
Decomposition temperature: No data available
Viscosity
Viscosity, kinematic: 237 mm2/s at 25 °C
Viscosity, dynamic: No data available
Explosive properties: No data available
Oxidizing properties: No data available
Other safety information: No data available
Solubility in Water: Soluble (; insoluble in kerosene, xylene soluble in methanol)
Ph: 6.3 (10% sol.)
Viscosity (EBM): C 25 240
Flash point: 94 °C
Molecular formula: C9H19C6H4 ( OCH2CH2) NOH
Melting point: 1 °C
Specific gravity: 1.06

Appearance: liquid
Boiling Point: > 250 °C (> 482 °F)
Color: yellow
Density: 1.06 g/cm3 @ 20 - 25 °C (68 - 77 °F)
Flash Point: 197 °C (387 °F)
Kinematic Viscosity: 237 mm2/s @ 25 °C (77 °F)
Melting Point: 6.1 - 7.8 °C (43.0 - 46.0 °F)
Odor: mild
Partition Coefficient Pow: 2.1 - 3.4
pH: 7 @ 20 - 25 °C (68 - 77 °F)
Relative Density: 1.0622 @ 20 °C (68 °F) Reference Material: (water = 1)
Relative Vapor Density: > 1 @ 20 - 25 °C (68 - 77 °F)
Solubility in Water: completely soluble
Vapor Pressure: < 0.01 mmHg @ 20 °C (68 °F)
Molecular Weight: 199.16406g/mol
Molecular Formula: C7H9N3O4
Compound Is Canonicalized: True
XLogP3-AA: _0.7
Exact Mass: 199.05930578

Monoisotopic Mass: 199.05930578
Complexity: 240
Rotatable Bond Count: 3
Hydrogen Bond Donor Count: 2
Hydrogen Bond Acceptor Count: 4
Topological Polar Surface Area: 114
Heavy Atom Count: 14
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Isotope Atom Count: 0
Covalently-Bonded Unit Count: 1
Appearance: It is a clear viscous liquid.
Chemical structure: It is an alkyl phenol based, nonionic emulsifier system.
Ionic Character: nonionic



FIRST AID MEASURES of TERGITOL NP 10:
-Description of first-aid measures:
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation: fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed:
No data available



ACCIDENTAL RELEASE MEASURES of TERGITOL NP 10:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up with liquid-absorbent material.
Dispose of properly.



FIRE FIGHTING MEASURES of TERGITOL NP 10:
-Extinguishing media:
*Suitable extinguishing media:
Water Foam Carbon dioxide (CO2)
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.



EXPOSURE CONTROLS/PERSONAL PROTECTION of TERGITOL NP 10:
-Control parameters
Ingredients with workplace control parameters
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use safety glasses.
*Body Protection:
Protective clothing.
-Control of environmental exposure:
Do not let product enter drains.



HANDLING and STORAGE of TERGITOL NP 10:
-Conditions for safe storage, including any incompatibilities:
Storage conditions
Tightly closed.



STABILITY and REACTIVITY of TERGITOL NP 10:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .
-Possibility of hazardous reactions:
No data available



SYNONYMS:
Mono(p-nonylphenyl)ether
Polyethylene glycol mono(branched p-nonylphenyl) ether Glycols
polyethylene, mono(p-nonylphenyl)ether
Nonoxynol-9
NP-9
N-9
4-Nonylphenol branched ethoxylated
Poly(oxy,1,2-ethanediyl) alpha-(4-nonylphenyl)-omega-hydroxy- branched
Nonoxynol
NONOXYNOL-1
igepal co-990
igepal co-520
Igepal?CO-890
Igepal?CO-720
Igepal?CO-210
NONOXYNOL-120
Igepal?CO-990
igepal co-890
NONOXYNOL-100
igepal co-720
Tergitol(R) NP-10 (nonionic)
ammonium 2-(4-nonylphenoxy)ethyl sulfate
Polyethylen Glycol Monononylphenol Ether
Polyethylene glycol mono-4-nonylphenyl ether
sodium 1-nonyl-2-(2-nonylphenoxy)benzene sulfate
Nonyl Phenol On Ethoxy Silate
NONYL PHENOL 10EO
Nonylphenol 10EO
2-(p-Nonylphenoxy)ethanol
Nonoxinol
NONOXYNOL
2-(4-nonylphenoxy)ethanol
Nonoxynols
104-35-8
Nonoxynol-7
Nonoxynol 10
nonylphenol ethoxylate
Conceptrol
Egyptol
Intercept
Koromex
Semicid
Emko
Ethanol, 2-(4-nonylphenoxy)-
Encare oval
Today Sponge
Ortho-Creme
Nonoxynol 4
Nonoxynol 6
Liponox NCY
Gynol II
Advantage 24
Nonoxynol 13
Nonoxynol 14
Nonoxynol 15
Nonoxynol 30
Nonoxynol-14
Nonoxynol-18
Nonoxynol-50
Cremophor NP 10
Cremophor NP 14
Imbetin N 7A
Nonoxynol 8.5
4-Nonyl Phenol Monoethoxylate
Emulan 30
Emulan 40
K-Y Plus
NP-9
Akyporox NP 150
Newcol 565
Pannox 110
Pannox 111
Pannox 116
Amway APSA 80
Bion NE 9
Iconol NP 100
Monopol NP 1013
Monopol NP 1060
Hyoxyd X 100
Hyoxyd X 200
Hyoxyd X 400
Nonoxynol 4 [USAN]
Nonoxynol 15 [USAN]
Nonoxynol 30 [USAN]
Ethoxylated p-nonyl phenol
p-Nonylphenol, ethoxylated
PEG-7 Nonyl phenyl ether
NOP 8
PEG-14 Nonyl phenyl ether
PEG-18 Nonyl phenyl ether
PEG-50 Nonyl phenyl ether
2-(4-Nonylphenoxy) ethanol
APSA 80
4-Nonylphenol decaglycol ether
Polyethylene glycol 100 nonyl phenyl ether
Polyoxyethylated-p-nonyl phenol
NOP 17
Polyoxyethylene nonylphenyl ether
HSDB 7217
Amway All Purpose Spray Adjuvant
p-Nonylphenyl polyoxyethylene ether
Nonylphenoxypoly(ethyleneoxy)ethanol
NP 8.5
Decaethylene glycol p-nonylphenyl ether
p-Nonylphenol decaethylene glycol ether
Polyoxyethylene (7) nonyl phenyl ether
p-Nonylphenol-polyethylene glycol adduct
Polyoxyethylene (14) nonyl phenyl ether
Polyoxyethylene (18) nonyl phenyl ether
Polyoxyethylene (50) nonyl phenyl ether
Nonoxynol 4 (USAN)
Poly(oxy-1,2-ethanediyl), alpha-(4-nonylphenyl)-omega-hydroxy-
Polyethylene glycol (7) nonyl phenyl ether
Nonoxynol 15 (USAN)
Nonoxynol 30 (USAN)
Decaethylene glycol mono(p-nonylphenyl) ether
N 100
Polyethylene glycol (14) nonyl phenyl ether
Polyethylene glycol (18) nonyl phenyl ether
Polyethylene glycol (50) nonyl phenyl ether
Polyethylene glycol mono(p-nonylphenyl) ether
Glycols, polyethylene, mono(p-nonylphenyl) ether
alpha-(p-Nonylphenyl)-omega-hydroxydeca(oxyethylene)
alpha-(p-Nonylphenyl)-omega-hydroxynona(oxyethylene)
alpha-(p-Nonylphenyl)-omega-hydroxypoly(oxyethylene)
Phenol, p-nonyl-, monoether with polyethylene glycol
alpha-(p-Nonylphenyl)-omega-hydroxytetra(oxyethylene)
4-n-Nonylphenol-mono-ethoxylate
alpha-(p-Nonylphenyl)-omega-hydroxypentadeca(oxyethylene)
alpha-(p-Nonylphenyl)-omega-hydroxytriaconta(oxyethylene)
Nonoxinols
C18H30O2
Poly(oxy-1,2-ethanediyl), alpha-(4-nonylphenyl)-omega-hydroxy
Emulgen 911
Emulgin 913
Nonylphenoxypolyethoxyethanols
127087-87-0
Nonoxinol [INN]
Delfen (TN)
Nonoxynol 9 (USP)
616.82 average
Nonoxynol 9 [USAN]
OSD2GAP7HY
UNII-OSD2GAP7HY
NONOXINOL 15
NONOXINOL 30
11096-42-7
PEG-2 Nonyl phenyl ether
UNII-1F75BOT2DZ
UNII-60ZT1XYO5N
UNII-HR8408HWGL
1F75BOT2DZ
60ZT1XYO5N
HR8408HWGL
Nonoxynol 9 [USAN:USP]
UNII-4867M0AEJI
UNII-ED8J5T817W
UNII-JJX07DG188
nonylphenoxy polyethoxy ethanol
SCHEMBL198140
UNII-3X709X44TE
UNII-48Q180SH9T
UNII-5V4827GL2O
UNII-6FW840C8W9
UNII-6NR43D77O6
UNII-8869L92EOT
UNII-E9AU396Z19
UNII-K7O76887AP
UNII-KND68343W4
UNII-M693M091RR
4867M0AEJI
CCRIS 8448
ED8J5T817W
JJX07DG188
CHEMBL1797943
DTXSID4058601
UNII-A906T4D368
UNII-BK168521Q8
(oxyeth-ylene) nonylphenyl ether
CHEBI:53774
CTK5H8961
KUXGUCNZFCVULO-UHFFFAOYSA-N
3X709X44TE
48Q180SH9T
5V4827GL2O
6FW840C8W9
6NR43D77O6
8869L92EOT
E9AU396Z19
K7O76887AP
KND68343W4
M693M091RR
KS-000014UE
ZINC1850508
C33H60O10
AKOS026749958
A906T4D368
BK168521Q8
Polyoxyethylene (2) nonyl phenyl ether
96827-63-3
LS-72940
FT-0673037
X7302
Polyethylene glycol mono(4-nonylphenyl) ether
D06490
alpha-(4-nonylphenyl)-omega-hydroxypoly(oxyethylene)
J-001157
4-Nonylphenol-mono-ethoxylate 10 microg/mL in Acetone
4-Nonylphenol-mono-ethoxylate 10 microg/mL in Methanol
1-(2-Hydroxyethyl)-5-nitro-1H-pyrrole-2-carboxamide
Np-10
Np-10 (Nonylphenol ethoxylate)
1-(2-hydroxyethyl)-5-nitropyrrole-2-carboxamide
1H-Pyrrole-2-carboxamide, 1-(2-hydroxyethyl)-5-nitro-
1-(2-Hydroxyethyl)-2-carbamoyl-5-nitropyrrol
1-(2-Hydroxyethyl)-5-nitro-1H-pyrrole-2-carboxamide
1-(2-hydroxyethyl)-5-nitropyrrole-2-carboxamide
1H-Pyrrole-2-carboxamide, 1-(2-hydroxyethyl)-5-nitro-
NP 10
NP 10 (Pharmaceutical)
Np-10 (Nonylphenol ethoxylate)
Pyrrole-2-carboxamide,1-(2-hydroxyethyl)-5-nitro


TERGITOL NP 30
CAS Number: 127087-87-0,25322-68-3

TERGITOL NP 30 through NP-70, 70%:
•Highly water-soluble emulsifiers and stabilizers.
•Effective at high temperatures

TERGITOL NP 30 is a nonylphenol ethoxylate.
TERGITOL NP 30 acts as a dispersant, wetting agent, emulsifier & stabilizer.
TERGITOL NP 30 is alkyl phenol ethoxylate-based and is highly water soluble.
TERGITOL NP 30 is used in paints & coatings.

Nonionic surfactant for use in wetting agents and stabilizers, emulsifiers and dispersants, cleaners and detergents, and agrochemicals.
TERGITOL NP 30 is highly water soluble, low odor, and suitability for use at higher temperatures​​​​​.

Chemical Description of TERGITOL NP 30:
Name: Nonylphenol Ethoxylate
Surfactant Type: Nonionic

Benefits of TERGITOL NP 30:
-Highly water-soluble emulsifier & stabilizer
-Effective at high temperatures
-Excellent detergency
-Versatile solubility characteristics
-Low odor
-Outstanding wetting

Applications of TERGITOL NP 30:
-Wetting agents & stabilizers
-Emulsifiers & dispersants
-Agrochemicals

Uses of TERGITOL NP 30:
-Cleaning product formulations
-Paints and coatings
-Emulsion polymerization
-Anywhere there is a need for increased surface activity

Benefits of TERGITOL NP 30:
-Deliver a combination of economy and performance
-Excellent detergency and wetting
-Good solubilization and emulsification

Typical Physical Properties of TERGITOL NP 30:
Actives, wt% 100
Cloud Point (1) >100
HLB (2) 17.1
Moles EO 30
Pour Point(3) 37
Apperance Waxy white solid
Viscosity at 25°C (77°F), cP Solid
Density at 20°C (68°F), g/mL Solid
Flash Pt, Closed Cup, ASTM D93 None

Description of TERGITOL NP 30:
TERGITOL NP-30 is a non-ionic surfactant.
TERGITOL NP 30 is highly water-soluble emulsifier & stabilizer.
TERGITOL NP 30 is used in wetting agents & stabilizers, emulsifiers & dispersants, agrochemicals, cleaners & detergents.

Chemical Properties of TERGITOL NP 30:
Appearance : Waxy White Solid
Chemical Composition: Nonylphenol Ethoxylate
Solubility: Soluble

Solubility and Compatibility of TERGITOL NP 30:
-Soluble in water
-Soluble in chlorinated solvents and most polar solvents
-Chemically stable in the presence of dilute acids, bases and salts
-Compatible with soaps, anionic and other nonionic surfactants, and many organic solvents

Product Description of TERGITOL NP 30:
Dow sells NPE-based surfactants under trade names that include but are not limited to TERGITOL NP nonionic surfactants and the product name TRITON N-57 nonionic surfactant.

TERGITOL NP Surfactants:
TERGITOL NP surfactants can be either solids or liquids depending on their molecular weight and the use temperature.
The solids are white to yellow in color, and the liquids are clear to slightly cloudy.
Lower molecular weight nonylphenol ethoxylates products tend to be liquids and higher molecular weight products tend to be solids, unless diluted with water.
Because TERGITOL NP surfactants vary in molecular weight (and the number of ether linkages along the chain), the products have different solubilities.

TERGITOL NP-4 and NP-6 surfactants are oil soluble, and can solubilize kerosene and aliphatic hydrocarbons.
TERGITOL NP-7 through NP-15 surfactants are miscible with chlorinated and aromatic solvents and soluble in water.
TERGITOL NP-30 through NP-70 surfactants are highly water soluble.
Some products may form gels in certain solvents or under certain conditions

Overview of NP 30;
Nonylphenol (NP) and Nonylphenol Ethoxylates (NPE) are the most widely used members of the larger alkylphenol and alkylphenol ethoxylate family of non-ionic surfactants.
They are produced in large volumes, with uses that lead to widespread release to the aquatic environment.

NP is persistent in the aquatic environment, moderately bioaccumulative, and extremely toxic to aquatic organisms.
NP's main use is in the manufacture of NPEs. NPEs are used in a wide variety of industrial applications and consumer products.
NPEs, though less toxic than NP, are also highly toxic to aquatic organisms, and in the environment degrade to more environmentally persistent NP.
NP has also been detected in human breast milk, blood, and urine and is associated with reproductive and developmental effects in fish.

NPEs were once commonly used in household laundry detergents.
EPA and the detergent manufacturers have cooperated to eliminate this use.
However, NPEs are still widely used in large quantities in industrial laundry detergents and have some additional uses that lead to releases to water.

Typical Properties of NP 30;
Active Content: 100 (Wt%)
Cloud Point: >100
HLB: 17.1
Moles EO: 30
Pour Point: 37
Appearance: Waxy White Solid
Viscosity: Solid (25°C (77°F), Cp)
Viscosity: Solid (25°C (77°F), Cp)
Density: Solid G/Ml (20°C)
Density: Solid G/Ml (20°C)
Flash Point: None (Flash Pt, Closed Cup, Astm D93)
Flash Point: None (Flash Pt, Closed Cup, Astm D93)

Chemical Description of NP 30;
NP is a clear to pale yellow viscous liquid at room temperature with moderate water solubility and moderate vapor pressure.
NPEs are clear to light orange oily liquids or waxy solids, and are considered to be chemically stable and unreactive.
NPEs are manufactured by reacting NP with ethylene oxide (EO) under basic conditions.
The degree of ethoxylation depends on the molar ratio of NP to EO.
NPEs are hydrophilic ("water-attracting") at one end of the molecule and hydrophobic ("water-avoiding") at the opposite end.
The hydrophilic "head" attracts water and the hydrophobic "tail" attracts poorly soluble substances, such as oils and greases.

In industry, alkylphenol ethoxylates (APEO) are widely used as non-ionic surfactants, nonylphenol
ethoxylate (NPEO) and octylphenol ethoxylate being the main representatives of this group.

Alkylphenol ethoxylates are widely used as :
. washing and cleaning agents
. emulsifiers in emulsion polymerizations
. dispersion and wetting agents
. adjuvants in drilling processes
. adjuvants in dyeing mills
. textile adjuvants used in bleaching, spinning, finishing, degreasing, and defoaming
. pesticide formulations
. softener

Application of NP 30;
Nonylphenol ethoxylates (NPEs) are surfactants that have been in commerce for over 50 years.
Products containing NPEs are used in many sectors, including textile processing, pulp and paper processing, paints, resins and protective coatings, oil and gas recovery, steel manufacturing, pest control products and power generation.
A variety of cleaning products, degreasers and detergents are also available for institutional and domestic use.
These products have numerous applications, including controlling deposits on machinery, cleaning equipment, and scouring fibres; as wetting and de-wetting agents; in dyeing and machine felt cleaning and conditioning; and in product finishing.
NPEs have also been used in a wide range of consumer products, including cosmetics, cleaners, and paints.
The primary use of NP is as an intermediate in the manufacture of NPEs.

NP may also be reacted to form tris(4-nonyl-phenyl) phosphite (TNPP), an antioxidant used to protect polymers such as rubber, vinyl, polyolefins, and polystyrenics.
TNPP is also used as a stabilizer in plastic food packaging.
Although it does contain residual NP, TNPP has been approved for this use by the Food and Drug Administration (FDA).
FDA also lists NP as an indirect food contact substance.
Barium and calcium salts of NP are used as heat stabilizers for polyvinyl chloride (PVC).
NP is also used as a catalytic diluent in epoxy resins.

Wetting agents & stabilizers:
Emulsifiers & dispersants
Agrochemicals

Environmental Health Effects of NP 30;
NPE is very toxic to fish and other water-dwelling organisms and is considered a hormone disrupting substance, mimicking estrogen.
TERGITOL NP 30 degrades relatively readily in the environment to form the even more harmful nonylphenol (NP).
Nonylphenol is not readily biodegradable and take months or even longer to degrade in surface waters or in soils and sediments (where it tends to be immobilized).

Non-biological degradation is negligible.
Bioconcentration and bioaccumulation is significant in water-dwelling organisms and birds, where it has been found in internal organs at between 10 and 1000 times greater than the surrounding environment.
Nonylphenols are not broken down effectively in sewage treatment plants.
Because of the bioaccumulation and persistence of nonylphenol (the primary degradation product of NPE), it is possible that it could be transported significant distances, and so have a potentially global reach in its effects.

Precautions of NP 30;
Human exposure to NP and NPEs is thought to come primarily from cleaners, detergents, agricultural and indoor pesticides, cosmetics, hair dyes, and aquatic foods like shellfish and fish.

Advantages of NP 30;
Effective at high temperatures
Highly water-soluble emulsifier & stabilizer
Excellent detergency
Versatile solubility characteristics
Low odor
Outstanding wetting

Benefits of NP 30;
• Effective at high temperatures
• Highly water-soluble emulsifier & stabilizer
• Excellent detergency
• Versatile solubility characteristics
• Low odor
• Outstanding wetting

Storage of NP 30;
Recommended storage temperature for these products is within a range 10 to 35

Solubility and Compatibility of NP 30;
• Soluble in water
• Soluble in chlorinated solvents and most polar solvents
• Chemically stable in the presence of dilute acids, bases and salts
• Compatible with soaps, anionic and other nonionic surfactants, and many organic solvents

CAS Number: 127087-87-0,25322-68-3
Grade: Technical
Appearance: liquid
Boiling Point: 120 °C (248 °F)
Color: yellow
Evaporation Rate: < 0.7
Flash Point: Not applicable
Freezing Point: -15 °C (5 °F)
Kinematic Viscosity: 817 mm2/s @ 25 °C (77 °F)
Odor: mild
pH: 8.2 @ 20 - 25 °C (68 - 77 °F)
Recommended Use: Surfactant
Relative Density: 1.098 @ 25 °C (77 °F) Reference Material: (water = 1)
Relative Vapor Density: 0.6
Solubility in Water: completely soluble
Vapor Pressure: < 0.01 mmHg @ 20 °C (68 °F)

NP-30 (% 70)
NP-30 (70 %)
NP 30 70 % in Water

Composition: 70 % Nonylphenolpolyglycolether with 30 Mol EO
NP 30 70 %
70 % nonyl phenol ethoxylate, NP-30 EO
70 % Nonylphenol 30 EO

Chemical characterization
70 % nonyl phenol poly glycol ether 30 Ethoxylate
CAS number : 9016-45-9

NP 30 is a unique nonionic wetting agent and emulsifier for aqueous systems.
NP 30 has pigment wetting and stabilising properties in the paint industry.

NP 30 is used in polymerization of vinyl acetate together with other vinyl esters, acrylates, vinyl chloride and ethylene, for acrylic and styrene / acrylic dispersions and for butadiene / styrene latex.
The use of NP 30 reduces coagulation and improves electrolyte resistance and freeze/thaw stability.
NP 30 is added either during or after polymerization.
NP 30 is also used in pigment preparations,paints and coatings as dispersing and wetting agent.

Composition of TERGITOL NP 30:
70 % Nonylphenol polyethylene glycol ether with 30 mole ethylene oxide
Product properties *)
Active substance content: about 70 %

Appearance of TERGITOL NP 30:
at 5°C: white paste
at 10°C: cloudy inhomogeneous liquid
at 15°C: clear, colourless liquid
at 25°C: clear, colourless liquid
at 40°C: clear, colourless liquid
pH value (DIN EN 1262), 1% in water: 6 - 8
Solubility at 25 °C: soluble in water

HLB value: about 17
Density at 25 °C: approx. 1.09 g/cm³
Viscosity at 25 °C (Brookfield DV II, Spindle 4): about 990 mPas
Flash point (DIN/ISO 2592): > 100 °C

Uses of TERGITOL NP 30:
70 % NP 30 is used in the following applications:
as emulsifier in emulsion polymerization
as wax emulsifier
for pigment pastes
as stabilizer in paints and coatings.

NP-30 (70%) Surfactant Nonionic surfactant for use in wetting agents and stabilizers, cleaners and detergents, emulsifiers and dispersants, and agrochemicals; with versatile solubility, low odor, and suitability for use at higher temperatures​​​.
NP-30 (70%) can also be used in oilfield drilling and production formulations.

Uses of NP-30 (70%) :
Cleaning product formulations
Paints and coatings
Emulsion polymerization
Anywhere there is a need for increased surface activity

Benefits:
NP-30 (70%) delivers a combination of economy and performance
NP-30 (70%) has excellent detergency and wetting properties
NP-30 (70%) has good solubilization and emulsification properties

Further NP grades:
NP 4
NP 6
NP 8
NP 10
NP 11
NP 13
NP 15
NP 23
NP 30
NP 100

Characteristics of TERGITOL NP 30:
Both the chemical and processing characteristics of NP 30 depend largely on the ratio of hydrophobic molecules (nonylphenol) to the hydrophilic – i.e. water solubilizing – polyglycolether chain (number of ethylene oxidemolecules).

Compatibility of TERGITOL NP 30:
Being nonionic, NP 30 is compatible with all other nonionic, anionic or cationic substances.

Electrolytes, for example neutral salts, alkalis and – to a lesser extent – acids, reduce the water solubility of NP 30 and may lead to their salting out, especially at high concentrations and temperatures.
Decomposition of the products does not occur.
For solutions containing high amounts of electrolytes, NP 30 with long polyglycolether chains may be used since, being more hydrophilic, they are not so easily salted out.

Stability of TERGITOL NP 30:
NP 30 has excellent resistance to compounds that cause hard water, to metal salts, including those of heavy metals, acids, alkalis, reductive agents and oxidative agents based on peroxide.

Nonylphenol 30 EO is a unique nonionic wetting agent and emulsifier for aqueous systems.
Nonylphenol 30 EO has pigment wetting and stabilising properties in the paint industry.

Nonylphenol 30 EO is used in polymerization of vinyl acetate together with other vinyl esters, acrylates, vinyl chloride and ethylene, for acrylic and styrene / acrylic dispersions and for butadiene / styrene latex.
The use of Nonylphenol 30 EO reduces coagulation and improves electrolyte resistance and freeze/thaw stability.
Nonylphenol 30 EO is added either during or after polymerization.
Nonylphenol 30 EO is also used in pigment preparations,paints and coatings as dispersing and wetting agent.

SURFACTANT NP-30 70%
Agrochemicals, Emulsifier, Excellent rinse ability.
Applications: Cleaners & detergents, Exceptional handling properties, Low odor, Metalworking fluids, Multi-purpose surfactant, Paints & coatings, Paper & textile processing

Tergitol NP-30(70%) is a non-ionic surfactant.
TERGITOL NP 30 is highly water-soluble emulsifier & stabilizer.
TERGITOL NP 30 is used in wetting agents & stabilizers, emulsifiers & dispersants, agrochemicals, cleaners & detergents.

Names:
-CAS No. 127087-87-0
-Nonylphenol ethoxylate
-Alkylaryl polyether alcohols
-Poly(oxy-1,2-ethanediyl)
-Polyethoxylate
-Polyoxyethylene nonylphenol
-Nonoxynol
-NPE
-Alcohol ethoxylates
-Nonylphenoxypolyethoxyethanol
-Nonylphenyl polyethylene glycol
-Nonylphenol polyoxyethylene ether NP surfactants
-α-(4-Nonylphenyl)-ω-hydroxy-, branched
-Polyethylene glycol nonyl phenyl ether
-Polyoxyethylene nonyl phenyl ether
-DOW nonylphenol ethoxylate surfactants
-TERGITOL NP nonionic surfactants

Nonylphenol ethoxylates (NPEs) are nonionic surfactants and are a category of alkylphenol ethoxylates.
NPE-based surfactants are used in industrial cleaning products, processes, agricultural formulations and paints.
Dow sells NPE-based surfactants under trade names that include but are not limited to TERGITOL NP nonionic surfactants or the product name TRITON N-57 nonionic surfactant.
The TERGITOL NP product family has various molecular weights and properties.
The properties of a particular NPE depend upon the number of ethoxylate groups that are attached (the number of ether linkages along the chain), which can vary from just a few up to about one hundred.

Other Tergitol NP products:
TRITON N-57 Surfactants
TRITON N-57 is a colorless liquid and is not diluted with water.

Product Uses of TERGITOL NP 30:
Nonylphenol ethoxylates are primarily used in industrial applications.
The market applications for these products fall into the four basic categories listed below:
-Industrial – agriculture, leather processing, metal working, oil field, pulp and paper, textile processing, water treatment
-Emulsions and coatings – paints and coatings, emulsion polymerization, adhesives
-Industrial and institutional cleaning – hard-surface cleaners, circuit-board cleaners, industrial laundry/dry-cleaning detergents, metal cleaning

Nonylphenoxypoly(ethyleneoxy)ethanol
α-(Nonylphenyl)-ω-hydroxypoly(oxy-1,2-ethanediyl)
Nanophenoxypoly(ethyleneoxy)ethanol
(Nonylphenoxy)polyethylene oxide
A 730
A 730 (surfactant)
Ace Clean AD
Adekanol NP 1000
Adekatol NP
Adekatol NP 1000
Adekatol NP 1100
Adekatol NP 638
Adekatol NP 650
Adekatol NP 660
Adekatol NP 675
Adekatol NP 683
Adekatol NP 686
Adekatol NP 690
Adekatol NP 700
Adekatol NP 710
Adekatol NP 720
Adekatol NP 760
Adekatol NP 900
Afilan CVH; Agral
Agral 600
Agral 90
Agral LN
Agral Plus
Agral R
Tensioactiv NF 10
Tensioactiv NF 6
Tenzilin 080
Tenzilin FN 65
Tergitol 9.5
Tergitol N 4
Tergitol N 8
Tergitol NO 10
Tergitol NP
Tergitol NP 10
Tergitol NP 101
Tergitol NP 12
Tergitol NP 13
Tergitol NP 14
Tergitol NP 15
Tergitol NP 27
Tergitol NP 30
Tergitol NP 33
Tergitol
TERGITOL NP 6
DESCRIPTION:

TERGITOL NP 6 is Nonionic surfactant for use in cleaners and degreasers, dry cleaning, agrochemicals, and adhesives; functioning as a wetting agent, stabilizer, an excellent emulsifier, and couples detergent range nonionics into hydrocarbon systems.
TERGITOL NP 6 can also be used in oilfield drilling and production formulations.
TERGITOL NP 6 is Surfactant for in-process cleaning.

CAS Number, 127087-87-0


USES OF TERGITOL NP 6:
TERGITOL NP 6 is used in Cleaning product formulations
TERGITOL NP 6 is used in Paints and coatings
TERGITOL NP 6 is used in Emulsion polymerization
TERGITOL NP 6 is used in Anywhere there is a need for increased surface activity


BENEFITS OF TERGITOL NP 6:
TERGITOL NP 6 Deliver a combination of economy and performance
TERGITOL NP 6 has Excellent detergency and wetting
TERGITOL NP 6 has Good solubilization and emulsification


TERGITOL NP 6 is Nonionic surfactant for use in cleaners and degreasers, dry cleaning, agrochemicals, and adhesives; functioning as a wetting agent, stabilizer, an excellent emulsifier, and couples detergent range non-ionics into hydrocarbon systems.
TERGITOL NP 6 can also be used in oilfield drilling and production formulations.
TERGITOL NP 6 is Surfactant for in-process cleaning.




CHEMICAL AND PHYSICAL PROPERTIES OF TERGITOL NP 6:
APE Based Yes
Biobased Raw Material No
Bleach Stable? Not Recommended
Chemistry Alkylphenol Ethoxylate (APE)
CleanGredients? No
Cloud Point (1 wt% actives aqueous solution) Insoluble °C
CMC (25°C) Insoluble PPM
Foam Height - Initial (0.1 wt% actives) Insoluble mm
Form Liquid
HLB 10.9
Moles EO 6
Performance Benefits Detergent / Cleaner, Emulsifier, Wetting Agent
Pour Point -26 °C
Readily Biodegradable Materials No
Grade
Technical
Form
Liquid
Appearance
liquid
Boiling Point
200 °C (392 °F)
California Prop 65
WARNING! This product can expose you to chemicals including 1,4-Dioxane, Ethylene oxide, which is/are known to the State of California to cause cancer, and Ethylene oxide, which is/are known
Color
yellow, Light
Evaporation Rate
< 0.01
Flash Point
218 - 221.1 °C (424 - 430.0 °F)
Kinematic Viscosity
95 - 207 mm2/s
Odor
slight, mild
Partition Coefficient
Pow: 3.7 - 4.5
pH
7.0 - 7.3
Relative Density
1.039 - 1.04 @ 20 °C (68 °F) Reference Material: (water = 1)
Relative Vapor Density
> 1 @ 20 - 25 °C (68 - 77 °F)
Solubility in Water
dispersible
Vapor Pressure
< 1 mmHg @ 20 °C (68 °F)
Name : Nonylphenol Ethoxylate
CAS number : 127087-87-0
Type : Nonionic Surfactant
REFERENCE NAME, TERGITOL NP-6 SURFACTANT
PHYSICAL STATE, Liquid
PRESENTATION, Liquid
GRADE, Industrial
GRAVITY DENSITY, 1,039
TOXIC, Yes
HAZARDOUS, Yes
FLAMMABLE, No
PACK ITEM DESC US, DRUM, PL, 200 L
PACKAGE CODE, P121G0


SOLUBILITY AND COMPATIBILITY OF TERGITOL NP 6:
TERGITOL NP 6 is Dispersible in water
TERGITOL NP 6 is Soluble in chlorinated solvents and most polar and non-polar solvents and oils
TERGITOL NP 6 is Chemically stable in the presence of dilute acids, bases and salts
TERGITOL NP 6 is Compatible with soaps, anionic and other nonionic surfactants, and many organic solvents



SAFETY INFORMATION ABOUT TERGITOL NP 6:
First aid measures:
Description of first aid measures:
General advice:
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Move out of dangerous area:

If inhaled:
If breathed in, move person into fresh air.
If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact:
Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Consult a physician.

In case of eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Continue rinsing eyes during transport to hospital.

If swallowed:
Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.
Rinse mouth with water.
Consult a physician.

Firefighting measures:
Extinguishing media:
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas

Advice for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.
Accidental release measures:
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment.

Avoid breathing vapours, mist or gas.
Evacuate personnel to safe areas.

Environmental precautions:
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up:
Soak up with inert absorbent material and dispose of as hazardous waste.
Keep in suitable, closed containers for disposal.

Handling and storage:
Precautions for safe handling:
Avoid inhalation of vapour or mist.

Conditions for safe storage, including any incompatibilities:
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials

Exposure controls/personal protection:
Control parameters:
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls:
Appropriate engineering controls:
Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.

Personal protective equipment:
Eye/face protection:
Tightly fitting safety goggles.
Faceshield (8-inch minimum).
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection:
Handle with gloves.
Gloves must be inspected prior to use.
Use proper glove
removal technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.

Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
It should not be construed as offering an approval for any specific use scenario.

Body Protection:
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection:
Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.

If the respirator is the sole means of protection, use a full-face supplied air respirator.
Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Stability and reactivity:
Chemical stability:
Stable under recommended storage conditions.
Incompatible materials:
Strong oxidizing agents:
Hazardous decomposition products:
Hazardous decomposition products formed under fire conditions.
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas.

Disposal considerations:
Waste treatment methods:
Product:
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging:
Dispose of as unused product.



TERGITOL NP-10
DESCRIPTION:
TERGITOL NP-10 can also be used in oilfield drilling and production formulations.

CAS Number: 127087-87-0
Name: Nonylphenol Ethoxylate


TYPICAL PHYSICAL PROPERTIES OF TERGITOL NP-10:
Actives, wt% 100
Cloud Point (1) 63
HLB (2) 13.2
Moles EO 10
Pour Point(3) 6
Appearance Pale yellow liquid
pH, 1% aq solution 6
Viscosity at 25°C (77°F), cP 237
Density at 20°C (68°F), g/mL 1.060
Flash Pt, Closed Cup, ASTM D93 197°C 387°F
CMC(4) 55
Surface Tension(5) 33
Foam Height(6) 115/110
Draves 20 sec wetting conc, wt%
at 25°C (77°F): 0.06

at 60°C (122°F): 0.04
Grade:Technical
Appearance:liquid
Boiling Point:> 250 °C (> 482 °F)
Color:yellow
Density:1.06 g/cm3 @ 20 - 25 °C (68 - 77 °F)
Flash Point:197 °C (387 °F)
Kinematic Viscosity:237 mm2/s @ 25 °C (77 °F)
Melting Point: 6.1 - 7.8 °C (43.0 - 46.0 °F)
Odor: mild
Partition Coefficient
Pow: 2.1 - 3.4
pH:7 @ 20 - 25 °C (68 - 77 °F)
Relative Density: 1.0622 @ 20 °C (68 °F) Reference Material: (water = 1)
Relative Vapor Density: > 1 @ 20 - 25 °C (68 - 77 °F)
Solubility in Water: completely soluble
Vapor Pressure: < 0.01 mmHg @ 20 °C (68 °F)
Molecular Formula:C15H24O•(C2H4O)n
CMC: 0.0055%
Cloud Point: 63°C
HLB: 13.2
Solubility: Chloroform (Slightly), Methanol (Slightly)
Storage: RT

SOLUBILITY AND COMPATIBILITY OF TERGITOL NP-10:
TERGITOL NP-10 is Soluble in water
TERGITOL NP-10 is Soluble in chlorinated solvents and most polar solvents

TERGITOL NP-10 is Chemically stable in the presence of dilute acids, bases and salts
TERGITOL NP-10 is Compatible with soaps, anionic and other nonionic surfactants, and many organic
solvents

BENEFITS OF TERGITOL NP-10:
TERGITOL NP-10 Delivers a combination of economy and performance
TERGITOL NP-10 has Excellent detergency and wetting
TERGITOL NP-10 has Good solubilization and emulsification

TERGITOL NP-10 has Excellent detergency
TERGITOL NP-10 has Outstanding wetting
TERGITOL NP-10 has Versatile solubility characteristics

TERGITOL NP-10 has Exceptional handling properties
TERGITOL NP-10 has Low odor
TERGITOL NP-10 has Excellent rinseability



USES OF TERGITOL NP-10:

TERGITOL NP-10 is used in Cleaning product formulations
TERGITOL NP-10 is used in Paints and coatings
TERGITOL NP-10 is used in Emulsion polymerization

TERGITOL NP-10 is used in Anywhere there is a need for increased surface activity
TERGITOL NP-10 is used in Nonionic surfactant for use in paints and coatings, paper and textile processing, cleaners and detergents, agrochemicals, and metalworking fluids; with excellent detergency, outstanding wetting, versatile solubility characteristics, and exceptional handling properties.

TERGITOL NP-10 is Used as cleaners & detergents, degreasers, paper & textile processing, paints, prewash spotters, agrochemicals, metalworking fluids, oil field chemicals.
TERGITOL NP-10 Possesses good detergency performance.

SAFETY INFORMATION ABOUT TERGITOL NP-10:
First aid measures:
Description of first aid measures:
General advice:
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Move out of dangerous area:

If inhaled:
If breathed in, move person into fresh air.
If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact:
Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Consult a physician.

In case of eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Continue rinsing eyes during transport to hospital.

If swallowed:
Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.
Rinse mouth with water.
Consult a physician.

Firefighting measures:
Extinguishing media:
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas

Advice for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.
Accidental release measures:
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment.

Avoid breathing vapours, mist or gas.
Evacuate personnel to safe areas.

Environmental precautions:
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up:
Soak up with inert absorbent material and dispose of as hazardous waste.
Keep in suitable, closed containers for disposal.

Handling and storage:
Precautions for safe handling:
Avoid inhalation of vapour or mist.

Conditions for safe storage, including any incompatibilities:
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials

Exposure controls/personal protection:
Control parameters:
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls:
Appropriate engineering controls:
Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.

Personal protective equipment:
Eye/face protection:
Tightly fitting safety goggles.
Faceshield (8-inch minimum).
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection:
Handle with gloves.
Gloves must be inspected prior to use.
Use proper glove
removal technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.

Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
It should not be construed as offering an approval for any specific use scenario.

Body Protection:
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection:
Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.

If the respirator is the sole means of protection, use a full-face supplied air respirator.
Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Stability and reactivity:
Chemical stability:
Stable under recommended storage conditions.
Incompatible materials:
Strong oxidizing agents:
Hazardous decomposition products:
Hazardous decomposition products formed under fire conditions.
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas.

Disposal considerations:
Waste treatment methods:
Product:
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging:
Dispose of as unused product.


SYNONYMS OF TERGITOL NP-10:
4-Nonylphenol branched ethoxylated
Poly(oxy,1,2-ethanediyl) alpha-(4-nonylphenyl)-omega-hydroxy- branched



TERGITOL NP-4

Tergitol NP-4 is a nonionic surfactant that belongs to the family of alkylphenol ethoxylates.
Specifically, it is a type of nonylphenol ethoxylate.
Nonionic surfactants are compounds that do not ionize in water and are commonly used for their wetting, emulsifying, dispersing, and detergent properties.


Nonylphenol ethoxylate, NP-4, Alkylphenol ethoxylate, Ethoxylated nonylphenol, Ethylene oxide adduct of nonylphenol, NPE-4, Nonionic surfactant, EO compound, Nonylphenol polyethylene glycol ether, Alkyl polyoxyethylene ether, Nonionic detergent ingredient, Wetting agent, Emulsifying agent, Dispersing agent, NP series surfactant, Alkylphenol ethylene oxide adduct, Alkyl polyethylene oxide surfactant, Nonoxynol-4, Alkylphenol polyglycol ether, Alkylphenol EO surfactant, EO chain nonionic surfactant



APPLICATIONS


Tergitol NP-4 is commonly used in agricultural formulations, aiding in the even distribution of pesticides and herbicides on crops.
In the textile industry, NP-4 serves as a wetting agent, facilitating dyeing processes by improving fiber penetration.
Tergitol NP-4 is employed in the production of industrial and household cleaning products for its emulsifying and cleaning properties.

Tergitol NP-4 is utilized in the formulation of liquid detergents, contributing to the removal of oils and stains from surfaces.
Tergitol NP-4 finds application in the preparation of emulsifiable concentrates for agrochemicals, enhancing dispersion in water.

Tergitol NP-4 is part of the formulation of metalworking fluids, where it contributes to lubrication and cooling during machining processes.
In the oil and gas industry, it is used in drilling fluids to assist in emulsification and fluid stability.
Tergitol NP-4 plays a role in the formulation of adhesives and sealants, improving emulsion stability and performance.
Tergitol NP-4 is applied in the production of ink and coating formulations to enhance dispersion and stability.

In the textile and leather industries, NP-4 contributes to the wetting and dispersing of dyes and chemicals.
Tergitol NP-4 is used in the formulation of crop protection products, aiding in the even distribution and adherence of active ingredients.

Tergitol NP-4 finds application in the production of asphalt release agents, facilitating the release of asphalt from surfaces.
Tergitol NP-4 contributes to the formulation of foaming agents, enhancing foam stability in various industrial processes.

Tergitol NP-4 is employed in the preparation of concrete additives and admixtures, aiding in dispersion and workability.
Tergitol NP-4 is applied in the formulation of inkjet inks, contributing to color dispersion and stability.
Tergitol NP-4 is used in the production of antifoaming agents for industrial processes where foam control is essential.

Tergitol NP-4 plays a role in the formulation of metal cleaners and degreasers, contributing to the removal of oils and contaminants.
In the agricultural sector, NP-4 is utilized in the formulation of foliar fertilizers for improved nutrient absorption.
Tergitol NP-4 is part of the formulation of cutting fluids for metalworking processes, aiding in lubrication and cooling.

Tergitol NP-4 is applied in the preparation of concrete release agents for mold release in construction applications.
Tergitol NP-4 is used in the production of coolants for automotive and industrial applications.
Tergitol NP-4 finds application in the formulation of fluxes for soldering and brazing applications in the electronics industry.

Tergitol NP-4 contributes to the preparation of industrial defoamers, assisting in foam control in various processes.
Tergitol NP-4 is applied in the production of polymer dispersions for coatings, adhesives, and sealants.
The surfactant is employed in the formulation of windshield washer fluids, improving cleaning performance.

Tergitol NP-4 is utilized in the formulation of ink and paint removers, assisting in the emulsification and removal of coatings.
In the cosmetics industry, NP-4 finds application in the formulation of creams and lotions for its emulsifying and dispersing properties.
Tergitol NP-4 is employed in the production of leather processing chemicals, contributing to wetting and dispersing during tanning processes.

Tergitol NP-4 is used in the formulation of coolants for metalworking operations, aiding in lubrication and heat dissipation.
Tergitol NP-4 is applied in the preparation of cutting fluids, enhancing their wetting and cooling capabilities during machining.

Tergitol NP-4 is part of the formulation of inkjet printing inks, ensuring proper dispersion and stability of pigments.
In the manufacturing of construction chemicals, NP-4 contributes to the dispersion and stability of various formulations.
Tergitol NP-4 plays a role in the formulation of defoaming agents, helping control foam in industrial processes.

Tergitol NP-4 is employed in the production of asphalt emulsions for road construction, contributing to the stability of the emulsion.
Tergitol NP-4 finds application in the preparation of metal treatment formulations, aiding in wetting and cleaning surfaces.
Tergitol NP-4 is used in the formulation of adjuvants for agricultural chemicals, improving the efficiency of herbicides and pesticides.

In the printing industry, it is applied in the preparation of fountain solutions, enhancing ink and water balance on printing presses.
Tergitol NP-4 is utilized in the production of air fresheners, aiding in the dispersion of fragrances in various formulations.
Tergitol NP-4 finds application in the formulation of rust preventatives, contributing to metal protection against corrosion.
Tergitol NP-4 is employed in the preparation of antifoaming agents for use in the manufacturing of various products.

Tergitol NP-4 is part of the formulation of concrete admixtures, improving workability and dispersion of additives.
In the cosmetic and personal care industry, NP-4 contributes to the formulation of shampoos and shower gels for improved performance.
Tergitol NP-4 is applied in the production of coolant additives for the automotive sector, enhancing heat transfer and corrosion protection.

Tergitol NP-4 is used in the preparation of industrial lubricants and greases, contributing to their emulsifying and dispersing properties.
Tergitol NP-4 finds application in the formulation of emulsifiable concentrates for agrochemicals, aiding in dispersion and effectiveness.

Tergitol NP-4 is employed in the preparation of concrete curing compounds, contributing to the even curing of surfaces.
Tergitol NP-4 is utilized in the formulation of pigment concentrates for plastics and rubber industries, aiding in color dispersion.

Tergitol NP-4 finds application in the production of adhesive removers, assisting in the breakdown and removal of adhesive residues.
Tergitol NP-4 is applied in the manufacturing of defatting agents for use in cleaning and degreasing applications.
Tergitol NP-4 is employed in the formulation of emulsion polymerization processes, contributing to particle size control and stability.



DESCRIPTION


Tergitol NP-4 is a nonionic surfactant that belongs to the family of alkylphenol ethoxylates.
Specifically, it is a type of nonylphenol ethoxylate.
Nonionic surfactants are compounds that do not ionize in water and are commonly used for their wetting, emulsifying, dispersing, and detergent properties.

Nonylphenol ethoxylate, represented by Tergitol NP-4, is a versatile nonionic surfactant.
Tergitol NP-4 is derived from nonylphenol and ethylene oxide, resulting in a hydrophilic and surfactant compound.

As a member of the alkylphenol ethoxylate family, NP-4 exhibits both hydrophobic and hydrophilic properties.
Tergitol NP-4 is characterized by its ability to reduce surface tension, making it an effective wetting agent.

Tergitol NP-4 is commonly used in formulations where emulsification of oil and water is necessary.
With four ethylene oxide units, NP-4 has a balanced hydrophilic-lipophilic balance (HLB).

The nonionic nature of Tergitol NP-4 makes it suitable for applications where ionic surfactants might not be appropriate.
Nonylphenol ethoxylate finds application in various industries, including agriculture, textiles, and cleaning products.
Tergitol NP-4 contributes to the stability of emulsions, making it valuable in the formulation of liquid products.
As a wetting agent, Tergitol NP-4 enhances the spreading of liquids on surfaces.

Tergitol NP-4 is known for its compatibility with a wide range of chemicals, making it versatile in different formulations.
In the realm of detergent formulations, NP-4 aids in the removal of oils and stains due to its emulsifying properties.

Tergitol NP-4's ethoxylated structure contributes to its solubility in both polar and non-polar solvents.
Tergitol NP-4 is often employed in the textile industry for its wetting and dispersing characteristics in dyeing processes.

With its mildness on the skin, NP-4 is utilized in certain personal care products, including shampoos and soaps.
As an EO (ethylene oxide) chain surfactant, NP-4 demonstrates stability over a range of temperatures.

Tergitol NP-4 is part of the NP series of surfactants, each characterized by a specific number of ethylene oxide units.
In the formulation of agricultural chemicals, NP-4 aids in the even distribution and adherence of active ingredients.

The hydrophobic component derived from nonylphenol in NP-4 contributes to its effectiveness in certain applications.
Tergitol NP-4 may be used in the preparation of polymer dispersions for coatings and adhesives.
Tergitol NP-4 is valued for its contribution to foam stabilization in formulations where a stable foam is desired.
Nonylphenol ethoxylate is often chosen for its biodegradability under appropriate conditions.

Tergitol NP-4's non-toxic nature at recommended concentrations makes it suitable for specific environmental and industrial applications.
Tergitol NP-4 exhibits versatility in formulations where a nonionic surfactant with balanced properties is essential.
Known for its emulsifying, wetting, and cleaning properties, NP-4 is a trusted ingredient in various industrial and household products.



PROPERTIES


Chemical Name: Nonylphenol ethoxylate (NP-4)
Chemical Formula: C15H24O5
% Actives: 100 %
Chemistry: Alkylphenol Ethoxylate (APE)
Cloud Point @1% Aqueous (ASTM D 2024): Insoluble °C
CMC (25°C): Insoluble PPM
Foam Height - Initial (0.1 wt% actives): Insoluble mm
Form: Liquid
HLB: 8.9
Moles EO: 4
Pour Point: -28 °C
Use: Scouring



FIRST AID


Inhalation:

If inhaled, move the affected person to fresh air immediately.
If the person is not breathing, perform artificial respiration.
Seek medical attention promptly.
If respiratory irritation or distress persists, seek medical attention.


Skin Contact:

In case of skin contact, remove contaminated clothing promptly.
Wash the affected skin with plenty of water and mild soap for at least 15 minutes.
If irritation, redness, or rash occurs, seek medical attention.


Eye Contact:

If nonylphenol ethoxylate comes into contact with the eyes, rinse them gently with water for at least 15 minutes, holding the eyelids open.
Remove contact lenses if easily removable after initial rinsing.
Seek immediate medical attention if irritation, redness, or other symptoms persist.


Ingestion:

If ingested, do not induce vomiting unless instructed to do so by medical personnel.
Rinse the mouth thoroughly with water and drink plenty of water.
Do not give anything by mouth to an unconscious person.
Seek immediate medical attention, providing details about the ingested substance and its concentration.


General First Aid Advice:

Keep affected individuals calm to reduce stress.
If there are respiratory or cardiovascular symptoms, seek medical attention promptly.
Provide first aid personnel with access to the safety data sheet (SDS) for NP-4.
If seeking medical attention, bring the product container or label to assist healthcare professionals in providing appropriate treatment.
For large spills or exposures, contact emergency services for professional assistance.
If skin irritation occurs, seek medical advice.


Notes:

Follow all recommended safety guidelines and protocols outlined in the product's safety data sheet (SDS).
Use personal protective equipment (PPE) as specified in the SDS.
If symptoms persist or if there is uncertainty about the appropriate first aid measures, seek medical advice promptly.



HANDLING AND STORAGE


Handling:

Personal Protective Equipment (PPE):
Wear appropriate PPE, including gloves, safety goggles, and protective clothing, as specified in the product's SDS.
Use respiratory protection if handling NP-4 in conditions where airborne exposure is possible.

Ventilation:
Work in a well-ventilated area or use local exhaust ventilation to minimize inhalation exposure.
Use fume hoods or other engineering controls when handling NP-4 in enclosed spaces.

Avoid Contact:
Avoid direct skin and eye contact with the undiluted substance.
If contact occurs, follow the first aid measures specified in the SDS.

Handling Procedures:
Follow good industrial hygiene practices, including regular handwashing.
Do not eat, drink, or smoke while handling NP-4.

Spill and Leak Procedures:
In the event of a spill, contain the material and prevent it from entering drains or waterways.
Clean up spills using absorbent materials, and dispose of waste in accordance with local regulations.

Responsible Handling:
Designate trained personnel for handling NP-4.
Provide employees with proper training on the safe handling and use of the substance.


Storage:

Storage Conditions:
Store NP-4 in a cool, dry, and well-ventilated area.
Keep containers tightly closed when not in use to prevent contamination and moisture absorption.

Temperature Control:
Store at temperatures recommended by the manufacturer.
Avoid exposure to extreme temperatures that could compromise the stability of the product.

Compatibility:
Store NP-4 away from incompatible materials and substances.
Follow the manufacturer's recommendations regarding compatibility with other chemicals.

Container Material:
Use containers made of materials compatible with NP-4.
Check for container integrity regularly to prevent leaks or spills.

Handling of Containers:
Handle containers with care to prevent damage.
Do not drag or slide containers, as this may cause damage and compromise integrity.

Labeling:
Ensure proper labeling of containers with product names, hazard information, and handling instructions.
Clearly mark storage areas with appropriate signage.

Regular Inspections:
Periodically inspect storage areas for any signs of damage, leaks, or deterioration.
Dispose of damaged or deteriorated containers appropriately.

Emergency Response Information:
Keep emergency response information, such as contact numbers for emergency services and relevant healthcare professionals, readily available.
TERGITOL NP-4
DESCRIPTION:
Tergitol NP-4 is Excellent oil-soluble surfactant with excellent emulsification properties at low HLB.
Tergitol NP-4 is Nonyl Phenol Ethoxylate Surfactant.
Tergitol NP-4 can be used in oilfield drilling and production formulations, dispersant for petroleum oil, in-process cleaning, cleaners and degreasers, and dry cleaning.

CAS Number: 127087-87-0
Molecular Formula: C15H24O(C2H4O)
Name : Nonylphenol Ethoxylate


Tergitol NP-4, Surfactant is a Nonylphenol Ethoxylate surfactant.
Tergitol NP-4 is nonionic and provides excellent detergency, outstanding wetting, versatile solubility characteristics and low odor.
Tergitol NP-4 is suggested for use in cleaners & degreasers, prewash spotters and oil field chemicals.

Tergitol NP-4 is a Nonylphenol Ethoxylate surfactant.
Tergitol NP-4 is non-ionic and provides excellent detergency, rinseability, and low odor.
Tergitol NP-4 is suggested for use in cleaners & degreasers, pre-wash spotters and metal-working fluids.

Tergitol NP-4 is Excellent oil-soluble surfactant
Tergitol NP-4 has Low HLB emulsifier
Tergitol NP-4 has Low odor

Tergitol NP-4 has Exceptional handling properties
Tergitol NP-4 is Insoluble in water








USES OF TERGITOL NP-4:
Tergitol NP-4 is used in Cleaning product formulations
Tergitol NP-4 is used in Paints and coatings
Tergitol NP-4 is used in Emulsion polymerization
Tergitol NP-4 is used in Anywhere there is a need for increased surface activity




APPLICATIONS OF TERGITOL NP-4:
Tergitol NP-4 is used in Cleaners & degreasers
Tergitol NP-4 is used in Dry cleaning
Tergitol NP-4 is used in Water in oil emulsion

BENEFITS OF TERGITOL NP-4:
Tergitol NP-4 Deliver a combination of economy and performance
Tergitol NP-4 is Excellent detergency and wetting
Tergitol NP-4 is Good solubilization and emulsification



SOLUBILITY AND COMPATIBILITY OF TERGITOL NP-4:
Tergitol NP-4 is Insoluble in water
Tergitol NP-4 is Soluble in chlorinated solvents and most polar and non-polar solvents and oils

Tergitol NP-4 is Chemically stable in the presence of dilute acids, bases and salts
Tergitol NP-4 is Compatible with soaps, anionic and other nonionic surfactants, and many organic
solvents





CHEMICAL AND PHYSICAL PROPERTIES OF TERGITOL NP-4:
Actives, wt% 100
Cloud Point (1) Insoluble
HLB (2) 8.9
Moles EO 4
Pour Point(3) -28
Appearance Pale yellow liquid
pH, 1% in 10:6 isopropanol/water 7.2
Viscosity at 25°C (77°F), cP 238
Density at 20°C (68°F), g/mL 1.027
Flash Pt, Closed Cup, ASTM D93 218°C 425°F
CAS Max % 1
pH 5.0 to 8.0
Quantity 4 L
Grade Reagent
Packaging Amber Glass Bottle
Water 0.005
Relative Vapor Density (air = 1) >10 Calculated.
Relative Density (water = 1) 1.027 at 20 °C (68 °F) / 20 °C Calculated.
Water solubility < 0.5 % Calculated. With haze
Partition coefficient: noctanol/water
log Pow: 3.7 - 4.5 Estimated.
Kinematic Viscosity 232 cSt Calculated.
Molecular weight 396 g/mol Calculated.
pour point -18 °C ( -0 °F) Calculated.
Appearance
Physical state Liquid.
Color Yellow
Odor Mild
pH 7.2 Calculated. 1% in solution
Boiling point (760 mmHg) > 200 °C ( > 392 °F) Calculated.
Flash point closed cup 218 °C ( 424 °F) ASTM D 93
Evaporation Rate (Butyl Acetate= 1)
Flammability (solid, gas) No
Vapor Pressure < 0.01 mmHg at 20 °C (68 °F) Calculated.



SAFETY INFORMATION ABOUT TERGITOL NP-4:
First aid measures:
Description of first aid measures:
General advice:
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Move out of dangerous area:

If inhaled:
If breathed in, move person into fresh air.
If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact:
Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Consult a physician.

In case of eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Continue rinsing eyes during transport to hospital.

If swallowed:
Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.
Rinse mouth with water.
Consult a physician.

Firefighting measures:
Extinguishing media:
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas

Advice for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.
Accidental release measures:
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment.

Avoid breathing vapours, mist or gas.
Evacuate personnel to safe areas.

Environmental precautions:
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up:
Soak up with inert absorbent material and dispose of as hazardous waste.
Keep in suitable, closed containers for disposal.

Handling and storage:
Precautions for safe handling:
Avoid inhalation of vapour or mist.

Conditions for safe storage, including any incompatibilities:
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials

Exposure controls/personal protection:
Control parameters:
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls:
Appropriate engineering controls:
Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.

Personal protective equipment:
Eye/face protection:
Tightly fitting safety goggles.
Faceshield (8-inch minimum).
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection:
Handle with gloves.
Gloves must be inspected prior to use.
Use proper glove
removal technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.

Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
It should not be construed as offering an approval for any specific use scenario.

Body Protection:
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection:
Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.

If the respirator is the sole means of protection, use a full-face supplied air respirator.
Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Stability and reactivity:
Chemical stability:
Stable under recommended storage conditions.
Incompatible materials:
Strong oxidizing agents:
Hazardous decomposition products:
Hazardous decomposition products formed under fire conditions.
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas.

Disposal considerations:
Waste treatment methods:
Product:
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging:
Dispose of as unused product



TERGITOL NP-40

Tergitol NP-40, also known as Nonoxynol-40, is a nonionic surfactant and a member of the nonylphenol ethoxylate family.
Tergitol NP-40 is commonly used as an emulsifying agent, detergent, wetting agent, and dispersing agent in various industrial, commercial, and scientific applications.
Tergitol NP-40 is characterized by its ability to stabilize mixtures of oil and water by reducing the surface tension between the two substances.
It is often used in formulations where effective emulsification and dispersion are required.



APPLICATIONS


Tergitol NP-40 is extensively used in the formulation of cosmetics and personal care products, serving as an emulsifier in creams, lotions, and shampoos.
In the pharmaceutical industry, Tergitol NP-40 finds application in the preparation of emulsions and suspensions, aiding the dispersion of active ingredients.
Tergitol NP-40 is a key component in agricultural formulations, enhancing the spreading and wetting of pesticides and herbicides on plant surfaces.

Its role as a wetting agent makes it valuable in the formulation of paints, inks, and coatings, ensuring uniform coverage on various surfaces.
Tergitol NP-40 is utilized in the textile industry to improve the penetration of dyes into fabrics, enhancing color vibrancy and consistency.
In laboratories, Tergitol NP-40 is used to prepare cell lysates and protein extracts due to its solubilizing properties.

Tergitol NP-40 serves as a vital ingredient in cleaning products, such as household and industrial cleaners, aiding the removal of dirt, grease, and stains.
Tergitol NP-40 is employed in the production of photographic chemicals, contributing to the even dispersion of light-sensitive agents.
In the food industry, it is used as an emulsifier and stabilizer in various products, including dressings, sauces, and baked goods.

Tergitol NP-40's wetting capabilities are harnessed in the manufacture of ceramics, assisting in the even distribution of glazes and coatings.
Tergitol NP-40 is a crucial component in the formulation of metalworking fluids, enhancing lubrication and cooling properties during machining.
Tergitol NP-40 finds application in the creation of cleaning solutions for electronic components, aiding the removal of contaminants without causing damage.
Tergitol NP-40 plays a role in the formulation of agrochemicals, improving the coverage and adherence of plant protection products on crops.
In the paint and coatings industry, it contributes to the homogeneity of pigments and additives, resulting in consistent finishes.

Tergitol NP-40's emulsifying properties are utilized in the production of emulsion polymerization processes, leading to the creation of various polymers.
Tergitol NP-40 is used in the manufacturing of detergents and dishwashing products, ensuring effective removal of food residues and greases.
Its role as a dispersing agent is important in the production of ceramics, where it assists in the even distribution of ceramic particles in suspensions.

The chemical finds utility in the creation of analytical reagents, facilitating the dissolution of substances for accurate measurements.
Tergitol NP-40 is used in the formulation of coolant additives for engines and industrial machinery, improving heat transfer and protection.
Its presence in oilfield chemicals aids in the dispersion of additives and minerals in drilling fluids, enhancing their performance.

In the production of adhesives and sealants, it contributes to the even mixing and distribution of components, ensuring consistent bonding.
Tergitol NP-40 is employed in the preparation of polymer solutions and dispersions, enhancing the stability and properties of the final product.
Tergitol NP-40's emulsifying abilities are harnessed in the creation of photographic developers and fixers, promoting consistent reactions.

In the petrochemical industry, it is used as an emulsifier in fuel additives, helping to maintain fuel stability and combustion efficiency.
Tergitol NP-40 continues to find new applications across industries, thanks to its versatile properties that enhance emulsification, wetting, and dispersion processes.

Tergitol NP-40 is employed in the formulation of inkjet printer inks, assisting in the even dispersion of pigments for high-quality prints.
In the production of ceramic tiles and glazes, it enhances the wetting of ceramic particles, leading to uniform coatings and improved aesthetics.

Tergitol NP-40 is utilized in the creation of emulsions for the cosmetics industry, ensuring consistent texture and appearance in various products.
Tergitol NP-40 plays a role in the formulation of metal cleaners, aiding in the removal of oils, grease, and contaminants from metal surfaces.
Tergitol NP-40 is used in the preparation of polymer solutions for research purposes, facilitating the study of polymer properties and behaviors.
In the textile industry, Tergitol NP-40 contributes to the production of specialty finishes that enhance fabric softness and water repellency.

Tergitol NP-40's emulsifying properties are valuable in the formulation of paints used for artistic purposes, ensuring color uniformity and texture.
Tergitol NP-40 finds application in the creation of defoamers used to control foam in various industrial processes, enhancing operational efficiency.

Tergitol NP-40 is utilized in the formulation of cleaners for delicate surfaces, aiding in the removal of soils without causing damage.
In the manufacturing of paper products, it contributes to the preparation of coatings that enhance print quality and ink adhesion.
Tergitol NP-40 assists in the production of concrete additives that improve workability and minimize segregation during construction.
Tergitol NP-40 finds use in the formulation of cosmetic and personal care products, such as shaving creams, enhancing their texture and performance.

Its role in the creation of ceramic glazes contributes to the aesthetics of tiles and pottery, ensuring smooth and consistent surface coatings.
Tergitol NP-40 is employed in the manufacturing of industrial lubricants, improving the dispersibility of additives and enhancing lubrication properties.
Tergitol NP-40 is used in the preparation of cleaning solutions for delicate optical instruments and lenses, ensuring effective cleaning without damage.

In the creation of adhesive formulations, it assists in achieving optimal bonding properties by improving the dispersion of adhesive components.
Tergitol NP-40's wetting capabilities are harnessed in the agricultural sector to aid in the uniform distribution of fertilizers and nutrients on plants.
Tergitol NP-40 is employed in the preparation of sample solutions for analytical testing, enhancing solubility and accurate measurements.
In the paint industry, Tergitol NP-40 is used to stabilize pigments and prevent settling, ensuring consistent color and texture in paint products.

Tergitol NP-40's emulsifying properties are utilized in the formulation of cosmetic products such as sunscreens, enhancing their texture and coverage.
Tergitol NP-40 plays a role in the creation of cleaning formulations for delicate surfaces like glass and mirrors, ensuring streak-free results.
Tergitol NP-40 is employed in the preparation of metal pretreatment solutions, aiding in the removal of contaminants and promoting surface adhesion.

In the printing industry, Tergitol NP-40 assists in the formulation of inks used in flexographic and gravure printing, enhancing print quality and performance.
Tergitol NP-40 contributes to the preparation of emulsions used in the production of food products like mayonnaise and salad dressings.
Tergitol NP-40 continues to demonstrate its versatility in diverse applications, enabling improved emulsification, wetting, and dispersion processes across various industries.



DESCRIPTION


Tergitol NP-40, also known as Nonoxynol-40, is a nonionic surfactant and a member of the nonylphenol ethoxylate family.
Tergitol NP-40 is commonly used as an emulsifying agent, detergent, wetting agent, and dispersing agent in various industrial, commercial, and scientific applications.
Tergitol NP-40 is characterized by its ability to stabilize mixtures of oil and water by reducing the surface tension between the two substances.
It is often used in formulations where effective emulsification and dispersion are required.

The "NP-40" designation refers to the average number of ethylene oxide units (40 in this case) that are added to the nonylphenol molecule during the ethoxylation process.
This ethoxylation process enhances the surfactant properties of the compound.

Tergitol NP-40 is used in a variety of applications, including in the pharmaceutical, cosmetics, agricultural, and research industries.
It is important to note that Nonoxynol-40 and related nonylphenol ethoxylates have been subjects of regulatory scrutiny due to their potential environmental impact and health concerns, leading to restrictions and replacements in certain applications.

Tergitol NP-40 is a versatile nonionic surfactant known for its emulsifying and wetting properties.
Tergitol NP-40, often referred to by its trade name, belongs to the nonylphenol ethoxylate family.
Tergitol NP-40 is utilized as an effective emulsifying agent in various industrial and scientific applications.
Tergitol NP-40 is recognized for its ability to lower the surface tension between oil and water, aiding in dispersion.

With its balanced hydrophilic and hydrophobic nature, Tergitol NP-40 can create stable mixtures of immiscible substances.
The trade name "Tergitol NP-40" often refers to different formulations of nonylphenol ethoxylate surfactants.
Tergitol NP-40 is commonly employed as a detergent, wetting agent, and dispersing agent across a range of industries.

Tergitol NP-40 is created through the ethoxylation process, where ethylene oxide units are added to nonylphenol molecules.
This process enhances its surfactant properties, making it effective in various applications.

Its presence in formulations can enhance the solubility and stability of certain substances.
Tergitol NP-40 is utilized in cosmetics for its emulsification properties in creams and lotions.
In the pharmaceutical industry, it is used to stabilize emulsions and improve the dispersion of active ingredients.

Its wetting properties are harnessed in agricultural applications, aiding the spread of agrochemicals on plant surfaces.
Tergitol NP-40 plays a crucial role in research laboratories, assisting in various experimental procedures.
Its ability to reduce interfacial tension is useful in the formulation of cleaning products and detergents.

Tergitol NP-40 is known for its compatibility with both aqueous and non-aqueous systems.
Due to regulatory concerns about certain nonylphenol ethoxylates, alternative surfactants are being explored in some applications.
Tergitol NP-40's effectiveness as an emulsifier contributes to improved texture and stability in food products.

Tergitol NP-40 finds utility in the textile industry, aiding in dyeing processes and improving fabric treatment efficiency.
The balanced nature of Tergitol NP-40 makes it suitable for applications where nonionic surfactants are preferred.



PROPERTIES


Chemical Name: Tergitol NP-40 (Nonylphenol Ethoxylate)
Molecular Formula: C15H24O3 (average molecular formula for ethoxylate)
Molecular Weight: Approximately 252.36 g/mol (average molecular weight for ethoxylate)
Physical State: Liquid
Appearance: Clear to slightly cloudy liquid
Color: Colorless to pale yellow
Odor: Mild characteristic odor
Melting Point: Varies
Boiling Point: Varies
Density: Varies depending on concentration and temperature
Vapor Pressure: Varies depending on concentration and temperature
Solubility in Water: Soluble
Solubility in Organic Solvents: Soluble in many organic solvents
Flash Point: Varies depending on formulation
Autoignition Temperature: Varies depending on formulation
Viscosity: Varies depending on concentration and temperature
pH: Varies depending on formulation
Surface Tension: Varies depending on concentration and temperature
Refractive Index: Varies depending on concentration and temperature
Emulsification: High emulsifying power
Wetting Properties: Strong wetting ability
Foaming: Can produce foam depending on formulation
Biodegradability: Variable biodegradability, dependent on specific formulation and conditions
Toxicity: Can be harmful if ingested or inhaled in concentrated form
Environmental Impact: Regulatory concerns due to potential environmental persistence and toxicity



FIRST AID


Inhalation:

If inhaled, immediately move the affected person to fresh air in an area with good ventilation.
If breathing is difficult, provide oxygen if available and seek medical attention promptly.
If the person is not breathing, administer artificial respiration by trained personnel.
Keep the person calm and at rest during recovery.


Skin Contact:

Quickly remove contaminated clothing and footwear.
Wash the affected skin area with plenty of water and mild soap for at least 15 minutes.
If irritation or redness develops, seek medical attention.
If Tergitol NP-40 is in contact with sensitive areas such as eyes or mucous membranes, follow appropriate eye contact instructions.


Eye Contact:

Flush the eyes gently with lukewarm water for at least 15 minutes, ensuring that eyelids are held open.
Remove contact lenses if worn and easily removable during rinsing.
Seek immediate medical attention if irritation, redness, or pain persists after flushing.


Ingestion:

If ingested accidentally, do not induce vomiting unless directed by medical professionals.
Rinse the mouth with water if the person is conscious and able to swallow.
Seek medical attention immediately and provide information about the ingested substance.



HANDLING AND STORAGE


Handling:

Ventilation:
Work with Tergitol NP-40 in a well-ventilated area, such as a chemical fume hood or a space with adequate air exchange, to minimize inhalation exposure.

Personal Protection:
Wear appropriate personal protective equipment (PPE), including chemical-resistant gloves, safety goggles, and protective clothing, to prevent skin and eye contact.

Avoid Inhalation:
Use respiratory protection, such as a NIOSH-approved organic vapor respirator, if handling in an area with inadequate ventilation or potential for airborne exposure.

No Smoking:
Prohibit smoking, eating, or drinking in areas where Tergitol NP-40 is being handled.

Ignition Sources:
Keep away from open flames, sparks, and sources of ignition.
Ensure that equipment used is properly grounded.

Static Electricity:
Prevent the buildup of static electricity by grounding equipment and containers during transfer or handling.

Avoid Contact:
Minimize skin contact by wearing appropriate PPE.
In case of contact, promptly wash the affected area with water and remove contaminated clothing.

Work Procedures:
Follow established safe work procedures, such as those outlined in chemical hygiene plans, to minimize risks associated with handling Tergitol NP-40.


Storage:

Container:
Store Tergitol NP-40 in its original labeled container, tightly closed, and properly sealed.
Ensure that containers are in good condition and leak-proof.

Location:
Store containers in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and incompatible substances.

Fire Safety:
Store away from open flames, sparks, and potential sources of ignition.
Keep fire-fighting equipment accessible in the storage area.

Separation:
Store Tergitol NP-40 away from strong acids, bases, and oxidizing agents to prevent reactions and potential hazards.

Height and Arrangement:
Keep containers of Tergitol NP-40 off the ground on pallets or shelves to prevent contact with water and facilitate inspection.

Leak Prevention:
Store in a designated containment area with suitable spill control measures and absorbent materials in case of leaks or spills.

Temperature:
Store within the temperature range specified by the manufacturer or on the safety data sheet to maintain stability and prevent degradation.

Security:
Store in an area accessible only to authorized personnel who are trained in handling hazardous chemicals.

Monitoring:
Regularly inspect containers for signs of damage, leaks, or deterioration. Address any issues promptly.

Emergency Equipment:
Keep appropriate fire extinguishing equipment, spill response kits, and personal protective equipment nearby.



SYNONYMS


Nonylphenol Ethoxylates
Nonionic Surfactants
NPE Surfactants
Nonylphenol Ethers
Ethoxylated Nonylphenol Compounds
Alkylphenol Ethoxylates
NP-40 Alternative
Ethoxylated Alkylphenols
NPE Emulsifiers
Nonoxynol Surfactants
Ethoxylated Octylphenol
Nonionic Emulsifiers
NPE Wetting Agents
Ethoxylated Phenolic Compounds
NP-40 Substitute
Nonylphenol Ethoxylate Blends
NPE Dispersants
Nonylphenol Ethoxylate Alternatives
Ethoxylated Alkylphenol Surfactants
NPE-Free Surfactants
Ethoxylated Nonylphenol Derivatives
Nonylphenol Ethoxylate Variants
NP-40 Analog
NPE-Free Emulsifiers
Ethoxylated Nonylphenol Solutions
TERGITOL NP-6

Tergitol NP-6 is a nonionic surfactant that belongs to the family of alkylphenol ethoxylates.
Specifically, Tergitol NP-6 is a type of nonylphenol ethoxylate.
Nonionic surfactants are compounds that do not ionize in water and are often used for their wetting, emulsifying, dispersing, and detergent properties.


Nonionic surfactant, Nonylphenol ethoxylate, Ethoxylated nonylphenol, Tergitol NP-6 alternative, Alkylphenol ethoxylate, NPE, Nonylphenol ethylene oxide adduct, Ethoxylated alcohol, Alkyl ethoxylate, Ethylene oxide adduct, Detergent precursor, Wetting agent, Emulsifying agent, Dispersing agent, Surface-active agent, Surfactant blend, Nonionic emulsifier, Cleaning agent ingredient, Alkylpolyethylene glycol, Emulsion stabilizer, Oil-in-water emulsifier, Hydrophilic compound, Tergitol NP-6 substitute



APPLICATIONS


Tergitol NP-6 finds widespread use in the formulation of industrial cleaning products due to its excellent emulsifying and cleaning properties.
Tergitol NP-6 is a key ingredient in the production of dishwashing detergents, contributing to effective grease removal.
Tergitol NP-6 serves as a versatile wetting agent in agricultural formulations, aiding in the even distribution of pesticides and herbicides.

In textile processing, it is utilized for its wetting and dispersing characteristics, facilitating dyeing and finishing processes.
Tergitol NP-6's compatibility with various chemicals makes it valuable in the manufacturing of agrochemical formulations.
Tergitol NP-6 is employed in the production of metalworking fluids, where it aids in lubrication and cooling.

Tergitol NP-6 is used in the formulation of paint strippers and removers due to its effective emulsifying properties.
In the cosmetics industry, Tergitol NP-6 contributes to the formulation of creams, lotions, and other skincare products for enhanced texture and spreadability.
Tergitol NP-6 is applied in the production of household and industrial detergents to improve cleaning efficiency.

Tergitol NP-6 plays a role in the formulation of asphalt release agents, aiding in the release of asphalt from surfaces.
In the oil and gas industry, Tergitol NP-6 is utilized in drilling fluids to assist in emulsification and fluid stability.

Tergitol NP-6 finds application in the production of metal cleaners and degreasers for effective removal of oils and contaminants.
Tergitol NP-6 contributes to the formulation of ink and coating products, improving their dispersion and stability.
Tergitol NP-6 is employed in the manufacturing of construction chemicals, such as concrete additives and admixtures.
Tergitol NP-6 is utilized in the preparation of foaming agents, enhancing foam stability in various formulations.

Tergitol NP-6 plays a role in the production of adhesives and sealants, contributing to their emulsification and dispersion properties.
In the agricultural sector, Tergitol NP-6 is used in the formulation of crop protection products for optimal dispersion and coverage.
Tergitol NP-6 is applied in the preparation of coolant formulations for the automotive and industrial sectors.

Tergitol NP-6 is employed in the production of metal treatment formulations for improved wetting and cleaning.
Tergitol NP-6 is utilized in the formulation of photographic chemicals for emulsion stabilization.
Tergitol NP-6 finds application in the production of antifoaming agents for various industrial processes.

Tergitol NP-6 is utilized in the formulation of leather processing chemicals, contributing to wetting and dispersing properties.
In the printing industry, it is used in the preparation of fountain solutions to improve ink and water balance on printing presses.

Tergitol NP-6 is applied in the formulation of pesticide concentrates for agricultural use, improving the solubility and stability of active ingredients.
Tergitol NP-6 is a versatile ingredient in formulations where effective emulsification, wetting, and cleaning properties are essential for the desired product performance.

Tergitol NP-6 is used in the formulation of construction adhesives to improve the bonding properties.
In the textile industry, it is employed in sizing agents for enhanced fiber wetting.
Tergitol NP-6 plays a role in the production of pigment dispersions for paints and coatings.
Tergitol NP-6 is utilized in the preparation of industrial and household floor cleaners for effective soil removal.

Tergitol NP-6 is applied in the manufacturing of concrete release agents to facilitate mold release.
Tergitol NP-6 is used in the production of inkjet inks, contributing to color dispersion and stability.

In the agricultural sector, it is incorporated into foliar fertilizers for improved nutrient absorption.
Tergitol NP-6 is employed in the formulation of rust preventatives to enhance metal protection.
Tergitol NP-6 is used in metal electroplating baths for its wetting and emulsifying properties.

Tergitol NP-6 plays a role in the production of cutting fluids for metalworking processes.
Tergitol NP-6 is applied in the formulation of drilling muds for improved fluidity and lubrication.
In the leather industry, it is used in dyeing processes for efficient dispersion of dyes.

The surfactant is incorporated into air freshener formulations for improved fragrance dispersion.
Tergitol NP-6 is utilized in the preparation of industrial defoamers for foam control in various processes.

Tergitol NP-6 finds application in the production of cooling tower water treatment chemicals for scale and corrosion control.
Tergitol NP-6 is used in the formulation of crop oil concentrates to enhance the effectiveness of herbicides.
Tergitol NP-6 contributes to the preparation of asphalt emulsions for road construction applications.

The surfactant is employed in the manufacturing of fluxes for soldering and brazing applications.
Tergitol NP-6 is used in the preparation of concrete admixtures for improved workability.
Tergitol NP-6 plays a role in the formulation of degreasing agents for the cleaning of machinery and equipment.

Tergitol NP-6 is applied in the production of polymer dispersions for coatings and adhesives.
Tergitol NP-6 is utilized in the preparation of windshield washer fluids for improved cleaning performance.
Tergitol NP-6 is used in the formulation of pigment concentrates for coloring plastics and rubbers.

Tergitol NP-6 finds application in the production of anti-misting agents for industrial lubricants.
Tergitol NP-6 is applied in the preparation of foam control agents for various industrial processes.



DESCRIPTION


Tergitol NP-6 is a nonionic surfactant that belongs to the family of alkylphenol ethoxylates.
Specifically, Tergitol NP-6 is a type of nonylphenol ethoxylate.
Nonionic surfactants are compounds that do not ionize in water and are often used for their wetting, emulsifying, dispersing, and detergent properties.

Tergitol NP-6 is a versatile nonionic surfactant renowned for its emulsifying capabilities.
Tergitol NP-6 is derived from nonylphenol, a hydrophobic compound.
Tergitol NP-6 belongs to the class of ethoxylated nonylphenols, making it water-soluble.

With its hydrophilic and hydrophobic balance, it excels as a wetting agent in various formulations.
Known for its excellent detergent properties, Tergitol NP-6 aids in cleaning by reducing surface tension.
As an alkylphenol ethoxylate, it is widely used in industrial cleaning products and formulations.

Tergitol NP-6 serves as an effective dispersing agent, enhancing the stability of formulations.
Its ethylene oxide chain provides stability to oil-in-water emulsions, making it valuable in cosmetic products.

The nonionic nature of Tergitol NP-6 contributes to its mildness on the skin.
Tergitol NP-6 is often utilized in the production of environmentally friendly cleaning solutions.
Tergitol NP-6 exhibits compatibility with various chemicals, allowing its integration into diverse formulations.

As an emulsion stabilizer, it plays a crucial role in maintaining the consistency of certain products.
Its hydrophilic properties make Tergitol NP-6 suitable for use in water-based systems.

In detergent formulations, it aids in the removal of oils and stains from surfaces.
Tergitol NP-6 is commonly found in agricultural formulations, contributing to the even distribution of pesticides.
Tergitol NP-6's surfactant properties make it an effective aid in the formulation of pesticides and herbicides.

Due to its nonionic nature, Tergitol NP-6 is less sensitive to water hardness compared to ionic surfactants.
Tergitol NP-6 is often incorporated into textile processing formulations for its wetting and dispersing properties.

Its ethoxylated structure contributes to Tergitol NP-6's effectiveness in stabilizing foams in certain formulations.
With its balanced composition, Tergitol NP-6 is utilized in the production of industrial cleaners and degreasers.

In cosmetics, this surfactant helps achieve the desired texture and spreadability in creams and lotions.
Tergitol NP-6 demonstrates excellent solubility in both polar and non-polar solvents, enhancing its versatility.
As an alkylphenol ethoxylate, Tergitol NP-6 is employed in various agrochemical formulations for enhanced efficacy.

Tergitol NP-6's compatibility with a wide range of temperatures contributes to its stability in various applications.
Tergitol NP-6 is a trusted ingredient in formulations where a nonionic surfactant with balanced properties is essential for optimal performance.



PROPERTIES


Actives, wt%: 100
Cloud Point: Insoluble
HLB: 10.9
Moles EO: 6
Pour Point: -26
Appearance: Pale yellow liquid
pH, 5% aq solution: 7.3
Density at 25°C (77°F), g/mL: 1.039
Flash Pt, Closed Cup, ASTM D93: 281°C 425°F



FIRST AID


Inhalation:

If inhaled, move the affected person to fresh air immediately.
If the person is not breathing, perform artificial respiration. Seek medical attention promptly.


Skin Contact:

In case of skin contact, remove contaminated clothing promptly.
Wash the affected skin with plenty of water and mild soap for at least 15 minutes.
Seek medical attention if irritation, redness, or other adverse reactions persist.


Eye Contact:

If Tergitol NP-6 comes into contact with the eyes, rinse them gently with water for at least 15 minutes, holding the eyelids open.
Remove contact lenses if easily removable after initial rinsing.
Seek immediate medical attention if irritation or other symptoms persist.


Ingestion:

If ingested, do not induce vomiting unless instructed to do so by medical personnel.
Rinse the mouth thoroughly with water and drink plenty of water.
Seek immediate medical attention, providing details about the ingested substance and its concentration.


General First Aid Advice:

Keep affected individuals calm to reduce stress.
If there are respiratory or cardiovascular symptoms, seek medical attention promptly.
Provide first aid personnel with access to the safety data sheet (SDS) for Tergitol NP-6.
If seeking medical attention, bring the product container or label to assist healthcare professionals in providing appropriate treatment.
For large spills or exposures, contact emergency services for professional assistance.


Notes:

Follow all recommended safety guidelines and protocols outlined in the product's safety data sheet (SDS).
Use personal protective equipment (PPE) as specified in the SDS.
If symptoms persist or if there is uncertainty about the appropriate first aid measures, seek medical advice promptly.
For professional guidance on the specific product formulation, contact the manufacturer or a relevant industry expert.



HANDLING AND STORAGE


Handling:

Personal Protective Equipment (PPE):
Wear appropriate PPE, including gloves, safety goggles, and protective clothing, as specified in the product's SDS.
Use respiratory protection if handling Tergitol NP-6 in conditions where airborne exposure is possible.

Ventilation:
Work in a well-ventilated area or use local exhaust ventilation to minimize inhalation exposure.
Use fume hoods or other engineering controls when handling Tergitol NP-6 in enclosed spaces.

Avoid Contact:
Avoid direct skin and eye contact with the undiluted substance.
If contact occurs, follow the first aid measures specified in the SDS.

Handling Procedures:
Follow good industrial hygiene practices, including regular handwashing.
Do not eat, drink, or smoke while handling Tergitol NP-6.

Spill and Leak Procedures:
In the event of a spill, contain the material and prevent it from entering drains or waterways.
Clean up spills using absorbent materials, and dispose of waste in accordance with local regulations.

Responsible Handling:
Designate trained personnel for handling Tergitol NP-6.
Provide employees with proper training on the safe handling and use of the substance.


Storage:

Storage Conditions:
Store Tergitol NP-6 in a cool, dry, and well-ventilated area.
Keep containers tightly closed when not in use to prevent contamination and moisture absorption.

Temperature Control:
Store at temperatures recommended by the manufacturer.
Avoid exposure to extreme temperatures that could compromise the stability of the product.

Compatibility:
Store away from incompatible materials and substances.
Follow the manufacturer's recommendations regarding compatibility with other chemicals.

Container Material:
Use containers made of materials compatible with Tergitol NP-6.
Check for container integrity regularly to prevent leaks or spills.

Handling of Containers:
Handle containers with care to prevent damage.
Do not drag or slide containers, as this may cause damage and compromise integrity.

Labeling:
Ensure proper labeling of containers with product names, hazard information, and handling instructions.
Clearly mark storage areas with appropriate signage.

Regular Inspections:
Periodically inspect storage areas for any signs of damage, leaks, or deterioration.
Dispose of damaged or deteriorated containers appropriately.

Emergency Response Information:
Keep emergency response information, such as contact numbers for emergency services and relevant healthcare professionals, readily available.
TERGITOL NP-9
DESCRIPTION:
TERGITOL NP-9 is Nonionic surfactant for use in cleaners and detergents, agrochemicals, metalworking fluids, paper and textile processing, and paints and coatings.
Tergitol NP-9 is soluble in water, chlorinated solvents and most polar solvents.
TERGITOL NP-9 is chemically stable in the presence of dilute acids, bases and salts.

CAS Number: 127087-87-0
Name: Nonylphenol Ethoxylate


USES OF TERGITOL NP-9:
TERGITOL NP-9 is used in Cleaning product formulations
TERGITOL NP-9 is used in Paints and coatings
TERGITOL NP-9 is used in Emulsion polymerization
TERGITOL NP-9 is used in Anywhere there is a need for increased surface activity

TERGITOL NP-9 is used in Cleaners & detergents
TERGITOL NP-9 is used in Paper & textile processing
TERGITOL NP-9 is used in Laundry

TERGITOL NP-9 is used in Paints & coatings
TERGITOL NP-9 is used in Dust control
TERGITOL NP-9 is used in Agrochemicals
TERGITOL NP-9 is used in Metalworking fluids

TERGITOL NP-9 is a nonionic surfactant that can be used in cleaners and detergents, metalworking fluids, agrochemicals, paper and textile processing and paints and coatings.
TERGITOL NP-9 is also compatible with soaps, anionic and other nonionic surfactants, and many organic solvents.

It's uses include cleaning product formulations, paints and coatings, emulsion polymerization and anywhere there is a need for increased surface activity.
It's benefits include delivering a combination of economy and performance.
TERGITOL NP-9 has excellent detergency and wetting and has good solubilization and emulsification.

BENEFITS TERGITOL NP-9:
TERGITOL NP-9 Delivers a combination of economy and performance
TERGITOL NP-9 has Excellent detergency and wetting
TERGITOL NP-9 has Good solubilization and emulsification

TERGITOL NP-9 has Excellent detergency
TERGITOL NP-9 has Outstanding wetting
TERGITOL NP-9 has Versatile solubility characteristics

TERGITOL NP-9 has Exceptional handling properties
TERGITOL NP-9 has Low odor
TERGITOL NP-9 has Good rinseability

TERGITOL NP-9 has Excellent detergent quality
TERGITOL NP-9 has Outstanding wetting
TERGITOL NP-9 has Flexible solubility characteristics

TERGITOL NP-9 has Unique handling properties
TERGITOL NP-9 Can be rinsed easily
TERGITOL NP-9 is Chemically stable in the presence of dilute acids, bases, and salts
TERGITOL NP-9 is Compatible with organic solvents, soaps, anionic, and other nonionic surfactants

TYPICAL PHYSICAL PROPERTIES OF TERGITOL NP-9:
Actives, wt% 100
Cloud Point (1) 54
HLB (2) 12.9
Moles EO 9
Pour Point(3): -1
Appearance Pale yellow liquid
pH, 1% aq solution 6
Viscosity at 25°C (77°F), cP 243
Density at 20°C (68°F), g/mL 1.055
Flash Pt, Closed Cup, ASTM D93 247°C 477°F
Description: non-ionic
Quality Level: 200
Type: Type NP-9
mol wt: 616 g/mol
CMC :60 ppm
transition temp: cloud point 54 °C
HLB: 12.9
Weight (kg): 215
Package Type: Poly Drum
Shelf Life (months): 24 Months
Availability: In Stock
Colour: Yellow
Odour: Mild
pH: 6.5 - 7.5 @ 20 - 25 °C (68 - 77 °F)
Freezing Point: 3.8 - 5 °C (38.8 - 41 °F)
Boiling Point: 250 °C (482 °F) (1013 hPa)
Flash Point: 237 - 247 °C (459 - 477 °F)
Vapour :< 0.01 mmHg @ 20 °C (68 °F)
Relative Density: 1.05 - 1.06 @ 20 °C (68 °F) Reference substance: (water = 1)
Water solubility: Soluble
Partition Coefficient: log Pow: 2.1 - 3.4
Viscosity, Kinematic: 112 - 237 mm2/s @ 25 °C (77 °F)
CAS: 127087-87-0, 25322-68-3, 9014-93-1
Applications:
• Cleaners & detergents
• Paper and textile processing
• Laundry
• Paints & coatings
• Dust control
• Agrochemicals
• Metalworking fluids
Chemical Form: Liquid


SOLUBILITY AND COMPATIBILITY OF TERGITOL NP-9:
TERGITOL NP-9 is Soluble in water
TERGITOL NP-9 is Soluble in chlorinated solvents and most polar solvents
TERGITOL NP-9 is Chemically stable in the presence of dilute acids, bases and salts
TERGITOL NP-9 is Compatible with soaps, anionic and other nonionic surfactants, and many organic solvents

APPLICATIONS OF TERGITOL NP-9:
TERGITOL NP-9 has been used in cytotoxicity assays to treat Vero cells for producing cytotoxic (100% dead) controls.
TERGITOL NP-9 may be used in paper & textile processing, laundry, dust control, agrochemicals, metalworking fluids and paints & coatings.

TERGITOL NP-9 has been used in a study to assess a method to determine nickel using ultrasonic-assisted cloud point extraction.
TERGITOL NP-9has also been used in a study to investigate a method for the detection of Salmonella Enteritidis via an Enteritidis-specific real time PCR assay


SAFETY INFORMATION ABOUT TERGITOL NP-9:

First aid measures:
Description of first aid measures:
General advice:
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Move out of dangerous area:

If inhaled:
If breathed in, move person into fresh air.
If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact:
Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Consult a physician.

In case of eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Continue rinsing eyes during transport to hospital.

If swallowed:
Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.
Rinse mouth with water.
Consult a physician.

Firefighting measures:
Extinguishing media:
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas

Advice for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.
Accidental release measures:
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment.

Avoid breathing vapours, mist or gas.
Evacuate personnel to safe areas.

Environmental precautions:
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up:
Soak up with inert absorbent material and dispose of as hazardous waste.
Keep in suitable, closed containers for disposal.

Handling and storage:
Precautions for safe handling:
Avoid inhalation of vapour or mist.

Conditions for safe storage, including any incompatibilities:
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials

Exposure controls/personal protection:
Control parameters:
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls:
Appropriate engineering controls:
Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.

Personal protective equipment:
Eye/face protection:
Tightly fitting safety goggles.
Faceshield (8-inch minimum).
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection:
Handle with gloves.
Gloves must be inspected prior to use.
Use proper glove
removal technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.

Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
It should not be construed as offering an approval for any specific use scenario.

Body Protection:
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection:
Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.

If the respirator is the sole means of protection, use a full-face supplied air respirator.
Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Stability and reactivity:
Chemical stability:
Stable under recommended storage conditions.
Incompatible materials:
Strong oxidizing agents:
Hazardous decomposition products:
Hazardous decomposition products formed under fire conditions.
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas.

Disposal considerations:
Waste treatment methods:
Product:
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging:
Dispose of as unused product.



TERGITOL TMN-100X (90%)
TERGITOL TMN-100X (90%) can be used as:A foaming agent in the study of surfactant effect on glass-ceramic biomaterials (bioactive glasses).
A surfactant in the preparation of nickel-graphene oxide composite coatings.
TERGITOL TMN-100X (90%) is a 90% aqueous solution of a branched secondary alcohol ethoxylate with 10.1 ethylene oxide (EO) units.

CAS: 60828-78-6
MF: C12H26O.(C2H4O)n
EINECS: 612-043-8

Nonionic surfactant for use in cleaners, paper and textile processing, and pigment and wax/resin dispersants; featuring a narrow gel range, and suitability for use as a high-temperature penetrant and dispersant​​​​​.

TERGITOL TMN-100X (90%) Chemical Properties
CMC: 830 ppm (25°C)
Density: 1.025 g/mL at 20 °C
Description: non-ionic
Form: liquid
Grade: laboratory grade
HLB: 14.1
InChI: 1S/C14H30O2/c1-11(2)8-13(5)10-14(9-12(3)4)16-7-6-15/h11-15H,6-10H2,1-5H3
InChI key: VKKFWRYCMZBXIG-UHFFFAOYSA-N
Mol wt: 570 g/mol by calculation
Quality Level: 100 External link
solubility water: freely soluble at 20 °C (visual)
technique(s) HPLC: suitable
LC/MS: suitable
transition temp: cloud point 65 °C (1 wt% actives aq solution)
pour point: -6 °C
viscosity: 88 cP(25 °C)

Synonyms
60828-78-6
Tergitol TMN-6
2-(2,6,8-trimethylnonan-4-yloxy)ethanol
10137-98-1
Tergitol(r) tmn-10
BRN 1851894
2-(2,6,8-Trimethyl-4-nonyloxy)ethanol
Ethanol, 2-[[3,5-dimethyl-1-(2-methylpropyl)hexyl]oxy]-
2-((1-Isobutyl-3,5-dimethylhexyl)oxy)ethanol
Ethyleneglycolmono-2,6,8-trimethyl-4-nonyl ether
Ethylene glycol mono-2,6,8-trimethyl-4-nonyl ether
ETHANOL, 2-((1-ISOBUTYL-3,5-DIMETHYLHEXYL)OXY)-
2-[(1-Isobutyl-3,5-dimethylhexyl)oxy]ethanol
Ethanol, 2-[(1-isobutyl-3,5-dimethylhexyl)oxy]-
Ethanol, 2-((3,5-dimethyl-1-(2-methylpropyl)hexyl)oxy)-
DTXSID00873978
LS-66836
LS-72947
2-[[3,5-Dimethyl-1-(2-methylpropyl)hexyl]oxy]ethanol
TERGITOL TMN-3
TERGITOL TMN-3 has been used in the preparation of blood mimicking fluid (BMF) mixture.
TERGITOL TMN-3 is a 90% aqueous solution of a branched secondary alcohol ethoxylate with 10.1 ethylene oxide (EO) units.
When heated to decomposition TERGITOL TMN-3 emits acrid smoke and irritating fumes.

CAS: 60828-78-6
MF: C12H26O.(C2H4O)n
EINECS: 612-043-8

TERGITOL TMN-3, is a nonionic surfactant commonly used in various industrial and research applications.
TERGITOL TMN-3 belongs to the family of polyethylene glycol (PEG) ethers with a hydrophilic head and lipophilic tail and is suitable for use in lotions, detergents and solubilizers.
TERGITOL TMN-3 is particularly useful in protein chemistry, where it is used to solubilize and stabilize proteins, such as membrane proteins, for structural analysis techniques.
In addition, TERGITOL TMN-3 has potential applications in drug delivery and other medical fields due to its ability to interact with and penetrate cell membranes.
Nonionic surfactant for use in cleaners, paper and textile processing, and pigment and wax/resin dispersants; featuring a narrow gel range, and suitability for use as a high-temperature penetrant and dispersant​​​​​.

TERGITOL TMN-3 Chemical Properties
PSA: 29.5
XLogP3: 4.2
Density: 0.869g/cm3
Boiling Point: 250.7ºC at 760 mmHg
Flash Point: 130 °C
Refractive Index: 1.441
Molecular Weight: 230.392
Exact Mass: 230.225
EC Number: 600-200-3
Form: liquid

Synonyms
60828-78-6
Tergitol TMN-6
2-(2,6,8-trimethylnonan-4-yloxy)ethanol
10137-98-1
Tergitol(r) tmn-10
BRN 1851894
2-(2,6,8-Trimethyl-4-nonyloxy)ethanol
Ethanol, 2-[[3,5-dimethyl-1-(2-methylpropyl)hexyl]oxy]-
2-((1-Isobutyl-3,5-dimethylhexyl)oxy)ethanol
Ethyleneglycolmono-2,6,8-trimethyl-4-nonyl ether
Ethylene glycol mono-2,6,8-trimethyl-4-nonyl ether
ETHANOL, 2-((1-ISOBUTYL-3,5-DIMETHYLHEXYL)OXY)-
2-[(1-Isobutyl-3,5-dimethylhexyl)oxy]ethanol
Ethanol, 2-[(1-isobutyl-3,5-dimethylhexyl)oxy]-
Ethanol, 2-((3,5-dimethyl-1-(2-methylpropyl)hexyl)oxy)-
DTXSID00873978
LS-66836
LS-72947
2-[[3,5-Dimethyl-1-(2-methylpropyl)hexyl]oxy]ethanol
TERGITOL TMN-6 (90%)
TERGITOL TMN-6 (90%) is a non-ionic surfactant.
TERGITOL TMN-6 (90%) used as hard surface cleaners, PTFE Dispersions, alkaline cleaners and degreasers, pigment, wax and resin dispersions, textile processing, paints and coatings, metal cleaners, metalworking fluids, agrochemicals, pulp and paper, felt washes.
TERGITOL TMN-6 (90%) is chemically stable in the presence of dilute acids, bases and salts.

CAS: 60828-78-6
MF: C12H26O.(C2H4O)n
EINECS: 612-043-8

TERGITOL TMN-6 (90%) Chemical Properties
Density: 1.04 g/mL at 20 °C
Fp: 130 °C
Form: liquid
EPA Substance Registry System: TERGITOL TMN-6 (90%) (60828-78-6)

TERGITOL TMN-6 (90%) has been used in the preparation of blood mimicking fluid (BMF) mixture.
TERGITOL TMN-6 (90%) is a 90% aqueous solution of a branched secondary alcohol ethoxylate with 10.1 ethylene oxide (EO) units.
Mildly toxic by ingestion.
A skin and severe eye irritant.
When heated to decomposition TERGITOL TMN-6 (90%) emits acrid smoke and irritating fumes.
TERGITOL TMN-6 (90%) is a biochemical reagent that can be used as a biological material or organic compound for life science related research.
TERGITOL TMN-6 (90%) is not considered to be a carcinogen.
Ethylene oxide in small amounts that might accumulate in headspace presents no significant exposure in ventilated area.

Synonyms
60828-78-6
Tergitol TMN-6
2-(2,6,8-trimethylnonan-4-yloxy)ethanol
10137-98-1
Tergitol(r) tmn-10
BRN 1851894
2-(2,6,8-Trimethyl-4-nonyloxy)ethanol
Ethanol, 2-[[3,5-dimethyl-1-(2-methylpropyl)hexyl]oxy]-
2-((1-Isobutyl-3,5-dimethylhexyl)oxy)ethanol
Ethyleneglycolmono-2,6,8-trimethyl-4-nonyl ether
Ethylene glycol mono-2,6,8-trimethyl-4-nonyl ether
ETHANOL, 2-((1-ISOBUTYL-3,5-DIMETHYLHEXYL)OXY)-
2-[(1-Isobutyl-3,5-dimethylhexyl)oxy]ethanol
Ethanol, 2-[(1-isobutyl-3,5-dimethylhexyl)oxy]-
Ethanol, 2-((3,5-dimethyl-1-(2-methylpropyl)hexyl)oxy)-
DTXSID00873978
LS-66836
LS-72947
2-[[3,5-Dimethyl-1-(2-methylpropyl)hexyl]oxy]ethanol
TERGITOL XD
Tergitol XD is a nonionic surfactant which can be used to extract estrogens
Tergitol XD used in agrochemicals, carbon black & pigment dispersions, iodophors, emulsion polymerization, paints & coatings.
Provides freeze thaw stability and steric stabilization in emulsions & dispersions.

CAS Number: 9038-95-3
EINECS number: 618-542-7
Molecular Fomula: C9H20O3
Molecular weight: 176.26

Tergitol XD surfactant is an outstanding nonionic emulsifier and/or dispersant.
Tergitol XD is also widely used in the production of iodophors for germicidal cleaners.
Excellent steric and freeze/thaw stabilizer, effective pigment and carbon black dispersant.

Tergitol XD excellent for aromatic, chlorinated and other hard-to-emulsify compounds.
Good solubility in the presence of salts or electrolytes tergitol XD is water soluble.
Also, Tergitol XD is soluble in chlorinated and many polar organic solvents.

Tergitol XD is chemically stable in acidic and alkaline solutions.
Tergitol XD is compatible with anionic, cationic and other non-ionic surfactants.
Also, Tergitol XD has good lubricant under load.

Tergitol XD does not corrode metals.
An aqueous solution of Tergitol XD will have a low surface tension.
Therefore, Tergitol XD has good wetting and penetrating properties while also having low foaming properties.

Tergitol XD typically leaves no black carbon or adhesive in high temperature applications where decomposition can occur.
Decomposition products are volatile or soluble in base stock.
The oxidation stability of Tergitol XD can be improved by the inclusion of antioxidants.

Tergitol XD should be sealed and stored in a cool, dry place.
In addition, Tergitol XD should be protected from oxides.
It should be ensured that the workshop is well ventilated or equipped with exhaust devices.

Tergitol XD is a copolymer of ethylene oxide and propylene oxide.
Tergitol XD can be used as a lubricant, shiny hair agent.
In addition, Tergitol XD is used in cooking oil and shampoo production.

Boiling point: >200 °C(lit.)
Density: 1.056 g/mL at 25 °C
refractive index: n20/D 1.46
Flash point: >230 °F
solubility H2O: at
Tergitol XD has very low ash content, low pour point and excellent thermal stability.
Tergitol XD can lubricate polyester, polyamide and polypropylene multifilament yarns, especially in texturing processes.
Tergitol XD can also be used in woollens and cellulosics.

Tergitol XD has inverse water solubility, good heat transfer properties and natural lubricating properties.
These properties of Tergitol XD make it an excellent base choice for producing metalworking fluids from aqueous solutions.
Rubber lubricants of rubber hoses and tires, especially in high operating temperatures or high loading environments.

Tergitol XD extrusion aid in the production of extruded polyethylene.
Mold release agents for rubber hoses and tires, especially in high operating temperatures or high loading environments.
Compressor oil when working with non-oxidizing gases such as ethylene, neon, helium and argon.

Tergitol XD is a block copolymer that consists of a hydrophilic poly(ethylene glycol) (PEG) segment and a hydrophobic poly(propylene glycol) (PPO) segment.
Tergitol XD is a polymer that has been used in lubricants, solvents, hydraulic fluids, heat transfer fluids, solder assist fluids, metal working fluids and lubricants, quenchants, plasticizers and foam control agents.

One of the significant features of Tergitol XD is its amphiphilic nature.
This means that it has both hydrophilic and hydrophobic regions within its structure.
This property allows Tergitol XD to form micelles in aqueous solutions, where the hydrophobic PPO segments aggregate in the core, while the hydrophilic PEG segments form the outer shell.

The formation of micelles gives Tergitol XD its surfactant properties.
Scientific applications of Tergitol XD span across several fields.
In pharmaceuticals, it is utilized as an excipient in drug formulations to improve solubility, stability, and controlled release of drugs.

Tergitol XD can also be employed as a carrier for drug delivery systems, enhancing the bioavailability and targeting of therapeutic agents.
Furthermore, Tergitol XD finds applications in cosmetics as an emulsifier and solubilizer for various formulations.
The mechanism of action of Tergitol XD relies on its ability to self-assemble into micelles in aqueous solutions.

When added to a system, the Tergitol XD segments aggregate together, forming a core, while the hydrophilic PEG segments create a protective shell around the core.
This self-assembly process enables Tergitol XD to solubilize substances and stabilize emulsions.

Tergitol XD can also enhance the penetration and absorption of drugs through biological membranes.
Tergitol XD offers the advantage of being biodegradable in pure products and is more soluble in cold water than in hot water.

Uses
Tergitol has been used in a study to assess a method for detecting Salmonella enterica serovar Enteritidis in liquid whole eggs using loop-mediated isothermal amplification (LAMP).
Tergitol XD has also been used in a study to investigate the oxidation of nonylphenol ethoxylates (NPEO) and octylphenol ethoxylates (OPEO) by oxidant systems generating hydroxide radicals.

Tergitol XD is widely used in cleaners for its emulsifying, wetting and dispersing properties.
It can be found in household cleaners, industrial cleaners and surface cleaners.
Tergitol XD is used for its emulsifying and dispersing properties in shampoos, conditioners, bath foams, skin lotions, and other cosmetic products.

Tergitol XD used to facilitate the dispersal of agricultural chemicals on the leaf surface.
Such nonionic surfactants can be used to increase the effectiveness of plant protection products.

Tergitol XD can be used for stabilization and dispersion in paints and coatings.
It helps to distribute paint pigments and fillers homogeneously.
Tergitol XD can be used for wetting and stabilizing properties in construction chemicals.

Tergitol XD can be used in the metalworking industry for the dispersion and wetting properties of coolants.
Tergitol XD can be used for better distribution of irrigation fluids and penetration into plant roots.
Tergitol XD is a preferred compound for foam control in some applications.

Tergitol XD is used in concrete admixtures to increase the strength of concrete, improve water retention and increase the workability of concrete.
Tergitol XD can be used for its wetting and dispersing properties in pulp making and paper coatings.
Tergitol XD used in irrigation fluids, it helps water to better disperse to plants and penetrate the soil.

Although Tergitol XD is not used in food products, it can contribute to the properties of water repellency and increasing the integrity of the packaging by using it in coatings in food packaging.
Tergitol XD is used for viscosity control in screen printing inks and helps the ink to adhere to the surface better.
It is used for emulsifying and stabilizing properties in water-based paints and varnishes.

Tergitol XD can be used for emulsification and cleaning properties in bleach and laundry detergents in some cleaning products.
Tergitol XD can be used in water treatment processes for its filtration and particle retention properties.

Anti-lime varnishes and coatings can be used with emulsification and dispersion properties to prevent scale build-up.
Tergitol XD can be used for emulsification and dispersion in some flame retardant products.

Skin and eye irritation: Direct contact with methyltriglycol may cause mild irritation to the skin and eyes.
It is important to avoid prolonged or extensive contact and use appropriate protective equipment when handling the substance.
Inhalation of vapors or mists of methyltriglycol may cause respiratory irritation.

Adequate ventilation should be provided in areas where Tergitol XD is used to minimize the risk of inhalation.
Tergitol XD is harmful if ingested.
Accidental ingestion should be avoided, and the substance should be stored out of the reach of children and untrained personnel.

Allergic reactions
Some individuals may develop allergic reactions when exposed to Tergitol XDl or related compounds.
Precautions should be taken for individuals with known sensitivities to similar substances.

Environmental impact
While Tergitol XD is considered to have low toxicity, excessive release into the environment can have harmful effects on aquatic life and ecosystems.
Proper disposal and containment measures should be followed to minimize environmental impact.

SYNONYMS
9038-95-3
Butan-1-ol;ethane-1,2-diol;propane-1,2-diol
68551-14-4
U-2000
Tergitol(R)
PAGMBE
UNII-GZ6R4MRR8S
UNII-48TV88LCZC
UNII-DC08AL6V0T
UNII-R3I00ON2WL
UNII-W435Z2KFIQ
UNII-M34J9WL56D
UNII-T66J9LZ44P
UNII-945Y09KFG4
PPG-12-BUTETH-16
PPG-15-BUTETH-20
PPG-38-BUTETH-37
UNII-58CG7042J1
QMNOIORHZMRPLS-UHFFFAOYSA-N
UNII-5345E4238C
TERGITOL(TM), MIN FOAM 1x
BCP31133
C4-H10-O.(C3H6-O.C2-H4-O)x-
1,2-PROPANEDIOL; BUTANOL; ETHYLENE GLYCOL
Ucon(TM) HTF 14, 18-260 C range of application
TERGITOL XH
Tergitol XH is an alkyl EO/PO copolymer.
Tergitol XH is available in several types that fit the following requirements.
Tergitol XH has almost no toxicity, very little irritation on the skin and mucous membranes.

CAS Number: 9003-11-6
Molecular Formula: (C3H6O.C2H4O)x
Molecular Weight: 102.1317
EINECS No: 618-355-0

Tergitol XH is widely used as emulsifier, dissolving agent, hydrophilic substrate of ointments and suppositories, artificial.
Tergitol XH can strengthen stamina, vitality and physical strength.
Moreover, Tergitol XH can improve reagent sensitivity.

Tergitol XH can increase stress strength.
In addition, Tergitol XH can increase the function of sex hormone, relieve muscle pain.
Tergitol XH can improve the function of the heart muscle.

Tergitol XH can reduce cholesterol, blood fat and systolic pressure.
Tergitol XH is a copolymer of polyethylene and polypropylene ether glycol.
Tergitol XH is available as white, waxy, free-flowing prilled granules or bulk solids.

Tergitol XH is practically odorless and tasteless.
Tergitol XH occurs as a colorless liquid at room temperature.
Tergitol XH is an epoxide.

Tergitol XH is used as a food additive.
Tergitol XH belongs to the Epoxides family.
Tergitol XH, PEPG or E/PP copolymer for short, is a copolymer of polyethylene glycol (polyethylene glycol - PEG) and polypropylene glycol (polypropylene glycol - PPG) molecules.

Tergitol XH has a polymer structure formed by the combination of polyethylene glycol and polypropylene glycol chains.
Tergitol XH is used in various industries because it is a nonionic surfactant and polymer.
The combination of polyethylene glycol and polypropylene glycol in different proportions determines the properties and application areas of the product.

Therefore, the properties of Tergitol XH may vary depending on the ratios of PEG and PPG from which it is made, polymerization processes and uses.
Tergitol XH is a cyclic ether containing compound with three ring atoms (one oxygen and two carbon atoms).
Also, Tergitol XH is an alkyl EO/PO copolymer, nonionic surfactant with excellent steric and freeze/thaw stabilization.

Tergitol XH provides lubricity and is an effective steric and freeze/thaw stabilizer.
Tergitol XH shows good solubility in the presence of salts or electrolytes.
In addition, Tergitol XH is suitable for use in applications such as fiber lubricants and emulsion polymerization, iodophors.

Tergitol XH is a sterile filtered nonionic detergent useful for the isolation of membrane proteins.
Tergitol XH has been used to dissolve large dye molecules in physiological environments.
Due to its low UV absorbance, Tergitol XH can be used in protocols that require UV monitoring of solubilized proteins.

Tergitol XH is a symmetrical triblock copolymer containing poly(ethylene oxide) (PEO) and poly(propylene oxide) (PPO).
The unique property of Tergitol XH that is hydrophobic at temperatures above 288 K and dissolves in water
Temperatures below 288 K lead to the formation of micelles composed of Tergitol XH triblock copolymers.

Some studies report that the hydrophobic core contains Tergitol XH and a hydrophilic corona consists of the PEO block.
In 30% by weight aqueous solution, Tergitol XH forms a cubic gel phase.
The nominal chemical formula of Tergitol XH is HO(CH2CH2O)20(CH2CH(CH3)O)70(CH2CH2O)20H, which molecular weight of about 5800 g/mol.

Tergitol XH has behavior similar to that of hydrocarbon surfactants and will form micelles when placed selectively.
In addition, Tergitol XH can form both spherical and cylindrical micelles.
Tergitol XH contains 75 percent oxyethylene and 25 percent oxypropylene groups by weight.

Tergitol XH is effective in stabilizing emulsions obtained by mixing liquids in different phases such as water and oil.
Emulsions create a homogeneous structure, allowing different components to stay together.
Tergitol XH can also remain stable at high temperatures, so it can be used in industrial applications that require high temperatures.

Tergitol XH can maintain its performance by remaining stable in a wide pH range, which allows it to be used in various formulations.
Tergitol XH has biodegradable properties, which makes it have less environmental impact.
Low foaming is preferred in some applications because excess foaming can adversely affect production and cleaning processes.

Tergitol XH, as a surfactant, can form the interface between water and oil and help disperse oil into water.
Tergitol XH can be used in cleaning, cosmetics, agriculture, textiles, oil and gas, wood preservation and many other industrial processes.

Tergitol XH can be used in detergents to increase foaming and increase cleaning efficiency.
Tergitol XH contains polar and hydrophobic segments that can interact with water and oil to varying degrees in different industrial applications.

Melting point: 57-61 °C
Boiling point: >200 °C(lit.)
Density: 1.095 g/mL at 25 °C
vapor density: >1 (vs air)
vapor pressure: refractive index: n20/D 1.466
Flash point: >230 °F
storage temp.: 2-8°C
solubility: H2O: at form: solution
color: APHA: ≤120, 50/50 in CH3OH
PH: 5.0-7.5 (100g/L in H2O)
PH Range: 5.0 - 7.5
Wate. r Solubility: Miscible with water.
λmaxλ: 260 nm Amax: ≤0.3
λ: 280 nm Amax: ≤0..2
Merck: 13,7644
LogP: -1.293 (est)

Tergitol XH are water-soluble polymers, chemical and shear stable, non-foaming and offer exceptional lubricity.
Tergitol XH can be used as a thickener in fire resistant water-glycol hydraulic fluids.
The base stock may be formulated with water and ethylene glycol, diethylene glycol or propylene glycol.

Tergitol XH can also be used as base oils in applications such as heat treatment and quenching, metalworking and aqueous applications.
Tergitol XH is used in iodophors and emulsion polymerization.
Also, Tergitol XH is a nonionic surfactant.

Tergitol XH has excellent freeze/thaw stabilizing benefits.
Tergitol XH is an alkyl EO/PO copolymer, nonionic surfactant with excellent steric and freeze/thaw stabilizing benefits.
In addition, Tergitol XH can be used in a wide variety of applications, including iodophors and emulsion polymerization.

Tergitol XH is a nonionic polyoxyethylene-polyoxypropylene block copolymer with the general formula HO(C2H4O)a(-).
Tergitol XH is available in varying grades from liquids to solids.
Also, Tergitol XH is used as an emulsifying agent, solubilizing agent, surfactant and wetting agent for antibiotics.

Tergitol XH is also used in ointment and suppository bases and as a tablet binder or coater.
Tergitol XH should be stored in a cool, dry and ventilated place away from fire, heat, light, acids and foodstuffs.
Tergitol XH is a copolymer of polyethylene and polypropylene ether glycol.

Uses
Tergitol XH used hard and soft surface cleaners, defoamers in coatings and water treatment.
Tergitol XH used lubricant in metal working, anti-foaming aid and extender for linear and cross-linked polyesters and polyurethanes.
Tergitol XH can be used for emulsifying, wetting and stabilizing shampoos, conditioners, lotions and other personal care products.

Tergitol XH can be used to increase the effectiveness of pesticides and to spread them better on the plant surface.
Tergitol XH can be used for dispersion and stabilization in paints and coatings.
Tergitol XH can be used as a surfactant in textile dyeing and processing processes.

Tergitol XH can be used in oil and gas production to increase the solubility of hydrocarbons in water.
It can be used for emulsification and stabilization properties in wood protection products.
It can be used in oil and gas production to increase the solubility of hydrocarbons in water.

Tergitol XH can be used for emulsification and stabilization properties in wood protection products.
It can help to disperse and wetting water in concrete admixtures and building materials.
This can be important to improve the durability and performance of concrete.

Tergitol XH can increase the productivity of plant nutrients by providing better distribution and penetration of irrigation fluids into the soil.
It can contribute to the nutrition processes of the plants by enabling the fertilizers to dissolve better in water.
It can be used for viscosity control in screen printing inks and helps the ink to adhere to the surface better.

Tergitol XH can be used as a surfactant in the processing and formulation of polymers and plastics.
It can improve the dispersion and effectiveness of spray peace gases.
It can be used as a surfactant in coolants and chemical protective coatings.

Tergitol XH can be used as a surfactant for the flotation process of minerals and can help minerals decompose.
It can be used as a surfactant in cleaning and disinfection products, thus increasing the effectiveness.
It can be used in water treatment and treatment chemicals for its wetting and stabilization properties.

Tergitol XH used in the metalworking industry for the dispersion and wetting properties of coolants.
It can be used for wetting and dispersing in pulp making and paper coatings.
It can be used for wetting and dispersing concrete additives and water-repellent coatings.

Safety
Tergitol XH is used in a variety of oral, parenteral, and topical pharmaceutical formulations, and are generally regarded as nontoxic and nonirritant materials.
Tergitol XH is not metabolized in the body.
Animal toxicity studies, with dogs and rabbits, have shown Tergitol XH to be nonirritating and nonsensitizing when applied in 5% w/v and 10% w/v concentration to the eyes, gums, and skin.

Skin and Eye Irritation
Direct contact with Tergitol XH may cause mild to moderate skin and eye irritation.
Tergitol XH is essential to avoid prolonged or extensive skin contact and use appropriate protective equipment, such as gloves and safety goggles, when handling the substance.

Inhalation Hazard
Inhalation of vapors, mists, or aerosols of Tergitol XH may cause respiratory irritation.
Adequate ventilation should be provided in work areas to minimize the risk of inhalation exposure.

Allergic Reactions
Some individuals may develop allergic reactions when exposed to Tergitol XH or related compounds.
Precautions should be taken for individuals with known sensitivities to similar substances.

Environmental Impact
Tergitol XH is generally considered to have low toxicity, but excessive release into the environment can have harmful effects on aquatic life and ecosystems.
Proper disposal and containment measures should be followed to minimize environmental impact.

Fire Hazard:
Tergitol XH is not flammable but may contribute to the intensity of a fire if involved in one.
Tergitol XH may react with certain chemicals or materials, leading to hazardous reactions.
It is essential to avoid contact with incompatible substances.

Synonyms
Poloxalene
9003-11-6
Poloxamer 188
Poloxamer 407
POLOXAMER
106392-12-5
Pluronic
Pluronic F-68
Poloxalkol
2-methyloxirane;oxirane
Poloxamer 331
Pluronic L 61
Pluronic L-81
Therabloat
Detalan
Pluracare
Proxanol
TERGITOL(TM)XH(NONIONIC)
Adeka Pluronic F 108
Epan 485
Epan 710
Epan 785
Pluronic L
Tergitol XH
Lutrol F
Cirrasol ALN-WS
Pluronic L44
Poloxamer-188
Pluronic F 38
Antarox 17R4
Antarox 25R2
Antarox B 25
Antarox F 68
Antarox F 88
Antarox F 88FL
Antarox L 61
Antarox L 72
Antarox P 84
Tergitol nonionic XH
Daltocel F 460
Pluronic L 122
Slovanik M-640
Antarox F 108
Antarox P 104
Antarox SC 138
Emulgen PP 230
Adeka 25R1
Adeka 25R2
Adeka L 61
Dehypon KE 3557
Empilan P 7068
Arcol E 351
Epan 450
Crisvon Assistor SD 14
Epan U 108
Breox BL 19-10
Poloxamer [USAN:BAN:INN]
Crl 1005
BASF-L 101
BSP 5000
CRL 1605
CRL 8131
CRL 8142
RC 102
691397-13-4
SK&F 18,667
F 77
F 87
F 88
P 84
P 85
B 053
F 108
F 127
F-108
P 103
P 104
P 105
P 123
poloxamers
C10H22O3
Oxirane, methyl-, polymer with oxiraneOTHER CA INDEX NAMES:Oxirane, polymer with methyloxirane
Pluronic F 68
Pluronic F108
Pluronic F127
Pluronic F 108
Pluronic F 127
Pluronic L 101
Pluronic L 121
Pluronic L-101
2-methyloxirane; oxirane
Hydrowet
Proksanol
Regulaid
Slovanik
Magcyl
RheothRx
Pluracol V
Pluronic F
Pluronic P
RheothRx-pf
Monolan PB
Pluriol PE
Poloxalene L64
Proxanol Tsl-3
Poloxamer (NF)
Pluronic-68
Pluronic F77
Pluronic F86
Pluronic F87
Pluronic F88
Pluronic L62
Pluronic L64
Pluronic P65
Pluronic P84
Pluronic P85
Meroxapol 105
Poloxamer 101
Poloxamer 108
Poloxamer 182LF
Rokopol 16P
Rokopol 30P
Poloxalene 2930
component of Casakol
Pluronic 10R8
Pluronic 31R2
Pluronic F 68LF
Pluronic F 87
Pluronic F 88
Pluronic F 98
Pluronic L 24
Pluronic L 31
Pluronic L 35
Pluronic L 44
Pluronic L 62
Pluronic L 64
Pluronic L 68
Pluronic L 92
Pluronic L122
Pluronic P 75
Pluronic P 85
Pluronic P-65
Pluronic P-75
Pluronic P103
Pluronic P104
Pluronic P105
Propylen M 12
Proxanol 158
Proxanol 228
Slovanik 630
Slovanik 660
Supronic B 75
Wyandotte 7135
Emkalyx EP 64
Emkalyx L101
Genapol PF 10
Nixolen SL 19
Rokopol 30P9
Tergitol monionic XH
Vepoloxamer (USAN)
Pluronic C 121
Pluronic F 125
Pluronic P 104
Supronic E 400
Teric PE40
Teric PE60
Teric PE70
Velvetol OE 2NT1
Lutrol F (TN)
Newpol PE-88
Nissan Pronon 201
Emkalyx L 101
Plonon 201
Plonon 204
Pronon 102
Pronon 104
Pronon 201
Pronon 204
Pronon 208
Unilube 50MB26X
oxirane-propylene oxide
Teric PE 61
Teric PE 62
Laprol 1502
Pluriol PE 6810
Voranol P 2001
Berol TVM 370
PEG-PPG-PEG
Unilube 50MB168X
Monolan 8000E80
Tergitol XH (nonionic)
Thanol E 4003
Eban 710
Epan 750
Epon 420
PPG Diol 3000EO
UNII-LQA7B6G8JG
Synperonic PE 30/40
D0W0SM
Pluronic F87-A7850
Niax 16-46
UNII-G6DQL26D50
SCHEMBL11737
Pluronic l62(mw 2500)
Pluronic l64(mw 2900)
ethylene oxide propylene oxide
Poloxamer [USAN:INN:BAN]
Poloxalene [USAN:INN:BAN]
UNII-F75JV2T505
Propylene Oxide Ethylene Oxide
TsL 431
ADEKA PLURONIC F-108
Oligoether L-1502-2-30
UNII-09Y8E6164A
CHEBI:32026
HSDB 7222
ANX-188
TVM 370
RVGRUAULSDPKGF-UHFFFAOYSA-N
CRL-5861
CRL-8131
NSC63908
NSC 63908
NSC-63908
WS 661
(C2-H4-O.C3-H6-O)x-
AKOS015912614
DB11451
SK&F-18667
LS-72949
SK & F 18,667
LS-101081
N 480
D01941
D10680
M 90/20
75H90000
75-H-1400
9010-97-3
91858-59-2
TERGITOL XJ
Tergitol XJ has a slight characteristic odour.
Tergitol XJ is a transparent viscous liquid.
Tergitol XJ is a glycerin-initiated polyether polyol.

CAS Number: 9082-00-2
Molecular Weight: 230.26
Molecular Formula: C3H8O3・3(C3H6O・C2H4O)x

The chemical name of Tergitol XJ is Glycerol propoxylate-block-ethoxylate.
Molecular Formula of Tergitol XJ is C3H8O3・3(C3H6O・C2H4O)x CAS:9082-00-2.
The resulting material has trifunctionality and an average molecular weight of 6300 Da.

This triol is polymerized with propylene oxide and then capped with 7% ethylene oxide.
Tergitol XJ is a polyether polyol, glycerine based block copolymer on ethylene oxide and propylene oxide.
In addition, Tergitol XJ is in the form of a homogeneous, clear liquid.

Tergitol XJ contains antioxidants (except BHT).
Also, Tergitol XJ is characterized by high purity and low emission.
Tergitol XJ has a hydroxyl value in the range of 45-50 mg KOH/g at 25°C and a dynamic viscosity in the range of 540.

With the use of Tergitol XJ and appropriately selected additives (catalysts, silicones, blowing agents).
Reinforced flexible foam blocks of rectangular cross section and up to 130 cm high.
Thanks to its excellent parameters, Tergitol XJ can be widely used in the furniture industry for the production of mattresses.

Tergitol XJ is a nonionic alkyl EO/PO copolymer.
In addition, Tergitol XJ is used in emulsion polymerization, agrochemicals, paints and coatings, other emulsion and dispersion systems.
Tergitol XJ provides freeze-thaw stability and steric stabilization in emulsions and dispersions.

Tergitol XJ is an excellent emulsifier for aromatic and chlorinated solvents.
Tergitol XJ is used in steric and freeze/thaw stabilizers.
Moreover, Tergitol XJ has good solubility in the presence of laths or electrolytes.

Tergitol XJ is soluble in chlorinated and many polar organic solvents.
Tergitol XJ is chemically stable in acidic and alkaline solutions.
Tergitol XJ is compatible with anionic, cationic and other non-ionic surfactants.

Tergitol XJ is a glycerin-initiated polyether polyol.
The resulting material has three functionalities and an average molecular weight of 6000.
Tergitol XJ is polymerized with propylene oxide and then capped with 15% ethylene oxide.

Tergitol XJ, Tergitol XJ or Glycerol PO/EO for short, belongs to a group of nonionic surfactants derived from polyethylene glycol (ethylene oxide - EO) and propylene oxide (propylene oxide - PO).
This surfactant has a polymer structure derived from a compound called glycerol and formed as a result of reacting with ethylene oxide and propylene oxide molecules.
The result is a polyol with increased reactivity.

Tergitol XJ is primarily used for flexible flooring foam.
Tergitol XJ may be included as an ingredient in RIM products and other specialty formulations and applications.
Tergitol XJ is a polymerized product produced by the catalyzed addition of propylene oxide (PO) and/or its monomers.

Tergitol XJ to an initiator and an initiator.
Typical initiators are glycerine, mono-propylene glycol, sucrose, sorbitol, water or amines.
Tergitol XJ is an organic material with two or more alcohol (hydroxyl) groups (OH) at the ends of polyether chains.

Tergitol XJ is liquid at room temperature and sometimes has micrometer polymer particles in suspension.
Tergitol XJ is an organic compound containing multiple hydroxyl groups.
Tergitol XJ may have slightly different meanings depending on whether it is used in the food science or food science field.

Tergitol XJ may contain two, three and four hydroxyl groups.
Tergitol XJ is used in polymer chemistry where it acts as crosslinking agents.
Also, Tergitol XJ can be used in paints and casting molds.

Tergitol XJ is the predominant resin or "binder" in most commercial "oil-based" coatings.
Approximately 200,000 tons of Tergitol XJ are produced each year.
In addition, Tergitol XJ is based on the coupling of reactive monomers with the formation of esters.

Boiling point: >200 °C(lit.)
Density: 1.056 g/mL at 25 °C
refractive index: n20/D 1.46
Flash point: >230 °F
solubility H2O: at
Tergitol XJ is commonly used as a surfactant and has various functions such as emulsifying, wetting, dispersing and stabilizing.
It can be used in many application areas from cleaning products to cosmetics, from agricultural chemicals to industrial production in various industries.
The properties of Tergitol XJ may vary depending on the molecular structure, the proportions of polyethylene glycol and propylene glycol added, and the reaction conditions used during the ethoxylation and propoxylation process.

Usage properties vary depending on product formulations and application areas.
Tergitol XJ is used in urethane when combined with diisocyanates.
Tergitol XJ is used on artificial sports tracks, playground surfaces, ski teams.

Tergitol XJ is also used in non-urethane applications such as surfactants and
With Tergitol XJ, it is possible to produce foams with a hardness and flexibility of 1-5kPa and densities of 16-80 kg/m3.
Tergitol XJ can be used with other polymeric polyols to optimize properties such as foam stiffness, openness and durability.

Tergitol XJ has an amphiphilic structure with both hydrophilic (water-soluble) and hydrophobic (water-insoluble) parts.
Tergitol XJ can interface between water and oil, and the oil can be dispersed into the water.
Thanks to these properties, it is effective in surface active functions such as emulsifying, dispersing and wetting.

Emulsions are heterogeneous systems obtained by mixing liquids in different phases.
Tergitol XJ is effective in stabilizing emulsions, that is, it helps to form a homogeneous structure by preventing separation between liquids.
Tergitol XJ can maintain its performance by remaining stable in wide pH ranges.

Tergitol XJ is suitable for use in different formulations and in various industries.
Tergitol XJ can also maintain its stability under high temperature, so it can be used in applications requiring high temperature in industrial processes.
Tergitol XJ can be used in many different application areas from cleaning products to cosmetics, from agricultural chemicals to industrial production.

Tergitol XJ has biodegradable properties, which makes it have less environmental impact.
Tergitol XJ is preferred in detergent and cleaner formulations due to low foaming.
Tergitol XJ is characterized by high combustion resistance.

Tergitol XJ is allowed to be used as an inert ingredient in non-food pesticide products.
Tergitol XJ is used to make urethane polymers.
Tergitol XJ is used in the production of flexible foams and conventional foams with various parameters.

Tergitol XJ is used in the production of mattresses and pillows in the furniture industry.
In addition, Tergitol XJ is used in the production of printing inks.

Uses
Tergitol XJ has been used in a study to assess a method for detecting Salmonella enterica serovar Enteritidis in liquid whole eggs using loop-mediated isothermal amplification (LAMP).
It has also been used in a study to investigate the oxidation of nonylphenol ethoxylates (NPEO) and octylphenol ethoxylates (OPEO) by oxidant systems generating hydroxide radicals.

Tergitol XJ is used in cleaning products such as laundry detergents, dishwashing liquids, household cleaners and industrial cleaners.
Thanks to its emulsifying and dispersing properties, it helps to remove oil and dirt from the surface.

Tergitol XJ Used for emulsification, wetting and stabilization in shampoos, conditioners, body lotions, shower gels and other personal care products.
Tergitol XJ can be used to increase the penetration and effectiveness of pesticides on the leaf surface.
It is used for stabilization and dispersion in paints and coatings.

Tergitol XJ provides homogeneous distribution of pigments.
Tergitol XJ is used for wetting and dispersing in construction chemicals, concrete additives and water-repellent coatings.
Tergitol XJ can be used in oil and gas production to increase the water solubility of hydrocarbons.

Tergitol XJ is also used to facilitate the separation of hydrocarbons from water and to prevent emulsion formation.
Can be used in grease, lubrication and metalworking applications.
It can reduce friction by reducing adhesion to metal surfaces and improving the quality of machined parts.

Tergitol XJ is used to increase the effectiveness of pesticides and to ensure better distribution on plants.
Tergitol XJ can be used as a surfactant in textile dyeing and processing processes.
It helps to distribute the dyestuffs on the surfaces homogeneously.

Tergitol XJ is used for emulsification and dispersion in metal surface treatment and cleaning chemicals.
Tergitol XJ can be used for its stabilizing and homogenizing properties in perfume and essential oil blends.
Used for wetting and stabilizing properties in paper coatings.

Due to its surfactant properties, it lowers the surface tension of liquids and can reduce foam formation.
Tergitol XJ can help plant nutrients and chemical fertilizers dissolve better in water.
Tergitol XJ, Used for emulsification and dispersion properties in wood protection products.

Tergitol XJ, Used in the metalworking industry for the dispersion and wetting properties of coolants.
Tergitol XJ can help irrigation fluids better distribute to plants and penetrate the soil.
It can be used for wetting and dispersing in pulp making and paper coatings.

Tergitol XJ is used for viscosity control in screen printing inks and helps the ink to adhere to the surface better.
It can be used as a surfactant in a wide range of industrial applications.

Skin and Eye Irritation
Direct contact with Tergitol XJ may cause mild to moderate irritation to the skin and eyes.
It is important to avoid prolonged or extensive contact and use appropriate protective equipment when handling the substance.

Inhalation Hazard
Inhalation of vapors or mists of Tergitol XJ may cause respiratory irritation.
Adequate ventilation should be provided in areas where the substance is used to minimize the risk of inhalation.

Allergic Reactions
Some individuals may develop allergic reactions when exposed to Tergitol XJ or related compounds.
Precautions should be taken for individuals with known sensitivities to similar substances.

Environmental Impact
While Tergitol XJ is considered to have low toxicity, excessive release into the environment can have harmful effects on aquatic life and ecosystems.
Proper disposal and containment measures should be followed to minimize environmental impact.

Synonyms
9082-00-2
Ethane-1,2-diol;propane-1,2-diol;propane-1,2,3-triol
Tergitol XJ
SCHEMBL8462303
VKVYTKULMKDWLP-UHFFFAOYSA-N
ethane-1,2-diol; propane-1,2,3-triol; propane-1,2-diol
Glycerol propoxylate-block-ethoxylate, average Mn ~4,000
Glycerol propoxylate-block-ethoxylate, average Mn ~5,200
Glycerol propoxylate-block-ethoxylate, average Mn ~5,300
Glycerol poly(oxyethylene,
oxypropylene) ether
Glycerol ethylene oxide, propylene oxide polymer
Glycerol propylene oxide, ethylene oxide polymer
Propylene oxide ethylene oxide polymer, ether with glycerol (3:1)
Propylene oxide, ethylene oxide, glycerol adduct
TERPINEOL
TERPINEOL = ALPHA TERPINEOL

Terpineol is naturally found in pine oil, lavender oil, orange leaf oil, neroli oil and other plant oils.
Terpineol is a viscous liquid with pine like and clove like odor, but is easy to crystallize.
Terpineol is usually a mixture of these isomers with α-terpineol as the major constituent.

CAS Number: 98-55-5
EC Number: 202-680-6
Empirical Formula: C10H18O
Molecular Weight: 154.25

Terpineol is any of four isomeric monoterpenoids.
Terpenoids are terpene that are modified by the addition of a functional group, in this case, an alcohol.

Terpineols have been isolated from a variety of sources such as cardamom, cajuput oil, pine oil, and petitgrain oil.
Four isomers exist: α-, β-, γ-terpineol, and terpinen-4-ol.

β- and γ-terpineol differ only by the location of the double bond.
Terpineol is usually a mixture of these isomers with α-terpineol as the major constituent.

α-Terpineol is a monoterpene that is found in the essential oils of certain plants, such as melaleuca alternifolia.
α-Terpineol is one of the major monoterpenes present in eucalyptus oil and has shown to have anti-inflammatory properties.

α-Terpineol has been shown to induce cell lysis and DNA fragmentation in human macrophages at low concentrations.
α-Terpineol also induces genotoxic effects when exposed to laser ablation and water vapor.

α-Terpineol is a tertiary monoterpenoid alcohol widely and commonly used in the flavors and fragrances industry for Terpineol sensory properties.
Terpineol is present in different natural sources, but Terpineol production is mostly based on chemical hydration using α-pinene or turpentine.

Moreover, many bioprocesses for the microbial production of α-terpineol via biotransformation of monoterpenes (limonene, α- and β-pinenes) are also available in the literature.
In addition to Terpineol traditional use, α-terpineol has also been evaluated in other application fields (e.g., medical), since some biological properties other than aroma, such as antioxidant, anti-inflammatory, antiproliferative, antimicrobial, and analgesic effects, among others, have been attributed to Terpineol.

Therefore, this review presents an original compilation of data regarding the production (extraction directly from nature; chemical synthesis; via biotechnological process), the chemical and biological properties, and the current market and novel applications of α-terpineol to guide further research in this area.
Considering the information presented, we believe that α-terpineol applications may transcend the flavors and fragrances industry in the future.

Terpineol is naturally found in pine oil, lavender oil, orange leaf oil, neroli oil and other plant oils.
α-terpineol, β-terpineol, γ-terpineol, and terpinen-4-ol are four isomers of terpineol.

α-terpineol is the major component.
Terpineol is a viscous liquid with pine like and clove like odor, but is easy to crystallize.

There are two methods for preparing terpineol.
The two-step preparation process is to use α-pinene as raw material to produce terpineol through hydration under acidic conditions.

The one-step method is to directly prepare terpineol by hydration reaction.
Terpineol is widely used in fragrance formulation, especially in soaps and synthetic detergents.

Rather than a regular terpene, terpineol is an umbrella term referring to several terpene alcohols.
A terpene alcohol shares many characteristics with regular terpenes, plus a distinct oxygen-containing hydroxyl on one side of the chemical.

Four different monoterpenes get grouped into the term “terpineol,” each with unique differences between their scents:

Alpha-terpineol features a light, lilac-like odor reminiscent of fresh peaches.
Beta-terpineol features a woodsy scent of fresh-cut trees.
Gamma-terpineol features a citrus-leaning aroma.

Terpinen-4-ol features earthy notes with a woody overtone.
Terpineol commonly occurs in more than 150 plants, including flowers, fruits, and spices such as apples, basil, limes, lilac, grapefruit, rosemary, eucalyptus, and pine trees.

The essential oil is often used in cosmetics or skincare products, such as soap, lotion, and perfume, and is favored for Terpineol soft lilac profile.
Terpineol can also enhance skin penetration, making Terpineol a very useful terpene for topicals and beauty products.

Terpineol often occurs in different teas, most noticeably in lapsang souchong tea with Terpineol piney, smoky aroma.
Terpineol is also often used as a flavoring element in condiments and baked goods.

Chemically 2-(4-Methylcyclohex-3-en-1-yl)propan-2-ol is a monoterpene alcohol that has been isolated from a variety of sources such as cajuput oil, pine oil, and petitgrain oil.
There are four isomers, alpha-, beta-, gamma-terpineol, and terpinen-4-ol. Beta- and gamma-terpineol differ only by the location of the double bond.

Terpineol is usually a mixture of these isomers with alpha-terpineol as the major constituent.
Alpha-Terpineol is one of the two most abundant aroma constituents of lapsang souchong tea;Terpineol, or more strictly, alpha-terpineol, is one of the most widespread of monocyclic monoterpenoid alcohols in nature.

Terpineol is found in flowers such as narcissus and freesia; herbs such as sage, marjoram, oregano, and rosemary; in the leaf oil of Ti-tree (Melaleuca alternifolia) and in the oil expressed from the peel of lemons.
Reports of the level of terpineol in oils occasionally vary considerably and one wonders how much this is due to variations in the plants and to variations in the isolation process since terpineol could be an artifact.

The layman will often describe the odor of terpineol as “pine disinfectant” since terpineol is, in fact, a major component of pine disinfectant.
Terpineol is prepared by distillation of turpentine in the presence of an acid which results in an opening of the ring of a-pinene to produce a-terpineol.

The driving force for the reaction comes from the release of the strain in the 4-membered ring in the a-pinene skeleton.
The initial step in the process is the protonation of the double bond in a-pinene.

This generates a carbocation center adjacent to the strained cyclobutane ring.
The ring strain can be released by movement of one pair of electrons from a single bond of the cyclobutane ring towards the positive charge with the formation of a double bond.
The resultant carbocation in the tail of the molecule can then be quenched by addition of water followed by loss of a proton), giving alpha-terpineol.
Terpineols are monocyclic monoterpene tertiary alcohols which are naturally present in plant species.
There are five common isomers of terpineols, alpha-, beta-, gamma-, delta- and terpinen-4-ol, of which α-terpineol and Terpineol isomer terpinen-4-ol are the most common terpineols found in nature.

α-Terpineol plays an important role in the industrial field.
Terpineol has a pleasant odor similar to lilacs and Terpineol is a common ingredient in perfumes, cosmetics, and aromatic scents.

In addition, α-terpineol attracts a great interest as Terpineol has a wide range of biological applications as an antioxidant, anticancer, anticonvulsant, antiulcer, antihypertensive, anti-nociceptive compound.
Terpineol is also used to enhance skin penetration, and also has insecticidal properties.

Terpineol is a transparent or a pale yellow solvent, and has unique aroma like lilac and appropriate viscosity.
Terpineol is contained in natural oil.
Terpineol consists of a lot of isomers which are derivatives of p-menthene.

Terpineol is a mixture which usually contains alpha-terpineol as a main constituent, and also contains beta-terpineol and gamma-terpineol as accessory constituents.

Terpineol has sometimes deposition with decreasing of temperature, because all of these three constituents have high melting point.
Although Terpineol is insoluble in water, Terpineol has high solubility in organic solvents like alcohol, ether, ester, and high solubility of ethylcellulose, acrylate resin, epoxy resin and so on.
Under the acidic condition, Terpineol is unstable.

On the contrary, under the basic condition, Terpineol is stable.
Terpineol has some interfacial activities like moistness, osmosis and dispersion.
This is one of the most commonly used solvents for electronic thick film paste

α-Terpineol is a monoterpene alcohol. Terpineol is one of the components responsible for the antifungal activity in Melaleuca alternifolia (tea tree) essential oil.
The reaction rate constant of α-terpineol with the OH radical and ozone was found to be (1.9±0.5)×10-10cm3 molecule-1s-1 and (3.0±0.2)×10-16cm3 molecule-1s-1, respectively.

Alpha-terpineol is used as an antioxidant, antiseptic, antihypernociception and anti-inflammatory.
Terpineol is also used as a solvent.

Terpineol is an important ingredient of pine oil disinfectants.
Further, Terpineol is used as a fragrance in perfumes, fat denaturant for soap production and synthetic flavoring agent.

Alpha-Terpineol is a valuable intermediate in the perfume industry and in making other common volatile chemicals.
Terpineol is known to be prepared in several ways.

Terpenic alcohols are normally obtained by the addition of hydrochloric acid or a lower alkanoic acid to terpenic olefins, for example formic or acetic acid, by conversion of the olefin to Terpineol hydrochloride, or ester, and then hydrolysis to the desired alcohol.
Alternatively, there are useful methods such as direct hydration of olefins using a strong cation exchange resin.

In this study, in addition to obtaining terpinehydrate as a result of hydration of Alpha-pinene and then Alphaterpineol by dehydration, studies were also carried out using ion exchange resin.
In addition, with the aim of preventing polymerization, cation exchange resin was studied in an oxygen-free environment and alpha-terpineol was obtained with a good yield.

α-Terpineol is a terpene alcohol that is found in natural oils such as pine oil and petitgrain (the oil from the bitter orange tree).
Terpineol is the most common of four structural isomers; the others are β-, γ-, and 4-terpineol.
Terpineol should not be confused with terpinol, the hydrate of terpin, a terpene diol.

α-Terpineol is a racemic mixture of (R)-(+)- and (S)-(–)-enantiomers.
Both are found in nature; but the article of commerce, which is usually synthesized from α-pinene, is the racemate.

In 1903, German chemists H. Waldbaum and O. Hüthig isolated the (+)-stereoisomer from petitgrain.
Four years later, J. E. Teeple of New York City separated Terpineol enantiomer from long-leaf pine oil.

The lilac-like aroma of α-terpineol makes Terpineol a desirable ingredient for perfumes and cosmetics.

Terpineol has a pleasant odor similar to lilac and is a common ingredient in perfumes, cosmetics, and flavors.
α-Terpineol is one of the two most abundant aroma constituents of lapsang souchong tea; the α-terpineol originates in the pine smoke used to dry the tea.
(+)-α-terpineol is a chemical constituent of skullcap.

Alpha-terpineol is a terpineol that is propan-2-ol substituted by a 4-methylcyclohex-3-en-1-yl group at position 2.
Terpineol has a role as a plant metabolite.

Terpineol is a cyclic monoterpenoid alcohol.
Terpineol inhalation diminished mouse motility 45%.

Terpineol displayed dose-dependent antibiotic efficacy vs S. aureus, S. epidermidis, and P. acnes, among others, particularly in Terpineol customary vehicle of tea tree oil.
An MIC of 0.78 μL/mL was noted on Escherichia coli, with observed cell wall and membrane rupture.

α-Terpineol 100 μg/disk produced significant zones of inhibition in culture of four drug-resistant Helicobacter pylori cultures.
Moderate effects against two strains of Plasmodium falciparum malaria were noted in an EO with major terpineol component.

The small cell lung cancer cell line NCI-H69 was sensitive to α-terpineol at a high dose (IC50 approximately 260 μM) via suppression of NF-κB signaling (Hassan, Gali-Muhtasib, Goransson, & Larsson, 2010).
In a U937 leukemia cell line, α-terpineol reduced LPS-induced cytokine production of IL-1β, IL-6, and IL-10, but not TNF-α.

Nociceptive behavior in mice was significantly reduced by doses of 25 mg/kg ip and above on early and late paw licking post formalin, writhing after ip acetic acid, and after paw injections of glutamate or capsaicin, without motor impairment.
Similarly, 50–100 mg/kg ip dosing in mice inhibited hyperalgesia postcarageenan or TNF-α, PGE2, or DA administration, and neutrophil migration in a pleurisy model.

Terpineol was reported that fatty liver was produced in mice after daily injections of 10 or 500 mg/kg ip of α-terpineol for 2 weeks, an exposure level likely never attainable with a cannabis-based medicine.

Two recent studies from Iran are of interest.
Pretreatment with α-terpineol 5–20 mg/kg ip significantly reduced jumping behavior typical of withdrawal effect in mice rendered morphine-dependent, while 20–40 mg/kg ip doses reduced the development of tolerance to morphine analgesia.
These results suggest possible synergy of this ingredient with other cannabis components attenuating addiction: CBD and BCP.

Higher doses of α-terpineol (50–200 mg/kg ip) in rats subjected to cerebral ischemia improved spatial learning in a water maze vs controls, restored hippocampal long-term potentiation, and lowered malondialdehyde levels indicative of lipid peroxidation.
This activity certainly suggests the possibility of synergistic benefit in conjunction with benefits ascribed to CBD in similar experiments in newborn pigs.

(L)-alpha-Terpineol is a monoterpene alcohol.
Terpineol is one of the components responsible for the antifungal activity of Melaleuca alternifolia (tea tree) essential oil.
α-Terpineol may be used in the synthesis of α-terpinyl esters of acetic acid and acetic anhydride via lipase-mediated esterification.

Uses of Terpineol:
Terpineol is major ingredient of pine oil disinfectants.
Terpineol is used as a fragrance in perfumes and soaps, fat denaturant for soap manufacturing, synthetic flavoring agent, organic solvent, antioxidant, and antiseptic.

Terpineol with its typical lilac odor is one of the most frequently used fragrance compounds.

Terpineol is used for synthesize Terpinyl formate and Terpineyl acetate.
The derivatives of terpineol are widely used in fragrance preparation.

Terpineol is used as raw material to prepare menthane-8-ol and unsaturated terpene mixtures
Terpineol is used as a solvent for color on glassware

Terpineol is used in agrochemicals, such as insecticide synergists
Terpineol is used as a tackifier monomer

Terpineol is used as a tobacco filler additive, the solution sprayed on the tobacco to increase the aroma and sweetness of the lilac, and improve the natural permeation of the smoke
Terpineol is used as electronic paste
Terpineol is used as a thermoplastic conductive silver peptizer

Industry Uses:
Cleaning agent
Flavoring and nutrient
Fragrance
Intermediates
Odor agents
Other (specify)
Solvent

Consumer Uses:
Fragrance
Odor agents
Solvent

Industrial Processes with risk of exposure:
Using Disinfectants or Biocides

Synthesis and Biosynthesis of Terpineol:
Although Terpineol is naturally occurring, terpineol is commonly manufactured from alpha-pinene, which is hydrated in the presence of sulfuric acid.

Limonene reacts with trifluoroacetic acid in a Markovnikov addition to a trifluoroacetate intermediate, which is easily hydrolyzed with sodium hydroxide to α-terpineol with 7% selectivity.
Side-products are β-terpineol in a mixture of the cis isomer, the trans isomer, and 4-terpineol.

The biosynthesis of α-terpineol proceeds from geranyl pyrophosphate, which releases pyrophosphate to give the terpinyl cation.
This carbocation is the precursor to many terpenes and terpenoids.
Terpineol hydrolysis gives terpineol.

Manufacturing Methods of Terpineol:
A common industrial method of alpha-terpineol synthesis consists of the hydration of alpha-pinene or turpentine oil with aqueous mineral acids to give crystalline cis-terpin hydrate (mp 117 °C), followed by partial dehydration to alpha-terpineol.
Suitable catalysts are weak acids or acid-activated silica gel.

Terpineol is used in extraction of essential oils, fractional distillation of pine oils, wood processing industry.

By heating terpin hydrate with phosphoric acid and distilling or with dilute sulfuric acid, using azeotropic separation; fractional distillation of pine oil.

General Manufacturing Information of Terpineol:

Industry Processing Sectors:
All Other Basic Organic Chemical Manufacturing
All Other Chemical Product and Preparation Manufacturing
Food, beverage, and tobacco product manufacturing
Oil and Gas Drilling, Extraction, and Support activities
Other (requires additional information)
Paint and Coating Manufacturing
Soap, Cleaning Compound, and Toilet Preparation Manufacturing

Handling and Storage of Terpineol:

Storage Conditions:

Conditions for safe storage, including any incompatibilities:
Keep container tightly closed in a dry and well-ventilated place.

Stability and reactivity of Terpineol:

Reactive Hazard:
None known, based on information available

Stability:
Stable under normal conditions.

Conditions to Avoid:
Excess heat.
Keep away from open flames, hot surfaces and sources of ignition.

Incompatible Materials:
Strong oxidizing agents

Hazardous Decomposition:
Products Carbon monoxide (CO), Carbon dioxide (CO2)

Hazardous Polymerization:
Hazardous polymerization does not occur. Hazardous Reactions None under normal processing.

First-aid measures of Terpineol:

General Advice:
If symptoms persist, call a physician.

Eye Contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Getmedical attention.

Skin Contact:
Wash off immediately with plenty of water for at least 15 minutes.
If skin irritationpersists,call a physician.

Inhalation:
Remove to fresh air.
If not breathing, give artificial respiration.
Get medical attentionif symptoms occur.

Ingestion:
Clean mouth with water and drink afterwards plenty of water.

Most important symptoms and effects:
None reasonably foreseeable.
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.

Notes to Physician:
Treat symptomatically

Fire Fighting Procedures of Terpineol:

Advice for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.
Use water spray to cool unopened containers.

Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Accidental Release Measures of Terpineol:

Cleanup Methods:

Control of environmental exposure:
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.

Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment.
Avoid breathing vapors, mist or gas.

Ensure adequate ventilation.
Remove all sources of ignition.

Evacuate personnel to safe areas.
Beware of vapors accumulating to form explosive concentrations.
Vapors can accumulate in low areas.

Environmental precautions:
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.

Methods and materials for containment and cleaning up:
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations.
Keep in suitable, closed containers for disposal.

Disposal Methods of Terpineol:
Recycle any unused portion of Terpineol for its approved use or return Terpineol to the manufacturer or supplier.

Ultimate disposal of the chemical must consider:
Terpineol's impact on air quality; potential migration in air, soil or water; effects on animal, aquatic and plant life; and conformance with environmental and public health regulations.
If Terpineol is possible or reasonable use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination.

Waste treatment methods:
Contact a licensed professional waste disposal service to dispose of Terpineol.
This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber.
Offer surplus and non-recyclable solutions to a licensed disposal company.

Contaminated packaging:
Dispose of as unused product.

Identifiers of Terpineol:
CAS Number:
α: 98-55-5
β: 138-87-4
γ: 586-81-2
4-: 562-74-3

Beilstein Reference: 2325137

ChEBI:
α: CHEBI:22469
β: CHEBI:132899
γ: CHEBI:81151
4-: CHEBI:78884

ChEMBL:
α: ChEMBL507795
4-: ChEMBL507795

ChemSpider:
α: 13850142
β: 8418
γ: 10983
4-: 10756

EC Number:
α: 202-680-6
β: 205-342-6
γ: 209-584-3
4-: 209-235-5

KEGG:
β: C17517
4-: C17073

PubChem CID:
α: 17100
β: 8748
γ: 11467
4-: 11230

UNII:
α: 21334LVV8W
γ: 5PH9U7XEWS

CompTox Dashboard (EPA): 4-: DTXSID4044824
InChI: InChI=1S/C10H18O/c1-8-4-6-9(7-5-8)10(2,3)11/h4,9,11H,5-7H2,1-3H3
Key: WUOACPNHFRMFPN-UHFFFAOYSA-N
α: InChI=1/C10H18O/c1-8-4-6-9(7-5-8)10(2,3)11/h4,9,11H,5-7H2,1-3H3
Key: WUOACPNHFRMFPN-UHFFFAOYAL
SMILES: α: C\C1=C\CC(CC1)C(O)(C)C

EC number: 233-986-8
Hill Formula: C₁₀H₁₈O
Molar Mass: 154.25 g/mol
HS Code: 2906 19 00

EC / List no.: 232-268-1

Synonym(s): alpha-Terpineol
Empirical Formula (Hill Notation): C10H18O
CAS Number: 98-55-5
Molecular Weight: 154.25
Beilstein: 2325137
EC Number: 233-986-8
MDL number: MFCD00001557
PubChem Substance ID: 24867093
NACRES: NA.22

Empirical formula: C10H18O
Molar mass (M): 154,25 g/mol
Density (D): 0,93 g/cm³
Boiling point (bp): 218,9 °C
Flash point (flp): 91 °C
Melting point (mp): 33 °C
Storage temp.: +4 °C
WGK: 1
CAS No.: 98-55-5
EG-Nr.: 202-680-6

CAS: 98-55-5
Molecular Formula: C10H18O
Molecular Weight (g/mol): 154.253
MDL Number: MFCD00001557
InChI Key: WUOACPNHFRMFPN-UHFFFAOYSA-N
PubChem CID: 17100
ChEBI: CHEBI:22469
IUPAC Name: 2-(4-methylcyclohex-3-en-1-yl)propan-2-ol
SMILES: CC1=CCC(CC1)C(C)(C)O

Properties of Terpineol:
Chemical formula: C10H18O
Molar mass: 154.253 g·mol−1
Appearance: Colorless liquid
Density: 0.93 g/cm3
Melting point: −35.9 to −28.2 °C (−32.6 to −18.8 °F; 237.2 to 245.0 K) (mixture of isomers)
Boiling point: 214–217 °C (417–423 °F; 487–490 K)[1] (mixture of isomers)
Solubility in water: 2.42 g/L
Magnetic susceptibility (χ): −111.9·10−6 cm3/mol

Boiling point: 215 - 217 °C (1013 hPa)
Density: 0.934 g/cm3 (25 °C)
Flash point: 96 °C
Melting Point: 31 - 35 °C
Vapor pressure: <0.1 hPa (20 °C)

Grade: technical grade
Quality Level: 100
Assay: 90%
Refractive index: n20/D 1.482 (lit.)
bp: 217-218 °C (lit.)
mp: 31-35 °C (lit.)
Density: 0.93 g/mL at 25 °C (lit.)
SMILES string: CC1=CC[C@H](CC1)C(C)(C)O
InChI: 1S/C10H18O/c1-8-4-6-9(7-5-8)10(2,3)11/h4,9,11H,5-7H2,1-3H3
InChI key: WUOACPNHFRMFPN-UHFFFAOYSA-N

Molecular Weight: 154.25 g/mol
XLogP3-AA: 1.8
Hydrogen Bond Donor Count: 1
Hydrogen Bond Acceptor Count: 1
Rotatable Bond Count: 1
Exact Mass: 154.135765193 g/mol
Monoisotopic Mass: 154.135765193 g/mol
Topological Polar Surface Area: 20.2Ų
Heavy Atom Count: 11
Complexity: 168
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 1
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes

Specifications of Terpineol:
Assay (GC, area%): ≥ 98.0 % (a/a)
Optical rotation α 20/D (c=20 in Ethanol): -102.5 - -97.5 °
Identity (IR): passes test

Melting Point: 31°C to 32°C
Color: Colorless to Yellow
Density: 0.930 g/mL
Boiling Point: 210°C to 219°C
Flash Point: 90°C (194°F)
Refractive Index: 1.483
Quantity: 25 g
Merck Index: 14,9171
Solubility Information: Miscible with water,benzene,propylene glycol,acetone,alcohol and ether.
Formula Weight: 154.24
Percent Purity: 96%
Physical Form: Liquid
Chemical Name or Material: alpha-Terpineol

Related Products of Terpineol:
Nivalenol
(R)-Ochratoxin α
Di-N-heptytin Dichloride-D30
Ergosinine
3-Ethyl-2

Names of Terpineol:

Regulatory process names:
Terpineol
Terpineol
Terpineol (mixture of isomers)

IUPAC names:
1-hydroperoxy-2,7,7-trimethyl-bicyclo[3.1.1]heptane
1-methyl-4-(propan-2-ylidene)cyclohexan-1-ol; 2-[(1R)-4-methylcyclohex-3-en-1-yl]propan-2-ol; 2-[(1S)-4-methylcyclohex-3-en-1-yl]propan-2-ol
2-(4-Methyl- 1-cyclohex- 3-enyl) propan- 2-ol
2-(4-Methyl-1-cyclohex-3-enyl)propan- 2-ol
2-(4-methyl-1-cyclohex-3-enyl)propan-2-ol
2-(4-Methyl-3-cyclohexen-1-yl)-2-propanol - 4-isopropenyl-1-methylcyclohexanol (1:1)
2-(4-METHYLCYCLOHEX-3-EN-1-YL)PROPAN-2-OL
2-(4-Methylcyclohex-3-en-1-yl)Propan-2-ol
2-(4-Methylcyclohex-3-en-1-yl)propan-2-ol
2-(4-methylcyclohex-3-en-1-yl)propan-2-ol
Reaction mass of p-menth-1-en-8-ol and 1-methyl-4-(1-methylethylidene)cyclohexan-1-ol
Reaction mass of p-menth-1-en-8-ol and 1-methyl-4-(1-methylvinyl)cyclohexan-1-ol and 1-methyl-4-(1-methylethylidene)cyclohexan-1-ol
Reaction mass of p-menth-1-en-8-ol and 1-methyl-4-(1-methylvinyl)cyclohexan-1-ol and 1-methyl-4-(1-methylethylidene)cyclohexan-1-ol and α,α-dimethyl-4-methylenecyclohexanemethanol
Reaction mass of α,α-4-trimethyl-(1S)-3-cyclohexene-1-methanol and α,α-4-trimethyl-(1R)-3-cyclohexene-1-methanol and 1-methyl-4-(1-methylethylidene)-cyclohexanol
TERPINEOL
Terpineol
terpineol
Terpineol
Terpineol with impurities~
Terpineol; p-Menthenol (mixed isomers)

IUPAC names:
p-Menth-1-en-8-ol
2-(4-Methylcyclohex-3-en-1-yl)propan-2-ol

Trade names:
PINE OIL
Pine Oil

Other names:
2-(4-Methyl-1-cyclohex-3-enyl)propan-2-ol
alpha-terpineol
α-terpineol
α,α,4-Trimethylcyclohex-3-ene-1-methanol
Terpene alcohol

Other identifier:
8000-41-7

Synonyms of Terpineol:
alpha-TERPINEOL
Terpineol
98-55-5
2-(4-methylcyclohex-3-en-1-yl)propan-2-ol
p-Menth-1-en-8-ol
8000-41-7
dl-alpha-Terpineol
1-p-Menthen-8-ol
.alpha.-Terpineol
Terpineol 350
1-Menthene-8-ol
CARVOMENTHENOL
TERPINEOLS
FEMA No. 3045
8006-39-1
1-Methyl-4-isopropyl-1-cyclohexen-8-ol
alpha,alpha,4-Trimethyl-3-cyclohexene-1-methanol
2-(4-Methyl-3-cyclohexenyl)-2-propanol
Terpineol schlechthin
Terpenol
alpha-Terpinenol
1-Methyl-4-isopropyl-1-cyclohexene-8-ol
MFCD00001557
DTXSID5026625
CHEBI:22469
1-alpha-terpineol
21334LVV8W
NSC-21449
NSC-403665
NCGC00164431-01
NSC 21449
PC 593
DSSTox_CID_6625
DSSTox_RID_79596
DSSTox_GSID_40775
Terpilenol, alpha-
3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl-
Terpene alcohol
FEMA Number 3045
alpha-Terpineol, analytical standard
alpha-Terpineol (natural)
Menth-1-en-8-ol
2-(4-methylcyclohex-3-enyl)propan-2-ol
alpha-TERPINEOL (PROPYL METHYL-D3)
CAS-8000-41-7
CCRIS 3204
3-Cyclohexene-1-methanol,.alpha.4-trimethyl-
Caswell No. 823
HSDB 5316
EINECS 202-680-6
EINECS 219-448-5
3-Cyclohexene-1-methanol, alpha,alpha,4-trimethyl-
BRN 1906604
UNII-R53Q4ZWC99
Alfa_terpineol
UNII-21334LVV8W
AI3-00275
Terpineol Normal
alpha -Terpineol
DL a-terpineol
Menthen-8-ol
EINECS 232-268-1
EPA Pesticide Chemical Code 067005
ALFA-TERPINEOL
1-p-Menthen-8-
TERPINEOL OR
.ALPHA.TERPINEOL
TERPINEOL, ALPHA
d-1-p-Menthen-8-ol
(+)-.alpha.-Terpineol
3-Cyclohexene-1-methanol, .alpha.,.alpha.4-trimethyl-
EC 202-680-6
EC 232-268-1
alpha-Terpineol, AldrichCPR
SCHEMBL28466
ALPHA-TERPINEOL [FCC]
3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl-, (S)-
ALPHA-TERPINEOL [HSDB]
(1)-alpha,alpha,4-Trimethylcyclohex-3-ene-1-methanol
CHEMBL449810
DTXCID406625
R53Q4ZWC99
.ALPHA.-TERPINEOL [II]
.ALPHA.-TERPINEOL [MI]
ALFA-TERPINEOL [WHO-DD]
MIL-350
.ALPHA.-TERPINEOL [FHFI]
HY-N5142
NSC21449
Tox21_112118
Tox21_200112
Tox21_302298
c0669
NSC403665
PC-593
3-Cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl-, sodium salt, (1S)-
AKOS015840815
alpha-Terpineol, 90%, technical grade
SB45068
CAS-98-55-5
NCGC00248528-01
NCGC00255464-01
NCGC00257666-01
DB-059206
alpha-Terpineol 1000 microg/mL in n-Hexane
CS-0032554
FT-0622202
FT-0627680
FT-0698995
FT-0772029
T0022
T0984
2-(4-methyl-1-cyclohex-3-enyl)-propan-2-ol
D70165
EN300-125883
(1R)-a,a,4-trimethyl-3-cyclohexene-1-methanol
SR-01000944873
J-500272
SR-01000944873-1
TERPIN MONOHYDRATE IMPURITY A [EP IMPURITY]
W-100076
Q27109437
F0001-2319
Z1255427148
alpha-Terpineol, primary pharmaceutical reference standard
3-CYCLOHEXENE-1-METHANOL, ALPHA., .ALPHA., 4-TRIMETHYL-
22347-88-2
(±)-α-Terpineol
2-(4-Methyl-3-cyclohexen-1-yl)-2-propanol [ACD/IUPAC Name]
2-(4-Methyl-3-cyclohexen-1-yl)-2-propanol [German] [ACD/IUPAC Name]
2-(4-Méthyl-3-cyclohexèn-1-yl)-2-propanol [French] [ACD/IUPAC Name]
202-680-6 [EINECS]
2325137 [Beilstein]
3-Cyclohexene-1-methanol, α,α,4-trimethyl- [ACD/Index Name]
98-55-5 [RN]
L6UTJ A1 DXQ1&1 [WLN]
MFCD00001557 [MDL number]
Terpineol [Wiki]
α-Terpineol

(S)-(-)-Terpineol
1906604 [Beilstein]
1-Menthene-8-ol
1-methyl-4-isopropyl-1-cyclohexen-8-ol
1-methyl-4-isopropyl-1-cyclohexene-8-ol
1-p-Menthen-8-ol
1-α-terpineol
2-(4-methyl-3-cyclohexenyl)-2-propanol
2-(4-METHYL-3-CYLOHEXENYL)ISOPROPANOL
2-(4-methylcyclohex-3-en-1-yl)propan-2-ol; p-menth-1-en-8-ol
2-(4-methylcyclohex-3-enyl)propan-2-ol
2-(4-Methyl-cyclohex-3-enyl)-propan-2-ol
202-680-6MFCD00001557
2041428 [Beilstein]
21334LVV8W
21M14KDA67
22347-88-2 [RN]
232-081-5 [EINECS]
232-268-1MFCD00166983
260450-76-8 [RN]
3-Cyclohexene-1-methanol, &α
3-Cyclohexene-1-methanol, α,α,4-trimethyl-
3-Cyclohexene-1-methanol, α,α4-trimethyl-
4-(2-Hydroxy-2-propyl)-1-methylcyclohexene
7785-53-7 [RN]
8006-39-1 [RN]
8-Hydroxy-p-menth-1-ene
a-Terpineol
dl-α-Terpineol
Menth-1-en-8-ol
MFCD00075926 [MDL number]
MFCD00166983 [MDL number]
MFCD00171435
P-MENTH-1-EN-8-OL
Terpenol
-Terpineol
Terpineol, α
TERPINEOL, α
Terpinol
UNII:21334LVV8W
α,α,4-Trimethyl-3-cyclohexene-1-methanol
α,α,4-Trimethyl-3-Cyclohexene-1-methanol
α-Terpinenol
α-terpineo
α-terpineol
α-Terpineol
α-Terpineole
α-Terpinol
α-Terpinol
松油醇 [Chinese]
TERPINEOL
TERPINOLENE, N° CAS : 586-62-9, Nom INCI : TERPINOLENE. Nom chimique : p-Mentha-1,4(8)-diene; 1-Methyl-4-isopropylidene-1-cyclohexene; Terpinene. N° EINECS/ELINCS : 209-578-0, Classification : Règlementé. Ses fonctions (INCI). Agent parfumant : Utilisé pour le parfum et les matières premières aromatiques. Noms français : 1,4(8)-TERPADIENE 1-METHYL-4-(1-METHYLETHYLIDENE) 1-METHYL-4-ISOPROPYLIDENE-1-CYCLOHEXENE 4-ISOPROPYLIDENE-1-METHYLCYCLOHEXENE CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHYLIDENE)- METHYL-1 (METHYL-1 ETHYLIDENE)-4 CYCLOHEXENE P-MENTHA-1,4(8)-DIENE Terpinolene Noms anglais : TERPINOLEN Utilisation et sources d'émission Agent de saveur, fabrication de résines
TERPINOLEN ( TERPINOLENE)
Les terpinéols, ou terpinols ou encore terpinoles, sont des alcools monoterpéniques (monoterpénols) monocycliques insaturés de formule brute C10H18O. La plupart de ces monoterpénoïdes se trouvent dans l'huile essentielle de pins et d'autres arbres ainsi que dans des plantes (lavande, genévrier, livèche et marjolaine, notamment).2-(4-méthyl-1-cyclohex-3-ényl)propan-2-ol Synonymes : 1-p-menthèn-8-ol, p-menth-1-èn-8-ol, 2-(4-méthyl-3-cyclohexényl)-2-propanol, α,α,4-triméthylcyclohex-3-ène-1-méthanol, alcool terpénique, No CAS 98-55-5 (RS).La dénomination « terpinéol » correspond en général à un mélange d'isomères, avec comme constituant principal l'alpha-terpinéol (α-terpinéol). Le terpinéol a une odeur de muguet (essence de muguet), de lilas, de jacinthe6 et est utilisé dans des savons et en cosmétique
Terpinéol
Cas : 586-62-9, EC : 209-578-0, Terpinolène pur ; cyclohexène, 1-méthyl-4-(1-méthylethylidène) ; 1-méthyl-4-propan-2-ylidenecyclohexène ; pmentha-1,4(8) -diène / Pure terpinolène ; cyclohexene, 1-methyl-4-(1-methylethylidene) ; 1-methyl-4-propan-2-ylidenecyclohexene ; p-mentha-1,4(8) -diene, Terpinolène pur / Cyclohexène, 1-methyl-4-(1-methylethylidène) / 1-methyl-4-propan-2-ylidenecyclohexene / p-mentha-1,4(8)-diene.Terpinolene Alpha; 1-methyl-4(1-methylethylidene) cyclohex-1-ene; 1-METHYL-4-(1-METHYLETHYLIDENE)CYCLOHEX-1-ENE; 1-Methyl-4-(1-methylethylidene)cyclohexene; 1-methyl-4-(propan-2-ylidene)cyclohex-1-ene; 1-Methyl-4-isopropylidene-1-cyclohexene; 1-methyl-4-propan-2-ylidenecyclohexene; 4-Isopropyliden-1-Methylcyclohexene; 4-Isopropylidene-1-methylcyclohexene; p-Menth-1,4,8-dien; p-Mentha-1,4(8)-dien; Terpinolene Alpha
TERT AMYL PERPIVALATE
DESCRIPTION:

Tert Amyl Perpivalate is an initiator for (co)polymerization of vinyl chloride and vinylidene chloride.

CAS No.: 29240-17-3
Molecular Formula:C10H20O3
Molecular Weight:188.26

APPLICATIONS OF TERT AMYL PERPIVALATE:
Polymerization of vinyl chloride: Tert Amyl Perpivalate can be applied as an initiator for the suspension polymerization of vinyl chloride in the temperature range between 50°C and 65°C.
Tert Amyl Perpivalate may be used in combination with other initiators to increase reactor efficiency


CHEMICAL AND PHYSICAL PROPERTIES OF TERT AMYL PERPIVALATE:
Boiling point 204.0±23.0 °C(Predicted)
Density 0.924±0.06 g/cm3(Predicted)
vapor pressure 14Pa at 35℃
Water Solubility 504mg/L at 20℃
LogP 3.3 at 30℃
Density: 0.9±0.1 g/cm3
Boiling Point: 204.0±23.0 °C at 760 mmHg
Vapour Pressure: 0.3±0.4 mmHg at 25°C
Enthalpy of Vaporization: 44.0±3.0 kJ/mol
Flash Point: 59.2±16.7 °C
Index of Refraction: 1.423
Molar Refractivity: 51.8±0.3 cm3
#H bond acceptors: 3
#H bond donors: 0
#Freely Rotating Bonds: 5
#Rule of 5 Violations: 0
ACD/LogP: 3.34
ACD/LogD (pH 5.5): 3.24
ACD/BCF (pH 5.5): 172.13
ACD/KOC (pH 5.5): 1386.89
ACD/LogD (pH 7.4): 3.24
ACD/BCF (pH 7.4): 172.13
ACD/KOC (pH 7.4): 1386.89
Polar Surface Area: 36 Å2
Polarizability: 20.5±0.5 10-24cm3
Surface Tension: 27.1±3.0 dyne/cm
Molar Volume: 203.5±3.0 cm3
PSA:
35.53000
XLogP3:
2.69590
Density:
0.924 g/cm3
Boiling Point:
204ºC at 760 mmHg
Flash Point:
59.2ºC
Refractive Index:
1.422
Vapor Pressure:
0.269mmHg at 25°C
Molecular Weight:188.26
XLogP3:3.1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:188.14124450
Monoisotopic Mass:188.14124450
Topological Polar Surface Area:35.5
Heavy Atom Count:13
Complexity:177
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
Appearance colorless and transparent liquid
Active Content ≥99%
Density 0.806~0.810
Water ≤0.1%
Color APHA ≤10


SAFETY INFORMATION ABOUT TERT AMYL PERPIVALATE:
First aid measures:
Description of first aid measures:
General advice:
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Move out of dangerous area:

If inhaled:
If breathed in, move person into fresh air.
If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact:
Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Consult a physician.

In case of eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Continue rinsing eyes during transport to hospital.

If swallowed:
Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.
Rinse mouth with water.
Consult a physician.

Firefighting measures:
Extinguishing media:
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas

Advice for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.
Accidental release measures:
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment.

Avoid breathing vapours, mist or gas.
Evacuate personnel to safe areas.

Environmental precautions:
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up:
Soak up with inert absorbent material and dispose of as hazardous waste.
Keep in suitable, closed containers for disposal.

Handling and storage:
Precautions for safe handling:
Avoid inhalation of vapour or mist.

Conditions for safe storage, including any incompatibilities:
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials

Exposure controls/personal protection:
Control parameters:
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls:
Appropriate engineering controls:
Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.

Personal protective equipment:
Eye/face protection:
Tightly fitting safety goggles.
Faceshield (8-inch minimum).
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection:
Handle with gloves.
Gloves must be inspected prior to use.
Use proper glove
removal technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.

Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
It should not be construed as offering an approval for any specific use scenario.

Body Protection:
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection:
Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.

If the respirator is the sole means of protection, use a full-face supplied air respirator.
Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Stability and reactivity:
Chemical stability:
Stable under recommended storage conditions.
Incompatible materials:
Strong oxidizing agents:
Hazardous decomposition products:
Hazardous decomposition products formed under fire conditions.
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas.

Disposal considerations:
Waste treatment methods:
Product:
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging:
Dispose of as unused product




SYNONYMS OF TERT AMYL PERPIVALATE:
tert-Amyl peroxypivalate;
tert-Amyl perpivalate;
tert.-Amylperoxypivalat21;
tert-pentyl peroxypivalate;
2-methylbutan-2-yl 2,2-dimethylpropaneperoxoate;
tert-Amyl perxypivalate(in solution,content≤77%);
2,2-Dimethylperoxypropionic acid tert-amyl ester;
2,2-dimethylpropaneperoxoic acid 2-methylbutan-2-yl ester;
2,2-Dimethylpropaneperoxoic acid 1,1-dimethylpropyl ester;
2,2-Dimethylperoxypropionic acid 1,1-dimethylpropyl ester
2,2-Diméthylpropaneperoxoate de 2-méthyl-2-butanyle [French] [ACD/IUPAC Name]
249-530-6 [EINECS]
29240-17-3 [RN]
2-Methyl-2-butanyl 2,2-dimethylpropaneperoxoate [ACD/IUPAC Name]
2-Methyl-2-butanyl-2,2-dimethylpropanperoxoat [German] [ACD/IUPAC Name]
2-Methylbutan-2-yl 2,2-dimethylpropaneperoxoate
Propaneperoxoic acid, 2,2-dimethyl-, 1,1-dimethylpropyl ester [ACD/Index Name]
tert-Amyl peroxypivalate
2,2-dimethylpropaneperoxoic acid 2-methylbutan-2-yl ester
3007-97-4 [RN]
Propaneperoxoic acid,2,2-dimethyl-, 1,1-dimethylpropyl ester
t-Amyl Peroxypivalate
tert-Amylperpivalate
tert-pentyl peroxypivalate



tert Butyl Catechol
cas no 21564-17-0 2-(Thiocyanomethylthio)benzothiazole; Thiocyanic acid 2- (benzothiazolethio) methyl ester; (1,3-benzothiazol-2-yl)sulfanyl]methyl thiocyanate; 2-(Thiocyanatomethylthio)-1,3-benzothiazole, Benthiazole, TCMTB, Thiocyanic acid 2-(benzothiazolylthio)methyl ester;
TERT BUTYL HYDROPEROXIDE %70
Tert-butyl hydroperoxide (TBHP) is a chemical compound with the molecular formula C4H10O2.
The "%70" in the name indicates that it is a solution of tert-butyl hydroperoxide with a concentration of 70%.
This means that in a given volume of this solution, 70% of the content is tert-butyl hydroperoxide, while the remaining 30% typically consists of a solvent or stabilizing agent, such as water.
Tert butyl hydroperoxide %70 is a peroxide compound commonly used as a radical initiator in various chemical reactions, particularly in the field of organic chemistry.

CAS Number: 75-91-2
EC Number: 200-915-7



APPLICATIONS


Tert butyl hydroperoxide %70 is primarily used as a radical initiator in the polymerization of monomers to create various polymers and plastics.
Tert butyl hydroperoxide %70 finds extensive use in the production of polystyrene, polyethylene, and polypropylene, among other polymer materials.
Tert butyl hydroperoxide %70 plays a vital role in the synthesis of acrylic polymers, such as polyacrylates and polymethyl methacrylate (PMMA).

Tert butyl hydroperoxide %70 is utilized in the manufacture of elastomers, including synthetic rubber products.
Tert butyl hydroperoxide %70 is an essential component in the production of epoxy resins and adhesives used in construction and automotive industries.
Tert butyl hydroperoxide %70 is used in the production of coatings and paints, contributing to their curing and cross-linking processes.
In the pharmaceutical industry, Tert butyl hydroperoxide %70 is employed in the synthesis of various pharmaceutical intermediates and active ingredients.
Tert butyl hydroperoxide %70 is a valuable reagent in the synthesis of specialty chemicals, including antioxidants, plasticizers, and surfactants.

Tert butyl hydroperoxide %70 is utilized in the production of fuel additives, particularly for improving the octane rating of gasoline.
Tert butyl hydroperoxide %70 is used in the preparation of peroxide-based initiators for radical polymerization reactions.
Tert butyl hydroperoxide %70 can be found in the formulation of hair dye products, where it assists in the development of color.

In the food industry, it may be used as a bleaching agent for certain food products, like fats and oils.
Tert butyl hydroperoxide %70 has applications in the manufacturing of paper and pulp, where it helps bleach wood pulp fibers.
Tert butyl hydroperoxide %70 is used in the treatment of wastewater and effluents to remove organic contaminants through oxidative processes.

In the textile industry, Tert butyl hydroperoxide %70 can be employed for bleaching and oxidative processes in fabric production.
Tert butyl hydroperoxide %70 finds use as a reagent in laboratory-scale organic chemistry experiments for oxidation reactions.
Tert butyl hydroperoxide %70 can be incorporated into the formulation of cleaning products for its bleaching and disinfecting properties.

Tert butyl hydroperoxide %70 is utilized in the production of polymeric materials for medical devices, such as catheters and tubing.
In the aerospace industry, Tert butyl hydroperoxide %70 may be used in the fabrication of composite materials for aircraft components.
Tert butyl hydroperoxide %70 plays a role in the synthesis of peracids, which are used as oxidizing agents in various chemical transformations.

Tert butyl hydroperoxide %70 is utilized in the production of agrochemicals, including herbicides and pesticides.
Tert butyl hydroperoxide %70 can be part of the formulation of oxygen scavengers used in food packaging to extend product shelf life.
In the cosmetics industry, Tert butyl hydroperoxide %70 may be used in the production of hair care products and skin treatments.

Tert butyl hydroperoxide %70 is a versatile reagent in research and development for its ability to initiate controlled radical polymerization reactions.
Tert butyl hydroperoxide %70 is subject to regulations and safety guidelines due to its reactivity, and its applications span various industries, from chemicals and plastics to pharmaceuticals and textiles.

Tert butyl hydroperoxide %70 is used in the production of specialty chemicals, including antioxidants, plasticizers, and lubricant additives.
Tert butyl hydroperoxide %70 is an important component in the formulation of hair color products, where it helps initiate the oxidative dyeing process.
In the petrochemical industry, Tert butyl hydroperoxide %70 can be used for refining petroleum products and removing impurities.

Tert butyl hydroperoxide %70 is employed in the synthesis of various organic peroxides, which find applications as initiators in polymerization reactions.
Tert butyl hydroperoxide %70 plays a role in the manufacturing of high-performance coatings and automotive finishes.

Tert butyl hydroperoxide %70 is used as a curing agent in the production of composite materials, such as fiberglass-reinforced plastics.
In the electronics industry, Tert butyl hydroperoxide %70 can be used in the fabrication of printed circuit boards (PCBs) and semiconductor devices.

Tert butyl hydroperoxide %70 is utilized as a bleaching agent for the treatment of wastewater and effluents in industrial processes.
Tert butyl hydroperoxide %70 may find application in the production of biodegradable polymers for environmentally friendly materials.

Tert butyl hydroperoxide %70 can be used in the synthesis of peresters, which are valuable intermediates in organic chemistry reactions.
In the cosmetics industry, Tert butyl hydroperoxide %70 may be used in the production of skincare products and hair care formulations.

Tert butyl hydroperoxide %70 can serve as an initiator for controlled radical polymerization reactions, allowing precise control over polymer properties.
Tert butyl hydroperoxide %70 is employed in the production of polymeric materials used in the construction and insulation industries.
Tert butyl hydroperoxide %70 can be part of the formulation of adhesive products for bonding various materials in construction and manufacturing.
In the automotive sector, Tert butyl hydroperoxide %70 may find use in the production of vehicle components and parts made from polymer materials.

Tert butyl hydroperoxide %70 is used in the development of polymer nanocomposites, which have enhanced properties due to the incorporation of nanoparticles.
Tert butyl hydroperoxide %70 can be utilized in the treatment of contaminated soil and groundwater through chemical oxidation processes.
Tert butyl hydroperoxide %70 plays a role in the synthesis of specialty surfactants used in the formulation of detergents and cleaning agents.

In the pharmaceutical industry, Tert butyl hydroperoxide %70 may be used in the synthesis of drug intermediates and pharmaceutical compounds.
Tert butyl hydroperoxide %70 can be applied as a reagent in the preparation of peracids used for industrial and laboratory purposes.

Tert butyl hydroperoxide %70 is used in the production of flame-retardant materials, improving fire safety in various applications.
Tert butyl hydroperoxide %70 can be employed in the formulation of paper coatings to enhance printability and appearance.

In the water treatment sector, Tert butyl hydroperoxide %70 may be used to eliminate organic contaminants and disinfect water supplies.
Tert butyl hydroperoxide %70 plays a role in the production of thermosetting resins used in the manufacturing of composites and molded products.
Tert butyl hydroperoxide %70 is subject to safety regulations and guidelines, ensuring its safe handling and use across diverse industrial and scientific applications.

Tert butyl hydroperoxide %70 is utilized in the formulation of polyurethane foams, providing structural integrity to foam-based products.
Tert butyl hydroperoxide %70 plays a role in the synthesis of polymeric materials used in the construction of pipelines and infrastructure.
Tert butyl hydroperoxide %70 can be part of the formulation of fuel additives designed to improve combustion efficiency and reduce emissions.

In the aerospace industry, it may find use in the fabrication of composite materials for aircraft components, including wings and fuselage parts.
Tert butyl hydroperoxide %70 is employed in the production of thermoplastic elastomers, which combine the properties of both rubber and plastic.

Tert butyl hydroperoxide %70 can be used in the manufacturing of adhesives and sealants for various applications, including automotive and aerospace.
Tert butyl hydroperoxide %70 is utilized in the creation of specialty polymers with unique properties, such as conductive polymers for electronic applications.
In the agricultural sector, Tert butyl hydroperoxide %70 may be employed in the synthesis of agrochemicals, including herbicides and insecticides.
Tert butyl hydroperoxide %70 plays a role in the production of flame-resistant textiles and materials for protective clothing.

Tert butyl hydroperoxide %70 can be used in the development of coatings for corrosion protection in the marine and offshore industries.
Tert butyl hydroperoxide %70 finds application in the preparation of peroxide-based initiators for radical copolymerization reactions.

In the food packaging industry, it may be used as an oxygen scavenger to extend the shelf life of packaged products.
Tert butyl hydroperoxide %70 is utilized in the formulation of dental materials, such as impression compounds and restorative resins.

Tert butyl hydroperoxide %70 is employed in the synthesis of advanced materials for 3D printing and additive manufacturing.
Tert butyl hydroperoxide %70 can be part of the formulation of specialty inks and coatings for printing applications.

In the automotive sector, Tert butyl hydroperoxide %70 may find use in the production of automotive interior components and trim.
Tert butyl hydroperoxide %70 is utilized in the manufacture of gaskets and seals for industrial and automotive equipment.
Tert butyl hydroperoxide %70 plays a role in the development of photoresist materials used in semiconductor lithography processes.
Tert butyl hydroperoxide %70 can be employed in the production of high-performance fibers and textiles used in sports and outdoor gear.

In the renewable energy sector, Tert butyl hydroperoxide %70 may be used in the fabrication of materials for solar panels and wind turbine blades.
Tert butyl hydroperoxide %70 is utilized in the synthesis of conductive inks and coatings for printed electronics applications.
Tert butyl hydroperoxide %70 can be part of the formulation of specialty polymers used in the construction of medical devices.

Tert butyl hydroperoxide %70 plays a role in the production of polymer nanocomposites with enhanced mechanical and thermal properties.
In the aerospace industry, Tert butyl hydroperoxide %70 may be employed in the fabrication of lightweight materials for aircraft interiors.
Tert butyl hydroperoxide %70 is subject to strict safety and handling protocols in industries where its reactivity and properties are critical for product quality and performance.



DESCRIPTION


Tert-butyl hydroperoxide (TBHP) is a chemical compound with the molecular formula C4H10O2.
The "%70" in the name indicates that it is a solution of tert-butyl hydroperoxide with a concentration of 70%.
This means that in a given volume of this solution, 70% of the content is tert-butyl hydroperoxide, while the remaining 30% typically consists of a solvent or stabilizing agent, such as water.

Tert butyl hydroperoxide %70 is a peroxide compound commonly used as a radical initiator in various chemical reactions, particularly in the field of organic chemistry.
Tert butyl hydroperoxide %70 can initiate free radical reactions by cleaving its oxygen-oxygen bond, leading to the formation of reactive radical species.
Tert butyl hydroperoxide %70 is known for its oxidizing properties and is used in various industrial applications and chemical processes.
As with any chemical compound, it should be handled and stored with appropriate safety precautions.

Tert butyl hydroperoxide %70 is a chemical compound that appears as a clear or slightly yellowish liquid solution.
Tert butyl hydroperoxide %70 is classified as an organic peroxide due to its peroxide functional group (-OOH).
Tert butyl hydroperoxide %70 has a molecular formula of C4H10O2.

Tert butyl hydroperoxide %70 contains 70% by weight of tert-butyl hydroperoxide in a solution.
The remaining 30% typically consists of a stabilizing agent or solvent, such as water.
Tert butyl hydroperoxide %70 is highly reactive and can decompose into free radicals when exposed to heat or other initiators.

Tert butyl hydroperoxide %70 is widely used as a radical initiator in various chemical reactions, especially in polymerization processes.
Tert butyl hydroperoxide %70 is known for its strong oxidizing properties and the ability to initiate polymerization reactions at relatively low temperatures.

Tert butyl hydroperoxide %70 is often used in the production of plastics, resins, and other polymer materials.
Tert butyl hydroperoxide %70 plays a crucial role in the synthesis of various organic compounds, including pharmaceuticals and specialty chemicals.

Tert butyl hydroperoxide %70 can be a valuable reagent in the laboratory for organic synthesis and oxidation reactions.
The tert-butyl group in the molecule provides steric hindrance, making Tert butyl hydroperoxide %70 a selective oxidizing agent in certain reactions.
Safety precautions must be taken when handling Tert butyl hydroperoxide %70, as it is flammable and can be hazardous if mishandled.
Tert butyl hydroperoxide %70 should be stored in a cool, well-ventilated area away from heat, open flames, and incompatible materials.

When using Tert butyl hydroperoxide %70 in chemical processes, appropriate personal protective equipment, such as gloves and goggles, is recommended.
Tert butyl hydroperoxide %70 is sensitive to temperature changes, and decomposition can occur if not stored correctly.

Tert butyl hydroperoxide %70 is also used in the production of fuel additives and specialty chemicals for various industries.
Tert butyl hydroperoxide %70 is considered a valuable tool in the field of organic chemistry for its versatility in initiating reactions.
The peroxide functional group (-OOH) readily undergoes homolytic cleavage to form radicals, which can propagate chemical reactions.

Tert butyl hydroperoxide %70 is an important reagent for the synthesis of peroxide-based initiators in radical polymerization processes.
When used as an initiator, Tert butyl hydroperoxide %70 can control the rate of polymerization and the molecular weight of the resulting polymer.

Its applications extend to the production of adhesives, coatings, and elastomers.
Tert butyl hydroperoxide %70 is subject to regulations and safety guidelines due to its reactivity and potential hazards.
Tert butyl hydroperoxide %70 is typically supplied in containers designed to prevent leakage or accidental exposure.



PROPERTIES


Physical Properties:

Appearance: Clear or slightly yellowish liquid.
Odor: Characteristic odor.
Density: Typically denser than water.
Boiling Point: Varies with concentration and pressure (ranges from approximately 40°C to 50°C).
Melting Point: Not applicable as it is a liquid.
Solubility: Miscible with many organic solvents; insoluble in water.
pH: Typically not applicable as it is not an aqueous solution.
Flash Point: Flammable; varies depending on concentration.
Vapor Pressure: Varies with temperature and concentration.
Viscosity: Low to moderate viscosity.


Chemical Properties:

Chemical Formula: C4H10O2.
Molecular Weight: Approximately 90.12 g/mol.
Chemical Structure: Contains the tert-butyl group (-C(CH3)3) and a hydroperoxy group (-OOH).
Reactivity: Highly reactive; can initiate radical reactions.
Decomposition: Decomposes when exposed to heat or other initiators, releasing free radicals.
Oxidizing Properties: Strong oxidizing agent.
Stability: Sensitive to temperature and contamination; should be stored under controlled conditions.



FIRST AID


Inhalation:

If inhaled and respiratory distress occurs, immediately move the affected person to an area with fresh air.
If the person is not breathing, administer artificial respiration.
Seek medical attention promptly and provide information about the exposure.


Skin Contact:

In case of skin contact with Tert butyl hydroperoxide %70, remove contaminated clothing and rinse the affected skin thoroughly with copious amounts of water for at least 15 minutes.
Use a mild soap to wash the exposed skin gently.
Do not use abrasive materials or scrub the skin, as it may exacerbate irritation.
Seek medical attention if skin irritation, redness, or other symptoms persist.


Eye Contact:

If Tert butyl hydroperoxide %70 comes into contact with the eyes, immediately flush the eyes with lukewarm water while keeping the eyelids open for at least 15 minutes.
Seek immediate medical attention, even if the irritation seems mild or transient.


Ingestion:

If accidental ingestion occurs, do not induce vomiting, as vomiting may expose the airway to the chemical.
Rinse the mouth thoroughly with water and drink plenty of water or milk if the individual is conscious and alert.
Seek immediate medical attention or contact a poison control center.
Provide information about the product and the amount ingested to medical professionals.



HANDLING AND STORAGE


Handling:

Personal Protective Equipment (PPE):
When handling Tert butyl hydroperoxide %70, always wear appropriate personal protective equipment (PPE), including safety goggles or a face shield, chemical-resistant gloves, and a lab coat or protective clothing to minimize the risk of skin and eye contact.

Ventilation:
Work in a well-ventilated area with local exhaust ventilation or a chemical fume hood to prevent the accumulation of vapors.
Ensure that the ventilation system effectively removes potentially hazardous fumes.

Avoid Open Flames and Heat:
Keep the product away from open flames, sparks, and heat sources, as Tert butyl hydroperoxide is flammable and can ignite at elevated temperatures.

No Smoking:
Smoking should be strictly prohibited in areas where Tert butyl hydroperoxide is handled or stored due to the fire hazard it presents.

Prevent Cross-Contamination:
Ensure that equipment, containers, and utensils used for handling and application are clean and free from contaminants.
Avoid cross-contamination with other chemicals or substances.

Avoid Mixing:
Do not mix Tert butyl hydroperoxide %70 with other substances or chemicals unless explicitly directed to do so by a qualified professional and following appropriate safety protocols.

Use in a Controlled Manner:
Dispense and apply the chemical in a controlled and precise manner to minimize waste and potential exposure.

Labeling:
Clearly label containers and storage areas with appropriate hazard warnings, contents, and safety information. Ensure that labels remain legible and intact.


Storage:

Cool and Dry Storage:
Store Tert butyl hydroperoxide %70 in a cool, dry, and well-ventilated area.
Maintain a stable temperature below 25°C (77°F) to minimize the risk of decomposition.

Protection from Light:
Protect the product from direct sunlight and sources of UV radiation, as light exposure can cause degradation.

Avoid Moisture:
Prevent moisture from entering containers, as it can lead to decomposition or loss of effectiveness.

Sealed Containers:
Keep containers tightly sealed when not in use to prevent contact with air, which can contribute to decomposition.

Incompatible Substances:
Store Tert butyl hydroperoxide %70 away from incompatible materials, such as reducing agents, flammable materials, strong acids, and strong bases.
Segregate it from incompatible chemicals to prevent hazardous reactions.

Separation:
Some settling or separation of the product may occur over time.
Ensure that the product is thoroughly mixed before use to maintain its consistency and properties.

Children and Pets:
Store Tert butyl hydroperoxide %70 out of the reach of children and pets to prevent accidental exposure or ingestion.



SYNONYMS


TBHP 70%
Tertiary butyl hydroperoxide 70%
TBHP solution
Tert-butylperoxyhydroperoxide 70%
TBHP70
Tert-butyl hydroperoxide solution
Tertiary butyl peroxide 70%
Tert-butyl hydroperoxide 70% solution
TBHP 70% peroxide
TBHP70 oxidizer
TBHP hydrogen peroxide
Tert-butylperoxyhydroperoxide 70% solution
TBHP oxidizing agent
Tert-butyl hydroperoxide 70% concentrate
TBHP oxidant
Tert-butyl hydroperoxide reagent
TBHP70 reactive compound
TBHP flammable liquid
Tert-butyl hydroperoxide peroxide solution
TBHP70 chemical reagent
TBHP oxidative agent
Tert-butyl hydroperoxide chemical compound
TBHP70 organic peroxide
TBHP reactive intermediate
Tert-butyl hydroperoxide initiator
TBHP 70% solution
Tert-butyl hydroperoxide 70% reagent
TBHP70 oxidant
Tert-butyl peroxohydroperoxide 70%
TBHP 70% peroxo compound
Tert-butyl hydroperoxide 70% concentrate
TBHP hydrogen peroxide solution
Tert-butylperoxyhydroperoxide 70% agent
TBHP70 reactive chemical
Tertiary butyl hydroperoxide solution
TBHP oxidative reagent
Tert-butyl hydroperoxide peroxide
TBHP70 initiator
Tert-butyl hydroperoxide oxidizer
TBHP reactive intermediate
Tert-butyl hydroperoxide oxidizing agent
TBHP70 chemical compound
Tert-butyl hydroperoxide peroxide solution
TBHP70 organic peroxide
Tert-butyl hydroperoxide reagent solution
TBHP flammable liquid
Tert-butylperoxyhydroperoxide 70% peroxide
TBHP oxidizing solution
Tert-butyl hydroperoxide peroxide reagent
TBHP70 radical initiator
TBHP 70% peroxo solution
Tert-butyl hydroperoxide 70% compound
TBHP70 hydrogen peroxide
Tert-butylperoxyhydroperoxide 70% reagent
TBHP oxidative compound
Tert-butyl hydroperoxide oxidizing solution
TBHP70 organic peroxo compound
Tert-butyl hydroperoxide peroxo agent
TBHP 70% oxidant
Tert-butyl hydroperoxide peroxide chemical
TBHP reactive peroxide
Tert-butyl hydroperoxide initiator solution
TBHP oxidizing reagent
TERT BUTYL HYDROPEROXIDE %70

Tert-butyl hydroperoxide (TBHP) is a chemical compound with the molecular formula C4H10O2.
The "%70" in the name indicates that it is a solution of tert-butyl hydroperoxide with a concentration of 70%.
This means that in a given volume of this solution, 70% of the content is tert-butyl hydroperoxide, while the remaining 30% typically consists of a solvent or stabilizing agent, such as water.
Tert butyl hydroperoxide %70 is a peroxide compound commonly used as a radical initiator in various chemical reactions, particularly in the field of organic chemistry.

CAS Number: 75-91-2
EC Number: 200-915-7



APPLICATIONS


Tert butyl hydroperoxide %70 is primarily used as a radical initiator in the polymerization of monomers to create various polymers and plastics.
Tert butyl hydroperoxide %70 finds extensive use in the production of polystyrene, polyethylene, and polypropylene, among other polymer materials.
Tert butyl hydroperoxide %70 plays a vital role in the synthesis of acrylic polymers, such as polyacrylates and polymethyl methacrylate (PMMA).

Tert butyl hydroperoxide %70 is utilized in the manufacture of elastomers, including synthetic rubber products.
Tert butyl hydroperoxide %70 is an essential component in the production of epoxy resins and adhesives used in construction and automotive industries.
Tert butyl hydroperoxide %70 is used in the production of coatings and paints, contributing to their curing and cross-linking processes.
In the pharmaceutical industry, Tert butyl hydroperoxide %70 is employed in the synthesis of various pharmaceutical intermediates and active ingredients.
Tert butyl hydroperoxide %70 is a valuable reagent in the synthesis of specialty chemicals, including antioxidants, plasticizers, and surfactants.

Tert butyl hydroperoxide %70 is utilized in the production of fuel additives, particularly for improving the octane rating of gasoline.
Tert butyl hydroperoxide %70 is used in the preparation of peroxide-based initiators for radical polymerization reactions.
Tert butyl hydroperoxide %70 can be found in the formulation of hair dye products, where it assists in the development of color.

In the food industry, it may be used as a bleaching agent for certain food products, like fats and oils.
Tert butyl hydroperoxide %70 has applications in the manufacturing of paper and pulp, where it helps bleach wood pulp fibers.
Tert butyl hydroperoxide %70 is used in the treatment of wastewater and effluents to remove organic contaminants through oxidative processes.

In the textile industry, Tert butyl hydroperoxide %70 can be employed for bleaching and oxidative processes in fabric production.
Tert butyl hydroperoxide %70 finds use as a reagent in laboratory-scale organic chemistry experiments for oxidation reactions.
Tert butyl hydroperoxide %70 can be incorporated into the formulation of cleaning products for its bleaching and disinfecting properties.

Tert butyl hydroperoxide %70 is utilized in the production of polymeric materials for medical devices, such as catheters and tubing.
In the aerospace industry, Tert butyl hydroperoxide %70 may be used in the fabrication of composite materials for aircraft components.
Tert butyl hydroperoxide %70 plays a role in the synthesis of peracids, which are used as oxidizing agents in various chemical transformations.

Tert butyl hydroperoxide %70 is utilized in the production of agrochemicals, including herbicides and pesticides.
Tert butyl hydroperoxide %70 can be part of the formulation of oxygen scavengers used in food packaging to extend product shelf life.
In the cosmetics industry, Tert butyl hydroperoxide %70 may be used in the production of hair care products and skin treatments.

Tert butyl hydroperoxide %70 is a versatile reagent in research and development for its ability to initiate controlled radical polymerization reactions.
Tert butyl hydroperoxide %70 is subject to regulations and safety guidelines due to its reactivity, and its applications span various industries, from chemicals and plastics to pharmaceuticals and textiles.

Tert butyl hydroperoxide %70 is used in the production of specialty chemicals, including antioxidants, plasticizers, and lubricant additives.
Tert butyl hydroperoxide %70 is an important component in the formulation of hair color products, where it helps initiate the oxidative dyeing process.
In the petrochemical industry, Tert butyl hydroperoxide %70 can be used for refining petroleum products and removing impurities.

Tert butyl hydroperoxide %70 is employed in the synthesis of various organic peroxides, which find applications as initiators in polymerization reactions.
Tert butyl hydroperoxide %70 plays a role in the manufacturing of high-performance coatings and automotive finishes.

Tert butyl hydroperoxide %70 is used as a curing agent in the production of composite materials, such as fiberglass-reinforced plastics.
In the electronics industry, Tert butyl hydroperoxide %70 can be used in the fabrication of printed circuit boards (PCBs) and semiconductor devices.

Tert butyl hydroperoxide %70 is utilized as a bleaching agent for the treatment of wastewater and effluents in industrial processes.
Tert butyl hydroperoxide %70 may find application in the production of biodegradable polymers for environmentally friendly materials.

Tert butyl hydroperoxide %70 can be used in the synthesis of peresters, which are valuable intermediates in organic chemistry reactions.
In the cosmetics industry, Tert butyl hydroperoxide %70 may be used in the production of skincare products and hair care formulations.

Tert butyl hydroperoxide %70 can serve as an initiator for controlled radical polymerization reactions, allowing precise control over polymer properties.
Tert butyl hydroperoxide %70 is employed in the production of polymeric materials used in the construction and insulation industries.
Tert butyl hydroperoxide %70 can be part of the formulation of adhesive products for bonding various materials in construction and manufacturing.
In the automotive sector, Tert butyl hydroperoxide %70 may find use in the production of vehicle components and parts made from polymer materials.

Tert butyl hydroperoxide %70 is used in the development of polymer nanocomposites, which have enhanced properties due to the incorporation of nanoparticles.
Tert butyl hydroperoxide %70 can be utilized in the treatment of contaminated soil and groundwater through chemical oxidation processes.
Tert butyl hydroperoxide %70 plays a role in the synthesis of specialty surfactants used in the formulation of detergents and cleaning agents.

In the pharmaceutical industry, Tert butyl hydroperoxide %70 may be used in the synthesis of drug intermediates and pharmaceutical compounds.
Tert butyl hydroperoxide %70 can be applied as a reagent in the preparation of peracids used for industrial and laboratory purposes.

Tert butyl hydroperoxide %70 is used in the production of flame-retardant materials, improving fire safety in various applications.
Tert butyl hydroperoxide %70 can be employed in the formulation of paper coatings to enhance printability and appearance.

In the water treatment sector, Tert butyl hydroperoxide %70 may be used to eliminate organic contaminants and disinfect water supplies.
Tert butyl hydroperoxide %70 plays a role in the production of thermosetting resins used in the manufacturing of composites and molded products.
Tert butyl hydroperoxide %70 is subject to safety regulations and guidelines, ensuring its safe handling and use across diverse industrial and scientific applications.

Tert butyl hydroperoxide %70 is utilized in the formulation of polyurethane foams, providing structural integrity to foam-based products.
Tert butyl hydroperoxide %70 plays a role in the synthesis of polymeric materials used in the construction of pipelines and infrastructure.
Tert butyl hydroperoxide %70 can be part of the formulation of fuel additives designed to improve combustion efficiency and reduce emissions.

In the aerospace industry, it may find use in the fabrication of composite materials for aircraft components, including wings and fuselage parts.
Tert butyl hydroperoxide %70 is employed in the production of thermoplastic elastomers, which combine the properties of both rubber and plastic.

Tert butyl hydroperoxide %70 can be used in the manufacturing of adhesives and sealants for various applications, including automotive and aerospace.
Tert butyl hydroperoxide %70 is utilized in the creation of specialty polymers with unique properties, such as conductive polymers for electronic applications.
In the agricultural sector, Tert butyl hydroperoxide %70 may be employed in the synthesis of agrochemicals, including herbicides and insecticides.
Tert butyl hydroperoxide %70 plays a role in the production of flame-resistant textiles and materials for protective clothing.

Tert butyl hydroperoxide %70 can be used in the development of coatings for corrosion protection in the marine and offshore industries.
Tert butyl hydroperoxide %70 finds application in the preparation of peroxide-based initiators for radical copolymerization reactions.

In the food packaging industry, it may be used as an oxygen scavenger to extend the shelf life of packaged products.
Tert butyl hydroperoxide %70 is utilized in the formulation of dental materials, such as impression compounds and restorative resins.

Tert butyl hydroperoxide %70 is employed in the synthesis of advanced materials for 3D printing and additive manufacturing.
Tert butyl hydroperoxide %70 can be part of the formulation of specialty inks and coatings for printing applications.

In the automotive sector, Tert butyl hydroperoxide %70 may find use in the production of automotive interior components and trim.
Tert butyl hydroperoxide %70 is utilized in the manufacture of gaskets and seals for industrial and automotive equipment.
Tert butyl hydroperoxide %70 plays a role in the development of photoresist materials used in semiconductor lithography processes.
Tert butyl hydroperoxide %70 can be employed in the production of high-performance fibers and textiles used in sports and outdoor gear.

In the renewable energy sector, Tert butyl hydroperoxide %70 may be used in the fabrication of materials for solar panels and wind turbine blades.
Tert butyl hydroperoxide %70 is utilized in the synthesis of conductive inks and coatings for printed electronics applications.
Tert butyl hydroperoxide %70 can be part of the formulation of specialty polymers used in the construction of medical devices.

Tert butyl hydroperoxide %70 plays a role in the production of polymer nanocomposites with enhanced mechanical and thermal properties.
In the aerospace industry, Tert butyl hydroperoxide %70 may be employed in the fabrication of lightweight materials for aircraft interiors.
Tert butyl hydroperoxide %70 is subject to strict safety and handling protocols in industries where its reactivity and properties are critical for product quality and performance.



DESCRIPTION


Tert-butyl hydroperoxide (TBHP) is a chemical compound with the molecular formula C4H10O2.
The "%70" in the name indicates that it is a solution of tert-butyl hydroperoxide with a concentration of 70%.
This means that in a given volume of this solution, 70% of the content is tert-butyl hydroperoxide, while the remaining 30% typically consists of a solvent or stabilizing agent, such as water.

Tert butyl hydroperoxide %70 is a peroxide compound commonly used as a radical initiator in various chemical reactions, particularly in the field of organic chemistry.
Tert butyl hydroperoxide %70 can initiate free radical reactions by cleaving its oxygen-oxygen bond, leading to the formation of reactive radical species.
Tert butyl hydroperoxide %70 is known for its oxidizing properties and is used in various industrial applications and chemical processes.
As with any chemical compound, it should be handled and stored with appropriate safety precautions.

Tert butyl hydroperoxide %70 is a chemical compound that appears as a clear or slightly yellowish liquid solution.
Tert butyl hydroperoxide %70 is classified as an organic peroxide due to its peroxide functional group (-OOH).
Tert butyl hydroperoxide %70 has a molecular formula of C4H10O2.

Tert butyl hydroperoxide %70 contains 70% by weight of tert-butyl hydroperoxide in a solution.
The remaining 30% typically consists of a stabilizing agent or solvent, such as water.
Tert butyl hydroperoxide %70 is highly reactive and can decompose into free radicals when exposed to heat or other initiators.

Tert butyl hydroperoxide %70 is widely used as a radical initiator in various chemical reactions, especially in polymerization processes.
Tert butyl hydroperoxide %70 is known for its strong oxidizing properties and the ability to initiate polymerization reactions at relatively low temperatures.

Tert butyl hydroperoxide %70 is often used in the production of plastics, resins, and other polymer materials.
Tert butyl hydroperoxide %70 plays a crucial role in the synthesis of various organic compounds, including pharmaceuticals and specialty chemicals.

Tert butyl hydroperoxide %70 can be a valuable reagent in the laboratory for organic synthesis and oxidation reactions.
The tert-butyl group in the molecule provides steric hindrance, making Tert butyl hydroperoxide %70 a selective oxidizing agent in certain reactions.
Safety precautions must be taken when handling Tert butyl hydroperoxide %70, as it is flammable and can be hazardous if mishandled.
Tert butyl hydroperoxide %70 should be stored in a cool, well-ventilated area away from heat, open flames, and incompatible materials.

When using Tert butyl hydroperoxide %70 in chemical processes, appropriate personal protective equipment, such as gloves and goggles, is recommended.
Tert butyl hydroperoxide %70 is sensitive to temperature changes, and decomposition can occur if not stored correctly.

Tert butyl hydroperoxide %70 is also used in the production of fuel additives and specialty chemicals for various industries.
Tert butyl hydroperoxide %70 is considered a valuable tool in the field of organic chemistry for its versatility in initiating reactions.
The peroxide functional group (-OOH) readily undergoes homolytic cleavage to form radicals, which can propagate chemical reactions.

Tert butyl hydroperoxide %70 is an important reagent for the synthesis of peroxide-based initiators in radical polymerization processes.
When used as an initiator, Tert butyl hydroperoxide %70 can control the rate of polymerization and the molecular weight of the resulting polymer.

Its applications extend to the production of adhesives, coatings, and elastomers.
Tert butyl hydroperoxide %70 is subject to regulations and safety guidelines due to its reactivity and potential hazards.
Tert butyl hydroperoxide %70 is typically supplied in containers designed to prevent leakage or accidental exposure.



PROPERTIES


Physical Properties:

Appearance: Clear or slightly yellowish liquid.
Odor: Characteristic odor.
Density: Typically denser than water.
Boiling Point: Varies with concentration and pressure (ranges from approximately 40°C to 50°C).
Melting Point: Not applicable as it is a liquid.
Solubility: Miscible with many organic solvents; insoluble in water.
pH: Typically not applicable as it is not an aqueous solution.
Flash Point: Flammable; varies depending on concentration.
Vapor Pressure: Varies with temperature and concentration.
Viscosity: Low to moderate viscosity.


Chemical Properties:

Chemical Formula: C4H10O2.
Molecular Weight: Approximately 90.12 g/mol.
Chemical Structure: Contains the tert-butyl group (-C(CH3)3) and a hydroperoxy group (-OOH).
Reactivity: Highly reactive; can initiate radical reactions.
Decomposition: Decomposes when exposed to heat or other initiators, releasing free radicals.
Oxidizing Properties: Strong oxidizing agent.
Stability: Sensitive to temperature and contamination; should be stored under controlled conditions.



FIRST AID


Inhalation:

If inhaled and respiratory distress occurs, immediately move the affected person to an area with fresh air.
If the person is not breathing, administer artificial respiration.
Seek medical attention promptly and provide information about the exposure.


Skin Contact:

In case of skin contact with Tert butyl hydroperoxide %70, remove contaminated clothing and rinse the affected skin thoroughly with copious amounts of water for at least 15 minutes.
Use a mild soap to wash the exposed skin gently.
Do not use abrasive materials or scrub the skin, as it may exacerbate irritation.
Seek medical attention if skin irritation, redness, or other symptoms persist.


Eye Contact:

If Tert butyl hydroperoxide %70 comes into contact with the eyes, immediately flush the eyes with lukewarm water while keeping the eyelids open for at least 15 minutes.
Seek immediate medical attention, even if the irritation seems mild or transient.


Ingestion:

If accidental ingestion occurs, do not induce vomiting, as vomiting may expose the airway to the chemical.
Rinse the mouth thoroughly with water and drink plenty of water or milk if the individual is conscious and alert.
Seek immediate medical attention or contact a poison control center.
Provide information about the product and the amount ingested to medical professionals.



HANDLING AND STORAGE


Handling:

Personal Protective Equipment (PPE):
When handling Tert butyl hydroperoxide %70, always wear appropriate personal protective equipment (PPE), including safety goggles or a face shield, chemical-resistant gloves, and a lab coat or protective clothing to minimize the risk of skin and eye contact.

Ventilation:
Work in a well-ventilated area with local exhaust ventilation or a chemical fume hood to prevent the accumulation of vapors.
Ensure that the ventilation system effectively removes potentially hazardous fumes.

Avoid Open Flames and Heat:
Keep the product away from open flames, sparks, and heat sources, as Tert butyl hydroperoxide is flammable and can ignite at elevated temperatures.

No Smoking:
Smoking should be strictly prohibited in areas where Tert butyl hydroperoxide is handled or stored due to the fire hazard it presents.

Prevent Cross-Contamination:
Ensure that equipment, containers, and utensils used for handling and application are clean and free from contaminants.
Avoid cross-contamination with other chemicals or substances.

Avoid Mixing:
Do not mix Tert butyl hydroperoxide %70 with other substances or chemicals unless explicitly directed to do so by a qualified professional and following appropriate safety protocols.

Use in a Controlled Manner:
Dispense and apply the chemical in a controlled and precise manner to minimize waste and potential exposure.

Labeling:
Clearly label containers and storage areas with appropriate hazard warnings, contents, and safety information. Ensure that labels remain legible and intact.


Storage:

Cool and Dry Storage:
Store Tert butyl hydroperoxide %70 in a cool, dry, and well-ventilated area.
Maintain a stable temperature below 25°C (77°F) to minimize the risk of decomposition.

Protection from Light:
Protect the product from direct sunlight and sources of UV radiation, as light exposure can cause degradation.

Avoid Moisture:
Prevent moisture from entering containers, as it can lead to decomposition or loss of effectiveness.

Sealed Containers:
Keep containers tightly sealed when not in use to prevent contact with air, which can contribute to decomposition.

Incompatible Substances:
Store Tert butyl hydroperoxide %70 away from incompatible materials, such as reducing agents, flammable materials, strong acids, and strong bases.
Segregate it from incompatible chemicals to prevent hazardous reactions.

Separation:
Some settling or separation of the product may occur over time.
Ensure that the product is thoroughly mixed before use to maintain its consistency and properties.

Children and Pets:
Store Tert butyl hydroperoxide %70 out of the reach of children and pets to prevent accidental exposure or ingestion.



SYNONYMS


TBHP 70%
Tertiary butyl hydroperoxide 70%
TBHP solution
Tert-butylperoxyhydroperoxide 70%
TBHP70
Tert-butyl hydroperoxide solution
Tertiary butyl peroxide 70%
Tert-butyl hydroperoxide 70% solution
TBHP 70% peroxide
TBHP70 oxidizer
TBHP hydrogen peroxide
Tert-butylperoxyhydroperoxide 70% solution
TBHP oxidizing agent
Tert-butyl hydroperoxide 70% concentrate
TBHP oxidant
Tert-butyl hydroperoxide reagent
TBHP70 reactive compound
TBHP flammable liquid
Tert-butyl hydroperoxide peroxide solution
TBHP70 chemical reagent
TBHP oxidative agent
Tert-butyl hydroperoxide chemical compound
TBHP70 organic peroxide
TBHP reactive intermediate
Tert-butyl hydroperoxide initiator
TBHP 70% solution
Tert-butyl hydroperoxide 70% reagent
TBHP70 oxidant
Tert-butyl peroxohydroperoxide 70%
TBHP 70% peroxo compound
Tert-butyl hydroperoxide 70% concentrate
TBHP hydrogen peroxide solution
Tert-butylperoxyhydroperoxide 70% agent
TBHP70 reactive chemical
Tertiary butyl hydroperoxide solution
TBHP oxidative reagent
Tert-butyl hydroperoxide peroxide
TBHP70 initiator
Tert-butyl hydroperoxide oxidizer
TBHP reactive intermediate
Tert-butyl hydroperoxide oxidizing agent
TBHP70 chemical compound
Tert-butyl hydroperoxide peroxide solution
TBHP70 organic peroxide
Tert-butyl hydroperoxide reagent solution
TBHP flammable liquid
Tert-butylperoxyhydroperoxide 70% peroxide
TBHP oxidizing solution
Tert-butyl hydroperoxide peroxide reagent
TBHP70 radical initiator
TBHP 70% peroxo solution
Tert-butyl hydroperoxide 70% compound
TBHP70 hydrogen peroxide
Tert-butylperoxyhydroperoxide 70% reagent
TBHP oxidative compound
Tert-butyl hydroperoxide oxidizing solution
TBHP70 organic peroxo compound
Tert-butyl hydroperoxide peroxo agent
TBHP 70% oxidant
Tert-butyl hydroperoxide peroxide chemical
TBHP reactive peroxide
Tert-butyl hydroperoxide initiator solution
TBHP oxidizing reagent
Tert Butyl Hydroperoxide
2,2,2-Trihydroxytriethylamine; TEA; 2,2',2''-Nitrilotriethanol; Triethanolamin; Tris(beta-hydroxyethyl)amine; Trolamine; Daltogen; Nitrilotriethanol; Sterolamide; Tri(hydroxyethyl)amine; Triethanolamin; Tris(2-hydroxyethyl)amine; 2,2',2''-Nitrilotriethanol; 2,2',2''-Nitrilotris(ethanol); Nitrilo-2,2',2"-triethanol; 2,2,2-Nitrilotriethanol; 2,2',2"-Nitrilotriethanol; Nitrilo-2,2',2''-triethanol; 2,2',2''-trihydroxy Triethylamine; Triethylolamine; Trihydroxytriethylamine; Tris(beta-hydroxyethyl)amine cas no: 102-71-6
TERT BUTYL PERACETATE 50%
DESCRIPTION:
Tert Butyl Peracetate 50% is an initiator for polymerization of ethylene and (meth)acrylates.
Tert Butyl Peracetate 50% is sensitive to heat. Storage of this material must be done so with stringent temperature control measures. Its explosion hazard is also mitigated by mixing the peroxide with an inert solid.

CAS Number: 107-71-1
Molecular Weight: 132.16
Linear Formula: CH3CO3C(CH3)3


APPLICATIONS OF TERT BUTYL PERACETATE 50%:
Tert Butyl Peracetate 50% Allows the direct copper catalyzed acetoxylation of β-lactams at the 4-position.
Reagent used as a methyl-radical source under photoredox catalysis in conjunction with photocatalyst for late-stage functionalization of biologically active heterocycles.
Tert Butyl Peracetate 50% can be used for the market segments: polymer production and acrylics production with their different applications/functions



CHEMICAL AND PHYSICAL PROPERTIES OF TERT BUTYL PERACETATE 50%:
Form: liquid
t1/2: 10 hr(101 °C, 0.2 M in benzene)
concentration: 50 wt. % in odorless mineral spirits
refractive index: n20/D 1.412
density: 0.828 g/mL at 25 °C
Chemical family
Organic peroxide
CAS number
107-71-1
Physical form
Liquid
Regional availability
Africa, Europe, India, Middle East
Molecular Weight
132.2
Chemical name
tert-Butyl peroxyacetate, 50% solution in isododecane
Color Undesignated
Formula Weight 132.16
Percent Purity 49 to 51%
Packaging Plastic bottle
Quantity 250 mL
Physical Form Solution
Chemical Name or Material tert-Butyl peroxyacetate, 50% Solution In Aromatic Free Mineral Spirit
CAS
107-71-1, 64742-48-9
Molecular Formula
C6H12O3
Molecular Weight (g/mol)
132.159
MDL Number
MFCD00048240
InChI Key
SWAXTRYEYUTSAP-UHFFFAOYSA-N
Synonym
tert-butyl peroxyacetate, t-butyl peracetate, tert-butyl peracetate, lupersol 70, t-butyl peroxyacetate, ethaneperoxoic acid, 1,1-dimethylethyl ester, trigonox f-c50, unii-fj3f3s50cs, peroxyacetic acid, tert-butyl ester, fj3f3s50cs
PubChem CID
61019
IUPAC Name
tert-butyl ethaneperoxoate
Molecular Weight
132.16 g/mol
XLogP3-AA
1.1
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
3
Rotatable Bond Count
3
Exact Mass
132.078644241 g/mol
Monoisotopic Mass
132.078644241 g/mol
Topological Polar Surface Area
35.5Ų
Heavy Atom Count
9
Formal Charge
0
Complexity
101
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes


SAFETY INFORMATION ABOUT TERT BUTYL PERACETATE 50%:
First aid measures:
Description of first aid measures:
General advice:
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Move out of dangerous area:

If inhaled:
If breathed in, move person into fresh air.
If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact:
Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Consult a physician.

In case of eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Continue rinsing eyes during transport to hospital.

If swallowed:
Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.
Rinse mouth with water.
Consult a physician.

Firefighting measures:
Extinguishing media:
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas

Advice for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.
Accidental release measures:
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment.

Avoid breathing vapours, mist or gas.
Evacuate personnel to safe areas.

Environmental precautions:
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up:
Soak up with inert absorbent material and dispose of as hazardous waste.
Keep in suitable, closed containers for disposal.

Handling and storage:
Precautions for safe handling:
Avoid inhalation of vapour or mist.

Conditions for safe storage, including any incompatibilities:
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials

Exposure controls/personal protection:
Control parameters:
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls:
Appropriate engineering controls:
Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.

Personal protective equipment:
Eye/face protection:
Tightly fitting safety goggles.
Faceshield (8-inch minimum).
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection:
Handle with gloves.
Gloves must be inspected prior to use.
Use proper glove
removal technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.

Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
It should not be construed as offering an approval for any specific use scenario.

Body Protection:
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection:
Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.

If the respirator is the sole means of protection, use a full-face supplied air respirator.
Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Stability and reactivity:
Chemical stability:
Stable under recommended storage conditions.
Incompatible materials:
Strong oxidizing agents:
Hazardous decomposition products:
Hazardous decomposition products formed under fire conditions.
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas.

Disposal considerations:
Waste treatment methods:
Product:
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging:
Dispose of as unused product


SYNONYMS OF TERT BUTYL PERACETATE 50%:


tert-Butyl peroxyacetate
107-71-1
tert-Butyl peracetate
tert-butyl ethaneperoxoate
t-Butyl peracetate
Lupersol 70
Trigonox F-C50
t-Butyl peroxyacetate
ETHANEPEROXOIC ACID, 1,1-DIMETHYLETHYL ESTER
Peroxyacetic acid, tert-butyl ester
UNII-FJ3F3S50CS
EINECS 203-514-5
FJ3F3S50CS
NSC 118417
BRN 1701510
4-02-00-00391 (Beilstein Handbook Reference)
NSC-118417
SCHEMBL24499
BUTYL PERACETATE, TERT-
DTXSID9029142
ACETYL TERT-BUTYL PEROXIDE
SWAXTRYEYUTSAP-UHFFFAOYSA-N
Ethaneperoxoic acid tert-butyl ester
NSC118417
AKOS015892841
WLN: 1X1 & 1 & OOV1
Ethaneperoxoic acid,1-dimethylethyl ester
Q27278013





TERT BUTYL PER-ISO-NONANOATE
DESCRIPTION:

Tert Butyl Per-Iso-Nonanoate is Colourless, mobile liquid, consisting of technically pure tert.butylperoxy-3,5,5- trimethylhexanoate (tert.butylperisononanoate).
This branched, aliphatic perester is used as an initiator (radical source) in the polymerisation of monomers (e.g. ethylene, styrene).


Cas NO.: 153302-08-0
EINECS: 236-050-7
Mw: 230.34374
Molecular Formula: C13H24O4
IUPAC Name: tert-butyl 3-(5-methylhexyl)dioxirane-3-carboxylate

CHEMICAL AND PHYSICAL PROPERTIES OF TERT BUTYL PER-ISO-NONANOATE:
Molecular Weight
244.33 g/mol
XLogP3-AA
3.9
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
4
Rotatable Bond Count
8
Exact Mass
244.16745924 g/mol
Monoisotopic Mass
244.16745924 g/mol
Topological Polar Surface Area
51.4Ų
Heavy Atom Count
17
Formal Charge
0
Complexity
261
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Appearance colourless liquid
Peroxide content ca. 99 % w/w
Active oxygen ca. 6.88 % w/w
De-sensitising agent none
Density at 20°C ca. 0.89 g/cm3
Viscosity at 20°C ca. 5.0 mPa•s
Refractive index at 20°C ca. 1.431
Miscibility immiscible with water
miscible with alcohols, phthalate
Critical temperature (SADT) ca. 60°C
Cold storage stability to below -25°C
Kick-off temperature ca. 80°C
Recommended storage temperature below 30°C

SAFETY INFORMATION ABOUT TERT BUTYL PER-ISO-NONANOATE:
First aid measures:
Description of first aid measures:
General advice:
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Move out of dangerous area:

If inhaled:
If breathed in, move person into fresh air.
If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact:
Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Consult a physician.

In case of eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Continue rinsing eyes during transport to hospital.

If swallowed:
Do NOT induce vomiting.
Never give anything by mouth to an unconscious person.
Rinse mouth with water.
Consult a physician.

Firefighting measures:
Extinguishing media:
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas

Advice for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.
Accidental release measures:
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment.

Avoid breathing vapours, mist or gas.
Evacuate personnel to safe areas.

Environmental precautions:
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up:
Soak up with inert absorbent material and dispose of as hazardous waste.
Keep in suitable, closed containers for disposal.

Handling and storage:
Precautions for safe handling:
Avoid inhalation of vapour or mist.

Conditions for safe storage, including any incompatibilities:
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials

Exposure controls/personal protection:
Control parameters:
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls:
Appropriate engineering controls:
Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.

Personal protective equipment:
Eye/face protection:
Tightly fitting safety goggles.
Faceshield (8-inch minimum).
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection:
Handle with gloves.
Gloves must be inspected prior to use.
Use proper glove
removal technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.

Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
It should not be construed as offering an approval for any specific use scenario.

Body Protection:
Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection:
Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls.

If the respirator is the sole means of protection, use a full-face supplied air respirator.
Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so.
Do not let product enter drains.
Discharge into the environment must be avoided.

Stability and reactivity:
Chemical stability:
Stable under recommended storage conditions.
Incompatible materials:
Strong oxidizing agents:
Hazardous decomposition products:
Hazardous decomposition products formed under fire conditions.
Carbon oxides, Nitrogen oxides (NOx), Hydrogen chloride gas.

Disposal considerations:
Waste treatment methods:
Product:
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging:
Dispose of as unused product








SYNONYMS OF TERT BUTYL PER-ISO-NONANOATE:
CTK8D8285;
DTXSID00276147;
DTXSID40864365;
EC 236-050-7;
Einecs 236-050-7;
Hexaneperoxoic acid, 3,5,5-trimethyl-, 1,1-dimethylethyl ester;
NS00008185;
Q27269552;
TBPMH;
t-Butyl 3,5,5-trimethylperoxyhexanoate;
2-Methyl-2-propanyl 3,5,5-trimethylhexaneperoxoate [ACD/IUPAC Name]
2-Methyl-2-propanyl-3,5,5-trimethylhexanperoxoat [German] [ACD/IUPAC Name]
3,5,5-Triméthylhexaneperoxoate de 2-méthyl-2-propanyle [French] [ACD/IUPAC Name]
Hexaneperoxoic acid, 3,5,5-trimethyl-, 1,1-dimethylethyl ester [ACD/Index Name]
tert-Butyl 3,5,5-trimethylhexaneperoxoate
TERT-BUTYL 3,5,5-TRIMETHYLHEXANOYLPEROXIDE
tert-Butyl peroxy-3,5,5-trimethylhexanoate
132160-38-4 [RN]
153302-08-0 [RN]
6-tert-butyldioxy-3,5,5-trimethylhexanoate
tert-butyl 3,5,5-trimethylperoxyhexanoate
tert-Butyl perisononanoate
tert-butylperoxy-3,5,5-trimethylhexanoate

TERT BUTYL PEROXY -2- ETHYL HEXANOATE 99%
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is a colorless liquid.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is particularly sensitive to temperature rises and contamination.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is regarded as an intermediate fire hazard; however, it has low impact sensitivity.

CAS Number: 3006-82-4
Molecular Formula: C12H24O3
Molecular Weight: 216.32
EINECS Number: 221-110-7

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% has a half-life in benzene of 10.0 h at 162°F (72°C).
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is used as a medium temperature initiator for the polymerization of vinyl monomers and the curing of styrene-unsaturated polyester resins.
Above a given "Control Temperature" they decompose violently.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is generally stored or transported with inert solids to mitigate the explosion hazard.
An organic peroxide initiator used as a polymerization initiator for all vinyl monomers, such as vinyl acetate, vinyl chloride, methacrylic acid, styrene, ethylene, etc.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99%, often abbreviated as TBPEH or TBPEH-99%, is a chemical compound used as a radical initiator in various chemical processes.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is a perester compound with the molecular formula C12H24O3.
TBPEH has a peroxy functional group (OO) and consists of a tert-butyl group, a 2-ethylhexyl group, and a peroxyester linkage.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99%s chemical formula is usually written as (CH3)3C-O-(CH2)6-C(O)OOC(CH2)3CH3.

Use as a Radical Initiator: Like di-tert-butyl peroxide, Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is used as a radical initiator in various chemical processes, especially in the polymerization of monomers to form polymers.
When Tert Butyl Peroxy -2- Ethyl Hexanoate 99% decomposes, it generates free radicals (such as alkyl and alkoxyl radicals) that initiate the polymerization reactions.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is employed in the production of various polymer materials, including plastics, rubber, coatings, and adhesives.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99%s use allows for the controlled and efficient formation of polymer chains and cross-linking, leading to materials with desired properties.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% indicates that the product is highly pure, with the active TBPEH compound accounting for at least 99% of the total composition.
The remaining 1% or less may consist of stabilizers, impurities, or other substances added to enhance the compound's stability or handling.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99%, like other peroxides, should be handled with care due to its potential for thermal decomposition and flammability.
Safety precautions and guidelines for its storage, transportation, and usage are essential to minimize risks.
Proper storage is crucial for maintaining the stability of Tert Butyl Peroxy -2- Ethyl Hexanoate 99%.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% should be stored in a cool, well-ventilated area, away from heat sources, open flames, and incompatible materials.
Special containers designed for peroxide storage may be used.
The use and transport of Tert Butyl Peroxy -2- Ethyl Hexanoate 99% are typically regulated, and users are required to be trained in its safe handling and storage.

Compliance with local, state, and federal regulations is essential.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is commonly used to initiate the polymerization of resins in the production of composite materials.
This process leads to the formation of strong and durable composite structures that are used in various industries, including aerospace, automotive, and construction.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is often employed to cross-link thermosetting polymers.
In this context, it acts as a cross-linking agent to create a three-dimensional network of covalent bonds within the polymer structure, enhancing its mechanical properties, heat resistance, and chemical resistance.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is known for its stability at elevated temperatures, making it suitable for initiating polymerization reactions at higher processing temperatures, which can be necessary for some specialized applications.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is used in the formulation of adhesives and sealants to initiate the curing process.
This allows the adhesive or sealant to bond and harden effectively, which is vital for applications such as construction, automotive assembly, and manufacturing of bonded products.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% safely is essential. It is highly flammable and can decompose upon heating, posing risks of fire or explosion.

Proper safety protocols, such as wearing personal protective equipment (PPE), and following safety data sheets and guidelines are critical when working with TBPEH.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% often perform quality control tests to ensure the compound's purity and consistency.
Ensuring that the TBPEH is stored and handled correctly is crucial for maintaining its effectiveness as an initiator.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99%, like other peroxides, can be incompatible with certain substances.
Mixing it with incompatible materials can lead to dangerous reactions.
Therefore, it's important to know the compatibility of Tert Butyl Peroxy -2- Ethyl Hexanoate 99% with other chemicals or materials in a given process.

Depending on the region and industry, the handling, transportation, and use of Tert Butyl Peroxy -2- Ethyl Hexanoate 99% may be subject to specific regulations and may require certification and training in its safe handling.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is manufactured on a commercial scale to meet the demands of various industries.
Manufacturers ensure batch consistency and purity through quality control procedures and testing.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is sometimes used as part of custom initiator systems.
These systems can be fine-tuned to meet specific polymerization requirements, allowing for precise control over reaction kinetics and the properties of the resulting polymer.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can be incorporated into controlled release initiator systems for applications that require a sustained release of free radicals over an extended period.

This can be important in certain curing processes and material applications.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can be used to achieve faster polymerization or curing processes, reducing production times and increasing efficiency in manufacturing.
Research in the field of polymer chemistry continues to explore new initiator compounds and methodologies.

Scientists are working on the development of safer, more efficient, and more sustainable initiator systems.
In some cases, Tert Butyl Peroxy -2- Ethyl Hexanoate 99% may be used in the manufacture of food packaging materials to enhance their performance characteristics and extend the shelf life of food products.
Initiators like Tert Butyl Peroxy -2- Ethyl Hexanoate 99% are important in the production of advanced materials for energy storage and conversion technologies, such as lithium-ion batteries, fuel cells, and photovoltaics.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can be used for modifying the properties of existing polymers.
By introducing new cross-links or modifying existing ones, it's possible to change the mechanical, thermal, or chemical properties of polymers.

Melting point: -30°C
Boiling point: 248.9±23.0 °C(Predicted)
Density: 0.89
vapor pressure: 2Pa at 20℃
Flash point: 85°C
pka: -4.8[at 20 ℃]
Water Solubility: 46.3mg/L at 20℃
LogP: 4.79 at 20℃

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is valued for its high reaction efficiency, which means that it can effectively initiate polymerization reactions with relatively small amounts of the initiator.
This can lead to cost savings in industrial processes.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is used in the production of coatings, such as paints and varnishes.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% serves as an initiator to start the polymerization of resins in these coatings, which results in durable and protective finishes for various surfaces.
The use of Tert Butyl Peroxy -2- Ethyl Hexanoate 99% in various polymerization processes helps enhance the performance characteristics of end products.
This includes improvements in tensile strength, impact resistance, thermal stability, and resistance to environmental factors.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can be tailored for specific applications by adjusting its concentration and formulation in reaction mixtures.
This customization allows manufacturers to achieve desired product properties.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is typically available in various forms, including liquids and pastes.

The packaging and storage of Tert Butyl Peroxy -2- Ethyl Hexanoate 99% are designed to prevent contamination and degradation.
Proper storage conditions, such as temperature control, are essential to maintain its stability.
In some cases, Tert Butyl Peroxy -2- Ethyl Hexanoate 99% may be used in combination with other initiators to achieve specific polymerization goals.

Understanding the compatibility of Tert Butyl Peroxy -2- Ethyl Hexanoate 99% with other initiators and additives is important for optimizing polymerization processes.
Ongoing research aims to improve the efficiency and safety of initiators like Tert Butyl Peroxy -2- Ethyl Hexanoate 99%.
This includes the development of novel initiator systems and the exploration of their applications in emerging fields and technologies.

While peroxides like Tert Butyl Peroxy -2- Ethyl Hexanoate 99% are widely used, their environmental impact and the generation of hazardous waste are concerns.
Research is ongoing to develop more sustainable and environmentally friendly initiator systems.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% explodes with great violence when rapidly heated to a critical temperature; pure form is shock sensitive and detonable [Bretherick 1979 p. 602].
Decomposes violently or explosively at temperatures 0-10°C owing to self- accelerating exothermic decomposition; Several explosions were due to shock, heat or friction; amines and certain metals can cause accelerated decomposition [Bretherick 1979 p. 156].

Uses
Tert Butyl Peroxy -2- Ethyl Hexanoate 99%, also known as Trigonox 21S or PEROXAN PO-30 , is an initiator for (co)polymerization of ethylene, styrene, acrylonitrile and (meth)acrylates.
Curing agent for unsaturated polyester resins.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is used for high pressure polymerization of ethylene in both autoclave and tubular processes, usually in combination with other peroxides of varying degrees of activity.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can be used for the market segments: polymer production, thermoset composites and acrylics with their different applications/functions.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is used in the following products: polymers.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is used for the manufacture of: plastic products.

Release to the environment of Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can occur from industrial use: as processing aid and as processing aid.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is most commonly employed to initiate the polymerization of various monomers.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% plays a crucial role in the production of a wide range of polymer materials, including plastics, rubbers, elastomers, and thermosetting resins.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is used for cross-linking elastomers and thermosetting polymers.
The cross-linking process enhances the mechanical properties, heat resistance, and chemical resistance of the materials.
This is particularly important in the manufacturing of tires, hoses, and gaskets.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is used to initiate the polymerization of resins in the production of composite materials.
This results in the creation of strong and lightweight composite structures that find applications in aerospace, automotive, construction, and more.
In the formulation of adhesives and sealants, TBPEH serves as an initiator to start the curing process, allowing these materials to bond to surfaces effectively.

This is essential for construction, automotive assembly, and other bonding applications.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is used in the production of coatings, such as paints and varnishes.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% initiates the polymerization of resins in these coatings, which provides a protective and durable finish on surfaces.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can be used as a blowing agent in the production of foam materials, such as expanded polystyrene (EPS) or polyurethane foam.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% facilitates the expansion and solidification of foam materials.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is used in the production of plastics, including thermoplastics and thermosetting plastics.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99%s use contributes to the controlled formation of polymer chains, leading to the production of various plastic products.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is utilized to initiate polymerization reactions for fabric treatments, providing textiles with specific properties.
In research and development, Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is a valuable tool for scientists working on the synthesis of new materials, compounds, and chemical reactions, particularly in the field of polymer chemistry.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can be employed in water treatment processes to initiate oxidative reactions, breaking down contaminants and pollutants in wastewater.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% may be used in the production of food packaging materials to enhance their performance characteristics and extend the shelf life of food products.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% helps create food-safe materials with improved properties.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% play a role in the development of advanced materials for energy storage technologies.
This includes applications in lithium-ion batteries, fuel cells, and supercapacitors, where controlled polymerization is crucial.
In some cases, Tert Butyl Peroxy -2- Ethyl Hexanoate 99% may find use in the development of medical devices and pharmaceutical products, where it contributes to the polymerization or cross-linking of specific materials required for these applications.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can be used in the production of construction materials such as coatings, adhesives, and sealants.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% helps create durable and weather-resistant materials for use in construction and infrastructure projects.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is versatile and can be part of customized initiator systems that are adjusted to meet specific manufacturing requirements, allowing for precise control over reaction kinetics and product properties.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99%'s used in the textile industry to create specialized coatings and treatments for textiles, giving them specific properties such as resistance to water, stains, or fire.
In laboratories and research facilities, Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is essential for developing and testing new materials, compounds, and processes, particularly in the field of polymer chemistry.
Manufacturers and researchers conduct quality control tests to ensure the purity and consistency of Tert Butyl Peroxy -2- Ethyl Hexanoate 99%, ensuring it meets specific standards for various applications.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can be employed to modify existing polymers or create customized materials with specific properties, depending on the needs of various industries.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is also subject to ongoing research and development efforts aimed at improving their environmental impact and sustainability, including the generation of less hazardous waste.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can be used for creating materials for drug delivery, tissue engineering, and other applications.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% helps in the polymerization of biocompatible polymers to produce medical implants, drug carriers, and controlled-release systems.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is used in the automotive industry for the production of various components, including interior and exterior parts.
The polymerization process initiated by TBPEH helps create lightweight, durable, and heat-resistant materials.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is utilized for producing composite materials that are vital for aircraft and spacecraft components.
The lightweight yet strong properties of composites are advantageous for these applications.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is used in the formulation of paints and coatings designed to withstand harsh marine environments.

These coatings protect ships, offshore structures, and marine equipment from corrosion and environmental damage.
Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can be applied in the manufacturing of materials for photovoltaic devices, such as solar panels.
Initiators like Tert Butyl Peroxy -2- Ethyl Hexanoate 99% are used in the production of specific polymers used in solar cell technology.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is integral to the production of advanced materials used in the electronics and semiconductor industries, contributing to the manufacturing of electronic components and devices.
The tire industry relies on initiators like Tert Butyl Peroxy -2- Ethyl Hexanoate 99% to cross-link the rubber compounds used in tire production.
Cross-linking enhances the mechanical properties, heat resistance, and tread wear of tires.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can be used to create packaging materials with enhanced performance characteristics, such as improved sealing properties, resistance to chemicals, and better barrier properties.
Industrial coatings, such as those used in the protection of steel structures, pipelines, and tanks, often contain Tert Butyl Peroxy -2- Ethyl Hexanoate 99% to improve their resistance to corrosion and environmental degradation.

Tert Butyl Peroxy -2- Ethyl Hexanoate 99% can be used in the development of flame-retardant materials used in applications where fire resistance is critical, such as in construction and transportation industries.
Initiators like Tert Butyl Peroxy -2- Ethyl Hexanoate 99% contribute to the production of tires and sealing materials used in the automotive industry, enhancing their mechanical properties and durability.

Safety Profile
When working with Tert Butyl Peroxy -2- Ethyl Hexanoate 99%, it's important to refer to the product's safety data sheet (SDS) provided by the manufacturer.
This document contains crucial safety and handling information, including precautions, first-aid measures, and storage recommendations.
Based on available data,Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is considered to be very toxictowards aquatic organisms and is classified according to EC 1272/2008 regulation.

Several tests have shown that Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is degradable by hydrolysisand also by biotic degradation in water: this substance is inherently biodegradable.
As aconsequence, Tert Butyl Peroxy -2- Ethyl Hexanoate 99% is neither PBT nor vPvB.

Synonyms
3006-82-4
tert-butyl 2-ethylhexaneperoxoate
Hexaneperoxoic acid, 2-ethyl-, 1,1-dimethylethyl ester
tert-Butyl peroxy-2-ethylhexanoate
tert-Butyl 2-ethylperoxyhexanoate
KGA9W7ZS5I
2-Ethyl-hexaneperoxoic acid 1,1-dimethylethyl ester
Peroxyhexanoic acid, 2-ethyl-, tert-butyl ester
INTEROX TBPEH
PERCURE O
UNII-KGA9W7ZS5I
CHALOXYD P 1310
SCHEMBL210333
tert-butyl 2-ethylperhexanoate
DTXSID0027511
Tert-Butylperoxy-2-Ethylhecanoate
EINECS 221-110-7
AKOS024437786
AS-68928
2-ETHYLHEXANOYL TERT-BUTYL PEROXIDE
FT-0689243
EC 221-110-7
EN300-367472
Q27282239
TERT BUTYL PEROXY-2-ETHYL HEXANOATE 75%

Tert-butyl peroxy-2-ethylhexanoate, typically referred to as TBPEH or Tert butyl peroxy-2-ethyl hexanoate 75%, is a chemical compound that belongs to the class of organic peroxides.
Tert butyl peroxy-2-ethyl hexanoate 75% is often used as a free radical initiator in various chemical processes, particularly in the production of polymers and plastics.
The "75%" in its name indicates the concentration of the active ingredient, which means that Tert butyl peroxy-2-ethyl hexanoate 75% contains 75% of the active peroxide compound and 25% other ingredients or stabilizers to improve its stability and handling characteristics.

CAS Number: 104-76-7



APPLICATIONS


Tert butyl peroxy-2-ethyl hexanoate 75% is widely used as a free radical initiator in the polymerization of styrene and other monomers in the plastics industry.
Tert butyl peroxy-2-ethyl hexanoate 75% is a key ingredient in the production of polystyrene, which is used in packaging materials, disposable utensils, and insulation.
Tert butyl peroxy-2-ethyl hexanoate 75% is employed in the manufacturing of acrylonitrile-butadiene-styrene (ABS) plastics, commonly found in automotive parts, toys, and consumer electronics.

Tert butyl peroxy-2-ethyl hexanoate 75% plays a vital role in the production of polyethylene (PE) and polypropylene (PP) materials, which are used in a wide range of applications, including packaging, pipes, and automotive components.
Tert butyl peroxy-2-ethyl hexanoate 75% is used in the creation of polyvinyl chloride (PVC) plastics, which find applications in construction, electrical cables, and medical devices.

In the rubber industry, it is utilized to initiate the vulcanization process, leading to the formation of durable rubber compounds.
Tert butyl peroxy-2-ethyl hexanoate 75% contributes to the manufacture of synthetic rubber, enhancing its strength, elasticity, and resistance to wear and tear.

Tert butyl peroxy-2-ethyl hexanoate 75% is a critical component in the production of ethylene propylene diene monomer (EPDM) rubber, which is used in roofing materials, automotive seals, and gaskets.
Tert butyl peroxy-2-ethyl hexanoate 75% is employed in the formulation of silicone rubber, known for its excellent resistance to extreme temperatures and chemicals.

Tert butyl peroxy-2-ethyl hexanoate 75% aids in the creation of elastomeric materials used in the production of seals and gaskets for industrial and automotive applications.
Tert butyl peroxy-2-ethyl hexanoate 75% is used in the production of latex gloves, providing elasticity and strength to the rubber material.

Tert butyl peroxy-2-ethyl hexanoate 75% is a valuable initiator in the manufacture of thermosetting resins used in composite materials for aerospace and automotive components.
Tert butyl peroxy-2-ethyl hexanoate 75% plays a role in the formulation of adhesives and sealants, ensuring their ability to bond various materials effectively.

In the printing industry, it is employed in the production of inks that adhere well to various substrates.
Tert butyl peroxy-2-ethyl hexanoate 75% is used to create high-performance coatings for automotive and industrial applications, providing durability and corrosion resistance.

Tert butyl peroxy-2-ethyl hexanoate 75% contributes to the production of polyester resins used in fiberglass-reinforced composites for boats, tanks, and construction panels.
Tert butyl peroxy-2-ethyl hexanoate 75% is employed in the formulation of epoxy resins, commonly used in the manufacture of laminates, coatings, and electronic components.
Tert butyl peroxy-2-ethyl hexanoate 75% plays a role in the production of acrylic-based adhesives used in tapes, labels, and graphic films.

Tert butyl peroxy-2-ethyl hexanoate 75% is utilized in the creation of crosslinked polyethylene (PEX) pipes for plumbing and heating systems.
In the aerospace industry, it is used to produce composite materials for aircraft components, providing lightweight and high-strength properties.
Tert butyl peroxy-2-ethyl hexanoate 75% is an essential ingredient in the production of polyurethane foams, used in mattresses, furniture, and insulation.

Tert butyl peroxy-2-ethyl hexanoate 75% contributes to the creation of high-impact polystyrene (HIPS), which is used in the packaging industry for food containers and disposable products.
Tert butyl peroxy-2-ethyl hexanoate 75% is employed in the formulation of specialty plastics, such as polyphenylene sulfide (PPS), known for its chemical resistance and thermal stability.

Tert butyl peroxy-2-ethyl hexanoate 75% is used in the production of molding compounds for electrical and electronic applications, including connectors and switches.
Tert butyl peroxy-2-ethyl hexanoate 75% is a versatile compound that plays a fundamental role in the development of a wide range of polymer-based products used in various industries, from everyday consumer goods to advanced technology applications.
Tert butyl peroxy-2-ethyl hexanoate 75% is utilized in the creation of high-impact, durable, and weather-resistant plastic automotive components, including bumpers, grilles, and interior trim.

In the construction industry, it is used to manufacture polyvinyl butyral (PVB) interlayer films for laminated safety glass used in architectural windows and automotive windshields.
Tert butyl peroxy-2-ethyl hexanoate 75% plays a role in the production of thermoplastic elastomers (TPEs), which are used in the fabrication of soft-touch grips and handles for tools and appliances.
Tert butyl peroxy-2-ethyl hexanoate 75% is employed in the formulation of thermoplastic polyurethanes (TPUs), ideal for applications like flexible tubing, hoses, and footwear.
Tert butyl peroxy-2-ethyl hexanoate 75% is used in the creation of polyethylene terephthalate (PET) resins, the primary material for producing beverage bottles, food containers, and polyester fabrics.

Tert butyl peroxy-2-ethyl hexanoate 75% contributes to the production of acrylate-based polymers used in pressure-sensitive adhesives for labels, tapes, and graphic films.
Tert butyl peroxy-2-ethyl hexanoate 75% is employed in the synthesis of polybutylene terephthalate (PBT) resins, utilized in electrical connectors, automotive parts, and appliance components.
Tert butyl peroxy-2-ethyl hexanoate 75% is essential in the manufacturing of polyacetal (POM) or acetal copolymer, known for its low friction and excellent wear resistance, making it suitable for gears and bearings.

Tert butyl peroxy-2-ethyl hexanoate 75% is used to create polyphenylene oxide (PPO) or polyphenylene ether (PPE) resins, valued for their electrical insulating properties and flame resistance in electrical applications.
Tert butyl peroxy-2-ethyl hexanoate 75% contributes to the production of polyether ether ketone (PEEK) polymers, which are used in demanding engineering applications, such as aerospace components and medical implants.

In the textile industry, it is employed to enhance the performance of polyester fibers, improving their strength, dyeability, and wrinkle resistance.
Tert butyl peroxy-2-ethyl hexanoate 75% plays a role in the production of melt-blown and spun-bonded polypropylene nonwovens used in hygiene products, filters, and disposable medical apparel.

Tert butyl peroxy-2-ethyl hexanoate 75% is used to initiate the polymerization of vinyl chloride monomers, leading to the production of polyvinyl chloride (PVC) resin used in pipes, cable insulation, and vinyl flooring.
Tert butyl peroxy-2-ethyl hexanoate 75% contributes to the creation of thermosetting phenolic resins, employed in the manufacturing of brake linings, circuit boards, and aerospace components.
Tert butyl peroxy-2-ethyl hexanoate 75% is utilized in the formulation of polyimide materials, known for their high-temperature stability and use in electronics, aerospace, and semiconductor applications.

In the automotive industry, it is employed in the production of composite materials used for lightweighting vehicles and improving fuel efficiency.
Tert butyl peroxy-2-ethyl hexanoate 75% plays a role in the development of polymeric foams, including expanded polystyrene (EPS) and extruded polystyrene (XPS), used for insulation in construction and packaging.

Tert butyl peroxy-2-ethyl hexanoate 75% is used in the manufacture of thermosetting polyester resins, which find applications in boat hulls, wind turbine blades, and industrial tanks.
Tert butyl peroxy-2-ethyl hexanoate 75% contributes to the production of polyethylene naphthalate (PEN) films, utilized in flexible electronics, solar panels, and packaging.

Tert butyl peroxy-2-ethyl hexanoate 75% is employed in the creation of thermoplastic polyolefin (TPO) materials, valued for their weather resistance and used in roofing membranes and automotive parts.
In the electrical industry, it is used in the production of epoxy-based insulating materials for transformers, circuit breakers, and electrical switches.
Tert butyl peroxy-2-ethyl hexanoate 75% plays a role in the development of thermosetting silicone rubber compounds, known for their flexibility, heat resistance, and electrical insulating properties.

Tert butyl peroxy-2-ethyl hexanoate 75% is utilized in the production of biodegradable polymers, contributing to sustainable packaging and agricultural applications.
Tert butyl peroxy-2-ethyl hexanoate 75% is employed in the formulation of polymer blends, allowing manufacturers to tailor materials with specific properties for diverse applications.

Tert butyl peroxy-2-ethyl hexanoate 75% continues to drive innovation in various industries, contributing to the development of advanced materials and products that enhance our daily lives and address diverse industrial needs.
Tert butyl peroxy-2-ethyl hexanoate 75% is used in the production of thermoplastic polyesters, such as polyethylene terephthalate glycol-modified (PETG), which is valued for its clarity, toughness, and ease of processing in the manufacture of food containers, medical devices, and displays.

In the automotive sector, it contributes to the manufacturing of polyurethane foam used in vehicle seating, cushioning, and sound insulation.
Tert butyl peroxy-2-ethyl hexanoate 75% is employed in the formulation of thermosetting melamine-formaldehyde resins, which are used to produce durable laminate surfaces for countertops, tabletops, and cabinetry.

Tert butyl peroxy-2-ethyl hexanoate 75% plays a role in the creation of thermoplastic elastomer compounds used for automotive weatherstripping, seals, and gaskets.
Tert butyl peroxy-2-ethyl hexanoate 75% is utilized in the production of acrylonitrile-styrene-acrylate (ASA) polymers, known for their excellent weather resistance, making them suitable for outdoor applications like automotive trim and signage.
Tert butyl peroxy-2-ethyl hexanoate 75% contributes to the development of thermosetting epoxy-acrylic hybrid resins used for UV-curable coatings on various substrates, including metals and plastics.

Tert butyl peroxy-2-ethyl hexanoate 75% is employed in the manufacture of crosslinked polyethylene foam, used for insulation in HVAC systems, construction, and automotive applications.
Tert butyl peroxy-2-ethyl hexanoate 75% is used in the creation of thermosetting phenolic foam insulation materials, providing excellent fire resistance and thermal performance in building applications.
Tert butyl peroxy-2-ethyl hexanoate 75% plays a role in the production of thermoplastic polyamide (nylon) resins, valued for their high strength, chemical resistance, and use in automotive components and consumer goods.

Tert butyl peroxy-2-ethyl hexanoate 75% is utilized in the formulation of chlorinated polyvinyl chloride (CPVC) resins, used for piping systems in industrial and commercial applications.
In the aerospace industry, it is employed to enhance the performance of epoxy-based composite materials used in aircraft structures and components.
Tert butyl peroxy-2-ethyl hexanoate 75% contributes to the development of thermoplastic fluoropolymer resins, known for their exceptional chemical resistance and electrical properties in applications like wire and cable insulation.

Tert butyl peroxy-2-ethyl hexanoate 75% is used in the creation of thermosetting bismaleimide (BMI) resins, which are heat-resistant materials employed in aerospace and high-performance electronics.
Tert butyl peroxy-2-ethyl hexanoate 75% plays a role in the formulation of thermoplastic polyetherimide (PEI) resins, known for their high-temperature stability, electrical insulating properties, and use in electronics and aerospace.

Tert butyl peroxy-2-ethyl hexanoate 75% is employed in the production of thermosetting urea-formaldehyde resins, which are used as adhesives for wood products and particleboard.
Tert butyl peroxy-2-ethyl hexanoate 75% contributes to the manufacturing of thermoplastic cyclic olefin copolymers (COC), valued for their optical clarity and use in medical and optical applications.
Tert butyl peroxy-2-ethyl hexanoate 75% is utilized in the formulation of thermosetting polybenzoxazine resins, known for their excellent flame resistance and mechanical properties in aerospace and electronics.

Tert butyl peroxy-2-ethyl hexanoate 75% is used to initiate the polymerization of vinyl acetate monomers, leading to the production of polyvinyl acetate (PVAc) adhesives and emulsions used in wood bonding, paper coatings, and textiles.
In the renewable energy sector, it contributes to the production of composite materials used in wind turbine blades, enabling efficient energy generation.
Tert butyl peroxy-2-ethyl hexanoate 75% plays a role in the formulation of high-performance thermosetting composites used in sporting goods, such as tennis rackets, golf club heads, and bicycle frames.

Tert butyl peroxy-2-ethyl hexanoate 75% is employed in the development of conductive polymer materials used in flexible electronics, sensors, and printed circuits.
Tert butyl peroxy-2-ethyl hexanoate 75% is used in the creation of thermoplastic elastomeric compounds for medical tubing, ensuring flexibility and biocompatibility.
Tert butyl peroxy-2-ethyl hexanoate 75% contributes to the formulation of thermosetting resins for the manufacture of carbon fiber-reinforced composites used in lightweight automotive components and aerospace structures.

Tert butyl peroxy-2-ethyl hexanoate 75% is utilized in the production of thermoplastic copolymers for 3D printing applications, enabling the creation of complex and customizable parts.
Across industries, Tert butyl peroxy-2-ethyl hexanoate 75% continues to find innovative applications, contributing to the development of advanced materials and products that meet the evolving needs of modern technology and manufacturing.



DESCRIPTION


Tert-butyl peroxy-2-ethylhexanoate, typically referred to as TBPEH or Tert butyl peroxy-2-ethyl hexanoate 75%, is a chemical compound that belongs to the class of organic peroxides.
Tert butyl peroxy-2-ethyl hexanoate 75% is often used as a free radical initiator in various chemical processes, particularly in the production of polymers and plastics.
The "75%" in its name indicates the concentration of the active ingredient, which means that Tert butyl peroxy-2-ethyl hexanoate 75% contains 75% of the active peroxide compound and 25% other ingredients or stabilizers to improve its stability and handling characteristics.

Tert butyl peroxy-2-ethyl hexanoate 75% is an organic peroxide compound used in various industrial applications.
Tert butyl peroxy-2-ethyl hexanoate 75% is a clear, colorless liquid with a characteristic odor.
The "75%" in its name signifies that it contains 75% of the active peroxide compound and 25% other ingredients or stabilizers.
Its chemical formula is C10H20O3, representing its molecular structure.

Tert butyl peroxy-2-ethyl hexanoate 75% is classified as a free radical initiator, playing a crucial role in initiating polymerization reactions.
Tert butyl peroxy-2-ethyl hexanoate 75% is commonly used in the production of polymers, plastics, and rubbers.

When Tert butyl peroxy-2-ethyl hexanoate 75% decomposes, it releases free radicals that facilitate the crosslinking of polymer chains.
This crosslinking process results in the formation of a three-dimensional network within polymer materials.
Tert butyl peroxy-2-ethyl hexanoate 75% is sensitive to heat, shock, friction, and contamination, requiring careful handling.

Proper safety precautions, such as personal protective equipment (PPE), are necessary when working with this chemical.
It is essential to follow strict safety guidelines and regulations to prevent accidents and ensure workplace safety.

Tert butyl peroxy-2-ethyl hexanoate 75% is a valuable tool in the plastics and rubber industry.
Tert butyl peroxy-2-ethyl hexanoate 75% aids in improving the mechanical properties, durability, and performance of polymer materials.
Tert butyl peroxy-2-ethyl hexanoate 75% is known for its ability to initiate controlled polymerization reactions.
Tert butyl peroxy-2-ethyl hexanoate 75% is typically stored in cool, dry, and well-ventilated areas away from heat sources and open flames.

Tert butyl peroxy-2-ethyl hexanoate 75% is used in various industrial sectors, including automotive, construction, and aerospace.
Manufacturers often provide detailed safety data sheets (SDS) and product information to ensure safe handling.
Tert butyl peroxy-2-ethyl hexanoate 75% is also employed in the formulation of adhesives and coatings.

Tert butyl peroxy-2-ethyl hexanoate 75% is classified as a hazardous substance due to its sensitivity to various factors.
Tert butyl peroxy-2-ethyl hexanoate 75% should not be ingested or allowed to come into contact with skin, eyes, or clothing.

In case of accidental exposure, appropriate first aid measures and medical attention should be sought.
Tert butyl peroxy-2-ethyl hexanoate 75% is an essential component in the production of high-quality plastic and rubber products.
Tert butyl peroxy-2-ethyl hexanoate 75% contributes to the development of materials with enhanced heat resistance and performance.
Proper storage, handling, and disposal procedures are critical to maintaining safety when working with this compound.



PROPERTIES


Chemical Formula: C14H28O3
Common Name: Tert butyl peroxy-2-ethyl hexanoate 75%
CAS Number: 3006-82-4 (This is a common CAS number for this type of chemical, but specific formulations may have different CAS numbers.)
Appearance: Clear, colorless liquid.
Odor: Characteristic, organic peroxide odor.
Molecular Weight: Approximately 244.37 g/mol.
Concentration: 75% active ingredient in the provided form.
Solubility: Soluble in various organic solvents.
Density: Varies depending on the specific formulation and concentration.
Melting Point: Typically below -20°C (-4°F).
Boiling Point: Varies depending on the specific formulation.
Flash Point: Varies depending on the specific formulation.
Chemical Class: Organic peroxide.
Stability: Sensitive to heat, shock, friction, and contamination.
Decomposition: Gradual decomposition releases oxygen radicals, which can initiate polymerization reactions.
Polymerization Initiator: Used to initiate controlled polymerization in the production of plastics and rubbers.



FIRST AID


Inhalation (Breathing in vapors or aerosols):

Remove the affected person from the contaminated area to an area with fresh air.
If the person is experiencing difficulty breathing, seek immediate medical attention.
If the person has stopped breathing or has no pulse, administer CPR (Cardiopulmonary Resuscitation) if trained to do so.


Skin Contact:

Immediately remove contaminated clothing and shoes.
Wash the affected skin thoroughly with copious amounts of water for at least 15 minutes. Use a mild soap if available.
Seek medical attention if irritation, redness, or chemical burns develop.
Do not use abrasive materials, hot water, or strong solvents, as they can exacerbate skin irritation.


Eye Contact:

Rinse the eyes gently but thoroughly with lukewarm, low-pressure water for at least 15 minutes while keeping the eyelids open.
If contact lenses are worn, remove them if it can be done safely during rinsing.
Seek immediate medical attention, and continue rinsing the eyes until professional medical help is obtained.
Do not delay seeking medical attention, even if initial rinsing provides relief.


Ingestion (Swallowing):

Do not induce vomiting unless directed to do so by a medical professional.
Rinse the mouth and drink plenty of water or milk if the person is conscious and not experiencing severe symptoms.
Seek immediate medical attention or contact a poison control center for guidance.
If the chemical is ingested, avoid consuming food or beverages, and do not attempt to neutralize it with substances like vinegar or baking soda.



HANDLING AND STORAGE


Handling:

Personal Protective Equipment (PPE):
Always wear the appropriate PPE, which may include chemical-resistant gloves, safety goggles or a face shield, and suitable protective clothing.
Ensure that all PPE is in good condition and properly fitted.

Ventilation:
Use this chemical in a well-ventilated area or under local exhaust ventilation to control and reduce exposure to vapors or aerosols.
Avoid breathing vapors or aerosols by using a suitable respiratory protection device if necessary.

Avoid Contact:
Avoid skin, eye, and clothing contact with the chemical.
Do not ingest or taste the chemical, and avoid smoking, eating, or drinking in areas where it is handled.

Handling Precautions:
Handle the chemical with care to prevent spills or leaks.
Do not use damaged containers or equipment that may lead to leakage.

Storage Compatibility:
Store the chemical away from incompatible materials, such as strong acids, bases, and reducing agents, to prevent hazardous reactions.
Ensure that storage areas are clearly labeled and segregated for hazardous materials.

Static Electricity:
Ground and bond containers and equipment to prevent the buildup of static electricity, as organic peroxides can be sensitive to electrostatic discharges.

Avoid High Temperatures:
Store the chemical away from heat sources, open flames, and direct sunlight, as it can be sensitive to heat and temperature extremes.


Storage:

Location:
Store Tert butyl peroxy-2-ethyl hexanoate 75% in a cool, dry, well-ventilated area designated for hazardous materials.
Ensure that the storage area complies with local regulations and is adequately equipped to handle spills or emergencies.

Temperature:
Store at temperatures within the recommended range specified by the manufacturer.
Avoid exposure to extreme temperatures, as elevated temperatures can accelerate decomposition.

Container Integrity:
Ensure that containers used for storage are in good condition, free from damage or defects that may lead to leakage.
Keep containers tightly closed when not in use.

Segregation:
Store the chemical away from incompatible substances, following guidelines provided in the SDS.

Labeling:
Clearly label containers with the product name, hazard information, and handling precautions.
Maintain legible and updated labels.

Emergency Equipment:
Keep suitable emergency equipment, such as spill kits, eyewash stations, and safety showers, accessible in the storage area.

Monitoring:
Regularly monitor storage conditions and containers for signs of damage or deterioration.
Implement a regular inspection and maintenance schedule.

Security:
Restrict access to the storage area to authorized personnel only.
Comply with security regulations and guidelines if applicable.

Fire Safety:
Implement fire safety measures in the storage area, including fire extinguishers and sprinkler systems.
Store away from ignition sources.

Documentation:
Maintain accurate records of receipt, usage, and disposal of the chemical as required by regulations.



SYNONYMS


Tert butyl peroxy-2-ethyl hexanoate 75%
Tert-butyl peroxy-2-ethylhexanoate 75%
Tert-butyl peroxy-2-ethylhexanoate solution (75%)
TBPEH
Peroxydicarbonate of 2-ethylhexyl 75%
Di(2-ethylhexyl) peroxydicarbonate 75%
Peroxycarbonate of 2-ethylhexyl 75%
Di(2-ethylhexyl) dicarbonate solution (75%)
TBPEH organic peroxide (75%)
2-Ethylhexyl percarbonate 75%
Peroxidic initiator for polymers (75%)
Tert butyl peroxy-2-ethyl hexanoate 75% peroxide solution
2-Ethylhexyl carbonate peroxide (75%)
Initiator for polymerization processes (75%)
Organic peroxide TBPEH (75%)
Peroxidic compound of 2-ethylhexanol (75%)
Tert butyl peroxy-2-ethyl hexanoate 75% crosslinking agent
Polymerization initiator TBPEH (75%)
Peroxydicarbonate solution for plastics (75%)
Tert-butyl percarbonate of 2-ethylhexanol (75%)
Peroxycarbonate of octyl alcohol (75%)
Peroxydicarbonate of 2-ethylhexane (75%)
Peroxidic initiator of 2-ethylhexyl carbonate (75%)
Peroxide compound TBPEH (75%)
Peroxidic solution for polymer processing (75%)
Tert-butyl 2-ethylhexyl peroxydicarbonate 75%
TBPH-75
Tert-butyl peroxy 2-ethylhexyl dicarbonate 75%
Tert-butyl peroxo-2-ethylhexanoate 75%
2-Ethylhexyl tert-butyl percarbonate 75%
2-Ethylhexyl peroxycarbonate 75%
TBEC-75
TBPC-75
Tert-butyl peroxy 2-ethylhexyl carbonate 75%
Di(2-ethylhexyl) dicarbonate peroxide solution (75%)
Tert-butyl 2-ethylhexyl peroxycarbonate 75%
Peroxidic compound of octyl alcohol (75%)
Peroxycarbonate of 2-ethylhexanol 75%
TBPC organic peroxide (75%)
Peroxycarbonate solution for rubber and plastics (75%)
2-Ethylhexyl tert-butyl carbonate peroxide (75%)
Tert-butyl peroxydicarbonate of octanol (75%)
Organic peroxide initiator TBEC (75%)
Peroxidic initiator of 2-ethylhexyl carbonate (75%)
TBPH-75 peroxide solution
Peroxycarbonate of octanol 75%
Tert-butyl peroxo-2-ethylhexyl dicarbonate 75%
Peroxydicarbonate of 2-ethylhexyl alcohol (75%)
Tert-butyl peroxy 2-ethylhexyl carbonate 75%
TBEC-75 organic peroxide solution
TERT BUTYLPEROXY PIVALATE 75% SOLUTION
Tert Butylperoxy Pivalate 75% Solution is a colorless clear liquid with the molecular formula of C13H26O4, and it is often used as an initiator in polystyrene production.
Tert Butylperoxy Pivalate 75% Solution is an initiator for (co)polymerization of ethylene, vinyl chloride, vinylidene chloride and (meth)acrylates.
Tert Butylperoxy Pivalate 75% Solution is compounds characterized by the presence of an oxygen-oxygen linkage in the molecular structure.

CAS Number: 6731-36-8
Molecular Formula: C17H34O4
Molecular Weight: 302.46
EINECS Number: 229-782-3

Tert Butylperoxy Pivalate 75% Solution is a chemical compound that is typically used as a radical initiator in various chemical processes, especially in the polymerization of monomers to produce polymers and other materials.
Tert Butylperoxy Pivalate 75% Solution are sensitive to heat and contamination, since these conditions will cleave the oxy-oxy bonds to form free radicals.
However, Tert Butylperoxy Pivalate 75% Solution has a high degree of thermal sensitivity.

The polymerization of monomers is one of the main fields of application for organic peroxides.
In this bulletin would like to give you a rough overview on the use of Tert Butylperoxy Pivalate 75% Solution for the free-radical polymerization.
Next will be a short overview on the different types of polymerization processes for monomers.

Tert Butylperoxy Pivalate 75% Solution is a reactive oxygen species that has been used as an oxidant in organic synthesis.
Tert Butylperoxy Pivalate 75% Solution is typically produced by the oxidation of tert-butanol with hydrogen peroxide and sodium citrate.
Tert Butylperoxy Pivalate 75% Solution has been shown to be highly resistant to degradation, even at high pH values.

Tert Butylperoxy Pivalate 75% Solution has also been shown to induce neuronal death in vivo, which may be due to its ability to produce hydroxyl radicals and other reactive oxygen species.
Tert Butylperoxy Pivalate 75% Solution can be used for wastewater treatment because it reacts with organic matter and produces less sludge than chlorine.
Tert Butylperoxy Pivalate 75% Solution also has the ability to react with chemicals in a variety of ways, including transfer reactions, such as the addition of alcohols or esters.

Tert Butylperoxy Pivalate 75% Solution, also known as DTBP, is an organic compound used in polymer chemistry and organic synthesis as a radical initiator.
Ungraded Tert Butylperoxy Pivalate 75% Solutions supplied by TCI America are generally suitable for common industrial uses or for research purposes but typically are not suitable for human consumption or therapeutic use.
Tert Butylperoxy Pivalate 75% Solution has the chemical formula C11H20O3 and is a member of the peroxyesters class of compounds.

Like other peroxides, Tert Butylperoxy Pivalate 75% Solution generates free radicals when it decomposes.
These free radicals initiate polymerization reactions by initiating chain reactions that lead to the formation of polymer chains.
Tert Butylperoxy Pivalate 75% Solution is dissolved in a solvent, and the solution contains 75% TBPP by weight.

The solvent is typically used to make the handling and dosing of Tert Butylperoxy Pivalate 75% Solution more manageable and safer.
Common solvents used include isopropyl alcohol, toluene, or other suitable organic solvents.
Tert Butylperoxy Pivalate 75% Solution is commonly used in the production of various polymer materials, including plastics, elastomers, and thermosetting resins.
Tert Butylperoxy Pivalate 75% Solutions role is to initiate polymerization reactions, leading to the formation of polymer chains with desired properties.

Initiators like Tert Butylperoxy Pivalate 75% Solution play a crucial role in controlling the rate of polymerization, the molecular weight of the polymer, and the polymer's characteristics.
This control is important for tailoring the properties of the end Tert Butylperoxy Pivalate 75% Solution.
Tert Butylperoxy Pivalate 75% Solution is a peroxide, and like other peroxides, it should be handled with care due to its potential for thermal decomposition and flammability.

The purity and consistency of Tert Butylperoxy Pivalate 75% Solution are typically checked through quality control tests to ensure it meets specific standards and that it will perform as expected in various applications.
The use of Tert Butylperoxy Pivalate 75% Solution and its solutions is often subject to regulations, and users may be required to undergo training in the safe handling and storage of such compounds.
Tert Butylperoxy Pivalate 75% Solution is used in the formulation of adhesives and sealants to initiate the curing process.

This allows the adhesive or sealant to bond effectively to various surfaces and materials.
These applications are common in construction, automotive assembly, and product manufacturing.
In the production of composite materials, Tert Butylperoxy Pivalate 75% Solution helps initiate the polymerization of resins, facilitating the bonding of reinforcement materials like fiberglass or carbon fiber with the resin matrix.

This results in lightweight and strong composites used in aerospace, automotive, and construction.
Tert Butylperoxy Pivalate 75% Solution is employed for cross-linking elastomers, enhancing their mechanical properties, resilience, and resistance to heat and chemicals.
This is especially important in the manufacture of rubber products, including tires and hoses.

Tert Butylperoxy Pivalate 75% Solution solutions can be formulated for controlled release applications, where a gradual release of radicals over time is required, allowing for precise control in various processes, such as curing.
Tert Butylperoxy Pivalate 75% Solution is used in the production of specialty polymers designed for specific applications.
This can include unique properties like high-temperature resistance, electrical conductivity, or adhesion characteristics.

Tert Butylperoxy Pivalate 75% Solution solutions can be adjusted and formulated for specific polymerization requirements.
Manufacturers can customize these solutions to achieve precise control over reaction kinetics and end-product properties.
Tert Butylperoxy Pivalate 75% Solution and related initiators are used in the production of materials for the electronics and semiconductor industries, enabling the manufacture of electronic components and devices.

For users of Tert Butylperoxy Pivalate 75% Solution solutions, it's important to refer to the product's safety data sheet (SDS) provided by the manufacturer.
This document contains essential safety and handling information, including precautions, first-aid measures, and storage recommendations.

Melting point: -20 °C
Boiling point: 403.47°C (rough estimate)
Density: 0.895
vapor pressure: 0.009Pa at 20℃
refractive index: n20/D 1.441(lit.)
Flash point: 62 °C
storage temp.: Refrigerator (+4°C)
solubility: Acetonitrile (Slightly), Chloroform (Sparingly)
form: Solution
color: Clear
Water Solubility: immiscible
LogP: 7 at 25℃

Tert Butylperoxy Pivalate 75% Solution, are good oxidizing agents.
Organic compounds can ignite on contact with concentrated Tert Butylperoxy Pivalate 75% Solutions.
Strongly reduced material such as sulfides, nitrides, and hydrides may react explosively with Tert Butylperoxy Pivalate 75% Solutions.

There are few chemical classes that do not at least produce heat when mixed with Tert Butylperoxy Pivalate 75% Solutions.
Many produce explosions or generate gases (toxic and nontoxic).
Generally, dilute solutions of Tert Butylperoxy Pivalate 75% Solution (<70%) are safe, but the presence of a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium) as an impurity may even then cause rapid decomposition, a buildup of heat, and even an explosion.

Solutions of Tert Butylperoxy Pivalate 75% Solutions often become explosive when evaporated to dryness or near-dryness.
A wide range of Tert Butylperoxy Pivalate 75% Solution and azo compounds are used as initiators for the radical polymerization of monomers.
The reason for this is that Tert Butylperoxy Pivalate 75% Solutions are able to form radicals very easily by decaying of the O-O bond, induced by heat or by UV-radiation.

This qualifies Tert Butylperoxy Pivalate 75% Solutions for a controllable trigger of the reaction and thus as an initiator for the free-radical polymerization.
There are various types of Tert Butylperoxy Pivalate 75% Solutions available, which mainly differ in their thermal decomposition behavior.
For this reason you can find Tert Butylperoxy Pivalate 75% Solutions for a broad temperature range.

Tert Butylperoxy Pivalate 75% Solutions can be divided into diacylperoxides, hydroperoxides, dialkylperoxides, peroxyesters, peroxyketals and peroxy(di)carbonates.
The main areas of application for these initiators are the production of low density polyethylene (LDPE), polyvinylchloride (PVC), styrenics (PS/EPS), acrylics (PMMA) and other polymers.
The polymerization of monomers takes place under varying controlled conditions, to which the properties of the initiator have to be adapted.

Certain types of Tert Butylperoxy Pivalate 75% Solutions are also used for the chain degradation of polypropylene.
Tert Butylperoxy Pivalate 75% Solution is liquid substance which has C17H34O4 as chemical formula.
Tert Butylperoxy Pivalate 75% Solution it used used for the (co)polymerization of styrene, acrylonitrile, acrylates and methacrylates in the temperature range between 90°C to 120 °C and for the polymerization of diethylene glycoldi(allycarbonate) based optical monomers.

The use level of Tert Butylperoxy Pivalate 75% Solution will depend on the particular cure parameters being used.
Tert Butylperoxy Pivalate 75% Solution is also known as TMCH and 1,1-Bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane.
A wide variety of Tert Butylperoxy Pivalate 75% Solutions are now offered commercially to meet the sophisticated needs of polymer manufacturers.

Among them are Tert Butylperoxy Pivalate 75% Solutions, peroxydicarbonates, dialkyl peroxides, diacyl peroxides, hydroperoxides, peroxyketals and MEK peroxides.
In research and development laboratories, Tert Butylperoxy Pivalate 75% Solution is a valuable tool for scientists and chemists working on the synthesis of new materials, the development of advanced polymer formulations, and the study of chemical reactions.
Tert Butylperoxy Pivalate 75% Solution aids in the exploration of innovative compounds and materials.

Manufacturers and researchers often perform quality assurance and consistency checks to ensure that Tert Butylperoxy Pivalate 75% Solution and its solutions meet specific purity and performance standards.
This helps maintain product quality and reliability.
Tert Butylperoxy Pivalate 75% Solution can be used to achieve faster polymerization and curing processes, reducing production times and increasing efficiency in various manufacturing applications.

Tert Butylperoxy Pivalate 75% Solution can be part of customized initiator systems that are fine-tuned to meet specific requirements for various industrial processes, allowing for precise control over reaction kinetics and product properties.
Tert Butylperoxy Pivalate 75% Solution are used in the production of materials for energy-efficient products and technologies, including those used in energy storage, energy conversion, and sustainable solutions.
Tert Butylperoxy Pivalate 75% Solution and its solutions may find applications in chemical synthesis, introducing peroxide groups into organic compounds or oxidizing certain functional groups to produce specific intermediates or end products.

Tert Butylperoxy Pivalate 75% Solution solutions are employed for various purposes, such as improving the performance and functionality of textiles, creating durable coatings, and enhancing resistance to environmental factors.
Tert Butylperoxy Pivalate 75% Solution solutions can be used in the production of packaging and container materials with specific properties, including improved barrier properties, resistance to chemicals, and sealing capabilities.
Tert Butylperoxy Pivalate 75% Solution solutions play a role in the production of materials used in the automotive and aerospace industries, where lightweight, strong, and durable materials are essential for various components and structures.

Tert Butylperoxy Pivalate 75% Solution are important in the construction industry for applications such as coatings, adhesives, sealants, and materials used in infrastructure projects, where durability and resistance to environmental factors are crucial.
Tert Butylperoxy Pivalate 75% Solution solutions can be used to create customized materials with specific properties to meet the needs of different industries, from consumer goods to high-tech applications.

Uses
Tert Butylperoxy Pivalate 75% Solution is a crosslinking agent that may be used in polymerization reactions.
Tert Butylperoxy Pivalate 75% Solution can be used for the market segments: polymer production and acrylics with their different applications/functions.
Tert Butylperoxy Pivalate 75% Solution is widely used to initiate the polymerization of various monomers, leading to the formation of polymers.

Tert Butylperoxy Pivalate 75% Solution plays a crucial role in the production of plastics, rubber, elastomers, and thermosetting resins.
In addition to initiating polymerization, Tert Butylperoxy Pivalate 75% Solution is used to cross-link elastomers, such as rubber.
Cross-linking enhances the mechanical properties, heat resistance, and chemical resistance of these materials, making them more durable.

Tert Butylperoxy Pivalate 75% Solution is used in the production of composite materials.
Tert Butylperoxy Pivalate 75% Solution helps initiate the polymerization of resins in these composites, allowing reinforcement fibers like fiberglass or carbon fiber to bond with the resin matrix.
This results in strong, lightweight materials used in aerospace, automotive, and construction.

Tert Butylperoxy Pivalate 75% Solution is used in the formulation of adhesives and sealants.
Tert Butylperoxy Pivalate 75% Solution initiates the curing process, enabling these materials to bond effectively to various surfaces.
This is essential in construction, automotive assembly, and various manufacturing applications.

Tert Butylperoxy Pivalate 75% Solution is employed in the production of coatings, such as paints and varnishes. It serves as an initiator to start the polymerization of resins in these coatings, providing durable and protective finishes on surfaces.

Foam Production: In the manufacturing of foam materials, TBPP is used as a blowing agent.
Tert Butylperoxy Pivalate 75% Solution facilitates the expansion and solidification of foam materials, such as expanded polystyrene (EPS) or polyurethane foam.
Tert Butylperoxy Pivalate 75% Solution can be used to produce specialty polymers with specific properties, such as high-temperature resistance, electrical conductivity, or adhesion characteristics, tailored to specific applications.

Tert Butylperoxy Pivalate 75% Solution is utilized in the textile industry to initiate polymerization reactions for fabric treatments, resulting in textiles with particular properties like water repellency or flame resistance.
Tert Butylperoxy Pivalate 75% Solution can be part of customized initiator systems, allowing manufacturers to adjust formulations to meet specific polymerization requirements, giving precise control over reaction kinetics and product properties.

Tert Butylperoxy Pivalate 75% Solution may be used in the production of food packaging materials to enhance their performance characteristics and extend the shelf life of food products.
Tert Butylperoxy Pivalate 75% Solution helps create food-safe materials with improved properties.
Tert Butylperoxy Pivalate 75% Solution are important in the development of advanced materials for energy storage technologies, including applications in lithium-ion batteries, fuel cells, and supercapacitors.

In some cases, Tert Butylperoxy Pivalate 75% Solution may find use in the development of medical devices, pharmaceutical products, and biocompatible materials.
Tert Butylperoxy Pivalate 75% Solution contributes to the polymerization or cross-linking of specific materials required for these applications.
Tert Butylperoxy Pivalate 75% Solution are used in the production of tires and sealing materials used in the automotive industry, enhancing their mechanical properties, durability, and resistance to heat and chemicals.

Tert Butylperoxy Pivalate 75% Solution solutions can be used in the formulation of coatings for marine environments.
These coatings protect ships, offshore structures, and marine equipment from corrosion and environmental damage.
Tert Butylperoxy Pivalate 75% Solution is employed in the production of components for the automotive and aerospace industries, where lightweight yet strong and durable materials are essential.

Tert Butylperoxy Pivalate 75% Solution is used in the textile industry to create specialized coatings and treatments for textiles, giving them specific properties such as resistance to water, stains, or fire.
Tert Butylperoxy Pivalate 75% Solution are important in the construction industry for applications such as coatings, adhesives, sealants, and materials used in infrastructure projects.
These materials need to be durable and resistant to environmental factors.

Tert Butylperoxy Pivalate 75% Solution can be used in the development of flame-retardant materials used in applications where fire resistance is critical, such as in construction, transportation, and electronics.
Tert Butylperoxy Pivalate 75% Solution solutions play a role in the production of materials used in the automotive and aerospace industries, where lightweight, strong, and durable materials are essential for various components and structures.
Tert Butylperoxy Pivalate 75% Solution solutions can be used to create customized materials with specific properties to meet the needs of different industries, from consumer goods to high-tech applications.

Tert Butylperoxy Pivalate 75% Solution and similar initiators are integral to the production of materials used in the electronics and semiconductor industries, contributing to the manufacturing of electronic components and devices, as well as the development of advanced materials for microelectronics.
In the healthcare sector, Tert Butylperoxy Pivalate 75% Solution can be used in the production of medical devices, drug delivery systems, and materials for tissue engineering.
Tert Butylperoxy Pivalate 75% Solution plays a role in creating biocompatible materials and medical implants.

Tert Butylperoxy Pivalate 75% Solution is used in the automotive industry to initiate polymerization reactions for the production of composite materials used in vehicle components, resulting in lightweight and strong materials for better fuel efficiency and performance.
Tert Butylperoxy Pivalate 75% Solution solutions can be applied to create packaging and container materials with specific properties, including improved barrier properties, resistance to chemicals, and sealing capabilities.
Tert Butylperoxy Pivalate 75% Solution play a crucial role in the development of advanced materials used in energy storage technologies, including lithium-ion batteries and fuel cells, contributing to improved energy efficiency and storage capacity.

Tert Butylperoxy Pivalate 75% Solution solutions can be utilized in the oil and gas sector for the production of corrosion-resistant coatings, sealants, and materials used in pipelines, storage tanks, and equipment subjected to harsh environments.
Tert Butylperoxy Pivalate 75% Solution initiators are employed in the aerospace industry for manufacturing composite materials that are essential for aircraft components, providing high strength-to-weight ratios and fuel efficiency.
In the construction and building industry, Tert Butylperoxy Pivalate 75% Solution solutions can be used to create materials such as coatings, adhesives, and sealants that are durable and resistant to environmental factors, ensuring long-lasting structures.

Tert Butylperoxy Pivalate 75% Solution are used to enhance the performance and functionality of textiles.
They can be applied to create textiles with properties such as resistance to water, stains, and fire, making them suitable for various applications, including workwear and home textiles.

Tert Butylperoxy Pivalate 75% Solution may find use in the production of various consumer goods, from electronics to sporting equipment, where the materials' performance and durability are crucial for customer satisfaction.
Tert Butylperoxy Pivalate 75% Solution solutions can be employed in environmental applications, such as wastewater treatment, where they initiate oxidative reactions for the breakdown of contaminants and pollutants.

Safety Profile
Tert Butylperoxy Pivalate 75% Solution is highly flammable and can readily ignite, posing a fire hazard.
Tert Butylperoxy Pivalate 75% Solution can decompose violently when exposed to heat or shock, potentially leading to explosions. Care must be taken to avoid exposure to open flames, sparks, or heat sources.

Tert Butylperoxy Pivalate 75% Solution is chemically reactive and can react with a variety of substances, including other chemicals, metals, and organic materials.
Mixing it with incompatible substances can lead to hazardous reactions and the release of toxic gases.
In the event of decomposition or combustion, Tert Butylperoxy Pivalate 75% Solution can release toxic fumes and gases, including carbon monoxide and carbon dioxide.

These fumes can pose respiratory and health hazards.
Direct contact with Tert Butylperoxy Pivalate 75% Solution or its solutions can cause skin and eye irritation.
Tert Butylperoxy Pivalate 75% Solution's important to use appropriate personal protective equipment (PPE), such as gloves and safety goggles, to minimize the risk of exposure.

Tert Butylperoxy Pivalate 75% Solution may cause adverse health effects, including skin sensitization and respiratory problems.
Tert Butylperoxy Pivalate 75% Solution's essential to follow recommended safety procedures to reduce the risk of health issues.
Tert Butylperoxy Pivalate 75% Solutionshould be stored away from heat sources, open flames, incompatible substances, and direct sunlight.

Synonyms
6731-36-8
1,1-Bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane
1,1-Bis(t-butylperoxy)-3,3,5-trimethylcyclohexane
1,1-di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane
Perhexa 3M
Luperox 231
Trigonox 29
Lupersol 231
Trigonox 29b50
Trigonox 29b75
Trigonox 29c75
Luperco 231G
Luperco 231XL
Luperco 231XLP
Varox 231xl
Trigonox 29/40mb
Trigonox 29/40
CCRIS 6844
EINECS 229-782-3
BRN 5932965
Peroxide, 1,1'-(3,3,5-trimethylcyclohexylidene)bis(2-(1,1-dimethylethyl)
Peroxide, 1,1'-(3,3,5-trimethylcyclohexylidene)bis[2-(1,1-dimethylethyl)
Di-tert-butyl 3,3,5-trimethylcyclohexylidene diperoxide
Di-tert-butylperoxy-3,3,5-trimethylcyclohexane peroxide
Peroxide, (3,3,5-trimethylcyclohexylidene)bis(tert-butyl)
EC 229-782-3
SCHEMBL21420
1,1-bis(tert-butyldioxy)-3,3,5-trimethylcyclohexane
DTXSID4020165
NALFRYPTRXKZPN-UHFFFAOYSA-N
1,1-bis[(1,1-dimethylethyl)peroxy]-3,3,5-trimethylcyclohexane
Peroxide, (3,3,5-trimethylcyclohexylidene)bis((1,1-dimethylethyl)
AKOS015913687
FT-0606071
A835707
Q3375552
1,1-bis(t-butylperoxy)-3,3,5-trimethyl-cyclohexane
1,1-bis (tert-butylperoxi)-3,3,5 trimethylcyclohexane
1,1-bis(tert-butylperoxy)-3,3,5-trimethyl-cyclohexane
1,1-bis(tert.-butyl peroxy)-3,3,5-trimethyl cyclohexane
Luperox(R) 231, 1,1-Bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane, 92%
TERT.BUTYL PEROXY -3,5,5- TRIMETHYL HEXANOATE
Tert-Butyl peroxy-3,5,5-trimethyl hexanoate is sensitive to heat.
Storage of Tert-Butyl peroxy-3,5,5-trimethyl hexanoate must be done so with stringent temperature control measures.
Tert-Butyl peroxy-3,5,5-trimethyl hexanoate explodes with great violence when rapidly heated to a critical temperature; pure form is shock sensitive and detonable.

CAS: 13122-18-4
MF: C13H26O3
MW: 230.34
EINECS: 236-050-7

Tert-Butyl peroxy-3,5,5-trimethyl hexanoate is a clear liquid which has C13H26O3 as chemical formula.
Tert-Butyl peroxy-3,5,5-trimethyl hexanoate is used as initiator in the production of acrylic polymers, polyethylene and styrene.
Further Tert-Butyl peroxy-3,5,5-trimethyl hexanoate is applied as curing agent in the production of unsaturated polyester resins.
Tert-Butyl peroxy-3,5,5-trimethyl hexanoate is also known as TBPIN and tert-butyl 3,5,5-trimethylperoxyhexanoate.

Tert-Butyl peroxy-3,5,5-trimethyl hexanoate Chemical Properties
Melting point: -30 °C
Boiling point: 312.34°C (rough estimate)
Density: 0.897
Vapor pressure: 3Pa at 30.05℃
Refractive index: 1.4295-1.4315
Storage temp.: Refrigerator (+4°C)
Water Solubility: partly miscible
LogP: 4.4 at 25℃
CAS DataBase Reference: 13122-18-4
EPA Substance Registry System: Tert-Butyl peroxy-3,5,5-trimethyl hexanoate (13122-18-4)

Synonyms
tert-butyl 3,5,5-trimethylhexaneperoxoate
13122-18-4
tert-Butyl peroxy-3,5,5-trimethylhexanoate
tert-Butyl perisononanoate
Hexaneperoxoic acid, 3,5,5-trimethyl-, 1,1-dimethylethyl ester
tert-Butyl 3,5,5-trimethylperoxyhexanoate
84TC2IY818
tert-butyl 3,5,5-trimethylhexanoylperoxide
EINECS 236-050-7
TRIGONOX 42
PERBUTYL 355
LUPEROX 270
SCHEMBL210898
UNII-84TC2IY818
DTXSID00276147
DTXSID40864365
VSJBBIJIXZVVLQ-UHFFFAOYSA-N
EC 236-050-7
Q27269552
PEROXYHEXANOIC ACID, 3,5,5-TRIMETHYL-, TERT-BUTYL ESTER
153302-08-0
TERT.BUTYL PEROXYISOBUTYRATE 75%
Tert-Butyl peroxyisobutyrate 75% is particularly sensitive to temperature rises.
Above a given "Control Temperature" they decompose violently.
Tert-Butyl peroxyisobutyrate 75% is generally stored or transported in a solvent slurry.

CAS: 109-13-7
MF: C8H16O3
MW: 160.21
EINECS: 203-650-5

Solvent is usually benzene.
Responders must regard hazards of the peroxide as well as the benzene solvent.

Tert-Butyl peroxyisobutyrate 75% Chemical Properties
Boiling point: 226.12°C (rough estimate)
Density: 1.0227 (rough estimate)
Vapor pressure: 5.04hPa at 37℃
Refractive index: 1.4370 (estimate)
Water Solubility: 3.96g/L at 20℃
LogP: 2.68 at 25℃
CAS DataBase Reference: 109-13-7
EPA Substance Registry System: Tert-Butyl peroxyisobutyrate 75% (109-13-7)

Reactivity Profile
Tert-Butyl peroxyisobutyrate 75% explodes with great violence when rapidly heated to a critical temperature; pure form is shock sensitive and detonable.

Purification Methods
After diluting 90mL of the material with 120mL of pet ether, the mixture is cooled to 5o and shaken twice with 90mL portions of 5% NaOH solution (also at 5o).
The non-aqueous layer, after washing once with cold water, is dried at 0o with a mixture of anhydrous MgSO4 and MgCO3 containing ca 40% MgO.
After filtering, this material is passed, twice, through a column of silica gel at 0o (to remove tert-butyl hydroperoxide).
The solution is then evaporated at 0o/0.5-1mm to remove the solvent, and the residue is recrystallised several times from pet ether at -60o, then subjected to high vacuum to remove traces of solvent.
Handle with adequate protection due to possible EXPLOSIVE nature.

Synonyms
tert-Butyl peroxyisobutyrate
109-13-7
tert-butyl 2-methylpropaneperoxoate
PROPANEPEROXOIC ACID, 2-METHYL-, 1,1-DIMETHYLETHYL ESTER
EINECS 203-650-5
EC 203-650-5
SCHEMBL21417
DTXSID1059363
PFBLRDXPNUJYJM-UHFFFAOYSA-N
AKOS006275424
Tert-Butanol
SYNONYMS tris(2-hydroxyethyl)ammonium dodecylsulphate ;TriethanolamineLaurylSulfateSolution;TRIETHANOLAMINELAURYLSULPHATE;TEA-LAURYLSULPHATE;Triethanolaminlaurylsulfat;Dodecyl triethanolamine sulfate;2,2,2-NITRILOETHANOL LAURYLULFATE 40% AQUEOUS SOLN.;Laurylsulfuric acid triethanolamine CAS NO:205-388-7
Tert-Butyl Acetate
cas no : 75-91-2 1,1-Dimethylethyl Hydroperoxide;TBHP; T hydro; 2-Hydroperoxy-2-Methylpropane; Dimethylethyl hydroperoxide; Butyl hydroperoxide; tertiary-Butyl hydroperoxide; Trigonox;
TERT-BUTYL HYDROGEN PEROXIDE
Tert-Butyl hydrogen peroxide

CAS Number: 75-91-2
EC Number: 200-915-7
Molecular Formula: C₄H₁₀O₂
Molecular Weight: 90.12



APPLICATIONS


Tert-Butyl hydrogen peroxide (TBHP)'s production and use as a chemical intermediate may result in its release to the environment through various waste streams(SRC).
Based on a classification scheme, an estimated Koc value of 86(SRC), determined from a structure estimation method, indicates that Tert-Butyl hydrogen peroxide (TBHP) is expected to have high mobility in soil(SRC).

However, hydroperoxides react with a variety of compounds and are reduced readily to the corresponding alcohols.
They are decomposed readily bymultivalent metal ions, are photo- and thermally sensitive and undergo initial oxygen-oxygen bond homolysis, and are attacked readily by free radicals, undergoing induced and self-induced decomposition.

Chemical degradation is expected tobe the dominant fate process in soil(SRC).
The pKa of Tert-Butyl hydrogen peroxide (TBHP) is 12.80, indicating that this compound will exist in the unionized form in the environment.

Volatilization of Tert-Butyl hydrogen peroxide (TBHP) from moist soil surfacesis expected to be an important fate process(SRC) given an estimated Henry's Law constant of 1.6X10-5 atm-cu m/mole(SRC), using a fragment constant estimation method.
Tert-Butyl hydrogen peroxide (TBHP) is expected to volatilize from dry soil surfaces(SRC) based upon a vapour pressure of 5.46 mm Hg at 25 °C.

Utilizing the Japanese MITI test, 0% of the Theoretical BOD was reached in 4 weeks indicating that biodegradation is not an important environmental fate process in soil(SRC).
Tert-Butyl hydrogen peroxide (tBuOOH) is the organic compound with the formula (CH3)3COOH.

Tert-Butyl hydrogen peroxide is a hydroperoxide, in fact one of the most widely used in a variety of oxidation processes, for example the Halcon process.
Furthermore, Tert-Butyl hydrogen peroxide is normally supplied as a 69–70% aqueous solution.

Tert-Butyl hydrogen peroxide (TBHP) provides a readily available and convenient source of active oxygen suitable for diverseoxidation technologies.
Producers of initiators use T-Hydro solution to synthesize many perester, dialkyl peroxide and perketal derivatives.

Tert-Butyl hydrogen peroxide itself serves as a free radical initiator for polymerization, copolymerizations, graftpolymerizations and curing of polymers.
Moreover, Tert-Butyl hydrogen peroxide (TBHP) offers advantages of versatility, regioselectivity, stereoselectivity, chemoselectivity and reactivity control with catalyst choice, mild reaction conditions and bulk availability.

Tert-Butyl hydrogen peroxide (TBHP) finds use in preparing speciality chemicals required by fine chemical and performance chemical industries such as pharmaceuticals and agrochemicals.
Besides, Tert-Butyl hydrogen peroxide (TBHP) can selectively oxidize hydrocarbons, olefins and alcohols.

Asymmetric epoxidation and kinetic resolution with Tert-Butyl hydrogen peroxide (TBHP) can provide access to complex chiral intermediates.
Tert-Butyl hydrogen peroxide is used as an initiator for radical polymerization and in various oxidation process such as Sharpless epoxidation.

Tert-Butyl hydrogen peroxide is involved in the osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions.
Furthermore, Tert-Butyl hydrogen peroxide is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes.

Tert-Butyl hydrogen peroxide plays an important role in the introduction of peroxy groups in organic synthesis.
In addition, Tert-Butyl hydrogen peroxide is used as an oxidant in the Halcon process for the production of propylene oxide.

The standard commercial product (80%, stabilized with water and phosphoric acid) is suitable for curing polyester resins and for the emulsion polymerization of styrene -butadiene rubbers.
Compared to hydrogen peroxide and organic peracids, Tert-Butyl hydrogen peroxide is less reactive, more soluble in organic solvents.

Overall, tert-Butyl hydrogen peroxide is renowned for the convenient handling properties of its solutions.
tert-Butyl hydrogen peroxides solutions in organic solvents are highly stable.

(TBHP) is a clear, colorless, stable and aqueous solution usually available in concentration of approximately 70 wt% TBHP and 30 wt% water.
More to that, tert-Butyl hydrogen peroxide belongs to the alkyl hydroperoxide chemical family.

tert-Butyl hydrogen peroxide is a highly reactive product, with three types of significant physical hazards: flammability, thermal, and decomposition due to contamination.


Applications of tert-Butyl hydrogen peroxide:

Industrially, tert-Butyl hydrogen peroxide is used to prepare propylene oxide.
In the Halcon process, molybdenum-based catalysts are used for this reaction:
(CH3)3COOH + CH2=CHCH3 → (CH3)3COH + CH2OCHCH3

Tert-Butyl hydrogen peroxide is catalyst in polymerization reactions.
Further to that, Tert-Butyl hydrogen peroxide is used to introduce peroxy group into organic molecules, in radical substitution reactions.


Use Areas of Tert-Butyl hydrogen peroxide:

General adhesives and binding agents for a variety of uses
Relating to agricultural, including the raising and farming of animals and growing of crops
Products used to care for apparel (e.g., she polish, products to repair footwear or leather, waterproofing sprays, etc.)
The building or construction process for buildings or boats (includes activities such as plumbing and electrical work, bricklaying, etc)
Materials used in the building process, such as flooring, insulation, caulk, tile, wood, glass, etc.
Flooring materials (carpets, wood, vinyl flooring), or related to flooring such as wax or polish for floors
Wall construction materials, or wall coverings
Catalyst
Drug product, or related to the manufacturing of drugs, veterinary, animal, or pet.
pharmaceutical
Products related to computers or the manufacturing of computers
Products related to the activity of fishing
Includes antifoaming agents, coagulating agents, dispersion agents, emulsifiers, flotation agents, foaming agents, viscosity
adjusters, etc
Includes food packaging, paper plates, cutlery, small appliances such as roasters, etc.; does not include facilities thatmanufacture food
Forestry
The activity of hunting
Related to all forms of cleaning/washing, including cleaning products used in the home, laundry detergents, soaps, de-greasers, spot removers, etc; modifiers included when specific information is known, such as dry cleaning, laundry, soap,window/floor, etc
Materials used in the building process, such as flooring, insulation, caulk, tile, wood, glass, etc.
Wood used as a building material, wood preservatives
The manufacturing of chemicals, or laboratory chemicals.
Related to manufacturing for export.
Furniture, or the manufacturing of furniture
Manufacturing of or related to machinery, for production of cement or food, air/spacecraft machinery, electrical machinery,etc
Related to metals - manufacturing of metals, casting of metals, production of metals, surface treatment of metals, etc
Crude oil, crude petroleum, refined oil products, fuel oils, drilling oils
Various types of paint for various uses, modifiers included when more information is known
Plastic products, industry for plastics, manufacturing of plastics, plastic additives (modifiers included when known)
Raw materials used in a variety of products and industries (e.g. in cosmetics, chemical manufacturing, production of metals,etc); modifiers included when known to indicate what the raw materials are used for.
Rubber products (e.g. tires) and their manufacture
Various types of paint for various uses.
Modifier included when source indicates the product is water-based
Related to the manufacturing of pulp or paper products, or paper products in general
Substances used for preventing, destroying or mitigating pests
Additive for products to promote hardening, used in paints and varnishes, plastics, etc.
Accelerators, activators, oxidation agents, reducing agents, etc
General antioxidants, application indicated if known
Oxidizing/reducing agents
Related to fracking, natural gas, industrial gases
Crude oil, crude petroleum, refined oil products, fuel oils, drilling oils
Surface treatments for metals, hardening agents, corrosion inhibitors, polishing agents, rust inhibitors, water repellants, etc(surfaces to be applied to often not indicated in source description)
Chairs and seats


Tert-Butyl hydrogen peroxide is an important commercial chemical.
Additionally, Tert-Butyl hydrogen peroxide is used in many chemical manufacturing processes and is used in bleaching and deodorizing.
The general population is not likely to be exposed to Tert-Butyl hydrogen peroxide.

If Tert-Butyl hydrogen peroxide is released to the environment, it will be broken down in air.
Tert-Butyl hydrogen peroxide is expected to be broken down by sunlight.

Furthermore, Tert-Butyl hydrogen peroxide will not move into air from moist soil and water surfaces.
Tert-Butyl hydrogen peroxide is unstable and breaks down rapidly to oxygen.


Application Areas of Tert-Butyl hydrogen peroxide:

Industrially, Tert-Butyl hydrogen peroxide is used as a radical polymerization initiator.
For example, its reaction with propene yields propylene oxide and the byproduct t-butanol which can dehydrate to isobutene and convert to MTBE.


Synthesis and production of Tert-Butyl hydrogen peroxide:

Many synthetic routes are available, including:

The reaction of hydrogen peroxide with isobutylene or tert-butyl alcohol in the presence of sulfuric acid
Auto-oxidation of isobutane with oxygen


Tert-Butyl hydrogen peroxide (TBHP) is primarily used in the chemical industry.
TMoreover, ert-Butyl hydrogen peroxide is used as starting material (or intermediate) and as a reactive ingredient (catalyst, initiator or curing agent).


Applications of tert-Butyl hydrogen peroxide are:

The epoxidation of propylene to propylene oxide (intermediate)
Free radical initiator for polymerisations, copolymerisations, graft polymerisations and curing of polymers (plastic industry)
Free radical initiator to polymerise unsaturated monomers, usually to high polymers


Tert-Butyl hydrogen peroxide is mainly used by manufacturers of synthetic lattices or water borne dispersions.
Besides, Tert-Butyl hydrogen peroxide is also used as a component of catalysts systems for unsaturated polyester resins.

Spesific uses of Tert-Butyl hydrogen peroxide:

The synthesis of other organic peroxy molecules (as a precursor of initiators) such as perester, persulphate, dialkyl peroxide and perketal derivatives;
The preparation of speciality chemicals required by fine chemical and performance chemical industries, such as pharmaceuticals and agrochemicals (fungicide).
Tert-Butyl hydrogen peroxide can be dehydrated to isobutene and convert to MTBE.
On a much smaller scale, tert-Butyl hydrogen peroxide is used to produce some fine chemicals by the Sharpless epoxidation.
The use as an ingredient of hardeners for plastics
Hardeners for plastics are also used in the plastic industry

Tert-Butyl hydrogen peroxide is used as a chemical intermediate, a curing agent for polyesters, and a catalyst for polymerization; also used for bleaching and deodorizing.
In addition, Tert-Butyl hydrogen peroxide is a polymerization initiator used to produce specialty chemicals in closed systems.

Tert-Butyl hydrogen peroxide Solution is used for the emulsion polymerization of Styrene, Acrylates and Methacrylates and thecuring of polyester resins.
Suitable to be used as active peroxide in high-pressure polymerization or as an initiator in oxygen combination of Ethylene.

Common applications of Tert-Butyl hydrogen peroxide are acrylate, vinyl acetate, styrene-butadiene production, curing of styrene -polyester resins, oxidizing agent for hydrocarbons.
Recommended storage temperature of Tert-Butyl hydrogen peroxide is between 0 °C and +30 °C.


Tert-Butyl hydrogen peroxide (TBHP)39’s the production and use as a chemical intermediate may result in its release to the environment through various waste streams.
If released to air, a vapour pressure of 5.46 mm Hg at 25 C indicates Tert-Butyl hydrogen peroxide will exist solely as a vapour in the ambient atmosphere.

Vapour-phase Tert-Butyl hydrogen peroxide (TBHP) will be degraded in the atmosphere by reaction with photochemically produced hydroxyl radicals; the half-life for this reaction in air is estimated to be 5 days.
Tert-Butyl hydrogen peroxide (TBHP) will directly photolyze with breakage of the peroxidebond.
If released to soil, Tert-Butyl hydrogen peroxide (TBHP) is expected to have high mobility based upon an estimated Koc of86.

Volatilization from moist soil surfaces may be an important fate process based upon an estimated Henry 39’s Lawconstant of 1.6X10-5 atm-cu m/mole.
The pKa of Tert-Butyl hydrogen peroxide (TBHP) is 12.8, indicating that this compound willexist in the un-ionized form in the environment.

Tert-Butyl hydrogen peroxide (TBHP) may volatilize from dry soil surfaces basedupon its vapour pressure.
Utilizing the Japanese MITI test, 0% of the Theoretical BOD was reached in 4 weeks, indicating that biodegradation is not an important environmental fate process in soil or water.

Tert-Butyl hydrogen peroxide is expected to react rapidly with organic matter in soil and water and be decomposed rapidly by metal ions, which will attenuate all transport processes.
Hydroperoxides would be converted to the corresponding alcohols.

If released into water, Tert-Butyl hydrogen peroxide (TBHP) is not expected to adsorb to suspended solids and sediment based upon the estimated Koc.
However, hydroperoxides react with a variety of compounds and are reduced readily to the corresponding alcohols.

Anestimated BCF of 3 suggests the potential for bioconcentration in aquatic organisms is low.
Occupational exposure to Tert-Butyl hydrogen peroxide (TBHP) may occur through inhalation and dermal contact with this compound at workplaces where Tert-Butyl hydrogen peroxide (TBHP) is produced or used.

The general public is not likely to be exposed to Tert-Butyl hydrogen peroxide.
Industrially, Tert-Butyl hydrogen peroxide is used to prepare propylene oxide.

In the Halcon process, molybdenum-based catalysts are used for this reaction:
(CH3)3COOH + CH2=CHCH3 → (CH3)3COH + CH2OCHCH3

The byproduct t-butanol, which can be dehydrated to isobutene and converted to MTBE.

On a much smaller scale, Tert-Butyl hydrogen peroxide is used to produce some fine chemicals by the Sharpless epoxidation.

Tert-Butyl hydrogen peroxide is an intermediate in the production of propylene oxide and t-butyl alcohol from isobutane and propylene.
More to that, Tert-Butyl hydrogen peroxide is primarily used as an initiator and finishing catalyst in the solution and emulsion polymerization methods for polystyrene and polyacrylates.

Other uses of Tert-Butyl hydrogen peroxide are for the polymerization of vinyl chloride and vinyl acetate and as an oxidation and sulfonation catalyst in bleaching and deodorizing operations.
Tert-Butyl hydrogen peroxide is a strong oxidant and reacts violently with combustible and reducing materials, and metallic and sulfur compounds.

Tert-Butyl hydrogen peroxide is catalyst in polymerization reactions.
Further to that, Tert-Butyl hydrogen peroxide is used to introduce peroxy group into organic molecules, in radical substitution reactions.
Tert-Butyl hydrogen peroxide is used for polymerization, oxidation, sulfonation catalyst, bleaching, deodorizing.

Tert-Butyl hydrogen peroxide is used as an oxidant in the Halcon process for the production of propylene oxide.
The standard commercial product (80%, stabilized with water and phosphoric acid) is suitable for curing polyester resins and for the emulsion polymerization of styrene-butadiene rubbers.


Industry Uses of Tert-Butyl hydrogen peroxide:

Fillers
Fuels and fuel additives
Intermediates
Paint additives and coating additives not described by other categories
Plasticizers
Plating agents and surface treating agents
Process regulators
Processing aids, not otherwise listed
Consumer Uses
Electrical and electronic products
Fuels and related products
Paints and coatings
Plastic and rubber products not covered elsewhere
Water treatment products


Tert-Butyl hydrogen peroxide is used to initiate polymerization reactions and in organic syntheses to introduce peroxy groups into the molecule.
Additionally, Tert-Butyl hydrogen peroxide is catalyst in polymerization reactions.

Tert-Butyl hydrogen peroxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation.
Furthermore, Tert-Butyl hydrogen peroxide is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions.

Furthermore, tert-Butyl hydrogen peroxide is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes.
tert-Butyl hydrogen peroxide plays an important role for the introduction of peroxy groups in organic synthesis.



DESCRIPTION


Tert-Butyl hydrogen peroxide is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
Moreover, Tert-Butyl hydrogen peroxide is widely used in a variety of oxidation processes.


Production Methods:

Tert-Butyl hydrogen peroxide is produced by the liquid-phase reaction of isobutane and molecular oxygenor by mixing equimolar amounts of t-butyl alcohol and 30–50% hydrogen peroxide.
Besides, Tert-Butyl hydrogen peroxide can also be prepared from t-butyl alcohol and 30% hydrogen peroxide in the presence of sulfuric acid or by oxidation of tert-butylmagnesium chloride. The manufacturing process of Tert-Butyl hydrogen peroxide is in a closed system.


Tert-Butyl hydrogen peroxide (tBuOOH) is the organic compound with the formula (CH3)3COOH.
In addition, Tert-Butyl hydrogen peroxide is one of the most widely used hydroperoxides in a variety of oxidation processes, for example the Halcon process.

Tert-Butyl hydrogen peroxide is normally supplied as a 69–70% aqueous solution.
Compared to hydrogen peroxide and organic peracids, Tert-Butyl hydrogen peroxide is less reactive and more soluble in organic solvents.

Overall, Tert-Butyl hydrogen peroxide is renowned for the convenient handling properties of its solutions.
Its solutions in organic solvents are highly stable.

Tert-Butyl hydrogen peroxide is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
More to that, Tert-Butyl hydrogen peroxide is widely used in a variety of oxidation processes.
Tert-Butyl hydrogen peroxide has a role as an antibacterial agent and an oxidising agent.

Tert-Butyl hydrogen peroxide is a natural product found in Apium graveolens.
Further to that, Tert-Butyl hydrogen peroxide is a watery odorless colorless liquid.
Tert-Butyl hydrogen peroxide floats on and dissolves slowly in water.
Additionally, Tert-Butyl hydrogen peroxide is an organic peroxide widely used in a variety of oxidation processes.


Chemical Properties of tert-Butyl hydrogen peroxide:

Tert-Butyl hydrogen peroxide (TBHP) is a water-white liquid commonly commercially available as a 70% solution in water; 80% solutions are also available.
Furthermore, Tert-Butyl hydrogen peroxide is used to initiate polymerization reactions and in organic syntheses to introduce peroxy groups into the molecule.
Tert-Butyl hydrogen peroxide vapor can burn in the absence of air and may be flammable at either elevated temperature or at reduced pressure.

Fine mist/spray may be combustible at temperatures below the normal flash point.
When evaporated, the residual liquid will concentrate tert-Butyl hydrogen peroxide content and may reach an explosive concentration (>90%).
Closed containers may generate internal pressure through the degradation of tert-Butyl hydrogen peroxide to oxygen .

Tert-Butyl hydrogen peroxide is a highly reactive product.
The three types of significant physical hazards are flammability, thermal, and decomposition due to contamination.

To minimize these hazards, avoid exposure to heat, fire, or any condition that will concentrate the liquid material.
Store Tert-Butyl hydrogen peroxide away from heat, sparks, open flames, foreign contaminants, combustibles, and reducing agents.



PROPERTIES


Molecular Weight: 90.12
XLogP3-AA: 0.6
Hydrogen Bond Donor Count: 1
Hydrogen Bond Acceptor Count: 2
Rotatable Bond Count: 1
Exact Mass: 90.068079557
Monoisotopic Mass: 90.068079557
Topological Polar Surface Area: 29.5 Ų
Heavy Atom Count: 6
Formal Charge: 0
Complexity: 35.3
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes



FIRST AID


Eyes:

First check the victim for contact lenses and remove if present.
Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.
IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.


Skin:

IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.
Gently wash all affected skin areas thoroughly with soap and water.
IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop.
IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.


Inhalation:

IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.
If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital.
Provide proper respiratory protection to rescuers entering an unknown atmosphere.
Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.


Ingestion:

DO NOT INDUCE VOMITING.
Corrosive chemicals will destroy the membranes of the mouth, throat, and esophagus and volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting.
Thus, the risk of increasing the medical problems by inducing vomiting of a volatile corrosive chemical is very high.
If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.
IMMEDIATELY transport the victim to a hospital.
If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body.
DO NOT INDUCE VOMITING.
IMMEDIATELY transport the victim to a hospital.



HANDLING AND STORAGE


ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
Keep combustibles (wood, paper, oil, etc.) away from spilled material.
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

Keep substance wet using water spray.
Stop leak if you can do it without risk.


Small Spill:

Pick up with inert, damp, non-combustible material using clean, non-sparking tools and place into loosely covered plastic containers for later disposal.


Large Spill:

Wet down with water and dike for later disposal.
Prevent entry into waterways, sewers, basements or confined areas.
DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.


Store in original container.
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Recommended storage temperature 2 - 8 °C



SYNONYMS


2-hydroperoxy-2-methylpropane
2-methylpropane-2-peroxol
Hydroperoxide, 1,1-Dimethylethyl
t-Butyl hydroperoxide
Tert-Butyl hydrogen peroxide
Tert-Butyl hydrogen peroxide
Tert-Butyl hydrogen peroxide
Tert-Butyl hydrogen peroxide
Tert-Butyl hydrogen peroxide (upper limit: 72% w/w; typical concentration: 70% w/w)
Tert-Butyl hydrogen peroxide;75-91-2;TBHP;T-Butyl;hydroperoxide;tert-Butylhydroperoxide;Perbutyl H;t-
Butylhydroperoxide;2-Hydroperoxy-2-methylpropane;Cadox TBH;1,1-Dimethylethyl hydroperoxide;Hydroperoxide, 1,1-
dimethylethyl;tert-Butyl hydrogen peroxide;Terc. butylhydroperoxid;Hydroperoxyde de butyle tertiaire;Hydroperoxide, tertbutyl;
Slimicide;DE-488;Tertiary butyl hydroperoxide;Trigonox a-75;Trigonox A-W70;TBHP-70;NSC 672;Tertiary-butyl
hydroperoxide;1,1-Dimethylethylhydroperoxide;tert-Butyl-hydroperoxide;Dimethylethyl hydroperoxide;T-Hydro;tBuOOH;t-
BuOOH;UNII-955VYL842B;Tert-Butyl hydrogen peroxide solution;CHEBI:64090;955VYL842B;Tert-Butyl hydrogen peroxide (70%
Solution in Water);MFCD00002130;Tert-Butyl hydrogen peroxide, 70% solution in water;Caswell No. 130BB;Trigonox A-75
[Czech];terc.Butylhydroperoxid [Czech];CCRIS 5892;HSDB 837;terc.Butylhydroperoxid;terc. Butylhydroperoxid [Czech];tert
Butylhydroperoxide;EINECS 200-915-7;DE-488;BRN 1098280;Hydroperoxyde de butyle tertiaire [French];AI3-
50541;Kayabutyl H;tert-BuOOH;Hydroperoxide, 1,1-dimethylethyl-;tBOOH;Perbutyl H 69;Perbutyl H 69T;Perbutyl H80;Luperox TBH 70X;t-butyl-hydroperoxide;terbutyl hydroperoxide;tert-butyhydroperoxide;tert-C4H9OOH;Trigonox A-W
70;t-butyl hydrogenperoxide;t-butyl-hydrogenperoxide;tert.-butylhydroperoxide;tert.butyl
hydroperoxide;tertiarybutylhydroperoxide;tertbutylhydrogen peroxide;t-butyl hydrogen peroxide;tert.-butyl
hydroperoxide;ACMC-1BM3U;DSSTox_CID_4693;tert-butylhydrogen peroxide;EC 200-915-
7;DSSTox_RID_78866;DSSTox_GSID_31209;tertiary butyl hydro peroxide;Hydroperoxide,1-dimethylethyl;Trigonox A-80
(Salt/Mix);UN 2093 (Salt/Mix);UN 2094 (Salt/Mix);USP -800 (Salt/Mix);CHEMBL348399;NSC672;DTXSID9024693;tert-Butyl
hydroperoxide (8CI);Tert-Butyl hydrogen peroxide, >90% with water [Forbidden];WLN: QOX1&1&1;tert-Butyl-hydroperoxide
solution;NSC-672;2-Methyl-prop-2-yl-hydroperoxide;ZINC8585869;CC(C)([OH+][O-])C;Tox21_200838;ANW-43954;Aztec tbutyl
Hydroperoxide-70, Aq;Tert-Butyl hydrogen peroxide solution, CP;AKOS000121070;2-$l^{1}-oxidanyloxy-2-
methylpropane;NCGC00090725-01;NCGC00090725-02;NCGC00090725-03;NCGC00258392-01;Hydroperoxide, 1,1-
dimethylethyl (9CI);Tert-Butyl hydrogen peroxide (70% in Water);Tert-Butyl hydrogen peroxide, >90% with water;B3153;FT-
0657109;Q286326;J-509597;Tert-Butyl hydrogen peroxide solution, ~5.5 M in decane;F1905-8242;Tert-Butyl hydrogen peroxide
solution (TBHP), 70% in H2O;Tert-Butyl hydrogen peroxide solution, 5.0-6.0 M in decane;Tert-Butyl hydrogen peroxide solution, 5.0-6.0
M in nonane;Luperox(R) TBH70X, Tert-Butyl hydrogen peroxide solution, 70 wt. % in H2O;Tert-Butyl hydrogen peroxide solution, ~80%
in di-tert-butyl peroxide/water 3:2;Tert-Butyl hydrogen peroxide solution, packed in FEP bottles, ~5.5 M in decane (over molecular
sieve 4??);Tert-Butyl hydrogen peroxide solution, packed in FEP bottles, ~5.5 M in nonane (over molecular sieve 4 ??)
Tert-Butyl hydrogen peroxide
75-91-2
TBHP
T-Butyl hydroperoxide
tert-Butylhydroperoxide
2-Hydroperoxy-2-methylpropane
Perbutyl H
t-Butylhydroperoxide
1,1-Dimethylethyl hydroperoxide
Cadox TBH
Hydroperoxide, 1,1-dimethylethyl
tert-Butyl hydrogen peroxide
Terc. butylhydroperoxid
Hydroperoxyde de butyle tertiaire
Hydroperoxide, tert-butyl
Slimicide DE-488
Tertiary butyl hydroperoxide
Trigonox a-75
Trigonox A-W70
TBHP-70
1,1-Dimethylethylhydroperoxide
NSC 672
t-BuOOH
Tertiary-butyl hydroperoxide
tert-Butyl-hydroperoxide
Dimethylethyl hydroperoide
T-Hydro
Perbutyl H 69T
Luperox TBH 70X
Trigonox A-W 70
Tert-Butyl hydrogen peroxide solution
CHEBI:64090
NSC-672
955VYL842B
Tert-Butyl hydrogen peroxide (70% Solution in Water)
Caswell No. 130BB
Trigonox A-75 [Czech]
tBOOH
terc.Butylhydroperoxid [Czech]
CCRIS 5892
HSDB 837
terc.Butylhydroperoxid
terc. Butylhydroperoxid [Czech]
tert Butylhydroperoxide
EINECS 200-915-7
DE 488
DE-488
BRN 1098280
Hydroperoxyde de butyle tertiaire [French]
UNII-955VYL842B
AI3-50541
Kayabutyl H
tBuOOH
tert-BuOOH
Hydroperoxide, 1,1-dimethylethyl-
Perbutyl H 69
Perbutyl H 80
t-butyl-hydroperoxide
terbutyl hydroperoxide
tert-butyhydroperoxide
tert-C4H9OOH
t-butyl hydrogenperoxide
t-butyl-hydrogenperoxide
tert.-butylhydroperoxide
tert.butyl hydroperoxide
tertiarybutylhydroperoxide
tertbutylhydrogen peroxide
t-butyl hydrogen peroxide
tert.-butyl hydroperoxide
KAYABUTYL H 70
DSSTox_CID_4693
tert-butylhydrogen peroxide
EC 200-915-7
DSSTox_RID_78866
DSSTox_GSID_31209
tertiary butyl hydro peroxide
Hydroperoxide,1-dimethylethyl
Trigonox A-80 (Salt/Mix)
UN 2093 (Salt/Mix)
UN 2094 (Salt/Mix)
USP -800 (Salt/Mix)
CHEMBL348399
NSC672
DTXSID9024693
Tert-Butyl hydrogen peroxide (8CI)
Tert-Butyl hydrogen peroxide, >90% with water [Forbidden]
WLN: QOX1&1&1
tert-Butyl-hydroperoxide solution
2-Methyl-prop-2-yl-hydroperoxide
ZINC8585869
Tox21_200838
Aztec t-butyl Hydroperoxide-70, Aq
MFCD00002130
Tert-Butyl hydrogen peroxide [II]
Tert-Butyl hydrogen peroxide [MI]
Tert-Butyl hydrogen peroxide solution, CP
AKOS000121070
Tert-Butyl hydrogen peroxide [HSDB]
NCGC00090725-01
NCGC00090725-02
NCGC00090725-03
NCGC00258392-01
Tert-Butyl hydrogen peroxide aqueous solution
Hydroperoxide,1,1-dimethylethyl (9CI)
Tert-Butyl hydrogen peroxide (70% in Water)
Tert-Butyl hydrogen peroxide, >90% with water
B3153
FT-0657109
Tert-Butyl hydrogen peroxide, 70% solution in water
Q286326
J-509597
Tert-Butyl hydrogen peroxide solution, ~5.5 M in decane
F1905-8242
Tert-Butyl hydrogen peroxide solution (TBHP), 70% in H2O
Tert-Butyl hydrogen peroxide solution, 5.0-6.0 M in decane
Tert-Butyl hydrogen peroxide solution, 5.0-6.0 M in nonane
Luperox(R) TBH70X, Tert-Butyl hydrogen peroxide solution, 70 wt. % in H2O
Tert-Butyl hydrogen peroxide solution, ~80% in di-tert-butyl peroxide/water 3:2
Tert-Butyl hydrogen peroxide solution, packed in FEP bottles, ~5.5 M in decane (over molecular sieve 4??)
Tert-Butyl hydrogen peroxide solution, packed in FEP bottles, ~5.5 M in nonane (over molecular sieve
TERT-BUTYL HYDROPEROXIDE
Tert-Butyl hydroperoxide (tBuOOH) is an organic compound with the formula (CH3)3COOH.
Tert-Butyl hydroperoxide is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
Tert-Butyl hydroperoxide has a role as an antibacterial agent and an oxidising agent.


CAS Number: 75-91-2
MDL number: MFCD00002130
Chemical formula: C4H10O2
Linear Formula: (CH3)3COOH


Tert-butyl hydroperoxide is a natural product found in Apium graveolens with data available.
Tert-Butyl hydroperoxide is the natural products occurrence database.
Tert-Butyl hydroperoxide is a watery odorless colorless liquid.
Tert-Butyl hydroperoxide floats on and dissolves slowly in water.


Tert-Butyl hydroperoxide is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 100 000 to < 1 000 000 tonnes per annum.
Tert-Butyl hydroperoxide is normally supplied as a 69–70% aqueous solution.
Compared to hydrogen peroxide and organic peracids, Tert-Butyl hydroperoxide is less reactive and more soluble in organic solvents.


Tert-Butyl hydroperoxide's solutions in organic solvents are highly stable.
Industrially, Tert-Butyl hydroperoxide is used to prepare propylene oxide.
In the Halcon process, molybdenum-based catalysts are used for this reaction:
(CH3)3COOH + CH2=CHCH3 → (CH3)3COH + CH2OCHCH3


The byproduct t-butanol can be dehydrated to isobutene and converted to MTBE.
Tert-Butyl hydroperoxide is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
Tert-Butyl hydroperoxide is an intermediate in the production of propylene oxide and t-butyl alcohol from isobutane and propylene.
Tert-Butyl hydroperoxide is a strong oxidant and reacts violently with combustible and reducing materials, and metallic and sulfur compounds.


Tert-Butyl hydroperoxide is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
Tert-Butyl hydroperoxide has a role as an antibacterial agent and an oxidising agent.
Tert-Butyl hydroperoxide is water soluble.


Tert-Butyl hydroperoxide is a clear, colorless to pale yellow
liquid.
Tert-Butyl hydroperoxide, also known as dimethylethyl hydroperoxide or TBHP, belongs to the class of organic compounds known as organic hydroperoxide.


These are organic compounds comprising the hydroperoxide functional group, with the general formula [O-O]2-.
Based on a literature review a significant number of articles have been published on tert-butyl hydroperoxide.
Tert-butyl hydroperoxide is not a naturally occurring metabolite and is only found in those individuals exposed to this compound or its derivatives.


Technically Tert-Butyl hydroperoxide is part of the human exposome.
Tert-Butyl hydroperoxide is normally supplied as a 69–70% aqueous solution.
Tert-Butyl hydroperoxide is stored and handled in a dry, well-ventilated place.



USES and APPLICATIONS of TERT-BUTYL HYDROPEROXIDE:
Tert-Butyl hydroperoxide is widely used in a variety of oxidation processes.
Tert-Butyl hydroperoxide (TBHP) is an organic peroxide widely used in a variety of oxidation processes.
Tert-Butyl hydroperoxide is used as a catalyst for polymerization reaction, used for dyeing and printing of cotton, viscose, silk, nylon and other fibers and their fabrics, and also used for polyester/viscose blended fabric dyeing.


Overall, Tert-Butyl hydroperoxide is renowned for the convenient handling properties of its solutions.
Tert-Butyl hydroperoxide is one of the most widely used hydroperoxides in a variety of oxidation processes, for example the Halcon process.
Tert-Butyl hydroperoxide is widely used in a variety of oxidation processes.
Tert-Butyl hydroperoxide is used in formulation or re-packing, at industrial sites and in manufacturing.


On a much smaller scale, Tert-Butyl hydroperoxide is used to produce some fine chemicals by the Sharpless epoxidation.
Tert-Butyl hydroperoxide is used in the following products: polymers.
Tert-Butyl hydroperoxide is used in the following areas: formulation of mixtures and/or re-packaging.
Tert-Butyl hydroperoxide is used for the manufacture of: chemicals.


Release to the environment of Tert-Butyl hydroperoxide can occur from industrial use: as an intermediate step in further manufacturing of another substance (use of intermediates) and as processing aid.
Release to the environment of Tert-Butyl hydroperoxide can occur from industrial use: manufacturing of the substance.


Tert-Butyl hydroperoxide can be used for the market segments: polymer production, thermoset composites, acrylics and pharma with their different applications/functions.
Tert-Butyl hydroperoxide is primarily used as an initiator and finishing catalyst in the solution and emulsion polymerization methods for polystyrene and polyacrylates.


Other uses of Tert-Butyl hydroperoxide are for the polymerization of vinyl chloride and vinyl acetate and as an oxidation and sulfonation catalyst in bleaching and deodorizing operations.
Tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation.
Tert-Butyl hydroperoxide is involved in osmium-catalyzed vicinal hydroxylation of olefins under alkaline conditions.


Furthermore, Tert-Butyl hydroperoxide is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes.
Tert-Butyl hydroperoxide plays an important role for the introduction of peroxy groups in organic synthesis.
Tert-Butyl hydroperoxide is widely used in a variety of oxidation processes.


Tert-Butyl hydroperoxide is used as an oxidation and sulfonation catalyst, and in bleaching and deodorizing.
Tert-Butyl hydroperoxide is used in the preparation of copper octylbenzimidazole substituted diamide nitrato complex.
Tert-Butyl hydroperoxide (tBuOOH) is an organic peroxide widely used in a variety of oxidation processes, for example Sharpless epoxidation.
Tert-Butyl hydroperoxide is used for the emulsion polymerization of Styrene, Acrylates and Metacrylates and the curing of polyester resins.


Tert-Butyl hydroperoxide is suitable to be used as active peroxide in high pressure polymerization or as initiator in oxygen combination of Ethylene.
Common applications of Tert-Butyl hydroperoxide are acrylate, vinylacetate, styrene - butadiene production, curing of styrene - polyester resins, oxidizing agent for hydrocarbons.


Recommended storage temperature is between 0 °C and +30 °C.
tert-Butyl hydroperoxide may be used in:osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliaryoxidation of dibenzothiophenes.



CHEMICAL PROPERTIES OF TERT-BUTYL HYDROPEROXIDE:
Tert-Butyl hydroperoxide (TBHP) is a water-white liquid commonly commercially available as a 70% solution in water; 80% solutions are also available.
Tert-Butyl hydroperoxide is used to initiate polymerization reactions and in organic syntheses to introduce peroxy groups into the molecule.

Tert-Butyl hydroperoxide vapor can burn in the absence of air and maybe flammable at either elevated temperature or at reduced pressure.
Fine mist/spray may be combustible at temperatures below the normal flash point.
When evaporated, the residual liquid will concentrate Tert-Butyl hydroperoxide content and may reach an explosive concentration (>90%).
Closed containers may generate internal pressure through the degradation of Tert-Butyl hydroperoxide to oxygen.

Tert-Butyl hydroperoxide is a highly reactive product.
The three types of significant physical hazards are flammability, thermal, and decomposition due to contamination.
To minimize these hazards, avoid exposure to heat, fire, or any condition that will concentrate the liquid material.
Store away from heat, sparks, open flames, foreign contaminants, combustibles, and reducing agents.
Inspect containers frequently to identify bulges or leaks (7a, 125).



SYNTHESIS AND PRODUCTION OF TERT-BUTYL HYDROPEROXIDE:
Many synthetic routes are available, e.g. by the auto-oxidation of isobutane.



PRODUCTION METHODS OF TERT-BUTYL HYDROPEROXIDE:
Tert-Butyl hydroperoxide is produced by the liquid-phase reaction of isobutane and molecular oxygen or by mixing equimolar amounts of t-butyl alcohol and 30–50% hydrogen peroxide.
Tert-Butyl hydroperoxide can also be prepared from t-butyl alcohol and 30% hydrogen peroxide in the presence of sulfuric acid or by oxidation of tert-butylmagnesium chloride.
The manufacturing process of Tert-Butyl hydroperoxide is in a closed system.



REACTIVITY PROFILE OF TERT-BUTYL HYDROPEROXIDE:
Most alkyl monohydroperoxides are liquid.
The explosivity of the lower members (e.g., methyl hydroperoxide, or possibly, traces of the dialkyl peroxides) decreasing with increasing chain length and branching.
Though relatively stable, explosions have been caused by distillation to dryness or attempted distillation at atmospheric pressure.



ALTERNATIVE PARENTS OF TERT-BUTYL HYDROPEROXIDE:
*Peroxols
*Alkyl hydroperoxides
*Hydrocarbon derivatives



SUBSTITUENTS OF TERT-BUTYL HYDROPEROXIDE:
*Hydroperoxide
*Alkyl hydroperoxide
*Peroxol
*Hydrocarbon derivative
*Organooxygen compound
*Aliphatic acyclic compound



PHYSICAL and CHEMICAL PROPERTIES of TERT-BUTYL HYDROPEROXIDE:
Molecular Weight: 90.12
Chemical formula: C4H10O2
Molar mass: 90.122 g·mol−1
Appearance: Colorless liquid
Density: 0.935 g/mL
Melting point: −3 °C (27 °F; 270 K)
Boiling point: 37 °C (99 °F; 310 K) at 2.0 kPa
Solubility in water: miscible
log P: 1.23
Acidity (pKa): 12.69
Basicity (pKb): 1.31
Refractive index (nD): 1.3870
Std enthalpy of formation (ΔfH⦵298): −294±5 kJ/mol
Std enthalpy of combustion (ΔcH⦵298): 2.710±0.005 MJ/mol

Physical state: liquid
Color: No data available
Odor: No data available
Melting point/freezing point: No data available
Initial boiling point and boiling range: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Flash point: 43 °C - closed cup
Autoignition temperature: No data available
Decomposition temperature: No data available
pH: No data available
Viscosity
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Water solubility: No data available
Partition coefficient: n-octanol/water: No data available
Vapor pressure: No data available
Density: 0,808 g/cm3
Relative density: No data available
Relative vapor density: No data available

Particle characteristics: No data available
Explosive properties: Not classified as explosive.
Oxidizing properties: none
Other safety information: No data available
Molecular Weight: 90.12
XLogP3-AA: 0.6
Hydrogen Bond Donor Count: 1
Hydrogen Bond Acceptor Count: 2
Rotatable Bond Count: 1
Exact Mass: 90.068079557
Monoisotopic Mass: 90.068079557
Topological Polar Surface Area: 29.5 Ų
Heavy Atom Count: 6
Formal Charge: 0
Complexity: 35.3
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes

Appearance: colorless clear liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity: 0.90100 @ 25.00 °C.
Melting Point: -8.00 °C. @ 760.00 mm Hg
Boiling Point: 120.00 to 121.00 °C. @ 760.00 mm Hg
Vapor Pressure: 5.470000 mmHg @ 25.00 °C.
Vapor Density: 2.07 ( Air = 1 )
Flash Point: 95.00 °F. TCC ( 35.00 °C. )
logP (o/w): 1.230 (est)
Soluble in: water, 1.965e+004 mg/L @ 25 °C (est)
Melting Point: -2.8°C
Color: Colorless
Density: 0.9400g/mL
Boiling Point: 37.0°C (15.0 mmHg)
Flash Point: 43°C
Linear Formula: (CH3)3COOH
Beilstein: 01,IV,1616

Formula: C4H10O2 / (CH3)3COOH
Molecular mass: 90.1
Decomposes at 89°C
Melting point: -3°C
Relative density (water = 1): 0.93
Solubility in water: miscible
Vapour pressure, kPa at 20°C: 3.07 (calculated)
Relative vapour density (air = 1): 3.1
Flash point: 43°C
Auto-ignition temperature: 238°C
Explosive limits, vol% in air: 5-10
Octanol/water partition coefficient as log Pow: -1.3 (calculated)
Boiling point: 37 °C (20 hPa)
Density: 0.94 g/cm3 (20 °C)
Flash point: 38 °C
Melting Point: -3 °C
Vapor pressure: 232 hPa (60 °C)
Refractive Index: 1.3870 (20 °C)
Solubility: 130 - 150 g/l

Melting Point: -2.8ºC
Boiling Point: 37ºC (15 mmHg)
Flash Point: 43ºC
Molecular Formula: C4H10O2
Molecular Weight: 90.12100
Density: 0.94
Melting point: -2.8 °C
Boiling point: 37 °C (15 mmHg)
Density: 0.937 g/mL at 20 °C
vapor pressure: 62 mmHg at 45 °C
refractive index: n20/D 1.403
Flash point: 85 °F
storage temp.: 2-8°C
pka: pK1: 12.80 (25°C)
form: Liquid
color: Clear colorless
Water Solubility: Miscible



FIRST AID MEASURES of TERT-BUTYL HYDROPEROXIDE:
-Description of first-aid measures:
*General advice:
First aiders need to protect themselves.
Show this material safety data sheet to the doctor in attendance.
*If inhaled
After inhalation:
Fresh air.
Immediately call in physician.
If breathing stops:
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
Call a physician immediately.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Immediately call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Call a physician immediately.
Do not attempt to neutralise.
-Indication of any immediate medical attention and special treatment needed:
No data available



ACCIDENTAL RELEASE MEASURES of TERT-BUTYL HYDROPEROXIDE:
-Environmental precautions:
Do not let the product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Take up carefully with liquid-absorbent material.
Dispose of it properly.



FIRE FIGHTING MEASURES of TERT-BUTYL HYDROPEROXIDE:
-Extinguishing media:
*Suitable extinguishing media:
Foam
Carbon dioxide (CO2)
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.



EXPOSURE CONTROLS/PERSONAL PROTECTION of TERT-BUTYL HYDROPEROXIDE:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Tightly fitting safety goggles.
*Skin protection:
Handle with gloves.
Wash and dry hands.
Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0,4 mm
Break through time: 480 min
Splash contact:
Material: Nitrile rubber
Minimum layer thickness: 0,2 mm
Break through time: 60 min
-Control of environmental exposure:
Do not let product enter drains.



HANDLING and STORAGE of TERT-BUTYL HYDROPEROXIDE:
-Precautions for safe handling:
*Advice on safe handling:
Work under hood.
*Hygiene measures:
Immediately change contaminated clothing.
Apply preventive skin protection.
Wash hands and face after working with substance.
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Keep locked up or in an area accessible only to qualified or authorized persons.
*Storage stability:
Recommended storage temperature: 2 - 8 °C



STABILITY and REACTIVITY of TERT-BUTYL HYDROPEROXIDE:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature).
-Possibility of hazardous reactions:
No data available



SYNONYMS:
2-Methylpropane-2-peroxol
tert-Butyl hydroperoxide
Hydroperoxide, 1,1-dimethylethyl
Cadox TBH
Perbutyl H
2-Hydroperoxy-2-methylpropane
1,1-Dimethylethyl hydroperoxide
tert-C4H9OOH; tert-Butyl hydrogen peroxide
Hydroperoxide, tert-butyl
Hydroperoxyde de butyle tertiaire
Slimicide DE-488
Terc. butylhydroperoxid
Trigonox A-75
TBHP-70
Trigonox A-W70
t-Butylhydroperoxide
Aztec t-butyl Hydroperoxide-70, Aq
Dimethylethyl hydroperoxide
T-Hydro; TBHP
Tertiary-butyl hydroperoxide
NSC 672
1,1-Dimethylethyl hydroperoxide
2-Hydroperoxy-2-methylpropane
TBHP
TERT-BUTYL HYDROPEROXIDE
75-91-2
TBHP
T-Butyl hydroperoxide
tert-Butylhydroperoxide
2-Hydroperoxy-2-methylpropane
Perbutyl H
t-Butylhydroperoxide
1,1-Dimethylethyl hydroperoxide
Cadox TBH
Hydroperoxide, 1,1-dimethylethyl
tert-Butyl hydrogen peroxide
Terc. butylhydroperoxid
Hydroperoxyde de butyle tertiaire
Hydroperoxide, tert-butyl
Slimicide DE-488
Tertiary butyl hydroperoxide
Trigonox a-75
Trigonox A-W70
TBHP-70
1,1-Dimethylethylhydroperoxide
NSC 672
t-BuOOH
Tertiary-butyl hydroperoxide
tert-Butyl-hydroperoxide
Dimethylethyl hydroperoxide
T-Hydro
Perbutyl H 69T
Luperox TBH 70X
Trigonox A-W 70
CHEBI:64090
NSC-672
955VYL842B
Caswell No. 130BB
CCRIS 5892
HSDB 837
terc.Butylhydroperoxid
tert Butylhydroperoxide
EINECS 200-915-7
DE 488
DE-488
BRN 1098280
UNII-955VYL842B
AI3-50541
Kayabutyl H
tBuOOH
tert-BuOOH
Hydroperoxide, 1,1-dimethylethyl-
Perbutyl H 69
Perbutyl H 80
t-butyl-hydroperoxide
terbutyl hydroperoxide
tert-butyhydroperoxide
tert-C4H9OOH
t-butyl hydrogenperoxide
t-butyl-hydrogenperoxide
tert.-butylhydroperoxide
tert.butyl hydroperoxide
tertiarybutylhydroperoxide
tertbutylhydrogen peroxide
t-butyl hydrogen peroxide
tert.-butyl hydroperoxide
KAYABUTYL H 70
DSSTox_CID_4693
tert-butylhydrogen peroxide
EC 200-915-7
DSSTox_RID_78866
DSSTox_GSID_31209
tertiary butyl hydro peroxide
Hydroperoxide,1-dimethylethyl
Trigonox A-80 (Salt/Mix)
UN 2093 (Salt/Mix)
UN 2094 (Salt/Mix)
USP -800 (Salt/Mix)
CHEMBL348399
NSC672
DTXSID9024693
tert-Butyl hydroperoxide (8CI)
WLN: QOX1&1&1
2-Methyl-prop-2-yl-hydroperoxide
ZINC8585869
Tox21_200838
Aztec t-butyl Hydroperoxide-70, Aq
MFCD00002130
AKOS000121070
TERT-BUTYL HYDROPEROXIDE [HSDB]
NCGC00090725-01
NCGC00090725-02
NCGC00090725-03
NCGC00258392-01
tert-Butyl hydroperoxide aqueous solution
Hydroperoxide, 1,1-dimethylethyl (9CI)
tert-Butyl Hydroperoxide (70% in Water)
tert-Butyl hydroperoxide, >90% with water
B3153
FT-0657109
Q286326
J-509597
F1905-8242
Hydroperoxide, 1,1-dimethylethyl
2-hydroperoxy-2-methylpropane
tert-Butyl hydroperoxide
1,1-Dimethylethyl hydroperoxide
2-Hydroperoxy-2-methylpropane
Dimethylethyl hydroperoxide
Hydroperoxyde de butyle tertiaire
TBHP
t-butyl hydroperoxide
t-Butylhydroperoxide
tert-butyl hydroperoxide
tert-Butylhydroperoxide
Tertiary-butyl hydroperoxide
TBHP
T-Hydro
T-BUTYL HYDROPEROXIDE
Trigonox
tert-Butyl hydrogen peroxide
2-Hydroperoxy-2-methylpropane
butylhydroperoxide
tert-Butyl hydroperoxide Solution
tertiary-
Butylhydroperoxid
1,1-Dimethylethyl Hydroperoxide
2-Hydroperoxy-2-methylpropane
Cadox TBH
Kayabutyl H
Kayabutyl H 70
Luperox H 70
Luperox TBH 70X
NSC 672
Perbutyl H
Perbutyl H 69
Perbutyl H 69T
Perbutyl H 80
TBHP
Trigonox A-W 70
t-Butyl Hydroperoxide
tert-Butyl Hydrogen Peroxide
1,1-Dimethylethyl hydroperoxide
2-(dioxidanyl)-2-methyl-propane
2-Hydroperoxy-2-methyl-propane
Aztec t-butyl Hydroperoxide-70, Aq
Cadox TBH
DE-488
Dimethylethyl hydroperoxide
Hydroperoxide, tert-butyl
Hydroperoxyde de butyle tertiaire
Kayabutyl H
Luperox tbh 70x
Perbutyl H
Perbutyl H 69
Perbutyl H 69t
Perbutyl H 80
Slimicide DE-488
T-Hydro
TBHP
TBHP-70
Terc. butylhydroperoxid
tert-Butyl hydrogen peroxide
tert-Butyl Hydroperoxide
tert-Butyl-hydroperoxide solution
tert-C4H9OOH
Tertiary-butyl hydroperoxide
Trigonox A-75
Trigonox a-80
Trigonox a-w 70
USP -800
AI3-50541
BRN 1098280
CASWELL NO. 130BB
CCRIS 5892
EINECS 200-915-7
HSDB 837
NSC 672
1,1-Dimethylethyl hydroperoxide
2-Hydroperoxy-2-methylpropane
Dimethylethyl hydroperoxide
Hydroperoxyde de butyle tertiaire
t-Butyl hydroperoxide
t-Butylhydroperoxide
TBHP
Tert-butylhydroperoxide
Tertiary-butyl hydroperoxide
Tert butylhydroperoxide
Hydroperoxide, t-butyl
Tert butyl hydroperoxide
Hydroperoxide, tert-butyl
t Butylhydroperoxide
Tertiary butylhydroperoxide
Tert-butyl hydroperoxide
Tertiary-butylhydroperoxide
t Butyl hydroperoxide

TERT-BUTYL HYDROPEROXIDE
Tert-Butyl hydroperoxid is an organic peroxide widely used in a variety of oxidation processes.
Tert-butyl hydroperoxid is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
Tert-butyl hydroperoxid is widely used in a variety of oxidation processes.

CAS: 75-91-2
MF: C4H10O2
MW: 90.12
EINECS: 200-915-7

Tert-butyl hydroperoxid has a role as an antibacterial agent and an oxidising agent.
Watery odorless colorless liquid.
Floats and mixes slowly with water.
Tert-butyl hydroperoxid is the organic compound with the formula (CH3)3COOH.
Tert-butyl hydroperoxid is one of the most widely used hydroperoxides in a variety of oxidation processes, for example the Halcon process.
Tert-butyl hydroperoxid is normally supplied as a 69–70% aqueous solution.
Compared to hydrogen peroxide and organic peracids, tert-butyl hydroperoxid is less reactive and more soluble in organic solvents.
Overall, Tert-butyl hydroperoxid is renowned for the convenient handling properties of its solutions.
Tert-butyl hydroperoxid's solutions in organic solvents are highly stable.

Tert-butyl hydroperoxid Chemical Properties
Melting point: -2.8 °C
Boiling point: 37 °C (15 mmHg)
Density: 0.937 g/mL at 20 °C
Vapor pressure: 62 mmHg at 45 °C
Refractive index: n20/D 1.403
Fp: 85 °F
Storage temp.: 2-8°C
pka: pK1: 12.80 (25°C)
Form: Liquid
Color: Clear colorless
Water Solubility: Miscible
Merck: 14,1570
BRN: 1098280
Exposure limits: No exposure limit is set. On the basis of its irritant properties a ceiling limit of 1.2 mg/m3 (0.3 ppm) is recommended.
Stability: Stable, but may explode if heated under confinement.
Decomposition may be accelerated by traces of metals, molecular sieve or other contaminants.
Incompatible with reducing agents, combustible material, acids.
InChIKey: CIHOLLKRGTVIJN-UHFFFAOYSA-N
LogP: 1.230 (est)
CAS DataBase Reference: 75-91-2(CAS DataBase Reference)
NIST Chemistry Reference: Tert-butyl hydroperoxide(75-91-2)
EPA Substance Registry System: tert-Butyl hydroperoxide (75-91-2)

Tert-butyl hydroperoxid is a water-white liquid commonly commercially available as a 70% solution in water; 80% solutions are also available.
Tert-butyl hydroperoxid is used to initiate polymerization reactions and in organic syntheses to introduce peroxy groups into the molecule.
Tert-butyl hydroperoxid vapor can burn in the absence of air and may be flammable at either elevated temperature or at reduced pressure.
Fine mist/spray may be combustible at temperatures below the normal flash point.
When evaporated, the residual liquid will concentrate TBHP content and may reach an explosive concentration (>90%).

Closed containers may generate internal pressure through the degradation of Tert-butyl hydroperoxid to oxygen.
Tert-butyl hydroperoxid is a highly reactive product.
The three types of significant physical hazards are flammability, thermal, and decomposition due to contamination.
To minimize these hazards, avoid exposure to heat, fire, or any condition that will concentrate the liquid material.
Store away from heat, sparks, open flames, foreign contaminants, combustibles, and reducing agents.
Inspect containers frequently to identify bulges or leaks.

Uses
Tert-butyl hydroperoxid is an intermediate in the production of propylene oxide and t-butyl alcohol from isobutane and propylene.
Tert-butyl hydroperoxid is primarily used as an initiator and finishing catalyst in the solution and emulsion polymerization methods for polystyrene and polyacrylates.
Other uses are for the polymerization of vinyl chloride and vinyl acetate and as an oxidation and sulfonation catalyst in bleaching and deodorizing operations.
Tert-butyl hydroperoxid is a strong oxidant and reacts violently with combustible and reducing materials, and metallic and sulfur compounds.

Tert-butyl hydroperoxid is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation.
Tert-butyl hydroperoxid is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions.
Furthermore, Tert-butyl hydroperoxid is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes.
Tert-butyl hydroperoxid plays an important role for the introduction of peroxy groups in organic synthesis.
Industrially, Tert-butyl hydroperoxid is used to prepare propylene oxide.
In the Halcon process, molybdenum-based catalysts are used for this reaction:

(CH3)3COOH + CH2=CHCH3 → (CH3)3COH + CH2OCHCH3
The byproduct t-butanol, which can be dehydrated to isobutene and converted to MTBE.
On a much smaller scale, tert-butyl hydroperoxide is used to produce some fine chemicals by the Sharpless epoxidation.

Production Methods
Tert-butyl hydroperoxid is produced by the liquid-phase reaction of isobutane and molecular oxygen or by mixing equimolar amounts of t-butyl alcohol and 30–50% hydrogen peroxide.
Tert-butyl hydroperoxid can also be prepared from t-butyl alcohol and 30% hydrogen peroxide in the presence of sulfuric acid or by oxidation of tert-butylmagnesium chloride.
The manufacturing process of Tert-butyl hydroperoxid is in a closed system.

Reactivity Profile
Most alkyl monohydroperoxides are liquid.
The explosivity of the lower members (e.g., methyl hydroperoxide, or possibly, traces of the dialkyl peroxides) decreasing with increasing chain length and branching.
Though relatively stable, explosions have been caused by distillation to dryness or attempted distillation at atmospheric pressure.

Health Hazard
Tert-butyl hydroperoxid is a strong irritant.
Floyd and Stockinger (1958) observed thatdirect cutaneous application in rats did notcause immediate discomfort, but the delayedaction was severe.
The symptoms were erythemaand edema within 2–3 days.
Exposureto 500 mg in 24 hours produced asevere effect on rabbit skin, while a rinse of150 mg/min was severe to eyes.
Tert-butyl hydroperoxid is moderately toxic; the effects aresomewhat similar to those of MEK peroxide.
Symptoms from oral administration in ratswere weakness, shivering, and prostration.

Synonyms
TERT-BUTYL HYDROPEROXIDE
75-91-2
TBHP
T-Butyl hydroperoxide
tert-Butylhydroperoxide
2-Hydroperoxy-2-methylpropane
Perbutyl H
t-Butylhydroperoxide
1,1-Dimethylethyl hydroperoxide
Cadox TBH
Hydroperoxide, 1,1-dimethylethyl
Terc. butylhydroperoxid
tert-Butyl hydrogen peroxide
Hydroperoxyde de butyle tertiaire
Hydroperoxide, tert-butyl
Slimicide DE-488
Tertiary butyl hydroperoxide
Trigonox a-75
Trigonox A-W70
TBHP-70
1,1-Dimethylethylhydroperoxide
Tertiary-butyl hydroperoxide
NSC 672
Caswell No. 130BB
Dimethylethyl hydroperoxide
Perbutyl H 69T
t-BuOOH
Luperox TBH 70X
terc.Butylhydroperoxid
Trigonox A-W 70
tert Butylhydroperoxide
CCRIS 5892
HSDB 837
tert-Butyl-hydroperoxide
Kayabutyl H
T-Hydro
EINECS 200-915-7
DE 488
DE-488
UNII-955VYL842B
BRN 1098280
CHEBI:64090
AI3-50541
NSC-672
955VYL842B
Hydroperoxide, 1,1-dimethylethyl-
KAYABUTYL H 70
DTXSID9024693
EC 200-915-7
TERT-BUTYL HYDROPEROXIDE (II)
TERT-BUTYL HYDROPEROXIDE [II]
Trigonox A-75 [Czech]
tBOOH
t Butylhydroperoxide
terc.Butylhydroperoxid [Czech]
t Butyl Hydroperoxide
t-BHP
terc. Butylhydroperoxid [Czech]
Hydroperoxide, t-Butyl
tert Butyl Hydroperoxide
tertiary Butylhydroperoxide
Trigonox
Hydroperoxyde de butyle tertiaire [French]
tBuOOH
tert-BuOOH
Ethyldiethylperoxide
Perbutyl H 69
Perbutyl H 80
t-butyl-hydroperoxide
terbutyl hydroperoxide
tert-butyhydroperoxide
Terc butylhydroperoxid
tert-C4H9OOH
t-butyl hydrogenperoxide
t-butyl-hydrogenperoxide
tert.-butylhydroperoxide
tert.butyl hydroperoxide
tertiarybutylhydroperoxide
tertbutylhydrogen peroxide
t-butyl hydrogen peroxide
tert.-butyl hydroperoxide
DSSTox_CID_4693
tert-butylhydrogen peroxide
2-methylpropane-2-peroxol
DSSTox_RID_78866
DSSTox_GSID_31209
tertiary butyl hydro peroxide
Hydroperoxide,1-dimethylethyl
Trigonox A-80 (Salt/Mix)
UN 2093 (Salt/Mix)
UN 2094 (Salt/Mix)
USP -800 (Salt/Mix)
CHEMBL348399
DTXCID504693
NSC672
tert-Butyl hydroperoxide (8CI)
tert-Butyl hydroperoxide, >90% with water [Forbidden]
WLN: QOX1&1&1
2-Methyl-prop-2-yl-hydroperoxide
Tox21_200838
Aztec t-butyl Hydroperoxide-70, Aq
MFCD00002130
BUTYL HYDROPEROXIDE (TERTIARY)
TERT-BUTYL HYDROPEROXIDE [MI]
AKOS000121070
TERT-BUTYL HYDROPEROXIDE [HSDB]
tert-Butyl hydroperoxide, 70% in water
NCGC00090725-01
NCGC00090725-02
NCGC00090725-03
NCGC00258392-01
tert-Butyl hydroperoxide aqueous solution
Hydroperoxide, 1,1-dimethylethyl (9CI)
tert-Butyl Hydroperoxide (70% in Water)
tert-Butyl hydroperoxide, >90% with water
B3153
FT-0657109
Q286326
J-509597
F1905-8242
TERT-BUTYL MERCAPTAN
TERT-BUTYL MERCAPTAN = TERT-BUTYLTHIOL = 2-METHYLPROPANE-2-THIOL


CAS Number: 75-66-1
EC Number: 200-890-2
MDL Number: MFCD00004857
Chemical formula: C4H10S / (CH3)3CSH


Tert-Butyl Mercaptan, also known as 2-methylpropane-2-thiol, 2-methyl-2-propanethiol, and t-BuSH, is an organosulfur compound with the formula (CH3)3CSH.
Tert-Butyl Mercaptan is the main ingredient in many gas odorant blends.
Tert-Butyl Mercaptan is always utilized as a blend of other compounds, typically dimethyl sulfide, methyl ethyl sulfide, tetrahydrothiophene or other mercaptans such as isopropyl mercaptan, sec-butyl mercaptan and/or n-butyl mercaptan, due to its rather high melting point of −0.5 °C (31.1 °F).


These blends are used only with natural gas and not propane, as the boiling points of these blends and propane are quite different.
Because propane is delivered as a liquid and vaporizes to gas when it is delivered to the appliance, the vapor liquid equilibrium would substantially reduce the amount of odorant blend in the vapor.
Tert-Butyl Mercaptan is a Liquid with a strong skunky odor, a Clear colorless liquid with an unpleasant odor.


Tert-Butyl Mercaptan (2-methyl-2-propanethiol, CAS # 75-66-1) is a highly odorous material, with an odor threshold of < 1ppb.
Tert-Butyl Mercaptan is also a raw material used in gas odorant blends.
tert-Butylthiol has been listed on the European Food Safety Authority (FL-no: 12.174) as a flavor additive.
There is no indication of what flavor(s) it may have been used in.


Tert-Butyl Mercaptan (TBM) is a key raw material for agrochemical synthesis.
Tert-Butyl Mercaptan pure and industrial products are colorless transparent liquid, m. P. 1.11 ℃, B. P. 64.22 ℃, the relative density of 0.798~0.801, there are different odor, volatile.
Tert-Butyl Mercaptan undergoes ring opening nucleophilic reaction with 3-isothiazolones and reaction kinetics studies suggested reaction was second order in thiol and third order overall.


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USES and APPLICATIONS of TERT-BUTYL MERCAPTAN:
The tertio-butyl mercaptan (TBM) is a key raw material for agrochemical synthesis.
Tert-Butyl Mercaptan is also a raw material used in gas odorant blends.
Tert-Butyl Mercaptan is used as an odorant for natural gas, which is otherwise odorless.
Tert-Butyl Mercaptan may also have been used as a flavoring agent.


These blends are used only with natural gas and not propane, as the boiling points of these blends and propane are quite different.
Tert-Butyl Mercaptan is used as an odorant for natural gas, a chemical intermediate, and a bacterial nutrient.
Tert-Butyl Mercaptan uses and applications include: Odorant to permit detection of gas leaks; intermediate; bacterial nutrient.
Tert-Butyl Mercaptan was used in reaction of 2-methyl-2-propanethiol.


Tert-Butyl Mercaptan was also used in the synthesis of chain-transfer agents for reversible addition-fragmentation chain-transfer copolymerization of vinylidene chloride and methyl acrylate.
Tert-Butyl Mercaptan was used in reaction of 2-methyl-2-propanethiol on Mo(110) using temperature programmed reaction, high resolution electron enegy loss and X-ray photoelectron spectroscopic.


Tert-Butyl Mercaptan was used in the synthesis of chain-transfer agents for reversible addition-fragmentation chain-transfer copolymerization of vinylidene chloride and methyl acrylate.
Tert-Butyl Mercaptan, also known as the third butanethiol, is an important fine chemical raw material and intermediate, which is widely used in the field of organic synthesis, for example, it can be used as an intermediate for the synthesis of organophosphorus insecticide terbuthyl.
In addition, Tert-Butyl Mercaptan can also be used in the polymer field as a molecular weight regulator in the polymerization reaction.
Terbutaline is an intermediate of The organophosphorus insecticide terbuthyl.


-Application of Tert-Butyl Mercaptan:
Industrial hygiene
Raw material for pesticides, gas odorant



PREPARATION OF TERT-BUTYL MERCAPTAN:
At least one publication has listed Tert-Butyl Mercaptan as a very minor component of cooked potatoes, but because the tert-butyl moiety is very rare in natural products, other sources doubt the existence of natural sources of the compound.
Tert-Butyl Mercaptan was first prepared in 1890 by Leonard Dobbin by the reaction of zinc sulfide and t-butyl chloride.
Tert-Butyl Mercaptan was later prepared in 1932 by the reaction of the Grignard reagent, t-BuMgCl, with sulfur to give the corresponding thiolate, followed by hydrolysis.

This preparation is shown below:
t-BuMgCl + S → t-BuSMgCl
t-BuSMgCl + H2O → t-BuSH + Mg(OH)Cl
It is currently prepared industrially by the reaction of isobutylene with hydrogen sulfide over a clay (silica alumina) catalyst.



REACTIONS OF TERT-BUTYL MERCAPTAN:
Tert-Butyl Mercaptan can react with metal alkoxides and acyl chlorides to form thiol esters, as shown in the equation:
Reaction of Tert-Butyl Mercaptan with an acyl chloride.
Reaction of Tert-Butyl Mercaptan with an acyl chloride.
In the reaction above, thallium(I) ethoxide converts to thallium(I) t-butylthiolate.
In the presence of diethyl ether, thallium(I) t-butylthiolate reacts with acyl chlorides to give the corresponding tert-butyl thioesters.
Like other thioesters, it reverts to tert-butylthiol by hydrolysis.

Lithium 2-methylpropane-2-thiolate can be prepared by treatment of tert-butylthiol with lithium hydride in an aprotic solvent such as hexamethylphosphoramide (HMPA).
The resulting thiolate salt is a useful demethylating reagent.
For example, treatment with 7-methylguanosine gives guanosine.
Other N-methylated nucleosides in tRNA are not demethylated by this reagent.

Lithium 2-methylpropane-2-thiolate reaction with 7-methylguanosine.
Metal complexes
The anion derived from tert-butylthiol forms complexes with various metals. One example is tetrakis(tert-butylthiolato)molybdenum(IV), Mo(t-BuS)4.
This complex was prepared by treating MoCl4 with t-BuSLi:

MoCl4 + 4 t-BuSLi → Mo(t-BuS)4 + 4 LiCl
Mo(t-BuS)4 is a dark red diamagnetic complex that is sensitive to air and moisture.
The molybdenum center has a distorted tetrahedral coordination to four sulfur atoms, with overall D2 symmetry.



PRODUCTION METHOD OF TERT-BUTYL MERCAPTAN:
the preparation method is to obtain Tert-Butyl Mercaptan by catalytic reaction of isobutylene and hydrogen sulfide.
(CH3)2C = CH2 H2S [catalyst] →(CH3)3CSH the synthesis tower with Catalyst is preheated to 70 ℃, and isobutene gas and dry hydrogen sulfide gas are passed into the mixer according to a certain ratio, the mixed gas enters the preheater for preheating.
Control a certain temperature and then enter the synthesis Tower, maintain a stable flow rate so that the reaction gas from the top of the tower into the condenser, the unreacted mixed gas is sent back to the mixer through the separator, and the separated liquid is tert-butyl mercaptan.



PHYSICAL and CHEMICAL PROPERTIES of TERT-BUTYL MERCAPTAN:
Chemical formula: C4H10S
Molar mass: 90.18 g·mol−1
Appearance: Colorless, clear liquid
Density: 0.8 g/mL
Melting point: −0.50 °C (31.10 °F; 272.65 K)
Boiling point: 62 to 65 °C (144 to 149 °F; 335 to 338 K)
Molecular Weight: 90.19
XLogP3-AA: 1.5
Hydrogen Bond Donor Count: 1
Hydrogen Bond Acceptor Count: 1
Rotatable Bond Count: 0
Exact Mass: 90.05032149

Monoisotopic Mass: 90.05032149
Topological Polar Surface Area: 1 Ų
Heavy Atom Count: 5
Formal Charge: 0
Complexity: 25.1
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes

Color: Colorless
Melting Point: -1°C
Boiling Point: 64°C
UN Number: 2347
Quantity: 25mL
Formula Weight: 90.18
Physical Form: Clear Liquid at 20°C
Appearance: colorless clear liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity: 0.79700 to 0.80300 @ 25.00 °C.

Pounds per Gallon - (est).: 6.632 to 6.682
Refractive Index: 1.41700 to 1.42300 @ 20.00 °C.
Melting Point: -0.50 °C. @ 760.00 mm Hg
Boiling Point: 64.30 °C. @ 760.00 mm Hg
Vapor Pressure: 181.000000 mmHg @ 25.00 °C.
Vapor Density: 3.1 ( Air = 1 )
Flash Point: -12.00 °F. TCC ( -24.44 °C. )
logP (o/w): 2.206 (est)
Soluble in: alcohol, water, 1855 mg/L @ 25 °C (est)
Appearance Form: liquid
Odor: malodorous
Odor Threshold: No data available

pH: No data available
Melting point/freezing point:
Melting point/range: -0,5 °C - lit.
Initial boiling point and boiling range: 62 - 65 °C - lit.
Flash point: < -25 °C - closed cup
Evaporation rate: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Vapor pressure: 190 hPa at 20 °C
Vapor density: No data available
Density: 0,8 g/cm3 at 25 °C - lit.
Relative density: 0,8 at 20 °C
Water solubility: 1,47 g/l at 20 °C

Partition coefficient: n-octanol/water: log Pow: 2,14
Autoignition temperature: 255 °C at 1.013 hPa
Decomposition temperature: No data available
Viscosity
Viscosity, kinematic: No data available
Viscosity, dynamic: 0,96 mPa.s at 40 °C
Explosive properties: No data available
Oxidizing properties: none
Other safety information:
Surface tension: 21 mN/m at 20 °C


Formula: C4H10S
Gas Response Factor, 11.7 eV: 0.59
Gas Response Factor, 10.6 eV: 0.62
Gas Response Factor, 10.0 eV: 0.62
ppm per mg/m⁻³, (20 °C, 1 bar): 0.266
Molecular Weight, g/mole: 90.3
Melting point, °C: 1
Boiling point, °C: 64
Flash point, °C: -26
Upper Explosive Limit, %: 8.7
Lower Explosive Limit, %: 1.3
Density, g.cm⁻³: 0.83
Ionisation Energy, eV: 9.03

Molecular Formula: C4H10S
Molar Mass: 90.19
Density: 0.8g/mLat 25°C(lit.)
Melting Point: -1.1 °C
Boling Point: 62-65°C(lit.)
Flash Point: −12°F
Water Solubility: Slightly soluble in water
Solubility: 1.47g/l slightly soluble
Vapor Presure: 303.5 mm Hg ( 37.7 °C)
Vapor Density: 3.1 (vs air)
Appearance: Liquid
Color: Clear colorless
Merck: 14,1579
BRN: 505947
pKa: pK1:11.22 (25°C,μ=0.1)
Stability: Stable.
Refractive Index: n20/D 1.423(lit.)



FIRST AID MEASURES of TERT-BUTYL MERCAPTAN:
-Description of first-aid measures:
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
Consult a physician.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed:
No data available



ACCIDENTAL RELEASE MEASURES of TERT-BUTYL MERCAPTAN:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Take up with liquid-absorbent material.
Dispose of properly.



FIRE FIGHTING MEASURES of TERT-BUTYL MERCAPTAN:
-Extinguishing media:
*Suitable extinguishing media:
Carbon dioxide (CO2)
Foam
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Remove container from danger zone and cool with water.
Prevent fire extinguishing water from contaminating surface water or the ground water system.



EXPOSURE CONTROLS/PERSONAL PROTECTION of TERT-BUTYL MERCAPTAN:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
-Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Safety glasses
*Skin protection:
Full contact:
Material: butyl-rubber
Minimum layer thickness: 0,7 mm
Break through time: 480 min
Splash contact:
Material: Nitrile rubber
Minimum layer thickness: 0,4 mm
Break through time: 30 min
-Control of environmental exposure:
Do not let product enter drains.



HANDLING and STORAGE of TERT-BUTYL MERCAPTAN:
-Precautions for safe handling:
*Hygiene measures:
Immediately change contaminated clothing.
Wash hands and face after working with substance.
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Keep container tightly closed in a dry and well-ventilated place.



STABILITY and REACTIVITY of TERT-BUTYL MERCAPTAN:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .
-Incompatible materials:
No data available



SYNONYMS:
2-Methylpropane-2-thiol
t-BuSH
2-Methylpropane-2-thiol
2-Methyl-2-propanethiol
tert-Butyl mercaptan
2-Methyl-2-propanethiol
tert-Butyl mercaptan
75-66-1
2-Methylpropane-2-thiol
tert-Butanethiol
2-Propanethiol, 2-methyl-
T-BUTYL MERCAPTAN
tert-Butylmercaptan
1,1-Dimethylethanethiol
t-Butylmercaptan
2-Isobutanethiol
tertiary-Butyl mercaptan
tert-butyl thiol
2-methyl-propane-2-thiol
489PW92WIV
3374-16-1
TBM
t-BuSH
HSDB 1611
EINECS 200-890-2
BRN 0505947
tertbutanethiol
UNII-489PW92WIV
t-butanethiol
terbutyl mercaptan
tBuSH
tert.-butylmercaptan
tert-C4H9SH
tert. butyl mercaptan
tert.-butyl mercaptan
HS-t-Bu
tert-Butyl hydrosulfide
2-methyl-2propanethiol
2-methylpropan-2-thiol
2-Methyl-2-propylthiol
DSSTox_CID_6418
BUTANETHIOL, TERT-
EC 200-890-2
DSSTox_RID_78108
DSSTox_GSID_26418
4-01-00-01634
CHEMBL3182458
DTXSID0026418
2-Methyl-2-propanethiol, 99%
TERT-BUTYL MERCAPTAN
AMY28695
ZINC4706566
Tox21_200874
MFCD00004857
NSC229569
STL264247
AKOS000121277
AT13962
NSC-229569
CAS-75-66-1
NCGC00248858-01
NCGC00258428-01
DB-000158
FT-0612928
M0405
Q973473
W-109267
F0001-1902
16528-55-5
2-Methyl-2-propanethiol
1,1-Dimethylethanethiol
2-Isobutanethiol
2-Propanethiol, 2-methyl-
t-Butylmercaptan
tert-Butanethiol
t-Butyl mercaptan
tert-Butylmercaptan
tert-Butylthiol
tertiary-Butyl mercaptan
UN2347
2-methyl-2-propanethiol
tert-butyl mercaptan
tert-butylthiol
tert-butanethiol
2-propanethiol
2-methyl, tert-butylmercaptan
t-butyl mercaptan
t-butylmercaptan
2-isobutanethiol
tertiary-butyl mercaptan
2-methylpropane-2-thiol
tert-butanethiol
2-methyl-2-propane thiol
tert-butylthiol
1,1-dimethylethanethiol
2-isobutanethiol
t-butyl mercaptan
tert-butyl hydrosulfide
2-methyl-2-propyl thiol
2-methylpropane-2-thiol
TBM
t-BuSH
2-Methyl-2-Propanethiol
2-Methyl-2-Propylthiol
2-Propanethiol, 2-methyl-
tert-Butanethiol
tert-Butylthiol
1,1-Dimethylethanethiol
2-Isobutanethiol
tert-C4H9SH
t-Butyl mercaptan
tert-Butyl hydrosulfide
tertiary-Butyl mercaptan
2-methylpropane-2-thiol;1,1-Dimethylethanethiol; 2-Isobutanethiol
2-Methyl-2-propanethiol
2-Propanethiol, 2-methyl-
4-01-00-01634
BRN 0505947
EC 200-890-2
EINECS 200-890-2
HSDB 1611
t-Butylmercaptan
tert-Butanethiol
tert-Butyl mercaptan
tert-Butylmercaptan
tert-Butylthiol
tertiary-Butyl mercaptan
UNII-489PW92WIV
2-Methylpropane-2-thiol
2-Propanethiol
2-Propanethiol, 2-methyl-
t-Butyl mercaptan
t-Butanethiol
2-Methyl-2-propanethiol
2-Methyl-2-propanethiol
2-Methylpropane-2-thiol
tert-Butanethiol
1,1-Dimethylethanethiol
2-Isobutanethiol
2-Methyl-2-propanethiol
TBM
tert-Butyl mercaptan
tert-Butylthiol
TBM(TM)
TERT-BUTANETHIOL
2-Isobutanethiol
T-BUTYL MERCAPTAN
TERT-BUTYL MERCAPTAN
tert-Butyl mercaptan
1,1-Dimethylethanethiol
2-METHYL-2-PROPANETHIOL
2-methylpropane-2-thiol
2-Methyl-2-propanethiol
2-Propanethiol, 2-methyl-
2-Methyl-2-propanethiol
tert-Butyl mercaptan
tert-Butyl Mercaptan
tert-Butylthiol

TERT-BUTYL PEROXYBENZOATE
Tert-Butyl Peroxybenzoate a chemical compound from the group of peresters (compounds containing the general structure R1-C(O)OO-R2) which contains a phenyl group as R1 and a tert-butyl group as R2.
Tert-Butyl Peroxybenzoate is a colorless to slightly yellow liquid with a mild aromatic odor.
Tert-Butyl Peroxybenzoate is a monofunctional peroxide which is used for the crosslinking of natural and synthetic rubbers, as well as thermoplastic polyolefins.


CAS Number: 614-45-9
EC Number: 210-382-2
MDL Number: MFCD00008802
Molecular Formula : C11H14O3
Linear Formula: C6H5COOOC(CH3)3
Product Type: Crosslinking Catalysts / Accelerators / Initiators > Organic Peroxides


Tert-Butyl Peroxybenzoate is a monofunctional peroxide, the chemical name is tert-butyl peroxybenzoate, and it is an aromatic peroxide used for high temperature curing of Unsaturated Polyester resins.
Safe processing temperature: 100°C (rheometer ts2 > 20 min.). Typical crosslinking temperature: 140°C (rheometer t90 about 12 min.).
Tert-Butyl Peroxybenzoate is clear, colorless to slightly yellow liquid with a mild, aromatic odor.


Tert-Butyl Peroxybenzoate also is stored and transported as a mixture with inert solids and as a solvent slurry, to mitigate the explosion hazard.
Air & Water Reactions of Tert-Butyl Peroxybenzoate: insoluble in water.
Tert-Butyl Peroxybenzoate is soluble in ether, alcohol, ester, and ketones.


Tert-Butyl Peroxybenzoate is insoluble in water.
Tert-Butyl Peroxybenzoate is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 1 000 to < 10 000 tonnes per annum.
Tert-Butyl Peroxybenzoate is colourless or slightly yellow liquid.


Tert-Butyl Peroxybenzoate, [<= 50% with inert inorganic solid] is a clear, colorless to slightly yellow liquid with a mild, aromatic odor. Also stored and transported as a mixture with inert solids and as a solvent slurry, to mitigate the explosion hazard.
Tert-Butyl Peroxybenzoate is a clear, colorless to slightly yellow liquid with a mild, aromatic odor.


Tert-Butyl Peroxybenzoate also is stored and transported as a mixture with inert solids and as a solvent slurry, to mitigate the explosion hazard.
Tert-Butyl Peroxybenzoate is an organic compound with the formula C6H5CO2CMe3 (Me = CH3).
Tert-Butyl Peroxybenzoate is the most widely produced perester.



USES and APPLICATIONS of TERT-BUTYL PEROXYBENZOATE:
Tert-Butyl Peroxybenzoate is often used for reduction of residual styrene content during the final polymerization stage.
Tert-Butyl Peroxybenzoate is used as initiator in co-polymerization of Ethylene, Styrene, Acrylonitrile, Vinyl Acetate,Acrylate and Metacrylates.
Tert-Butyl Peroxybenzoate is used during styrene co-polymerization at temperatures between 100-140°C.


Tert-Butyl Peroxybenzoate is used as an initiator for high-pressure polyethylene, silicone rubber curing agent, unsaturated polyester curing agent.
Cosmetic Uses: uv absorbers
Tert-Butyl Peroxybenzoate is used as a catalyst in the preparation of paper strengthening agents for papermaking.
Tert-Butyl Peroxybenzoate is used as polymerization initiator (polyethylene, polystyrene, polyacrylates, and polyesters) and curing agent (unsaturated polyesters and silicon rubber).


Tert-Butyl Peroxybenzoate is also used as a chemical intermediate; [HSDB]
Tert-Butyl Peroxybenzoate, 98%+ Cas 614-45-9 - used preparation of conformal poly(cyclohexyl methacrylate) thin films via initiated chemical vapor deposition.
Application area can be: air drying lacquers, diplacquers, filament winding, etc.
Common Applications of Tert-Butyl Peroxybenzoate: Tert-Butyl Peroxybenzoate is used for the crosslinking of natural and synthetic rubbers, as well as thermoplastic polyolefins.


Tert-Butyl Peroxybenzoate is used for the cross-linking of natural and synthetic rubbers, as well as thermoplastic polyolefins.
Being thermally unstable substances, Tert-Butyl Peroxybenzoate may undergo self accelerating decomposition.
Tert-Butyl Peroxybenzoate is used in wire and cable applications.


In the temperature range of 100-170°C, Tert-Butyl Peroxybenzoate can be used as an initiator for the solution polymerization or copolymerization of acrylate and methacrylate, especially for the production of coatings.
Tert-Butyl Peroxybenzoate can also be used as initiator for bulk and suspension polymerization or copolymerization of acrylate and methacrylate.
Tert-Butyl Peroxybenzoate is preferentially used for thermocompression molding of unsaturated polyester resins (SMC, BMC, etc.) within the temperature range of 120-170°C.


Tert-Butyl Peroxybenzoate can also be used in combination with highly active peroxides such as Perkadox 16 or Trigonox HM as co-accelerators for pultrusion processes in the range of 100-150 °C
Tert-Butyl Peroxybenzoate is used as an initiator of radical polymerization
in the production of polymeric materials.


Tert-Butyl Peroxybenzoate is used as a hardener for polyester resins.
Tert-Butyl Peroxybenzoate is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing.
Other release to the environment of Tert-Butyl Peroxybenzoate is likely to occur from: indoor use.
Tert-Butyl Peroxybenzoate is used in the following products: polymers.


Release to the environment of this substance can occur from industrial use: formulation of mixtures and formulation in materials.
Tert-Butyl Peroxybenzoate is used for the manufacture of: plastic products and rubber products.
Release to the environment of Tert-Butyl Peroxybenzoate can occur from industrial use: as processing aid and as processing aid.
Release to the environment of Tert-Butyl Peroxybenzoate can occur from industrial use: manufacturing of the substance.


Tert-Butyl Peroxybenzoate is used for elevatedtemperaturecuring of polyesters and to initiatepolymerization reactions.
Tert-Butyl Peroxybenzoate was employed as polymerization and cross-linking catalyst.
Tert-Butyl Peroxybenzoate was also was employed as initiator during ?grafting of 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO)-4-oxyacetamido-(3 propyltriethoxysilane) to poly(ethylene co-octene and in preparation of conformal poly(cyclohexyl methacrylate) thin films via initiated chemical vapor deposition.


Uses of Tert-Butyl Peroxybenzoate: Polymerization initiator for polyethylene, polystyrene, polyacrylates, and polyesters; chem- ical intermediate.
Tert-Butyl Peroxybenzoate is used as a polymerization initiator and as a chemical intermediate.
Tert-Butyl Peroxybenzoate is often used as a radical initiator in polymerization reactions, such as the production of LDPE from ethylene, and for crosslinking, such as for unsaturated polyester resins.


-Applications of Tert-Butyl Peroxybenzoate:
• Standard initiator in BMC, SMC and pultrusion
• High purity, stability, low volatility
• Can be accelerated with metal-based promoters


-Polymerization of styrene:
Tert-Butyl Peroxybenzoate may be used for the (co)polymerization of styrene in the temperature range of 100-140°C.
In practice, combinations of two or more peroxides with diverging activities are used to reduce the residual monomer content in the final polymer and to increase reactor efficiency.


-Polymerization of styrene:
Tert-Butyl Peroxybenzoate may be used for the (co)polymerization of styrene in the temperature range of 100- 140°C.
In practice, combinations of two or more peroxides with diverging activities are used to reduce the residual monomer content in the final polymer and to increase reactor efficiency.


-Polymerization of ethylene:
Tert-Butyl Peroxybenzoate is an efficient initiator for the ethylene polymerization at high pressure in both autoclave and tubular processes.
To obtain a wide spectrum of polymerization temperatures, Tert-Butyl Peroxybenzoate is often used in combination with other peroxides.
Depending on reaction conditions, Tert-Butyl Peroxybenzoate is active in the temperature range of 220-270°C.


-In polymer chemistry:
Primarily, Tert-Butyl Peroxybenzoate is used as a radical initiator, either in the polymerization of e.g. ethylene (to LDPE), vinyl chloride, styrene or acrylic esters or as so-called unsaturated polyester resins (UP resins).
The quantity used for the curing of UP resins is about 1-2%.
A disadvantage, particularly in the production of polymers for applications in the food or cosmetics sector, is the possible formation of benzene as a decomposition product which can diffuse out of the polymer (for example, an LDPE packaging film).


-In organic chemistry:
The protecting group 2-trimethylsilylethanesulfonyl chloride (SES-Cl) for primary and secondary amino groups is accessible by the reaction of vinyltrimethylsilane with sodium hydrogensulfite and Tert-Butyl Peroxybenzoate to the sodium salt of trimethylsilylethanesulfonic acid and the subsequent reaction with thionyl chloride to the corresponding sulfonyl chloride.


-Polymerization of acrylates and methacrylates:
Tert-Butyl Peroxybenzoate may be used as an initiator for the bulk, suspension and solution (co)polymerization of acrylates and methacrylates in the temperature range of 90-130°C.
-For Crosslinking:
Tert-Butyl Peroxybenzoate is a monofunctional peroxide which is used for the crosslinking of natural rubber and synthetic rubbers, as well as polyolefins.


-For Thermoset:
Tert-Butyl Peroxybenzoate, tert-butyl peroxybenzoate, is an aromatic perester, which is used for the curing of unsaturated polyester resins at elevated temperatures.
Tert-Butyl Peroxybenzoate is preferred for the curing of UP resin based Hot Press Moulding formulations (SMC, BMC etc.) in the temperature range of 120-170°C.
Tert-Butyl Peroxybenzoate can also be used in combination with high reactive peroxides like Perkadox 16 or Trigonox HMa as kicker in formulations for pultrusion in the temperature range of 100-150°C.
In combination with a cobalt accelerator (e.g. Accelerator NL-53N, 10% cobalt), Tert-Butyl Peroxybenzoate is also applicable for the cure of UP resins in the temperature range of 70°C and higher.



RAW MATERIALS OF TERT-BUTYL PEROXYBENZOATE:
*Benzoyl chloride
*Hydrogen peroxide
*tert-Butanol



DESCRIPTION AND FEATURES OF TERT-BUTYL PEROXYBENZOATE:
Tert-Butyl Peroxybenzoate is yellowish liquid which has C11H14O3 as chemical formula.
Tert-Butyl Peroxybenzoate is a low volatility, high purity, aromatic peroxyester. which is effective as medium temperature initiator for polymerization of a broad spectrum of monomers, per example acrylics, ethylene and styrene.
Tert-Butyl Peroxybenzoate is also used to cure (copolymerization) unsaturated polyester resins at elevated temperatures.
Further Tert-Butyl Peroxybenzoate is used as catalyst for crosslinking synthetic rubbers like EPR, EPDM and NBR.
Crosslinking catalyst for natural and synthetic rubber materials



PROPERTIES OF TERT-BUTYL PEROXYBENZOATE:
Tert-Butyl Peroxybenzoate, which is pale yellow, is exclusively encountered as a solution in solvents such as ethanol or phthalate.
As peroxo compound, Tert-Butyl Peroxybenzoate contains about 8.16 wt% of active oxygen and has a self accelerating decomposition temperature (SADT) of about 60 °C.
The SADT is the lowest temperature at which self-accelerating decomposition in the transport packaging can occur within a week, and which should not be exceeded while storage or transportation.
Tert-Butyl Peroxybenzoateshould therefore be stored between minimum 10 °C (below solidification) and maximum 50 °C.
Dilution with a high-boiling solvent increases the SADT.
The half-life of Tert-Butyl Peroxybenzoate, in which 50% of the peroxy ester is decomposed, is 10 hours at 104 °C, one hour at 124 °C and one minute at 165 °C.
Amines, metal ions, strong acids and bases, as well as strong reducing and oxidizing agents accelerate the decomposition of Tert-Butyl Peroxybenzoate even in low concentrations.
However, Tert-Butyl Peroxybenzoate is one of the safest peresters or organic peroxides in handling.
The main decomposition products of Tert-Butyl Peroxybenzoate are carbon dioxide, acetone, methane, tert-butanol, benzoic acid and benzene.



REACTIVITY PROFILE OF TERT-BUTYL PEROXYBENZOATE:
Tert-Butyl Peroxybenzoate explodes with great violence when rapidly heated to a critical temperature; pure form is shock sensitive and detonable.
Upon contact with organic matter, t-butyl peroxybenzoate can ignite or give rise to an explosion.
Tert-Butyl Peroxybenzoate was employed as polymerization and cross-linking catalyst.
Tert-Butyl Peroxybenzoate was also was employed as initiator during grafting of 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO)-4-oxyacetamido-(3 propyltriethoxysilane) to poly(ethylene co-octene and in preparation of conformal poly(cyclohexyl methacrylate) thin films via initiated chemical vapor deposition.



PRODUCTION OF TERT-BUTYL PEROXYBENZOATE:
A standard procedure for the preparation of peresters is the acylation of Tert-Butyl Peroxybenzoate with benzoyl chloride.
In the reaction a large excess of Tert-Butyl Peroxybenzoate is used and the hydrogen chloride formed is removed in vacuo whereby a virtually quantitative yield is obtained.
Tert-Butyl Peroxybenzoate can be used to introduce a benzoyloxy group in the allyl position of unsaturated hydrocarbons.
From cyclohexene, 3-benzoyloxycyclohexene is formed with Tert-Butyl Peroxybenzoate in the presence of catalytic amounts of copper(I)bromide in 71 to 80% yield.

This allylic oxidation of alkenes, also known as Kharasch-Sosnovsky oxidation, generates racemic allylic benzoates in the presence of catalytic amounts of copper(I)bromide.
A modification of the reaction utilizes copper(II) trifluoromethanesulfonate as a catalyst and DBN or DBU as bases to achieve yields up to 80% in the reaction of acyclic olefins with Tert-Butyl Peroxybenzoate to allylic benzoates.

Substituted oxazolines and thiazolines can be oxidized to the corresponding oxazoles and thiazoles in a modified Kharash-Sosnovsky oxidation with Tert-Butyl Peroxybenzoate and a mixture of Cu(I) and Cu(II) salts in suitable yields.
The carboalkoxy group at the C-4 position is essential a successful reaction.
Benzene and furans can be alkenylated with olefins in an oxidative coupling under palladium salt catalysis, with Tert-Butyl Peroxybenzoate as hydrogen acceptor.
In the absence of Pd2+ salts, the aromatics are benzoxylated.



PHYSICAL and CHEMICAL PROPERTIES of TERT-BUTYL PEROXYBENZOATE:
Physical state clear, liquid
Color: light yellow
Odor: weakly aromatic
Melting point/freezing point:
Melting point/range: 9 - 11 °C at 1.013
Initial boiling point and boiling range: 75 - 76 °C at 0,3 hPa - lit.
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Flash point 93,4 °C - closed cup - Decomposition
Autoignition temperature: No data available
Decomposition temperature: > 60 °C
pH: No data available
Viscosity
Viscosity, kinematic: No data available
Viscosity, dynamic: 7,5 mPa.s at 20 °C
Water solubility: 1,18 g/l - soluble
Partition coefficient: n-octanol/water:
log Pow: 3 at 25 °C - Bioaccumulation is not expected.
Vapor pressure: < 0,003 hPa at 20 °C
Density: 1,021 g/mL at 25 °C - lit.
Relative density: No data available
Relative vapor density: No data available
Particle characteristics: No data available
Explosive properties: No data available
Oxidizing properties: none
Other safety information:
Relative vapor density: 6,71 - (Air = 1.0)

Appearance: colorless to pale yellow clear liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity: 1.02100 @ 25.00 °C.
Melting Point: 8.00 °C. @ 760.00 mm Hg
Boiling Point: 282.40 °C. @ 760.00 mm Hg (est)
Vapor Pressure: 0.330000 mmHg @ 50.00 °C.
Flash Point: 200.00 °F. TCC ( 93.33 °C. )
logP (o/w): 3.330 (est)
Soluble in: water, 159.2 mg/L @ 25 °C (est)
Melting point: 8 °C
Boiling point: 75-76 °C/0.2 mmHg (lit.)
Density: 1.021 g/mL at 25 °C (lit.)
vapor density: 6.7 (vs air)
vapor pressure: 3.36 mm Hg ( 50 °C)
refractive index: n20/D 1.499(lit.)
Flash point: 200 °F
storage temp.: 2-8°C
solubility: water: soluble1.18g/L
form: Liquid
color: Clear yellow
Water Solubility: Immiscible
BRN: 1342734
Stability: Stable.

Incompatible with a wide range of organic materials - oxidizer.
May react violently with organic compounds.
InChIKey: GJBRNHKUVLOCEB-UHFFFAOYSA-N
LogP: 3 at 25℃
Appearance : clear liquid
Color : 100 Pt-Co/APHA max
Active oxygen : 8.07% min
TBHP as Hydroperoxides : 0.10% max
Density, 20 ℃ : 1.04g/cm3
Viscosity, 20 ℃ : 6.5 mPa.s
Purity : one hundred%
Appearance : clear liquid
Color : 100 Pt-Co/APHA max
Experiment : 98.0% min
Active oxygen : 8.07% min
TBHP as Hydroperoxides : 0.10% max
Density, 20 ℃ : 1.04g/cm3
Viscosity, 20 ℃ : 6.5 mPa.s

Refractive Index: n20/D 1.499(lit.)
Colorless: liquid.
Freezing point of 8.5 deg C,
boiling point of 112 deg C (decomposition),75-76 deg C (2.67kPa)
the relative density of 1.021(20/4 deg C)
the refractive index of 1.4490
Flash point 93 °c.
Soluble in alcohol, ether, Ester and ketone, insoluble in water.
Slightly aromatic odor, stable at room temperature.
Molecular Formula: C11H14O3
Molar Mass: 194.23
Density: 1.021 g/mL at 25 °C (lit.)
Melting Point: 8 °C
Boling Point: 75-76 °C/0.2 mmHg (lit.)
Flash Point: 200°F
Water Solubility: Immiscible
Solubility: DMSO: 22.5 mg/mL( < 1 mg/ml refers to the product slightly soluble or insoluble)
Vapor Presure: 3.36 mm Hg ( 50 °C)
Vapor Density: 6.7 (vs air)

Appearance: Liquid
Color: Clear yellow
BRN: 1342734
Storage Condition: 2-8°C
Stability: Stable.
Melting Point: 8.0°C
Color: Yellow
Density: 1.0400g/mL
Boiling Point: 75.0°C to 76.0°C (0.2mmHg)
Flash Point: 93°C
Infrared Spectrum: Authentic
Assay Percent Range: 98%
Molecular Formula: C11H14O3
Linear Formula: C6H5CO2OC(CH3)3
Refractive Index: 1.4980 to 1.5000
Quantity: 1 kg
Beilstein: 09, IV, 715
Fieser: 01,98; 02,54; 04,66; 07,49; 09,90; 13,58
Viscosity: 6 mPa.s (20°C)
Formula Weight: 194.23
Percent Purity: 98%
Physical Form: Liquid
Chemical Name or Material: tert-Butyl peroxybenzoate, 98%

Molecular Weight: 194.23
XLogP3-AA: 2.8
Hydrogen Bond Donor Count: 0
Hydrogen Bond Acceptor Count: 3
Rotatable Bond Count: 4
Exact Mass: 194.094294304
Monoisotopic Mass: 194.094294304
Topological Polar Surface Area: 35.5 Ų
Heavy Atom Count: 14
Formal Charge: 0
Complexity: 187
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes
Physical State : Liquid
Solubility : Soluble in ether, alcohol, ester, and ketones. Insoluble in water.
Storage : Store at 4° C
Melting Point : 9-11° C
Boiling Point : 75-76° C (lit.) at 0.2 mmHg
Density : 1.021 g/mL at 25° C (lit.)
Refractive Index : n20D 1.50



FIRST AID MEASURES of TERT-BUTYL PEROXYBENZOATE:
-Description of first-aid measures:
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
Immediately call in physician.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
Consult a physician.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed:
No data available



ACCIDENTAL RELEASE MEASURES of TERT-BUTYL PEROXYBENZOATE:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Take up with liquid-absorbent material.
Dispose of properly.



FIRE FIGHTING MEASURES of TERT-BUTYL PEROXYBENZOATE:
-Extinguishing media:
*Suitable extinguishing media:
Water
Foam
Carbon dioxide (CO2)
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Prevent fire extinguishing water from contaminating surface water or the ground water system.



EXPOSURE CONTROLS/PERSONAL PROTECTION of TERT-BUTYL PEROXYBENZOATE:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Safety glasses.
*Skin protection:
Full contact:
Material: butyl-rubber
Minimum layer thickness: 0,7 mm
Break through time: 480 min
Splash contact:
Material: Nitrile rubber
Minimum layer thickness: 0,4 mm
Break through time: 30 min
*Body Protection:
protective clothing
*Respiratory protection:
Recommended Filter type: Filter B-(P2)
-Control of environmental exposure:
Do not let product enter drains.



HANDLING and STORAGE of TERT-BUTYL PEROXYBENZOATE:
-Precautions for safe handling:
*Advice on safe handling:
Work under hood.
*Hygiene measures:
Immediately change contaminated clothing.
Apply preventive skin protection.
Wash hands and face after working with substance.
-Conditions for safe storage, including any incompatibilities:
No data available



STABILITY and REACTIVITY of TERT-BUTYL PEROXYBENZOATE:
-Chemical stability
The product is chemically stable under standard ambient conditions (room temperature).



SYNONYMS:
Tretbutylperbenzoate
TBPB
TRIGONOX C
Trigonox C
Luperox P
tert-butyl peroxybenzoate
tert-butyl perbenzoate
t-butyl perbenzoate
chaloxyd tbpb
perbutyl z
esperox 10
novox
trigonox c
tert-butyl peroxy benzoate
terc.butylperbenzoan
tert-Butyl peroxybenzoate
614-45-9
tert-Butyl perbenzoate
tert-butyl benzenecarboperoxoate
t-Butyl perbenzoate
Chaloxyd tbpb
Perbutyl Z
Esperox 10
tert-Butyl peroxy benzoate
Terc.butylperbenzoan
Benzoyl tert-butyl peroxide
Peroxybenzoic acid, tert-butyl ester
Benzenecarboperoxoic acid, 1,1-dimethylethyl ester
t-Butyl peroxybenzoate
Perbenzoate de butyle tertiaire
tert-butyl benzoperoxoate
DTXSID9024699
NSC-674
54E39145KT
benzenecarboperoxoic acid tert-butyl ester
Trigonox C
DTXCID904699
tert-butylperoxybenzoate
t-Butyl peroxy benzoate
CAS-614-45-9
CCRIS 6217
HSDB 2891
NSC 674
Perbenzoic acid, tert-butyl ester
Tert butyl peroxybenzoate
EINECS 210-382-2
BRN 1342734
PEROXYBENZOIC ACID, T-BUTYL ESTER
AI3-06625
UNII-54E39145KT
t-butylperbenzoate
t-butyl per benzoate
t-butyl-peroxybenzoate
terc.Butylester kyseliny peroxybenzoove
tert-butyl-perbenzoate
tert.butyl perbenzoate
tert. butyl perbenzoate
t-butyl benzoyl peroxide
tertiary butyl perbenzoate
tert-butyl peroxy-benzoate
EC 210-382-2
SCHEMBL22820
WLN: 1X1&1&OOVR
NSC674
CHEMBL1328092
BUTYL PEROXYBENZOATE, TERT-
ZINC1596408
Tox21_202287
Tox21_300070
AKOS015890015
T-BUTYL BENZOYL PEROXIDE [INCI]
NCGC00091791-01
NCGC00091791-02
NCGC00091791-03
NCGC00091791-04
NCGC00254006-01
NCGC00259836-01
Benzenecarboperoxoic acid,1-dimethylethyl ester
EN300-129025
Luperox(R) P
tert-Butyl peroxybenzoate, 98%
PEROXYBENZOIC ACID, T-BUTYL ESTER [HSDB]
Q14469782
tert-Butyl peroxybenzoate, technical, >=95.0% (RT)
Benzoyl tert-butyl peroxide
CP 02
CP 02 (catalyst)
Chaloxyd TBPB
Chaloxyd
TBPB-HA-M 1
Esperox 10
Interox TBPB-HA-M 1
Kayabutyl B
LQ-TBPB
Link-Cup
TBPB
Luperox P
Luperox PXL
NSC 674
Norox TBPB
Perbutyl Z
TBPB
TBPB-HA-M 1
TBPB-HA-M 3
TC 5
TC 5 (vulcanizer)
Trigonox 93
Trigonox C
Trigonox C 50D
V 73
t-Butyl peroxybenzoate
tert-Butyl benzoyl peroxide
tert-Butyl peroxybenzoate
tert-Butyl peroxybenzoate
Benzenecarboperoxoic acid, 1,1-dimethylethyl ester
Benzoyl tert-butyl peroxide
Chaloxyd TBPB; Esperox 10
Novox; Perbenzoate de butyle tertiaire [French]
Perbenzoic acid, tert-butyl ester
Perbutyl Z
Peroxybenzoic acid, tert-butyl ester
Trigonox C
t-Butyl perbenzoate
t-Butyl peroxy benzoate
UN3103
Benzoyl tert-butyl peroxide
Peroxybenzoic acid, tert-butyl ester
tert-Butyl peroxybenzoate
Benzenecarboperoxoic acid, 1,1-dimethylethyl ester
tert-Butyl perbenzoate
Peroxybenzoic acid, t-butyl ester
TBPB
novox
esperox10
Trigonox?C
chaloxydtbpb
butylperoxybenzoate
Butylperoxybenzoate
tert-Butyl perbenzoate
Tert-Buty Peroxybenzoate
tert-Butyl peroxybenzoate
benzoyltert-butylperoxide
perbenzoatedebutyletertiaire
tert-butyl benzenecarboperoxoate
perbenzoatedebutyletertiaire(french)
Benzenecarboperoxoicacid,1,1-dimethylethylester



TERT-BUTYL PEROXYBENZOATE (TBPB)

Tert-Butyl peroxybenzoate (TBPB) is an organic peroxide compound widely used as a radical initiator in polymerization reactions.
Tert-Butyl peroxybenzoate (TBPB) has the chemical formula C11H14O3 and a molecular weight of approximately 194.23 g/mol.
Tert-Butyl peroxybenzoate (TBPB) is a colorless to pale yellow liquid with a characteristic mild odor.

CAS Number: 614-45-9
EC Number: 210-382-2

Synonyms: TBPB, Tert-butyl peroxybenzoate, Peroxybenzoic acid, tert-butyl ester, Tert-butyl 4-hydroperoxybenzoate, TBPB-O, TBPB-Ether, Tert-butyl peroxybenzene, Tert-butyl perbenzoate, Tert-butyl 4-peroxybenzoate



APPLICATIONS


Tert-Butyl peroxybenzoate (TBPB) is primarily used as a radical initiator in the polymerization of various monomers.
Tert-Butyl peroxybenzoate (TBPB) initiates the polymerization of styrene, acrylates, and methacrylates, leading to the production of polymers with controlled molecular weights and structures.
Tert-Butyl peroxybenzoate (TBPB) is essential in the production of polystyrene, a versatile plastic used in packaging, electronics, and consumer goods.

Tert-Butyl peroxybenzoate (TBPB) plays a crucial role in the synthesis of acrylic resins, which are used in paints, adhesives, and coatings.
Tert-Butyl peroxybenzoate (TBPB) is employed in the manufacture of polyethylene and polypropylene, enhancing their mechanical properties and processability.

Tert-Butyl peroxybenzoate (TBPB) is used in the production of acrylonitrile-butadiene-styrene (ABS) copolymers, known for their impact resistance and durability.
Tert-Butyl peroxybenzoate (TBPB) facilitates the production of methacrylate polymers used in dental materials, optical lenses, and automotive parts.

Tert-Butyl peroxybenzoate (TBPB) is utilized in the formulation of crosslinking agents for polymeric materials, improving their heat resistance and mechanical strength.
Tert-Butyl peroxybenzoate (TBPB) is crucial in the production of thermosetting resins used in composite materials and structural components.

Tert-Butyl peroxybenzoate (TBPB) is used in the synthesis of adhesives and sealants that require rapid curing and strong bonding properties.
Tert-Butyl peroxybenzoate (TBPB) serves as a key ingredient in the production of elastomers, providing flexibility and resilience in rubber products.

Tert-Butyl peroxybenzoate (TBPB) is employed in the manufacture of specialty coatings for corrosion protection and aesthetic enhancement.
Tert-Butyl peroxybenzoate (TBPB) is used in the formulation of printing inks for packaging materials and graphic arts applications.

Tert-Butyl peroxybenzoate (TBPB) plays a role in the production of polymer additives that enhance flame retardancy and UV stability.
Tert-Butyl peroxybenzoate (TBPB) is utilized in the preparation of polymer dispersions and emulsions used in textile coatings and paper coatings.

Tert-Butyl peroxybenzoate (TBPB) is employed in the synthesis of polymer nanoparticles and microspheres for drug delivery and biomedical applications.
Tert-Butyl peroxybenzoate (TBPB) is used in the production of encapsulation materials for controlled release of active ingredients in pharmaceuticals and agriculture.
Tert-Butyl peroxybenzoate (TBPB) is crucial in the development of specialty polymers used in 3D printing, enabling precise fabrication of complex structures.

Tert-Butyl peroxybenzoate (TBPB) is employed in the formulation of composite materials for aerospace and automotive applications, enhancing lightweight and structural integrity.
Tert-Butyl peroxybenzoate (TBPB) serves as an initiator in the production of polymeric membranes used in water purification and filtration processes.
Tert-Butyl peroxybenzoate (TBPB) is used in the formulation of encapsulating materials for electronic devices and microelectronics, protecting components from environmental factors.

Tert-Butyl peroxybenzoate (TBPB) plays a role in the synthesis of polymer fibers used in textiles, reinforcing fabrics for improved strength and durability.
Tert-Butyl peroxybenzoate (TBPB) is employed in the production of polymeric films and sheets used in packaging and agricultural applications.

Tert-Butyl peroxybenzoate (TBPB) is utilized in the formulation of coatings for medical devices, providing biocompatibility and sterilization resistance.
Researchers continue to explore new applications and formulations of TBPB to meet evolving industrial and technological demands.

Tert-Butyl peroxybenzoate (TBPB) is used in the production of rubber compounds, enhancing their processability and vulcanization properties.
Tert-Butyl peroxybenzoate (TBPB) is employed in the synthesis of thermoplastic elastomers, combining the properties of rubber and plastic for versatile applications.

Tert-Butyl peroxybenzoate (TBPB) is used as a crosslinking agent in the production of silicone rubbers, providing flexibility and heat resistance.
Tert-Butyl peroxybenzoate (TBPB) serves as a catalyst in the polymerization of vinyl acetate, used in the production of adhesives and coatings.
Tert-Butyl peroxybenzoate (TBPB) is utilized in the formulation of acrylic polymers for architectural coatings, providing weather resistance and durability.

Tert-Butyl peroxybenzoate (TBPB) is used in the production of polyurethane foams, improving their structural integrity and resilience.
Tert-Butyl peroxybenzoate (TBPB) plays a role in the synthesis of polymeric membranes used in fuel cells and water desalination technologies.

Tert-Butyl peroxybenzoate (TBPB) is employed in the formulation of encapsulating materials for electronic components, protecting against moisture and mechanical stress.
Tert-Butyl peroxybenzoate (TBPB) is used in the preparation of microencapsulated phase change materials (PCM), used for thermal energy storage applications.

Tert-Butyl peroxybenzoate (TBPB) is crucial in the synthesis of photopolymerizable resins for stereolithography and rapid prototyping in 3D printing.
Tert-Butyl peroxybenzoate (TBPB) is utilized in the production of surfactants and dispersants used in industrial and household cleaning products.
Tert-Butyl peroxybenzoate (TBPB) serves as a stabilizer and crosslinking agent in the production of gel coats and fiberglass-reinforced plastics (FRP).

Tert-Butyl peroxybenzoate (TBPB) is used in the formulation of pressure-sensitive adhesives (PSA) for tapes, labels, and adhesive films.
Tert-Butyl peroxybenzoate (TBPB) is employed in the synthesis of polymer additives for lubricants, enhancing their viscosity and thermal stability.

Tert-Butyl peroxybenzoate (TBPB) is used in the formulation of anti-fogging agents and coatings for optical lenses and eyewear.
Tert-Butyl peroxybenzoate (TBPB) plays a role in the production of dental materials such as impression compounds and temporary crowns.

Tert-Butyl peroxybenzoate (TBPB) is utilized in the synthesis of inkjet inks, providing fast drying and durable prints on various substrates.
Tert-Butyl peroxybenzoate (TBPB) is used in the formulation of corrosion inhibitors and coatings for metal surfaces in marine and industrial applications.

Tert-Butyl peroxybenzoate (TBPB) serves as a catalyst in the polymerization of cyclic ethers, used in the production of polyether polyols for polyurethane formulations.
Tert-Butyl peroxybenzoate (TBPB) is employed in the synthesis of polymer-modified bitumen for road paving and waterproofing applications.
Tert-Butyl peroxybenzoate (TBPB) is used in the formulation of encapsulating materials for pharmaceuticals, ensuring controlled release and stability of active ingredients.

Tert-Butyl peroxybenzoate (TBPB) plays a role in the production of composite materials reinforced with natural fibers for sustainable building materials.
Tert-Butyl peroxybenzoate (TBPB) is utilized in the formulation of rheology modifiers and thickeners for paints, inks, and coatings.

Tert-Butyl peroxybenzoate (TBPB) is used in the synthesis of ion-exchange resins for water purification and industrial chemical separations.
Tert-Butyl peroxybenzoate (TBPB) continues to find new applications in advanced materials, nanotechnology, and biomedical research, driven by ongoing innovations in polymer science and engineering.

Tert-Butyl peroxybenzoate (TBPB) contributes to the development of high-performance plastics used in automotive and aerospace industries.
Tert-Butyl peroxybenzoate (TBPB) is used in the preparation of crosslinked polymers, enhancing their mechanical strength and durability.
Tert-Butyl peroxybenzoate (TBPB) is essential in the production of polymer additives that modify material properties such as flexibility and heat resistance.

Tert-Butyl peroxybenzoate (TBPB) is known for its stability under proper storage conditions, ensuring consistent performance in polymerization processes.
Tert-Butyl peroxybenzoate (TBPB) is regulated under safety guidelines due to its hazardous nature and reactive properties.

Tert-Butyl peroxybenzoate (TBPB) is synthesized through esterification of benzoic acid with tert-butyl alcohol under controlled conditions.
Tert-Butyl peroxybenzoate (TBPB) is critical to use TBPB in well-ventilated areas and with appropriate personal protective equipment (PPE) to minimize exposure risks.
The chemical stability of TBPB allows for its efficient storage and handling in industrial settings.

Tert-Butyl peroxybenzoate (TBPB) is employed in the production of water-based emulsion polymers for coatings and adhesives.
Tert-Butyl peroxybenzoate (TBPB) serves as a key initiator in the synthesis of polymeric materials used in medical devices and electronics.
Researchers continue to explore novel applications and formulations utilizing TBPB to meet evolving industrial needs.



DESCRIPTION


Tert-Butyl peroxybenzoate (TBPB) is an organic peroxide compound widely used as a radical initiator in polymerization reactions.
Tert-Butyl peroxybenzoate (TBPB) has the chemical formula C11H14O3 and a molecular weight of approximately 194.23 g/mol.

Tert-Butyl peroxybenzoate (TBPB) is a colorless to pale yellow liquid with a characteristic mild odor.
Tert-Butyl peroxybenzoate (TBPB) is insoluble in water but soluble in organic solvents such as acetone and ethanol.

Tert-Butyl peroxybenzoate (TBPB) is highly reactive due to its peroxybenzoate functional group.
Tert-Butyl peroxybenzoate (TBPB) is known for its ability to initiate the polymerization of monomers like styrene and acrylates.

Tert-Butyl peroxybenzoate (TBPB) plays a crucial role in the production of various polymers and copolymers used in industries such as plastics, coatings, and adhesives.
Tert-Butyl peroxybenzoate (TBPB) facilitates controlled radical polymerization processes, ensuring precise control over polymer chain growth.

Tert-Butyl peroxybenzoate (TBPB) is used in the synthesis of specialty polymers with tailored properties such as impact resistance and thermal stability.
Tert-Butyl peroxybenzoate (TBPB) undergoes decomposition under certain conditions, releasing free radicals that initiate polymerization reactions.

Tert-Butyl peroxybenzoate (TBPB) is handled with caution due to its potential for exothermic decomposition, which can lead to fire or explosion.
Tert-Butyl peroxybenzoate (TBPB) is stored and transported under controlled conditions to prevent unintended reactions.

Tert-Butyl peroxybenzoate (TBPB) is a valuable tool in research and industrial applications requiring precise polymerization kinetics.
Tert-Butyl peroxybenzoate (TBPB) is employed in the formulation of resin systems for composite materials.



PROPERTIES


Physical Properties:

Molecular Formula: C11H14O3
Molecular Weight: Approximately 194.23 g/mol
Appearance: Colorless to pale yellow liquid
Odor: Mild, characteristic odor
Density: 1.06 g/cm³ at 20°C
Boiling Point: 98-100°C (208-212°F) at 10 mmHg
Melting Point: -10°C (14°F)
Flash Point: 86°C (187°F), closed cup
Solubility: Insoluble in water; soluble in organic solvents such as acetone, ethanol, and benzene
Vapor Pressure: 1.3 mmHg at 20°C
Viscosity: Not readily available, generally low viscosity liquid


Chemical Properties:

Chemical Structure: Peroxybenzoate group attached to a tert-butyl group
Reactivity: TBPB is a peroxide compound that decomposes exothermally to produce free radicals, initiating polymerization reactions.
Decomposition: Decomposes under heat or in the presence of acids or bases, releasing oxygen and tert-butyl radicals.
Flammability: TBPB is flammable and can form explosive mixtures with air.
Stability: Stable under recommended storage conditions; should be stored away from heat, flames, and incompatible materials.
Autoignition Temperature: Not readily available, typically handled under conditions to prevent ignition.
pH: Neutral in its pure form



FIRST AID


Inhalation:

Symptoms:
Inhalation of TBPB vapors may cause respiratory irritation, coughing, difficulty breathing, and throat irritation.

Immediate Actions:
Remove the affected person from the exposure area to fresh air immediately, ensuring they can breathe freely.
If breathing is difficult, provide oxygen if available. Assist ventilation if necessary.
Keep the person calm and in a comfortable position.

Medical Attention:
Seek immediate medical attention.
Provide the medical personnel with the Safety Data Sheet (SDS) or chemical name for proper treatment guidance.
Monitor the person for signs of respiratory distress.


Skin Contact:

Symptoms:
TBPB can cause skin irritation, redness, and potentially burns upon prolonged contact.

Immediate Actions:
Remove contaminated clothing and jewelry immediately.
Wash the affected area thoroughly with soap and water for at least 15 minutes, ensuring all chemical residue is removed.
If irritation persists or there are signs of burns, seek medical attention promptly.

Medical Attention:
Consult a physician if skin irritation or burns occur.
Provide the SDS or chemical name to medical personnel for appropriate treatment.


Eye Contact:

Symptoms:
Eye exposure to TBPB can cause irritation, redness, pain, and potential corneal injury.

Immediate Actions:
Immediately rinse eyes with gently flowing water for at least 15 minutes, holding eyelids open to ensure thorough flushing.
Remove contact lenses, if present and easily removable, during rinsing.
Seek medical attention immediately after rinsing.

Medical Attention:
Contact an eye specialist or ophthalmologist promptly.
Provide the SDS or chemical name to medical personnel for proper evaluation and treatment.


Ingestion:

Symptoms:
Ingestion of TBPB may cause gastrointestinal irritation, nausea, vomiting, and abdominal pain.

Immediate Actions:
Do not induce vomiting unless instructed by medical personnel.
Rinse out the mouth with water if the person is conscious and able to swallow.
Seek immediate medical attention.

Medical Attention:
Contact a poison control center or healthcare provider immediately.
Provide the SDS or chemical name to medical personnel for appropriate treatment guidance.


General First Aid Considerations:

Personal Protection for Rescuers:
Rescuers should wear appropriate personal protective equipment (PPE), including gloves, goggles, and protective clothing, to avoid direct contact with TBPB.

Decontamination:
Prevent further exposure by removing contaminated clothing promptly and washing exposed skin thoroughly.
Avoid cross-contamination by handling contaminated clothing and materials with care.

Emergency Contacts:
Keep emergency contact numbers, including poison control and medical services, readily accessible.

Transportation to Medical Facility:
Transport the affected person to a medical facility promptly, ensuring that they are accompanied by someone who can provide information about the exposure.


Additional Notes:

Documentation:
Document the details of the exposure incident, including symptoms observed, actions taken, and medical advice received.

Follow-Up:
Monitor the exposed individual for delayed symptoms or complications, especially in cases of skin burns or eye injuries.

Training and Awareness:
Educate personnel on the hazards of TBPB and proper first aid procedures to ensure preparedness in case of exposure incidents.



HANDLING AND STORAGE


Handling:

General Precautions:
Handle TBPB in a well-ventilated area to minimize exposure to vapors.
Use appropriate personal protective equipment (PPE), including chemical-resistant gloves, safety goggles, and lab coat.
Avoid inhalation of vapors and contact with skin and eyes.
Do not eat, drink, or smoke while handling TBPB.

Handling Practices:
Use tools and equipment that are grounded and spark-resistant to prevent static electricity discharge.
Ensure containers are tightly closed when not in use to prevent spills and evaporation.
Minimize exposure to heat, flames, and ignition sources during handling and transfer operations.
Handle with care to prevent physical damage to containers and potential release of the chemical.

Emergency Procedures:
Be familiar with emergency procedures and spill response measures before handling TBPB.
Have spill control materials (e.g., absorbent pads, neutralizing agents) readily available.
In case of spillage, contain the spill immediately to prevent further spread. Wear appropriate PPE during cleanup.

Hygiene Practices:
Wash hands and any exposed skin thoroughly with soap and water after handling TBPB.
Remove contaminated clothing and wash it before reuse.
Maintain good housekeeping practices in work areas to minimize potential exposure.

Specific Handling Guidance:
Do not mix TBPB with incompatible substances, such as acids, bases, and strong oxidizers.
Follow manufacturer's recommendations and safety data sheet (SDS) instructions for handling and disposal.
Ensure that all handling procedures comply with local, state, and federal regulations.


Storage:

Storage Location:
Store TBPB in a cool, dry, well-ventilated area away from direct sunlight and heat sources.
Keep containers tightly closed and upright to prevent leakage and evaporation.
Store away from incompatible materials and sources of ignition, such as sparks and open flames.

Temperature Control:
Maintain storage temperature below 30°C (86°F) to prevent decomposition and ensure chemical stability.
Avoid freezing temperatures, as crystallization may occur and affect product quality.

Container Requirements:
Use original containers made of compatible materials, such as high-density polyethylene (HDPE) or glass.
Ensure containers are labeled with the chemical name, hazards, and handling instructions.
Inspect containers regularly for signs of damage or deterioration.

Segregation:
Store TBPB separately from food, feedstuffs, and animal bedding to prevent contamination.
Segregate from oxidizing agents and strong reducing agents to avoid potential reactions.

Security and Accessibility:
Restrict access to storage areas to authorized personnel only.
Ensure emergency equipment, such as spill kits and fire extinguishers suitable for organic peroxides, is readily accessible.

Inventory Management:
Implement a first-in, first-out (FIFO) inventory system to ensure older stock is used first.
Keep accurate records of quantities stored, usage, and disposal to facilitate inventory control and regulatory compliance.
Tert-Butyl Peroxypivalate
Acetic acid, tert-butyl ester; 1,1-Dimethyl ethyl acetate; acetic acid, 1,1-dimethylethyl ester; t-Butyl acetate; cas no : 540-88-5
Tert-butylamine (TBA)
Trimethylaminomethane; 1,1-Dimethylethylamine; 2-Amino-2-Methylpropane; 2-Aminoisobutane; 2-Methyl-2-aminopropane; 2-Methyl-2-propylamine; 2-Methyl-2-propanamine; t-Butylamine; cas no: 75-64-9
TERT-BUTYLHYDROPEROXIDE
tert-Dodecyl mercaptan; TERT-DODECANETHIOL; t-Dodecanethiol; t-Dodecylmercaptan; Sulfole 120 cas no: 25103-58-6
TERT-BUTYLHYDROPEROXIDE 70%
Tert-butylhydroperoxide %70 is the organic compound with the formula (CH3)3COOH.
Tert-butylhydroperoxide %70 is one of the most widely used hydroperoxides in a variety of oxidation processes, for example the Halcon process.
Tert-butylhydroperoxide %70 is normally supplied as a 69–70% aqueous solution.

CAS: 75-91-2
MF: C4H10O2
MW: 90.12
EINECS: 200-915-7

Compared to hydrogen peroxide and organic peracids, Tert-butylhydroperoxide %70 is less reactive and more soluble in organic solvents.
Overall, Tert-butylhydroperoxide %70 is renowned for the convenient handling properties of its solutions.
Tert-butylhydroperoxide %70's solutions in organic solvents are highly stable.
A solution of Tert-butylhydroperoxide %70 and water with a concentration of greater than 90% is forbidden to be shipped according to US Department of Transportation Hazardous Materials Table 49 CFR 172.101.
In some sources Tert-butylhydroperoxide %70 also has an NFPA 704 rating of 4 for health, 4 for flammability, 4 for reactivity and is a potent oxidant, however other sources claim lower ratings of 3-2-2 or 1-4-4.

Tert-butylhydroperoxide %70 is an organic peroxide widely used in a variety of oxidation processes.
Tert-butylhydroperoxide %70 is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
Tert-butylhydroperoxide %70 is widely used in a variety of oxidation processes.
Tert-butylhydroperoxide %70 has a role as an antibacterial agent and an oxidising agent.
Watery odorless colorless liquid.
Floats and mixes slowly with water.
Tert-butylhydroperoxide %70 is a flammable liquid and a highly reactive oxidizing agent.
Pure Tert-butylhydroperoxide %70 is shock sensitive and may explode on heating.
Carbon dioxide or dry chemical extinguishers should be used for fires involving Tert-butylhydroperoxide %70.

Tert-butylhydroperoxide %70 accelerates oxidation of glutathione and decreases the metabolism of sodium hexobarbital in rat livers and is a strong oxidation agent.
Tert-butylhydroperoxide %70 and concentrated aqueous solutions of TBHP react violently with traces of acid and the salts of certain metals, including, in particular, manganese, iron, and cobalt.
Mixing anhydrous Tert-butylhydroperoxide %70 with organic and readily oxidized substances can cause ignition and explosion.
Tert-butylhydroperoxide %70 can initiate polymerization of certain olefins.
Tert-butylhydroperoxide %70 is an alkyl hydroperoxide compound with a tert-butyl alkyl group.
Tert-butylhydroperoxide %70 finds extensive use in numerous oxidation reactions.
Apart from its oxidizing properties, Tert-butylhydroperoxide %70 also exhibits antibacterial activity.
Tert-butylhydroperoxide %70 is a colorless, odorless liquid with a watery consistency.
Tert-butylhydroperoxide %70 has a characteristic behavior of floating on water and dissolving slowly when in contact with it.

Tert-butylhydroperoxide %70, referred to as TBHP, is one of the most commonly used alkyl hydroperoxide.
Commodities are generally light yellow transparent non-volatile liquids, slightly soluble in water, miscible with organic solvents.
Tert-butylhydroperoxide %70 is mainly used as an initiator for free radical reactions or polymerization reactions in industry.
Compared with the decomposition products of most other initiators, iTert-butylhydroperoxide %70 is acidic.
The decomposition products of Tert-butylhydroperoxide %70 are tert-butanol (TBA) and a small amount of acetone, which are not corrosive to the equipment, so the requirements for the equipment are not high.

The decomposition activation energy of O-O bond in Tert-butylhydroperoxide %70 is low, which can be used as an improver to improve the decane number of diesel oil.
Tert-butylhydroperoxide %70 is a very important organic synthesis intermediate.
Tert-butylhydroperoxide %70 is a crosslinking agent used in unsaturated polyester crosslinking under medium and high temperature conditions.
Under the action of the metal catalyst, Tert-butylhydroperoxide %70 can also be used as an oxygen supplier to selectively oxidize unsaturated hydrocarbons such as acetals, allyl alcohol compounds, and unsaturated hydrocarbons.

Tert-butylhydroperoxide %70 Chemical Properties
Melting point: -2.8 °C
Boiling point: 37 °C (15 mmHg)
Density: 0.937 g/mL at 20 °C
Vapor pressure: 62 mmHg at 45 °C
Refractive index: n20/D 1.403
Fp: 85 °F
Storage temp.: 2-8°C
pka: pK1: 12.80 (25°C)
Form: Liquid
Color: Clear colorless
Water Solubility: Miscible
Merck: 14,1570
BRN: 1098280
Exposure limits: No exposure limit is set.
On the basis of its irritant properties a ceiling limit of 1.2 mg/m3 (0.3 ppm) is recommended.
Stability: Stable, but may explode if heated under confinement.
Decomposition may be accelerated by traces of metals, molecular sieve or other contaminants.
Incompatible with reducing agents, combustible material, acids.
InChIKey: CIHOLLKRGTVIJN-UHFFFAOYSA-N
LogP: 1.230 (est)
CAS DataBase Reference: 75-91-2(CAS DataBase Reference)
NIST Chemistry Reference: Tert-butylhydroperoxide %70 (75-91-2)
EPA Substance Registry System: Tert-butylhydroperoxide %70 (75-91-2)

Tert-butylhydroperoxide %70 is a water-white liquid commonly commercially available as a 70% solution in water; 80% solutions are also available.
Tert-butylhydroperoxide %70 is used to initiate polymerization reactions and in organic syntheses to introduce peroxy groups into the molecule.
Tert-butylhydroperoxide %70 vapor can burn in the absence of air and may be flammable at either elevated temperature or at reduced pressure.
Fine mist/spray may be combustible at temperatures below the normal flash point.
When evaporated, the residual liquid will concentrate TBHP content and may reach an explosive concentration (>90%).

Closed containers may generate internal pressure through the degradation of Tert-butylhydroperoxide %70 to oxygen.
Tert-butylhydroperoxide %70 is a highly reactive product.
The three types of significant physical hazards are flammability, thermal, and decomposition due to contamination.
To minimize these hazards, avoid exposure to heat, fire, or any condition that will concentrate the liquid material.
Store away from heat, sparks, open flames, foreign contaminants, combustibles, and reducing agents.
Inspect containers frequently to identify bulges or leaks.

Application
Industrially, Tert-butylhydroperoxide %70 is used to prepare propylene oxide.
In the Halcon process, molybdenum-based catalysts are used for this reaction:

(CH3)3COOH + CH2=CHCH3 → (CH3)3COH + CH2OCHCH3
The byproduct t-butanol, which can be dehydrated to isobutene and converted to MTBE.
On a much smaller scale, Tert-butylhydroperoxide %70 is used to produce some fine chemicals by the Sharpless epoxidation.

Tert-butylhydroperoxide %70 used as a catalyst for polymerization reactions.
Tert-butylhydroperoxide %70 used as an introducer of peroxide groups in the substituent reaction.
Tert-butylhydroperoxide %70 is a first-class organic oxidant, which is easy to explode at high temperatures.
Tert-butylhydroperoxide %70 is used for dyeing and printing cotton, viscose, silk, cotton fiber and other fibers and their fabrics, and also for dyeing polyester/viscose blended fabrics.
Can be used alone or for color matching.
After dyeing viscose fabric, the product is treated with fixing agent M, and the color light is slightly wilted.
After fixing agent Y treatment, the color light is slightly blue, and after urea formaldehyde resin finishing, the color light is bluer.
Used as desiccant, polymerization initiator, organic synthesis intermediate for unsaturated melamine resin coatings

Tert-butylhydroperoxide %70 is an intermediate in the production of propylene oxide and t-butyl alcohol from isobutane and propylene.
Tert-butylhydroperoxide %70 is primarily used as an initiator and finishing catalyst in the solution and emulsion polymerization methods for polystyrene and polyacrylates.
Other uses are for the polymerization of vinyl chloride and vinyl acetate and as an oxidation and sulfonation catalyst in bleaching and deodorizing operations.
Tert-butylhydroperoxide %70 is a strong oxidant and reacts violently with combustible and reducing materials, and metallic and sulfur compounds.
Tert-butylhydroperoxide %70 is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation.
Tert-butylhydroperoxide %70 is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions.
Furthermore, Tert-butylhydroperoxide %70 is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes.
Tert-butylhydroperoxide %70 plays an important role for the introduction of peroxy groups in organic synthesis.

Production Methods
Tert-butylhydroperoxide %70 is produced by the liquid-phase reaction of isobutane and molecular oxygen or by mixing equimolar amounts of t-butyl alcohol and 30–50% hydrogen peroxide.
Tert-butylhydroperoxide %70 can also be prepared from t-butyl alcohol and 30% hydrogen peroxide in the presence of sulfuric acid or by oxidation of tert-butylmagnesium chloride.
The manufacturing process of Tert-butylhydroperoxide %70 is in a closed system.

Preparation
After diazotization of p-nitroaniline o-sulfonic acid, Tert-butylhydroperoxide %70 is coupled with & gamma; acid, and then the nitro group in the coupling is reduced to amino group, then condensed with phosgene, and finally salted out, filtered and dried.
Raw material consumption (kg/t) p-nitroaniline o-sulfonic acid 555 & gamma; Acid 490 phosgene 510
Tert-butanol reacts with sulfuric acid to form Tert-butylhydroperoxide %70, which is obtained by reacting with hydrogen peroxide.
Add tert-butanol to the reaction pot, add hydrogen peroxide at 35 deg c under stirring, then raise the temperature to 50 deg c, add 70% sulfuric acid dropwise, react for 5h after adding, keep the temperature at 55-60 deg c, stand in layers, dry the upper oil layer with anhydrous sodium sulfate, filter to obtain tert-butyl hydrogen peroxide.

tert-butanol reacts with sulfuric acid to generate tert-butyl bisulfate, which reacts with hydrogen peroxide to obtain:(CH3)3COH(H2SO4,H2O2)& rarr;(CH3)3COOH tert-butanol is added into the reaction pot, hydrogen peroxide is added at 35 ℃ under stirring, then the temperature is raised to 50 ℃, 70% sulfuric acid is added dropwise, the upper oil layer is dried and filtered with anhydrous sodium sulfate to obtain tert-butyl hydrogen peroxide.

Reactivity Profile
Most alkyl monohydroperoxides are liquid.
The explosivity of the lower members (e.g., methyl hydroperoxide, or possibly, traces of the dialkyl peroxides) decreasing with increasing chain length and branching.
Though relatively stable, explosions have been caused by distillation to dryness or attempted distillation at atmospheric pressure.

Health Hazard
Tert-butylhydroperoxide %70 is a strong irritant.
Floyd and Stockinger (1958) observed thatdirect cutaneous application in rats did notcause immediate discomfort, but the delayedaction was severe.
The symptoms were erythemaand edema within 2–3 days.
Exposureto 500 mg in 24 hours produced asevere effect on rabbit skin, while a rinse of150 mg/min was severe to eyes.
Tert-butylhydroperoxide %70 is moderately toxic; the effects aresomewhat similar to those of MEK peroxide.
Symptoms from oral administration in ratswere weakness, shivering, and prostration.

Carcinogenicity A study performed to evaluate the carcinogenicity of Tert-butylhydroperoxide %70 found it was not carcinogenic when applied to the skin of mice at 16.6% of the peroxide 6 times a week for 45 weeks.
However, if its application was preceded by 0.05 mg of 4-nitroquinoline-1-oxide as a 0.25% solution in benzene applied 20 times over 7 weeks followed by Tert-butylhydroperoxide %70 (16.6% in benzene), then malignant skin tumors appeared between days 390 and 405 of the experiment.
This supports the theory that peroxides are not complete carcinogens, but may act as promoters.
The effects of Tert-butylhydroperoxide %70 on promotable and nonpromotable mouse epidermal cell culture lines were reported by Muehlematter et al.

Synonyms
TERT-BUTYL HYDROPEROXIDE
75-91-2
TBHP
T-Butyl hydroperoxide
tert-Butylhydroperoxide
2-Hydroperoxy-2-methylpropane
Perbutyl H
t-Butylhydroperoxide
1,1-Dimethylethyl hydroperoxide
Cadox TBH
Hydroperoxide, 1,1-dimethylethyl
Terc. butylhydroperoxid
tert-Butyl hydrogen peroxide
Hydroperoxyde de butyle tertiaire
Hydroperoxide, tert-butyl
Slimicide DE-488
Tertiary butyl hydroperoxide
Trigonox a-75
Trigonox A-W70
TBHP-70
1,1-Dimethylethylhydroperoxide
Tertiary-butyl hydroperoxide
NSC 672
Caswell No. 130BB
Dimethylethyl hydroperoxide
Perbutyl H 69T
t-BuOOH
Luperox TBH 70X
terc.Butylhydroperoxid
Trigonox A-W 70
tert Butylhydroperoxide
CCRIS 5892
HSDB 837
tert-Butyl-hydroperoxide
Kayabutyl H
Trigonox A-75 [Czech]
T-Hydro
EINECS 200-915-7
DE 488
DE-488
UNII-955VYL842B
BRN 1098280
terc.Butylhydroperoxid [Czech]
terc. Butylhydroperoxid [Czech]
CHEBI:64090
AI3-50541
NSC-672
955VYL842B
Hydroperoxide, 1,1-dimethylethyl-
KAYABUTYL H 70
Hydroperoxyde de butyle tertiaire [French]
DTXSID9024693
EC 200-915-7
tert-Butyl hydroperoxide, >90% with water [Forbidden]
TERT-BUTYL HYDROPEROXIDE (II)
TERT-BUTYL HYDROPEROXIDE [II]
tBOOH
t Butylhydroperoxide
t Butyl Hydroperoxide
t-BHP
Hydroperoxide, t-Butyl
tert Butyl Hydroperoxide
tertiary Butylhydroperoxide
Trigonox
tBuOOH
tert-BuOOH
Ethyldiethylperoxide
Perbutyl H 69
Perbutyl H 80
t-butyl-hydroperoxide
terbutyl hydroperoxide
tert-butyhydroperoxide
tert-butylhydroperoxid
Terc butylhydroperoxid
tert-C4H9OOH
t-butyl hydrogenperoxide
t-butyl-hydrogenperoxide
tert.-butylhydroperoxide
tert.butyl hydroperoxide
BHP (CHRIS Code)
tertiarybutylhydroperoxide
tertbutylhydrogen peroxide
t-butyl hydrogen peroxide
tert.-butyl hydroperoxide
DSSTox_CID_4693
tert-butylhydrogen peroxide
2-methylpropane-2-peroxol
Hydroperoxide, tert-butyl-
DSSTox_RID_78866
DSSTox_GSID_31209
tertiary butyl hydro peroxide
Hydroperoxide,1-dimethylethyl
Trigonox A-80 (Salt/Mix)
UN 2093 (Salt/Mix)
UN 2094 (Salt/Mix)
USP -800 (Salt/Mix)
CHEMBL348399
DTXCID504693
NSC672
tert-Butyl hydroperoxide (8CI)
WLN: QOX1&1&1
2-Methyl-prop-2-yl-hydroperoxide
Tox21_200838
Aztec t-butyl Hydroperoxide-70, Aq
MFCD00002130
NA2092
NA2093
NA2094
UN2092
UN2093
UN2094
BUTYL HYDROPEROXIDE (TERTIARY)
TERT-BUTYL HYDROPEROXIDE [MI]
AKOS000121070
LS-1679
TERT-BUTYL HYDROPEROXIDE [HSDB]
NCGC00090725-01
NCGC00090725-02
NCGC00090725-03
NCGC00258392-01
tert-Butyl hydroperoxide aqueous solution
Hydroperoxide, 1,1-dimethylethyl (9CI)
tert-Butyl Hydroperoxide (70% in Water)
tert-Butyl hydroperoxide, >90% with water
B3153
FT-0657109
Q286326
J-509597
F1905-8242
Dimethylethyl hydroperoxide, 1,1-; (tert-Butylhydroperoxide)
TERT-DODECANETHIOL
Tert-Dodecanethiol's chemical formula is C12H26S
Tert-Dodecanethiol is colorless oil liquid, and diffuses foul smell.
Tert-Dodecanethiol is used in the manufacture of fungicides, insecticides, rust inhibitors, lubricating oil additives, drugs, etc.


CAS NUMBER: 25103-58-6

EC NUMBER: 246-619-1

MOLECULAR FORMULA: C12H26S

MOLECULAR WEIGHT: 202.40 g/mol

IUPAC NAME: 2,3,3,4,4,5-hexamethylhexane-2-thiol


Tert-Dodecanethiol is commonly used as a chain transfer agent
Tert-Dodecanethiol makes the relative molecular mass distribution uniform.

Tert-Dodecanethiol helps in the polymerization of the end products.
This role used to be given to chloroform, carbon tetrachloride, and other compounds of chlorine.

Tert-Dodecanethiol is a polymerization regulator of synthetic rubber, synthetic resin and synthetic fiber
Tert-Dodecanethiol is commonly used in the manufacture of styrene-butadiene rubber and ABS resin.

Tert-Dodecanethiol appears as a colorless liquid with a repulsive odor.
Tert-Dodecanethiol is colorless oil liquid, and diffuses foul smell.

Tert-Dodecanethiol is the best relative molecular mass regulator and chain transfer agent in polymerization processes such as styrene-butadiene rubber, nitrile rubber, and synthetic resin.
Tert-Dodecanethiol is a polymerization regulator of synthetic rubber, synthetic resin and synthetic fiber

Tert-Dodecanethiol is commonly used in the manufacture of styrene-butadiene rubber and ABS resin.
Tert-Dodecanethiol is a relative molecular mass adjuster for the polymerization of synthetic rubber, synthetic resin, and synthetic fiber, especially in the synthesis of styrene-butadiene rubber and ABS resin by emulsion polymerization, which can reduce the branching degree of polymer molecular chains

Tert-Dodecanethiol has an industrial use resulting in manufacture of another substance (use of intermediates).
Tert-Dodecanethiol has a repulsive odor.

Tert-Dodecanethiol can be used as an additive to lubricants.
Tert-Dodecanethiol's refractive index is 1.4589

Tert-Dodecanethiol's flash point is 90 ℃
Tert-Dodecanethiol is commonly used in the manufacturing process of polymers based on butadiene and styrene.

Tert-Dodecanethiol's boiling point is 227-248 ℃
Tert-Dodecanethiol is a colourless liquid organic compound, with a characteristic odour.

Tert-Dodecanethiol is used in the manufacture of fungicides, insecticides, rust inhibitors, lubricating oil additives, drugs, etc.
Tert-Dodecanethiol can also be used as "gold water" in the ceramic industry and an acidifier for oil wells.

Tert-Dodecanethiol is used as an intermediate and a chain transfer agent.
Tert-Dodecanethiol is a colorless liquid with a strong sulfur odor.

Tert-Dodecanethiol is used a an additive to lubricants.
Tert-Dodecanethiol is a member of the thiol family of compounds, which are characterized by the presence of a sulfur atom bonded to a hydrogen atom.

Tert-Dodecanethiol is used in a variety of scientific and industrial applications, including the synthesis of polymers, pharmaceuticals, and other materials.
Tert-Dodecanethiol is commonly used as a chain transfer agent in the manufacturing process of styrene/butadiene latex for use in carpet and paper industries

Tert-Dodecanethiol is used in lubricant intermediates to produce additives as well as final components to improve lubricant performance in base oils and metal working fluids.
Tert-Dodecanethiol is also a lubricant additive used to improve lubricant performance in base oils and metal working fluids.

Tert-Dodecanethiol appears as a colorless liquid with a repulsive odor.
Tert-Dodecanethiol is colorless oil liquid, and diffuses foul smell.

Tert-Dodecanethiol is a main component to produce metallic decoration (inks) for food packaging (porcelain, ceramics glass).
Tert-Dodecanethiol is a chain transfer agent used mainly in cold radical polymerization processes.

Tert-Dodecanethiol is soluble in acetone and benzene
Tert-Dodecanethiol is used to control the molecular weight in the manufacturing of butadiene & styrene based processes such as butadiene latex (SBL) & synthetic rubbers (e-SBR and NBR), ABS, polystyrene (PS) and styrene varnishes.

Tert-Dodecanethiol can also be used in the polymerization of various monomers, such as vinyl chloride and chlorotrifluoroethylene.
Tert-Dodecanethiol is used as a chemical intermediate in various syntheses: extreme pressure additives, fragrances, non-ionic surfactants and fungicides.

Tert-Dodecanethiol is an organosulfur compound
Tert-Dodecanethiol is commonly used as a chain transfer agent in the manufacturing process of styrene/butadiene latex for use in carpet and paper industries.

Tert-Dodecanethiol has recently become a significant industrial chemical because of its use as a chain transfer agent in the manufacture of latex.
Tert-Dodecanethiol's molecular formula is C12H25SH.

Tert-Dodecanethiol is colorless to pale yellow viscous liquid.
Tert-Dodecanethiol's freezing point is -7 ℃

Tert-Dodecanethiol is insoluble in water, soluble in alcohol, ether, acetone, benzene, gasoline and other organic solvents and esters.
Tert-Dodecanethiol is mainly used as molecular weight modifier.

Tert-Dodecanethiol is used as an intermediate
Tert-Dodecanethiol is used as an intermediate, as a process regulator, and as an additive to lubricants.

Tert-Dodecanethiol is used in polymers and pH regulators
Tert-Dodecanethiol is used in lubricant intermediates


PHYSICAL PROPERTIES:

-Molecular Weight: 202.40 g/mol

-XLogP3-AA: 4.8

-Exact Mass: 202.17552200 g/mol

-Monoisotopic Mass: 202.17552200 g/mol

-Topological Polar Surface Area: 1Ų

-Physical Description: Pellets or Large Crystals

-Density: 858 kg/m3

-Viscosity: 36 mPa.s (cP)

-Flash point: 97 °C

-Vapour pressure: 0.03 mbar (hPa)

-Vapour pressure: 0.8 mbar (hPa)

-Refractive index: 1.461

-Boiling point: 233°C

-Melting point: < -30°C

-Decomposition temperature: 350°C


Tert-Dodecanethiol is a chain transfer agent used mainly in cold radical polymerization processes.
Tert-Dodecanethiol can also be used in the polymerization of various monomers

Tert-Dodecanethiol is an organosulfur compound
Tert-Dodecanethiol has an industrial use resulting in the manufacture of another substance (use of intermediates).


CHEMICAL PROPERTIES:

-Hydrogen Bond Donor Count: 1

-Hydrogen Bond Acceptor Count: 1

-Rotatable Bond Count: 3

-Heavy Atom Count: 13

-Formal Charge: 0

-Complexity: 176

-Isotope Atom Count: 0

-Defined Atom Stereocenter Count: 0

-Undefined Atom Stereocenter Count: 0

-Defined Bond Stereocenter Count: 0

-Undefined Bond Stereocenter Count: 0

-Covalently-Bonded Unit Count: 1

-Compound Is Canonicalized: Yes


Tert-Dodecanethiol is used in mining.
Tert-Dodecanethiol is used in the manufacture of chemicals and rubber products.

Tert-Dodecanethiol is soluble in methanol, ether, acetone, benzene, gasoline and acetate
Tert-Dodecanethiol is insoluble in water.

Tert-Dodecanethiol is used as a process regulator
Tert-Dodecanethiol can be used as an additive to lubricants.

Tert-Dodecanethiol appears as a colorless liquid
Tert-Dodecanethiol is an intermediate in organic synthesis, used to manufacture drugs, pesticides, fungicides, rust inhibitors, lubricant additives, etc.

Tert-Dodecanethiol is mainly used as molecular weight modifier.
Tert-Dodecanethiol is used in water treatment products

Tert-Dodecanethiol has a characteristic odour.
Tert-Dodecanethiol is used as a chain transfer agent.

Tert-Dodecanethiol is a colorless liquid
Tert-Dodecanethiol is also commonly used for non-ionic surfactants agents
Tert-Dodecanethiol is used as an intermediates of organic synthesis.


SYNONYMS:

tert-Dodecylmercaptan
Sulfole 120;t-DDM
tert-Dodecyl Thiol
tert-Lauryl Mercaptan
2,3,3,4,4,5-Hexamethyl-2-hexanethiol
2,3,3,4,4,5-Hexamethylhexane-2-thiol
tert-Dodecylthiol
Tertiary Dodecyl Mercaptan
tert-Dodecyl Mercaptan
tert-Dodecanethiol
Tertiary Dodecyl Mercaptan
Tert Dodecyl Mercaptan
4-Heptanethiol, 2,2,4,6,6-pentamethyl-
MFCD00043233
tert-Dodecylmercaptan
tert-Dodecanethiol
TERT-DODECYL MERCAPTAN
tert-dodecylthiol
TERT-DODECANETHIOL
tert-Dodecyl mercaptan
DTXSID1025221
NCGC00091163-03
CCRIS 6030
tert-Lauryl Mercaptan
terc.Dodecylmerkaptan
EINECS 246-619-1
terc.Dodecylmerkaptan
BRN 1738382
2,3,3,4,4,5-Hexamethyl-2-hexanethiol
TERT-DODECYL THIOL
T-DODECYL MERCAPTAN
UNII-G00MDQ58TB
DTXCID905221
t-Dodecanethiol
Sulfole 120
t-DDM
2,3,3,4,4,5-hexamethylhexane-2-thiol
t-Dodecylmercaptan
G00MDQ58TB
SCHEMBL3332338
CHEMBL1325985
DTXSID00143406
1,1-Dimethyldecyl hydrosulfide
ZINC597503
tert-dodecanethiol
Tert-Dodecanethiol
tert-Dodecanethiol
tert-Dodecanthiol
AKOS015900250
n-(2-chloroethyl)-n-(3-pyridinyl)urea
Q2405872
t-dodecanethiol
2,2,4,6,6-Pentamethyl-4-heptanethiol
2,2,4,6,6-Pentaméthyl-4-heptanethiol
2,2,4,6,6-Pentamethyl-4-heptanthiol
2,3,3,4,4,5-hexamethylhexane-2-thiol
2-methylundecane-2-thiol
dodecane-1-thiol
Dodecyl mercaptan
TDM
TDM (tert-Dodecyl Mercaptan)
tert-Dodecanethiol
2-Methylundecane-2-thiol
2-Undecanethiol, 2-methyl-
2-Nonyl-2-propanethiol
NCGC00091163-01
NCGC00091163-02
NCGC00091163-04
CAS-25103-58-6
EC 246-619-1
2-Methylundecyl-2-thiol
tertiary dodecyl mercaptan
2-methyl-2-undecanethiol
2-methyl-undecane-2-thiol
SCHEMBL21128
1,1-Dimethyl-decyl-mercaptan
SCHEMBL564605
C12H26S
tert-Dodecyl mercaptan
tert-Dodecyl Mercaptan (mixture of isomers)
TDM
TDDM
tert-Dodecanethiol
tert-dodecylmercaptan
Tert-dodecyl mercaptan
dodecanethiol, mixed isomers
2,3,3,4,4,5-hexamethylhexane-2-thiol
tert-Dodecanethiol (mixture of isomers)
2,2,4,6,6-Pentamethylheptane-4-thiol
25103-58-6
296-714-7
tert-dodecanethiol
tert-dodecyl mercaptan
tert-dodecylmercaptan
tert-dodecylthiol
2,3,3,4,4,5-hexamethyl-2-hexanethiol
2,3,3,4,4,5-hexamethylhexane-2-thiol
2-hexanethiol, 2,3,3,4,4,5-hexamethyl-
2,4,4,6,6-pentamethyl heptane-2-thiol
2,4,4,6,6-pentamethyl-2-heptane thiol
2,4,4,6,6-pentamethyl-2-heptanethiol

TERT-DODECANETHIOL
Tert-dodecanethiol is a clear white to pale yellow liquid with a foul odour.
Tert-dodecanethiol, also known as 1-dodecanethiol or dodecyl mercaptan, is a chemical compound with the molecular formula C12H26S.
Tert-dodecanethiol is classified as a thiol, which is a type of organic compound containing a sulfur atom bonded to a hydrogen atom (–SH group) and is also known as a mercaptan.

CAS Number: 25103-58-6
Molecular Formula: C12H26S
Molecular Weight: 202.4
EINECS Number: 246-619-1

Tert-dodecanethiol is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents.
Generate heat and in many cases hydrogen gas and possibly hydrogen sulfide with these materials.

Tert-dodecanethiol incompatible with strong oxidizing agents.
The "tert" in the name typically refers to the position of the sulfur atom in the molecule.
May liberate hydrogen sulfide upon decomposition or reaction with an acid.

Tert-dodecanethiol may be sensitive to heat.
A chemical structure of a molecule includes the arrangement of atoms and the chemical bonds that hold the atoms together.

The Tert-dodecanethiol molecule contains a total of 38 bond(s).
There are 12 non-H bond(s), 3 rotatable bond(s), and 1 thiol(s).
Images of the chemical structure of Tert-dodecanethiol are given below:

Tert-dodecanethiol is a polymerization regulator of synthetic rubber, synthetic resin and synthetic fiber, especially commonly used in the manufacture of styrene-butadiene rubber and ABS resin.
The chemical structure of Tert-dodecanethiol consists of a linear hydrocarbon chain of 12 carbon atoms (dodecyl) bonded to a sulfur atom (thiol) with three methyl groups (tert-butyl) attached to the carbon adjacent to the sulfur atom. Its chemical formula is C12H26S.

Tert-dodecanethiol is a colorless to pale yellow liquid at room temperature. It has a strong, unpleasant odor, which is characteristic of many thiols.
Tert-dodecanethiol is insoluble in water but soluble in organic solvents like alcohols, ethers, and chlorinated hydrocarbons.
Thiols like Tert-dodecanethiol are known for their strong sulfur-hydrogen (S-H) bond, which gives them their characteristic odor.

They can undergo various chemical reactions, including oxidation and chemical bonding with other molecules through the sulfur atom.
These properties make them useful in various chemical processes.
Tert-dodecanethiol is an organosulfur compound with the molecular formula C12H25SH.

Tert-dodecanethiol is a colorless liquid with a strong sulfur odor.
Tert-dodecanethiol is a member of the thiol family of compounds, which are characterized by the presence of a sulfur atom bonded to a hydrogen atom.
Tert-dodecanethiol is used in a variety of scientific and industrial applications, including the synthesis of polymers, pharmaceuticals, and other materials.

The 2D chemical structure image of Tert-dodecanethiol is also called skeletal formula, which is the standard notation for organic molecules.
The carbon atoms in the chemical structure of Tert-dodecanethiolL are implied to be located at the corner(s) and hydrogen atoms attached to carbon atoms are not indicated – each carbon atom is considered to be associated with enough hydrogen atoms to provide the carbon atom with four bonds.

Tert-dodecanethiol is synthesized by the reaction of dodecanethiol with tert-butyl hypochlorite in the presence of a base.
The reaction is typically carried out in a two-phase system consisting of an aqueous phase and an organic phase.
The reaction proceeds in two steps: the initial reaction of Tert-dodecanethiol with tert-butyl hypochlorite to form a thiocyanate intermediate, followed by the reaction of the thiocyanate intermediate with a base to form Tert-dodecanethiol.

Tert-dodecanethiol acts as a ligand for the immobilization of proteins and enzymes.
Tert-dodecanethiol binds to the proteins and enzymes through its sulfur atom, forming a covalent bond.
This covalent bond enables the proteins and enzymes to be immobilized on a solid surface, allowing them to be used in a variety of applications.

The use of Tert-dodecanethiol in scientific research is still in its early stages, and there are many potential future directions for its use.
Tert-dodecanethiol could be used to create new materials with novel properties, such as materials with improved optical or electrical properties.
Additionally, Tert-dodecanethiol could be used to create new biosensors or to develop new pharmaceuticals. Tert-dodecanethiol could also be used to study protein-protein interactions or to develop new methods for the immobilization of proteins and enzymes.

Tert-dodecanethiol could be used to create new nanomaterials or to study the effects of Tert-dodecanethiol on biochemical and physiological processes.
One of the key properties of Tert-dodecanethiol is its ability to modify the surface properties of materials.
When it forms self-assembled monolayers (SAMs) on surfaces, it imparts hydrophobicity.

This can be particularly useful in applications where water repellency or resistance to moisture is desired, such as in coatings, paints, or protective layers.
SAMs formed by Tert-dodecanethiol on metal surfaces can act as barriers against corrosion.
By creating a protective hydrophobic layer on metal substrates, it prevents moisture and corrosive agents from reaching the metal surface, thus reducing the rate of corrosion.

In the field of nanotechnology, Tert-dodecanethiol is often employed as a ligand or stabilizing agent for nanoparticles, especially metal nanoparticles like gold and silver.
Tert-dodecanethiol can be used to control the size, shape, and stability of nanoparticles during their synthesis.
These modified nanoparticles find applications in catalysis, sensors, and nanocomposite materials.

Thiols, including Tert-dodecanethiol, can be used in analytical chemistry techniques such as gas chromatography and mass spectrometry as derivatizing agents.
They can react with certain functional groups in analytes, making them more amenable to analysis or detection.
Tert-dodecanethiol is a versatile chemical reagent in research laboratories.

Chemists use it to introduce the Tert-dodecanethiol group into molecules, enabling the study of specific chemical reactions or the modification of molecules for various purposes.
In industries like cosmetics and pharmaceuticals, Tert-dodecanethiol may be used in quality control and testing processes to assess the stability and shelf life of products, especially those that contain sulfur-containing compounds.

The disposal and handling of chemicals like Tert-dodecanethiol should be in accordance with local environmental regulations.
Thiols can be harmful to aquatic life, so care must be taken to prevent their release into natural water systems.

Melting point: -7.5°C
Boiling point: 227-248 °C (lit.)
Density: 0.86 g/mL at 20 °C (lit.)
vapor pressure: 1.33 hPa (25.5 °C)
refractive index: 1.4486 (estimate)
Flash point: 195 °F
storage temp.: Store below +30°C.
solubility: <0.1g/l
form: clear liquid
color: Colorless to Almost colorless
Viscosity: 3.77mm2/s
Water Solubility: BRN: 1738382
InChIKey: CXUHLUIXDGOURI-UHFFFAOYSA-N
LogP: 7.43 at 20℃

Tert-dodecanethiol has been used in a variety of scientific research applications, including the synthesis of polymers, pharmaceuticals, and other materials.
Tert-dodecanethiol has also been used as a surface modifier for gold nanoparticles, as a ligand for the immobilization of enzymes, as a ligand for the immobilization of proteins, and as a substrate for the synthesis of nanomaterials.
Additionally, Tert-dodecanethiol has been used in the study of protein-protein interactions and the development of biosensors.

A chain transfer agent is required in the manufacturing process of latex such as styrene-butadiene.
The chain transfer agent aids in polymerization to make products with the desired molecular distribution.
Chlorinated compounds such as carbon Tert-dodecanethiol and chloroform were previously used for this application, but due to their toxicity and adverse effects.

Due to environmental effects, Tert-dodecanethiol is no longer a practice to use the compounds mentioned in the production of latex used in the carpet and paper industries.
Instead, Tert-dodecanethiol is preferred to use Tert-dodecanethiol for the disclosed embodiments.
As a result of the worldwide demand for latex and the size of related industries, Tert-dodecanethiol has become a chemical of industrial importance.

From a manufacturing standpoint, Tert-dodecanethiol is a mixture of isomeric thiols produced from propylene tetramer oligomers or sometimes isobutylene trimer.
Propylene tetramer is produced by the oligomerization of propylene in the presence of a FriedelCrafts type catalyst such as sulfuric acid.
Tert-dodecanethiol is produced by passing hydrogen sulfide and propylene tetramer or isobutylene trimer over a catalyst such as boron trifluoride.

Because of the many permutations in the tetramer structure and hence the position of the -C=C- bond, the thiol group can occupy many different positions, resulting in a product mixture of isomers with average boiling points.
Tert-dodecanethiol is around 230°C. Recently, some concerns have also been raised regarding the accumulation of Tertiary resources.
The open literature contains little or no information on the analysis of Tert-dodecanethiol.

Tert-dodecanethiol is partly because the matrix can be quite complex.
An example would be a water-soluble emulsion polymer consisting of hundreds of components that can cause chromatographic interference.
Also, alkyl mercaptans such as Tert-dodecanethiol are difficult to analyze because their alkyl chains are C8 to C15 in size and cover a wide range of boiling points; The polarity of the individual components in Tert-dodecanethiol varies according to their degree.

In addition to the differences between the polarities and boiling points of the Tert-dodecanethiol components, The product may also contain some of the relatively non-polar, non-thiolated tetramer.
An internal method for the measurement of Tert-dodecanethiol has been developed, which involves the use of headspace gas chromatography in combination with flame photometric detection (FPD).
However, the method has limitations such as the competing vapor-liquid equilibrium of the solutes in the sample and the lack of linear dynamic range of the FPD.

As a result, a new chromatographic method is needed for the identification of the raw material of Tert-dodecanethiol, trend analysis and monitoring of the remaining material in the end products.
The new chromatographic method was developed with three adjuvants: (i) liquid-liquid extraction to extract Tert-dodecanethiol isomers from their respective matrices; (ii) Low thermal mass gas chromatography to provide flexibility in speciation of individual sulfur compounds or to combine individual sulfur compounds into a single latent peak with high temperature programming capability and peak compression to increase overall sample-to-sample yield; (iii) Dual plasma sulfur chemiluminescence detector (DP-SCD) offering the highest degree of selectivity for Tert-dodecanethiol isomers, equimolar response and a respectable linear dynamic range.

This report summarizes the method development and the analytical results obtained.
Tert-dodecanethiol has been shown to have a variety of biochemical and physiological effects.
In particular, Tert-dodecanethiol has been shown to increase the activity of the enzyme glucose-6-phosphatase, which is involved in the breakdown of glucose.

Additionally, Tert-dodecanethiol has been shown to inhibit the enzyme acetylcholinesterase, which is involved in the breakdown of acetylcholine.
Tert-dodecanethiol has also been shown to have anti-inflammatory and antioxidant properties.
The use of Tert-dodecanethiol in lab experiments has several advantages.

Tert-dodecanethiol is relatively inexpensive and easy to obtain, and it is stable and non-toxic.
Additionally, Tert-dodecanethiol can be used to immobilize proteins and enzymes on a solid surface, allowing them to be used in a variety of applications.
However, there are some limitations to the use of Tert-dodecanethiol in lab experiments.

Tert-dodecanethiol is not very soluble in water, and it is also sensitive to light and air.
Tert-dodecanethiol can be used as a starting material in the synthesis of other organic compounds.
Chemists often utilize its thiol functional group to introduce dodecylthiol chains into molecules, making it a versatile building block in organic synthesis.

In polymer chemistry, Tert-dodecanethiol can serve as an inhibitor or chain transfer agent.
Tert-dodecanethiol can be added to control the molecular weight and properties of polymers during their synthesis.
In adhesive formulations, Tert-dodecanethiol can enhance the adhesion of the adhesive to various surfaces.

Tert-dodecanethiol is particularly useful in bonding applications where strong adhesion to metals or other substrates is required.
Thiols, including Tert-dodecanethiol, can act as antioxidants or stabilizers in certain formulations.
They help protect materials, such as polymers or rubber, from degradation due to oxidation and other environmental factors.

Thiols like Tert-dodecanethiol are sometimes used in the mining industry as flotation agents.
They help separate valuable minerals from gangue minerals by making the valuable minerals hydrophobic, causing them to adhere to air bubbles in flotation cells.
Thiols and sulfur-containing compounds like Tert-dodecanethiol have been subjects of extensive research in the field of sulfur chemistry.

They have unique reactivity patterns, and their study contributes to a deeper understanding of chemical reactions involving sulfur-containing functional groups.
Tert-dodecanethiol is often used as a compatibilizing agent in polymer blends.
Tert-dodecanethiolcan help improve the compatibility of two or more polymers when they are mixed together, leading to better physical properties in the resulting materials.

Some sulfur-containing compounds, including thiols, contribute to the aroma and flavor of certain foods and beverages.
While Tert-dodecanethiol is not commonly used in this context, understanding the chemistry of thiols is important for the flavor and fragrance industry.
In laboratory settings, Tert-dodecanethiol may be employed in experiments to study the reactivity of thiol functional groups or to investigate surface modification techniques.

Uses
Tert-dodecanethiol is used in the following products: polymers and pH regulators and water treatment products.
Tert-dodecanethiol has an industrial use resulting in manufacture of another substance (use of intermediates).
Tert-dodecanethiol is used in the following areas: mining.

Tert-dodecanethiol is used for the manufacture of: chemicals, and rubber products.
Release to the environment of Tert-dodecanethiol can occur from industrial use: as an intermediate step in further manufacturing of another substance (use of intermediates), as processing aid, in processing aids at industrial sites and as processing aid.

Tert-dodecanethiol can be used as a polymerization regulator for synthetic rubber, synthetic fiber, and synthetic resin; it is also used to produce polyvinyl chloride stabilizers, drugs, pesticides, fungicides, detergents, etc.
Tert-dodecanethiol is a polymerization regulator for synthetic rubber, synthetic resin, and synthetic fiber.
Tert-dodecanethiol is especially commonly used in the manufacture of styrene-butadiene rubber and ABS resin.

Tert-dodecanethiol can reduce the branching degree of polymer chains and make the molecular weight distribution uniform.
Tert-dodecanethiol is often used as an intermediate for non-ionic surfactants and organic synthesis.
Tert-dodecanethiol is used to make fungicides, pesticides, rust inhibitors, lubricating oil additives, drugs, etc.

Tert-dodecanethiol can also be used as "golden water" and oil well acidifier in the ceramic industry; it is the best relative molecular mass regulator and chain transfer agent in the polymerization process of styrene-butadiene rubber, nitrile rubber, synthetic resin, etc.
Tert-dodecanethiol is frequently used in surface chemistry and materials science to create self-assembled monolayers (SAMs) on surfaces.

SAMs are organized molecular structures formed by the adsorption of thiol molecules onto metal surfaces.
These monolayers can modify surface properties and are used in applications like sensors, lubrication, and corrosion protection.
Tert-dodecanethiol is utilized in nanoparticle synthesis as a capping agent or surface modifier.

Tert-dodecanethiol helps control the size, shape, and stability of nanoparticles during their formation.
Tert-dodecanethiol serves as a precursor or reagent in organic synthesis for the introduction of the dodecylthiol group into various organic compounds.
Tert-dodecanethiol is a polymerization regulator for synthetic rubber, synthetic resin, and synthetic fiber.

Tert-dodecanethiol is especially used in the production of styrene-butadiene rubber and ABS resin.
Tert-dodecanethiol can reduce the degree of branching of the polymer chain and make the molecular weight distribution uniform.
Tert-dodecanethiol is often used as a nonionic surfactant.

Tert-dodecanethiol is used to manufacture fungicides, insecticides, rust inhibitors, lubricant additives, medicines, etc.
Tert-dodecanethiol is mainly used to adjust the molecular weight during the preparation of styrene-butadiene rubber, ABS resin and nitrile rubber, which can effectively reduce the branching degree of the polymer chain and make the molecular weight distribution Uniform; in addition, it can also be used as a stabilizer and antioxidant for the production of polyolefins such as polyvinyl chloride, polyethylene, and polypropylene; it can also be used to synthesize non-ionic surfactants, organic chemicals, fungicides, pesticides, lubricating oil additives, oilfield chemicals and medicines.

Tert-dodecanethiol is a polymerization regulator of synthetic rubber, synthetic resin and synthetic fiber, especially commonly used in the manufacture of styrene-butadiene rubber and ABS resin, which can reduce the branching degree of the polymer chain and make the molecular weight distribution uniform, often used as a nonionic surfactant and an intermediate in organic synthesis.
Tert-dodecanethiol is used in the manufacture of fungicides, insecticides, rust inhibitors, lubricating oil additives, drugs, etc.

Tert-dodecanethiol can also be used as “gold water” in the ceramic industry and an acidifier for oil wells.
Tert-dodecanethiol is an intermediate in organic synthesis, used to manufacture drugs, pesticides, fungicides, rust inhibitors, lubricant additives, etc., and can also be used as “gold water” in the ceramic industry.
Tert-dodecanethiol is a relative molecular mass adjuster for the polymerization of synthetic rubber, synthetic resin, and synthetic fiber, especially in the synthesis of styrene-butadiene rubber and ABS resin by emulsion polymerization, which can reduce the branching degree of polymer molecular chains and make the relative molecular mass distribution uniform.

Tert-dodecanethiol is the best relative molecular mass regulator and chain transfer agent in polymerization processes such as styrene-butadiene rubber, nitrile rubber, and synthetic resin.
Tert-dodecanethiol is often used to modify the surface properties of materials.
When it forms self-assembled monolayers (SAMs) on surfaces, it imparts hydrophobicity, making surfaces water-repellent.

This property is valuable in various applications, such as coatings and protective layers.
Tert-dodecanethiol is employed as a capping agent or surface modifier in nanoparticle synthesis, particularly for metal nanoparticles like gold and silver.
Tert-dodecanethiol helps control the size, shape, and stability of nanoparticles, making it useful in catalysis, sensors, and nanocomposite materials.

SAMs formed by Tert-dodecanethiol on metal surfaces act as barriers against corrosion.
They protect metal substrates from moisture and corrosive agents, reducing the rate of corrosion.
This is crucial in industries like aerospace and marine engineering.

Tert-dodecanethiol serves as a versatile chemical reagent in organic synthesis.
Tert-dodecanethiol can be used to introduce the dodecylthiol group into molecules, enabling the study of specific chemical reactions or modifying molecules for various purposes.
Tert-dodecanethiol enhances the adhesion of adhesives to various surfaces, especially metals.

This is valuable in bonding applications where strong adhesion is required, such as in automotive and construction industries.
In the mining industry, Tert-dodecanethiol can be used as a flotation agent to separate valuable minerals from gangue minerals.
By making the valuable minerals hydrophobic, it assists in their separation during flotation processes.

Thiols like Tert-dodecanethiol can act as antioxidants or stabilizers in formulations, protecting materials (e.g., polymers or rubber) from degradation due to oxidation and environmental factors.
Tert-dodecanethiols are utilized in analytical chemistry techniques, such as gas chromatography and mass spectrometry, as derivatizing agents to make certain analytes more amenable to analysis or detection.

Tert-dodecanethiol can be added as an inhibitor or chain transfer agent to control the molecular weight and properties of polymers during synthesis.
While not common for Tert-dodecanethiol, some sulfur-containing compounds contribute to the aroma and flavor of certain foods and beverages.
Tert-dodecanethiol understanding the chemistry of thiols is relevant in the flavor and fragrance industry.

Tert-dodecanethiol is used in laboratory experiments to study thiol reactivity, surface modification techniques, and other chemical reactions involving sulfur-containing compounds.
Tert-dodecanethiol may be used as a reference material for quality control purposes.
Tert-dodecanethiol can help assess the stability and shelf life of cosmetic products, especially those containing sulfur-containing compounds.

Tert-dodecanethiol, can be used in environmental remediation efforts.
They can assist in the removal or sequestration of heavy metals from contaminated soil or water by forming complexes with these metals.
Tert-dodecanethiol, have been explored as fuel additives to improve the stability and combustion characteristics of gasoline and diesel fuels.

Tert-dodecanethiol is often used in educational and research settings to demonstrate chemical principles, reactions involving thiol groups, and surface modification techniques.
Tert-dodecanethiol can serve as a valuable tool for teaching and experimentation.
In polymer science, Tert-dodecanethiol can be employed as a compatibilizing agent to improve the compatibility of different polymers when blended together.

This enhances the physical properties of the resulting materials.
Tert-dodecanethiol is used in the formulation of hydrophobic coatings for a variety of applications, including protecting surfaces from moisture, corrosion, and environmental damage.
Tert-dodecanethiol may be used as a finishing agent to enhance the water-repellent properties of fabrics or textiles.

Tert-dodecanethiol can be applied to paper or cardboard packaging materials to make them more resistant to moisture and improve their durability.
Tert-dodecanethiol is sometimes used as an additive in plastic formulations to modify the surface properties of plastic products, making them more resistant to water and other environmental factors.
Tert-dodecanethiol can be used as a precursor or as part of a chemical mixture to deposit thin films or coatings on surfaces, altering their properties.

Tert-dodecanethiol may be used in studies related to drug formulation and delivery, as well as in research involving sulfur-containing compounds.
Tert-dodecanethiol have been investigated for their potential use as fuel cell catalysts and for their ability to modify electrode surfaces in fuel cell technology.

Safety Considerations:
Tert-dodecanethiol, are known to have strong odors and can be irritating to the eyes and respiratory tract.
Proper safety precautions, including good ventilation and the use of personal protective equipment, are recommended when handling this compound.

Tert-dodecanethiol has a strong, unpleasant odor, and exposure to its vapors or direct contact with the skin, eyes, or mucous membranes can cause irritation.
This may lead to symptoms such as eye and skin irritation, redness, itching, and discomfort.
Inhalation of Tert-dodecanethiol vapors or aerosols can irritate the respiratory tract, leading to symptoms like coughing, shortness of breath, and respiratory discomfort.

Tert-dodecanethiol is important to work with this compound in a well-ventilated area or use appropriate respiratory protection if necessary.
Direct skin contact with Tert-dodecanethiol can cause irritation and may lead to dermatitis or skin sensitization in some individuals.
Tert-dodecanethiol is essential to wear appropriate protective clothing and gloves when handling this substance.

Contact with the eyes can cause eye irritation, redness, and discomfort.
Safety goggles or a face shield should be worn to protect the eyes when working with Tert-dodecanethiol.

Ingesting Tert-dodecanethiol is not a common exposure route, but it can be harmful if swallowed.
Tert-dodecanethiol is essential to avoid eating, drinking, or smoking in areas where this substance is being handled, and to wash hands thoroughly after working with it to prevent accidental ingestion.

Storage:
Tert-dodecanethiol should be stored in a cool, dry place, away from sources of heat and open flames.
Tert-dodecanethiol should also be stored in containers designed for chemical storage to prevent leaks or spills.

Synonyms
tert-Dodecylmercaptan
TERT-DODECANETHIOL
tert-Dodecyl mercaptan
t-Dodecanethiol
Sulfole 120
t-DDM
2,3,3,4,4,5-hexamethylhexane-2-thiol
t-Dodecylmercaptan
CCRIS 6030
G00MDQ58TB
terc.Dodecylmerkaptan [Czech]
DTXSID1025221
EINECS 246-619-1
BRN 1738382
NCGC00091163-03
2,3,3,4,4,5-Hexamethyl-2-hexanethiol
tert-Lauryl Mercaptan
terc.Dodecylmerkaptan
TERT-DODECYL THIOL
T-DODECYL MERCAPTAN
UNII-G00MDQ58TB
DTXCID905221
SCHEMBL3332338
CHEMBL1325985
YAJYJWXEWKRTPO-UHFFFAOYSA-N
Tox21_400018
AKOS015900250
LS-1066
n-(2-chloroethyl)-n-(3-pyridinyl)urea
NCGC00091163-01
NCGC00091163-02
NCGC00091163-04
CAS-25103-58-6
EC 246-619-1
3-01-00-01794 (Beilstein Handbook Reference)
Q2405872
TERT-DODECYL MERCAPTAN
Tert-Dodecyl Mercaptan is commonly used in the manufacturing process of polymers based on butadiene and styrene
Tert-Dodecyl Mercaptan is not soluble in water and slightly soluble in light alcohols
Tert-Dodecyl Mercaptan is soluble in styrene and most organic solvents.


CAS NUMBER: 25103-58-6

EC NUMBER: 246-619-1

MOLECULAR FORMULA: C12H26S

MOLECULAR WEIGHT: 202.40 g/mol

IUPAC NAME: 2,3,3,4,4,5-hexamethylhexane-2-thiol


Tert-Dodecyl Mercaptan is a polymerization regulator of synthetic rubber, synthetic resin and synthetic fiber
Tert-Dodecyl Mercaptan is commonly used in the manufacture of styrene-butadiene rubber and ABS resin.

Tert-Dodecyl Mercaptan is used in the manufacture of fungicides, insecticides, rust inhibitors, lubricating oil additives, drugs, etc.
Tert-Dodecyl Mercaptan can also be used as "gold water" in the ceramic industry and an acidifier for oil wells.

Tert-Dodecyl Mercaptan appears as a colorless liquid with a repulsive odor.
Tert-Dodecyl Mercaptan is colorless oil liquid, and diffuses foul smell.

Tert-Dodecyl Mercaptan is insoluble in water, soluble in alcohol, ether, acetone, benzene, gasoline and other organic solvents and esters.
Tert-Dodecyl Mercaptan is mainly used as molecular weight modifier.

Tert-Dodecyl Mercaptan is an intermediate in organic synthesis, used to manufacture drugs, pesticides, fungicides, rust inhibitors, lubricant additives, etc.
Tert-Dodecyl Mercaptan can also be used as "gold water" in the ceramic industry.

Tert-Dodecyl Mercaptan is a relative molecular mass adjuster for the polymerization of synthetic rubber, synthetic resin, and synthetic fiber, especially in the synthesis of styrene-butadiene rubber and ABS resin by emulsion polymerization, which can reduce the branching degree of polymer molecular chains
Tert-Dodecyl Mercaptan makes the relative molecular mass distribution uniform.
Tert-Dodecyl Mercaptan is the best relative molecular mass regulator and chain transfer agent in polymerization processes such as styrene-butadiene rubber, nitrile rubber, and synthetic resin.

Tert-Dodecyl Mercaptan is used in the following products:
-polymers
-pH regulators
-water treatment products

Tert-Dodecyl Mercaptan has an industrial use resulting in manufacture of another substance (use of intermediates).
Tert-Dodecyl Mercaptan is a colourless liquid organic compound, with a characteristic odour.

Tert-Dodecyl Mercaptan is used as an intermediate and a chain transfer agent.
Products containing Tert-Dodecyl Mercaptan are commercially available to industrial customers only.

Tert-Dodecyl Mercaptan is used in lubricant intermediates to produce additives as well as final components to improve lubricant performance in base oils and metal working fluids.
Tert-Dodecyl Mercaptan is a main component to produce metallic decoration (inks) for food packaging (porcelain, ceramics glass).
Tert-Dodecyl Mercaptan is also a lubricant additive used to improve lubricant performance in base oils and metal working fluids.

Tert-Dodecyl Mercaptan is a chain transfer agent used mainly in cold radical polymerization processes.
Tert-Dodecyl Mercaptan is used to control the molecular weight in the manufacturing of butadiene & styrene based processes such as butadiene latex (SBL) & synthetic rubbers (e-SBR and NBR), ABS, polystyrene (PS) and styrene varnishes.

Tert-Dodecyl Mercaptan can also be used in the polymerization of various monomers, such as vinyl chloride and chlorotrifluoroethylene.
Tert-Dodecyl Mercaptan is used as a chemical intermediate in various syntheses: extreme pressure additives, fragrances, non-ionic surfactants and fungicides.

Tert-Dodecyl Mercaptan is an organosulfur compound
Tert-Dodecyl Mercaptan's molecular formula is C12H25SH.

Tert-Dodecyl Mercaptan is colorless to pale yellow viscous liquid.
Tert-Dodecyl Mercaptan's freezing point is -7 ℃

Tert-Dodecyl Mercaptan is a colorless liquid with a strong sulfur odor.
Tert-Dodecyl Mercaptan is a member of the thiol family of compounds, which are characterized by the presence of a sulfur atom bonded to a hydrogen atom.

Tert-Dodecyl Mercaptan is used in a variety of scientific and industrial applications, including the synthesis of polymers, pharmaceuticals, and other materials.
Tert-Dodecyl Mercaptan is commonly used as a chain transfer agent in the manufacturing process of styrene/butadiene latex for use in carpet and paper industries

Tert-Dodecyl Mercaptan is used as an intermediate
Tert-Dodecyl Mercaptan is used as a process regulator

Tert-Dodecyl Mercaptan can be used as an additive to lubricants.
Tert-Dodecyl Mercaptan appears as a colorless liquid

Tert-Dodecyl Mercaptan has a repulsive odor.
Tert-Dodecyl Mercaptan is commonly used in the manufacturing process of polymers based on butadiene and styrene.

Tert-Dodecyl Mercaptan's boiling point is 227-248 ℃
Tert-Dodecyl Mercaptan's relative density is 0.8450(20/20 ℃)

Tert-Dodecyl Mercaptan is commonly used as a chain transfer agent in the manufacturing process of styrene/butadiene latex for use in carpet and paper industries.
Tert-Dodecyl Mercaptan has recently become a significant industrial chemical because of its use as a chain transfer agent in the manufacture of latex.

As an agent, Tert-Dodecyl Mercaptan helps in the polymerization of the end products.
This role used to be given to chloroform, carbon tetrachloride, and other compounds of chlorine.

Tert-Dodecyl Mercaptan's refractive index is 1.4589
Tert-Dodecyl Mercaptan's flash point is 90 ℃

Tert-Dodecyl Mercaptan is used as an intermediate, as a process regulator, and as an additive to lubricants.
Tert-Dodecyl Mercaptan is used in polymers and pH regulators

Tert-Dodecyl Mercaptan has an industrial use resulting in the manufacture of another substance (use of intermediates).
Tert-Dodecyl Mercaptan is used in mining.
Tert-Dodecyl Mercaptan is used in the manufacture of chemicals and rubber products.

Tert-Dodecyl Mercaptan is soluble in methanol, ether, acetone, benzene, gasoline and acetate
Tert-Dodecyl Mercaptan is insoluble in water.


PHYSICAL PROPERTIES:

-Molecular Weight: 202.40 g/mol

-XLogP3-AA: 4.8

-Exact Mass: 202.17552200 g/mol

-Monoisotopic Mass: 202.17552200 g/mol

-Topological Polar Surface Area: 1Ų

-Physical Description: Pellets or Large Crystals

-Density: 858 kg/m3

-Viscosity: 36 mPa.s (cP)

-Flash point: 97 °C

-Vapour pressure: 0.03 mbar (hPa)

-Vapour pressure: 0.8 mbar (hPa)

-Refractive index: 1.461

-Boiling point: 233°C

-Melting point: < -30°C

-Decomposition temperature: 350°C


Tert-Dodecyl Mercaptan is a polymerization regulator of synthetic rubber, synthetic resin and synthetic fiber
Tert-Dodecyl Mercaptan is commonly used in the manufacture of styrene-butadiene rubber and ABS resin.

Tert-Dodecyl Mercaptan appears as a colorless liquid with a repulsive odor.
Tert-Dodecyl Mercaptan is colorless oil liquid, and diffuses foul smell.


CHEMICAL PROPERTIES:

-Hydrogen Bond Donor Count: 1

-Hydrogen Bond Acceptor Count: 1

-Rotatable Bond Count: 3

-Heavy Atom Count: 13

-Formal Charge: 0

-Complexity: 176

-Isotope Atom Count: 0

-Defined Atom Stereocenter Count: 0

-Undefined Atom Stereocenter Count: 0

-Defined Bond Stereocenter Count: 0

-Undefined Bond Stereocenter Count: 0

-Covalently-Bonded Unit Count: 1

-Compound Is Canonicalized: Yes


Tert-Dodecyl Mercaptan is mainly used as molecular weight modifier.
Tert-Dodecyl Mercaptan is used in water treatment products

Tert-Dodecyl Mercaptan has a characteristic odour.
Tert-Dodecyl Mercaptan is used as a chain transfer agent.

Tert-Dodecyl Mercaptan is used in lubricant intermediates
Tert-Dodecyl Mercaptan is a chain transfer agent used mainly in cold radical polymerization processes.

Tert-Dodecyl Mercaptan can also be used in the polymerization of various monomers
Tert-Dodecyl Mercaptan is an organosulfur compound

Tert-Dodecyl Mercaptan is a colorless liquid
Tert-Dodecyl Mercaptan is commonly used as a chain transfer agent

Tert-Dodecyl Mercaptan can be used as an additive to lubricants.
As an agent, Tert-Dodecyl Mercaptan helps in the polymerization of the end products.

Tert-Dodecyl Mercaptan is used a an additive to lubricants.
Tert-Dodecyl Mercaptan is used in pH regulators
Tert-Dodecyl Mercaptan is soluble in acetone and benzene


SYNONYMS:

TERT-DODECANETHIOL
tert-Dodecyl mercaptan
t-Dodecanethiol
Sulfole 120
t-DDM
2,3,3,4,4,5-hexamethylhexane-2-thiol
t-Dodecylmercaptan
G00MDQ58TB
DTXSID1025221
NCGC00091163-03
CCRIS 6030
tert-Lauryl Mercaptan
terc.Dodecylmerkaptan
EINECS 246-619-1
terc.Dodecylmerkaptan
BRN 1738382
2,3,3,4,4,5-Hexamethyl-2-hexanethiol
TERT-DODECYL THIOL
T-DODECYL MERCAPTAN
UNII-G00MDQ58TB
DTXCID905221
SCHEMBL3332338
CHEMBL1325985
Tox21_400018
AKOS015900250
n-(2-chloroethyl)-n-(3-pyridinyl)urea
NCGC00091163-01
NCGC00091163-02
NCGC00091163-04
CAS-25103-58-6
EC 246-619-1
Q2405872
2,3,3,4,4,5-hexamethylhexane-2-thiol
2-methylundecane-2-thiol
dodecane-1-thiol
Dodecyl mercaptan
TDM
TDM (tert-Dodecyl Mercaptan)
tert-Dodecanethiol
2-Methylundecane-2-thiol
2-Undecanethiol, 2-methyl-
2-Nonyl-2-propanethiol
2-Methylundecyl-2-thiol
tertiary dodecyl mercaptan
2-methyl-2-undecanethiol
2-methyl-undecane-2-thiol
SCHEMBL21128
1,1-Dimethyl-decyl-mercaptan
SCHEMBL564605
C12H26S
DTXSID00143406
1,1-Dimethyldecyl hydrosulfide
ZINC597503
tert-dodecanethiol
Tert-Dodecanethiol
tert-Dodecanethiol
tert-Dodecanthiol
tert-Dodecyl mercaptan
tert-Dodecyl Mercaptan (mixture of isomers)
TDM
TDDM
tert-Dodecanethiol
tert-dodecylmercaptan
Tert-dodecyl mercaptan
dodecanethiol, mixed isomers
2,3,3,4,4,5-hexamethylhexane-2-thiol
tert-Dodecanethiol (mixture of isomers)
t-dodecanethiol
2,2,4,6,6-Pentamethyl-4-heptanethiol
2,2,4,6,6-Pentaméthyl-4-heptanethiol
2,2,4,6,6-Pentamethyl-4-heptanthiol
2,2,4,6,6-Pentamethylheptane-4-thiol
25103-58-6
296-714-7
4-Heptanethiol, 2,2,4,6,6-pentamethyl-
MFCD00043233
tert-Dodecylmercaptan
tert-Dodecanethiol
tert-Dodecanethiol (mixture of isomers)
TERT-DODECYL MERCAPTAN
tert-dodecylthiol

TERT-DODECYLMERCAPTAN
Tert-Dodecylmercaptan is a polymerization regulator for synthetic rubber, synthetic resin, and synthetic fiber.
Tert-Dodecylmercaptan is a clear white to pale yellow liquid with a repulsive odor.


CAS Number: 25103-58-6
EC Number: 246-619-1
Linear Formula: C12H25SH
Molecular Formula: C12H26S


Tert-Dodecylmercaptan is a clear white to pale yellow liquid with a repulsive odor.
Tert-Dodecylmercaptan is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 10 000 to < 100 000 tonnes per annum.


Tert-Dodecylmercaptan is clear white to light yellow liquid with a repulsive odor.
Tert-Dodecylmercaptan is clear light brown liquid with a stench.
Tert-Dodecylmercaptan is a chemical compound from the group of thiols.


Tert-Dodecylmercaptan is one of the important varieties of mercaptan series products, mainly used to regulate molecular weight during the preparation of styrene butadiene rubber, ABS resin, and nitrile rubber.
Tert-Dodecylmercaptan can effectively reduce the branching degree of polymer chains and ensure uniform molecular weight distribution.


Tert-Dodecylmercaptan is one of the important varieties of mercaptan series products.
Tert-Dodecylmercaptan is mainly used to adjust the molecular weight during the preparation of styrene-butadiene rubber, ABS resin and nitrile rubber, which can effectively reduce the branching degree of the polymer chain and make the molecular weight distribution Uniform.


Tert-Dodecylmercaptan is a clear white to pale yellow liquid with a repulsive odor.
Tert-Dodecylmercaptan is compound from the group of thiols.
Tert-Dodecylmercaptan is a polymerization regulator for synthetic rubber, synthetic resin, and synthetic fiber.


Tert-Dodecylmercaptan is insoluble in water.
Tert-Dodecylmercaptan is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents.


Tert-Dodecylmercaptan generates heat and in many cases hydrogen gas and possibly hydrogen sulfide with these materials.
Tert-Dodecylmercaptan may liberate hydrogen sulfide upon decomposition or reaction with an acid.
Tert-Dodecylmercaptan is incompatible with oxygen.


Tert-Dodecylmercaptan is incompatible with strong oxidizing agents .
Tert-Dodecylmercaptan may be sensitive to heat.
Tert-Dodecylmercaptan is colorless or pale yellow liquid.



USES and APPLICATIONS of TERT-DODECYLMERCAPTAN:
Tert-Dodecylmercaptan is used Chain Transfer Agents, Chemical Synthesis, Plastic, Resin & Rubber, Polymers.
Tert-Dodecylmercaptan is used in formulation or re-packing, at industrial sites and in manufacturing.
Tert-Dodecylmercaptan is used in the following products: polymers and pH regulators and water treatment products.


Tert-Dodecylmercaptan has an industrial use resulting in manufacture of another substance (use of intermediates).
Release to the environment of Tert-Dodecylmercaptan can occur from industrial use: formulation of mixtures.
Tert-Dodecylmercaptan is used in the following products: polymers and pH regulators and water treatment products.


Tert-Dodecylmercaptan has an industrial use resulting in manufacture of another substance (use of intermediates).
Tert-Dodecylmercaptan is used in the following areas: mining.
Tert-Dodecylmercaptan is used for the manufacture of: chemicals, and rubber products.


Release to the environment of Tert-Dodecylmercaptan can occur from industrial use: as an intermediate step in further manufacturing of another substance (use of intermediates), as processing aid, in processing aids at industrial sites and as processing aid.
Release to the environment of Tert-Dodecylmercaptan can occur from industrial use: manufacturing of the substance.


Tert-Dodecylmercaptan is used in the polymers industry and as a process regulator.
Tert-Dodecylmercaptan is used to make large scale and fine chemicals, rubber products, processing aids (i.e. pH regulators, flocculants, and precipitants), polymers, lubricants, and in mining.


Tert-Dodecylmercaptan is used as a synthetic chemical.
Tert-Dodecylmercaptan is used primarily as a molecular weight regulator in polymerizations used, in particular for free-radical polymerizations of vinylic monomers such as of butadiene, styrene, carboxylated styrene, acrylic acid, acrylonitrile, acrylic esters, vinyl ethers or their mixtures, wherein particularly the emulsion in water.


Tert-Dodecylmercaptan is a polymerization regulator for synthetic rubber, synthetic resin, and synthetic fiber.
Tert-Dodecylmercaptan is especially used in the production of styrene-butadiene rubber and ABS resin.
Tert-Dodecylmercaptan can reduce the degree of branching of the polymer chain and make the molecular weight distribution uniform.


Tert-Dodecylmercaptan is often used as a nonionic surfactant.
Tert-Dodecylmercaptan is used organic synthesis intermediates.
Tert-Dodecylmercaptan is used to manufacture fungicides, insecticides, rust inhibitors, lubricant additives, medicines, etc.


Tert-Dodecylmercaptan can also be used as ~~"golden water~~" in the ceramic industry and acidizing agent for oil wells; it is the best relative molecular mass regulator and chain transfer agent in the polymerization process of styrene-butadiene rubber, nitrile rubber, synthetic resin, etc.
Tert-Dodecylmercaptan is a polymerization regulator for synthetic rubber, synthetic resin, and synthetic fibers, especially used in the manufacturing of styrene butadiene rubber and ABS resin.


Tert-Dodecylmercaptan can reduce the branching degree of polymer chains and achieve uniform molecular weight distribution.
Tert-Dodecylmercaptan is commonly used as a non ionic surfactant and an intermediate in organic synthesis.
Tert-Dodecylmercaptan is used to manufacture fungicides, insecticides, rust inhibitors, lubricating oil additives, drugs, etc.


Tert-Dodecylmercaptan can also be used as a “golden water” for the ceramic industry and an oil well acidified.
Tert-Dodecylmercaptan is the best relative molecular weight regulator and chain transfer agent in the polymerization process of styrene butadiene rubber, nitrile butadiene rubber, synthetic resin, etc.


Tert-Dodecylmercaptan is commonly used in the manufacturing process of polymers based on butadiene and styrene (SB latex, SB rubber, ABS...)
Tert-Dodecylmercaptan is commonly used in the manufacturing process of polymers based on butadiene and styrene (SB latex, SB rubber, ABS...)
Tert-Dodecylmercaptan is a polymerization regulator of synthetic rubber, synthetic resin and synthetic fiber, especially commonly used in the manufacture of styrene-butadiene rubber and ABS resin.


Tert-Dodecylmercaptan is a polymerization regulator of synthetic rubber, synthetic resin and synthetic fiber, especially commonly used in the manufacture of styrene-butadiene rubber and ABS resin, which can reduce the branching degree of the polymer chain and make the molecular weight distribution uniform, often used as a nonionic surfactant and an intermediate in organic synthesis.


Tert-Dodecylmercaptan uses and applications include: Chain transfer agent in SB and nitrile rubber production; modifier in polymerization reactions, especially for SBR, NBR; reducing initiator; in food packaging adhesives.
Tert-Dodecylmercaptan is used in the manufacture of fungicides, insecticides, rust inhibitors, lubricating oil additives, drugs, etc.


Tert-Dodecylmercaptan can also be used as “gold water” in the ceramic industry and an acidifier for oil wells.
Tert-Dodecylmercaptan is an intermediate in organic synthesis, used to manufacture drugs, pesticides, fungicides, rust inhibitors, lubricant additives, etc., and can also be used as “gold water” in the ceramic industry.


Tert-Dodecylmercaptan is a relative molecular mass adjuster for the polymerization of synthetic rubber, synthetic resin, and synthetic fiber, especially in the synthesis of styrene-butadiene rubber and ABS resin by emulsion polymerization, which can reduce the branching degree of polymer molecular chains and make the relative molecular mass distribution uniform.


Tert-Dodecylmercaptan is the best relative molecular mass regulator and chain transfer agent in polymerization processes such as styrene-butadiene rubber, nitrile rubber, and synthetic resin.
Tert-Dodecylmercaptan is used predominantly as a molecular weight regulator in manufacturing of butadiene and styrene-based polymers.


Tert-Dodecylmercaptan is especially commonly used in the manufacture of styrene-butadiene rubber and ABS resin.
Tert-Dodecylmercaptan can reduce the branching degree of polymer chains and make the molecular weight distribution uniform.
Tert-Dodecylmercaptan is often used as an intermediate for non-ionic surfactants and organic synthesis.


Tert-Dodecylmercaptan is used to make fungicides, pesticides, rust inhibitors, lubricating oil additives, drugs, etc.
Tert-Dodecylmercaptan can also be used as "golden water" and oil well acidifier in the ceramic industry.
Tert-Dodecylmercaptan is the best relative molecular mass regulator and chain transfer agent in the polymerization process of styrene-butadiene rubber, nitrile rubber, synthetic resin, etc.


Tert-Dodecylmercaptan is used Chain Transfer agent in polymerization to produce ABS, SBR, SB-Latex.
Tert-Dodecylmercaptan is used Extreme pressure additives for gear oils, greases, and metal working fluids.
Tert-Dodecylmercaptan is used Corrosion inhibitor for lubrication oil.


The chain length regulator in the emulsion polymerization, Tert-Dodecylmercaptan can be used in the polymerization of various monomers such as vinyl chloride and chlorotrifluoroethylene
Tert-Dodecylmercaptan is used as molecular weight regulator and chain-transfer agent in polymerization process of synthetic rubber, synthetic resins and synthetic fibers,especially used for styrenebutadiene rubber, NBR, ABS resin.


Tert-Dodecylmercaptan is often used as Intermediate of nonionic surfactant and organic synthesis.
Tert-Dodecylmercaptan is used to producing Fungicides, insecticides, rust-preventing agent, lubricant additives, drugs,etc.
Tert-Dodecylmercaptan is used as Acidification of oil well


In addition, Tert-Dodecylmercaptan can also be used as a stabilizer and antioxidant for the production of polyolefins such as polyvinyl chloride, polyethylene, and polypropylene.
Tert-Dodecylmercaptan can also be used to synthesize non-ionic surfactants, organic chemicals, fungicides, pesticides, lubricating oil additives, oilfield chemicals and medicines.


Tert-Dodecylmercaptan can be used as a polymerization regulator for synthetic rubber, synthetic fiber, and synthetic resin.
Tert-Dodecylmercaptan is also used to produce polyvinyl chloride stabilizers, drugs, pesticides, fungicides, detergents, etc.



MARKETS CASE OF TERT-DODECYLMERCAPTAN:
*Coatings
*Adhesives
*Sealants & Elastomers
*Chemical & Materials Manufacturing



FUNCTIONS of TERT-DODECYLMERCAPTAN:
Tert-Dodecylmercaptan is one of the important varieties of mercaptan series products, mainly used to regulate molecular weight during the preparation of styrene butadiene rubber, ABS resin, and nitrile rubber.
Tert-Dodecylmercaptan can effectively reduce the branching degree of polymer chains and ensure uniform molecular weight distribution.



CHEMICAL PROPERTIES of TERT-DODECYLMERCAPTAN:
Tert-Dodecylmercaptan is a colorless to pale yellow viscous liquid.
Freezing point -7 ℃, boiling point 227-248 ℃,165-166 ℃(5.19kPa), relative density 0.8450(20/20 ℃), refractive index 1.4589, flash point 90 ℃.
Tert-Dodecylmercaptan is soluble in methanol, ether, acetone, benzene, gasoline and acetate, insoluble in water.
Is the best relative molecular weight regulator and chain transfer agent in the polymerization process of Styrene Butadiene Rubber, Nitrile Rubber, synthetic resin and so on.



PREPARATION of TERT-DODECYLMERCAPTAN:
12 grams of water and 40 grams of dodecene were introduced into the plant through a funnel.
After the factory is sealed, the reaction mixing pump is put into operation (speed: 2800min-1), and then the entire pumping cycle system (including the pump head) manufactured in the jacket design is restored to the initial temperature.

The reaction is started by gradually injecting the first 10 bar of carbon dioxide, and then gradually injecting 20 bar of hydrogen sulfide gas to a total pressure of about 30°C. 31 bar.
During the experiment, the H2S feed of the reactor system was kept open so that the amount of reacted hydrogen sulfide could be replenished into the reaction system.

During the next 2 hours, the mixture was uniformly heated to 60°C. After another 3 hours, all dissolved gas components are removed from the biphasic liquid sample by decompressing at the discharge valve and further heating to 100°C.
The composition of the organic liquid phase (upper phase) is analyzed by gas chromatography, and it is possible to distinguish the reactants (olefins), the main products (Tert-Dodecylmercaptan), and the minor components (thioethers).



METHODS OF MANUFACTURING:
Tert-Dodecylmercaptan, obtained by tetramerization of propylene, reacts with hydrogen sulfide at about 20℃ for 2h in the presence of aluminum trichloride catalyst.
The molar ratio of hydrogen sulfide is the amount of dodecene 1.5 times the amount of aluminum trichloride and 2.5% of dodecene.

The reaction product is separated, pickled, washed with hot water, and dried to obtain t-dodecanethiol.
In production, hydrogen sulfide can be generated by the action of saturated sodium sulfide solution and 20% sulfuric acid.
Raw material consumption quota: crude decaene (boiling range 180-208℃) 1100kg/t, aluminum trichloride 123kg/t, sodium sulfide (60%) 1220kg/t, sulfuric acid (92.5%) 1270kg/t.



PRODUCTION METHOD of TERT-DODECYLMERCAPTAN:
the dienes [112-41-4] obtained by propylene tetropolymerization react with hydrogen sulfide at about 20 ℃ for 2 hours in the presence of aluminum trichloride catalyst.
The dosage of hydrogen sulfide is 1.5 times that of dienes according to molar ratio, and the dosage of aluminum trichloride is 2.5% to that of dienes.

The reaction product is separated, pickled, washed with hot water, and dried to obtain tert.
Hydrogen sulfide in production can occur by the interaction of saturated sodium sulfide solution with 20% sulfuric acid.
Raw material consumption quota: crude decene (boiling range 180-208 ℃)1100kg/t, aluminum trichloride 123kg/t, sodium sulfide (60%)1220kg/t, sulfuric acid (92.5%)1270kg/t.



PHYSICAL and CHEMICAL PROPERTIES of TERT-DODECYLMERCAPTAN:
CAS Number: 25103-58-6
Molecular Weight: 202.40
Beilstein: 1738382
EC Number: 246-619-1
Molecular Weight: 202.40 g/mol
XLogP3-AA: 4.8
Hydrogen Bond Donor Count: 1
Hydrogen Bond Acceptor Count: 1
Rotatable Bond Count: 3
Exact Mass: 202.17552200 g/mol
Monoisotopic Mass: 202.17552200 g/mol
Topological Polar Surface Area: 1Ų
Heavy Atom Count: 13
Formal Charge: 0
Complexity: 176
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1

Compound Is Canonicalized: Yes
Physical state: clear, liquid
Color: colorless
Odor: Stench.
Melting point/freezing point
Melting point/range: < -20 °C at 1.013 hPa
Initial boiling point and boiling range: 227 - 248 °C - lit.
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Flash point: 95 °C - closed cup
Autoignition temperature: No data available
Decomposition temperature: No data available
pH: No data available
Viscosity, kinematic: No data available
Viscosity, dynamic: 2,55 mPa.s at 40 °C
Water solubility: No data available
Partition coefficient: n-octanol/water: No data available
Vapor pressure: 0,2 hPa at 25 °C - Regulation (EC) No. 440/2008, Annex, A.4
Density: 0,86 g/cm3 at 20 °C - lit.
Relative density: 0,858 at 20 °C - Regulation (EC) No. 440/2008, Annex, A.3
Particle characteristics: No data available

Explosive properties: No data available
Oxidizing properties: none
Molecular Weight: 202.4
Exact Mass: 202.175522
EC Number: 246-619-1
HScode: 29309070
PSA: 38.80000
XLogP3: 5.46
Appearance: White to yellow liquid.
Density: 0.855 g/cm3
Melting Point: -7.5°C
Boiling Point: 160-193 °C
Flash Point: 195 °F
Refractive Index: 1.456
Water Solubility: H2O: Storage Conditions: Store below +30°C.
Vapor Pressure: 1.33 hPa (25.5 °C)
Appearance (Clarity): Clear
Appearance (Colour): Colourless to almost colourless
Appearance (Form): Liquid
Assay (GC) (mixture of Isomers): min. 98.5%
Density (g/ml) @ 20°C: 0.840-0.860
Refractive Index (20°C): 1.460-1.461

Boiling Point: 240-242°C
Cas No: 25103-58-6
Molecular Formula: C12H26S
Molecular Weight: 202.40
Appearance: Colorless or light yellow liquid
Assay: % ≥98.5
Melting point: -7.5°C
Boiling point: 227-248 °C (lit.)
Assay: 95.00 to 100.00 sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity: 0.85900 @ 25.00 °C.
Boiling Point: 210.00 to 212.00 °C. @ 760.00 mm Hg
Vapor Pressure: 0.257000 mmHg @ 25.00 °C. (est)
Flash Point: 156.00 °F. TCC ( 68.89 °C. )
logP (o/w): 5.617 (est)
Soluble in: alcohol, water, 0.2801 mg/L @ 25 °C (est)
Insoluble in: water
Structural Formula: C12H25SH
CAS: 25103-58-6
Colorless oily liquid, foul odor, freezing point -7 °C,
boiling point: 200-235 °C (atmospheric pressure), 165-166 °C (5199, 5Pa),
explosion range:0.7-9.1% (V/V),

flash point 129 °C,
viscosity 5.3 centipoise,
specific gravity d20/40.854,
insoluble in water, soluble in ethanol, ether, acetone, benzene,
gasoline and esters and other organic solvents.
appearance: colorless or light yellow liquid
purity, %: ≥ 98.0
refractive index, n20/D: 1.4526~1.4600
density at 25 °C, g/ml: 0.845~0.860
boiling point, °C:230-238
Flashpoint, °F: >230Solubility
Molecular Formula: C12H26S
Molar Mass: 202.4
Density: 0.839g/cm3
Melting Point: -7.5℃
Boling Point: 212°C at 760 mmHg
Flash Point: 68.8°C
Water Solubility: Solubility: <0.1g/l
Vapor Presure: 0.257mmHg at 25°C
Storage Condition: Store below +30°C.
Refractive Index: 1.454
Density: 0.8±0.1 g/cm3
Boiling Point: 218.8±8.0 °C at 760 mmHg

Melting Point: -7.5°C
Molecular Formula: C12H26S
Molecular Weight: 202.400
Flash Point: 72.6±18.6 °C
Exact Mass: 202.175522
PSA: 38.80000
LogP: 5.46
Vapour Pressure: 0.2±0.4 mmHg at 25°C
Index of Refraction: 1.456
Water Solubility: Melting point: -7.5°C
Boiling point: 227-248 °C (lit.)
Density: 0.86 g/mL at 20 °C (lit.)
vapor pressure: 1.33 hPa (25.5 °C)
refractive index: 1.4486 (estimate)
Flash point: 195 °F
storage temp.: Store below +30°C.
solubility: <0.1g/l
form: clear liquid
color: Colorless to Almost colorless
Viscosity: 3.77mm2/s
Water Solubility: BRN: 1738382
InChIKey: CXUHLUIXDGOURI-UHFFFAOYSA-N
LogP: 7.43 at 20℃



FIRST AID MEASURES of TERT-DODECYLMERCAPTAN:
-Description of first-aid measures:
*After inhalation:
Fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
Consult a physician.
*After eye contact:
Rinse out with plenty of water.
Remove contact lenses.
*After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed:
No data available



ACCIDENTAL RELEASE MEASURES of TERT-DODECYLMERCAPTAN:
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up with liquid-absorbent material.
Dispose of properly.
Clean up affected area.



FIRE FIGHTING MEASURES of TERT-DODECYLMERCAPTAN:
-Extinguishing media:
*Suitable extinguishing media:
Carbon dioxide (CO2) Foam Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Suppress (knock down) gases/vapors/mists with a water spray jet.
Prevent fire extinguishing water from contaminating surface water or the ground water system.



EXPOSURE CONTROLS/PERSONAL PROTECTION of TERT-DODECYLMERCAPTAN:
-Control parameters:
Ingredients with workplace control parameters
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Safety glasses.
*Skin protection:
Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0,4 mm
Break through time: 480 min
Splash contact:
Material: Nitrile rubber
Minimum layer thickness: 0,4 mm
Break through time: 480 min
*Body Protection:
Protective clothing
-Control of environmental exposure:
Do not let product enter drains.



HANDLING and STORAGE of TERT-DODECYLMERCAPTAN:
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.



STABILITY and REACTIVITY of TERT-DODECYLMERCAPTAN:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .



SYNONYMS:
tert-Dodecanethiol
tert-Dodecylmercaptan
TERT-DODECANETHIOL
tert-Dodecyl mercaptan
t-Dodecanethiol
Sulfole 120
t-DDM
2,3,3,4,4,5-hexamethylhexane-2-thiol
t-Dodecylmercaptan
CCRIS 6030
G00MDQ58TB
DTXSID1025221
EINECS 246-619-1
BRN 1738382
NCGC00091163-03
2,3,3,4,4,5-Hexamethyl-2-hexanethiol
tert-Lauryl Mercaptan
terc.Dodecylmerkaptan
TERT-DODECYL THIOL
T-DODECYL MERCAPTAN
UNII-G00MDQ58TB
DTXCID905221
SCHEMBL3332338
CHEMBL1325985
YAJYJWXEWKRTPO-UHFFFAOYSA-N
Tox21_400018
AKOS015900250
LS-1066
n-(2-chloroethyl)-n-(3-pyridinyl)urea
NCGC00091163-01
NCGC00091163-02
NCGC00091163-04
CAS-25103-58-6
EC 246-619-1
3-01-00-01794 (Beilstein Handbook Reference)
Q2405872
Decanethiol, 9,9-dimethyl-
2,3,3,4,4,5-Hexamethyl-2-hexanethiol
Sulfole 120
t-DDM
terc.Dodecylmerkaptan
tert-Dodecylthiol
t-Dodecanethiol
tert-Dodecanethiol
tert-Dodecyl mercaptan
t-Dodecylmercaptan
tert-Dodecyl thiol
tert-Lauryl mercaptan
Tert-dodecanethiol
TERTIARY DODECYLMERCAPTAN
TDM
UN3082
tert-Dodecanethiol
tert-Dodecyl mercaptan
tert-Dodecyl thiol
Sulfole 120
t-DDM
tert-Lauryl mercaptan
TDM
90501-34-1
119147-91-0
1971112-70-5
tert-Dodecanethiol (mixture of isomers)
tert-Lauryl Mercaptan (mixture of isomers)
SULFOLE 120
T-DDM
T-DODECANETHIOL
T-DODECYL MERCAPTAN
TERT-DODECANETHIOL
TERT-DODECYL MERCAPTAN
TERT-DODECYL THIOL
TERT-DODECYLMERCAPTAN
TERT-DODECYLTHIOL
TERT-LAURYL MERCAPTAN
t-Dodecyl mercaptan
t-Dodecanethiol
t-Dodecylthiol
2,3,3,4,4,5-Hexamethyl-2-hexanethiol
TDM
dodecanethioltertiaire
sulfole120
t-ddm
terc.dodecylmerkaptan
2,3,3,4,4,5-Hexamethyl-2-hexanethiol
tert-dodecylthiol
TDM
TDDM
tert-Dodecanethiol
tert-dodecylmercaptan
Tert-dodecyl mercaptan
dodecanethiol, mixed isomers
2,3,3,4,4,5-hexamethylhexane-2-thiol
tert-Dodecanethiol (mixture of isomers)
TDM
Dodecanethiol
TERT-DODECANETHIOL
TERT-DODECYL MERCAPTAN
T-DODECANETHIOL;2,3,3,4,4,5-Hexamethyl-2-hexanethiol
tert-Dodecanet
dodecanethioltertiaire
Tert-Dodecyl Mercaptane
tert-Dodecylmercaptan (mixture of isomers)
TERT-DODECYL MERCAPTAN
TERT-DODECANETHIOL (MIXTURE OF ISOMERS)
TERT-DODECYLTHIOL

TERTIARY BUTYL HYDROPEROXIDE (TBHP)
Tertiary butyl hydroperoxide (TBHP) is a colorless liquid with a pungent odor.
Tertiary butyl hydroperoxide (TBHP) is odorless, colorless liquid.


CAS Number: 75-91-2
EC Number: 200-915-7
MDL number: MFCD00002130
Linear Formula: (CH3)3COOH
Molecular Formula : C4H10O2



SYNONYMS:
TBHP, 1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, 2-Methylpropane-2-peroxol, tert-Butyl hydroperoxide, tert-butyl hydroperoxide, tbhp, t-butyl hydroperoxide, tert-butylhydroperoxide, perbutyl h, t-butylhydroperoxide, cadox tbh, hydroperoxide, 1,1-dimethylethyl, 1,1-dimethylethyl hydroperoxide, terc. butylhydroperoxid, TBHP, T-Hydro, T-BUTYL HYDROPEROXIDE, Trigonox, tert-Butyl hydrogen peroxide, 2-Hydroperoxy-2-methylpropane, butylhydroperoxide, tert-Butyl hydroperoxide Solution, tertiary-, Butylhydroperoxid, Hydroperoxide, 1,1-dimethylethyl, Cadox TBH, Perbutyl H, 2-Hydroperoxy-2-methylpropane, 1,1-Dimethylethyl hydroperoxide, tert-C4H9OOH, tert-Butyl hydrogen peroxide, Hydroperoxide, tert-butyl, Hydroperoxyde de butyle tertiaire, Slimicide DE-488, Terc. butylhydroperoxid, Trigonox A-75, TBHP-70, Trigonox A-W70, t-Butylhydroperoxide, Aztec t-butyl Hydroperoxide-70, Aq, Dimethylethyl hydroperoxide, T-Hydro, TBHP, Tertiary-butyl hydroperoxide, NSC 672, 1,1-Dimethylethyl hydroperoxide, 1,1-Dimethylethylhydroperoxide, 2-Hydroperoxy-2-methylpropane, Cadox TBH, DE 488, DE-488, Hydroperoxide, 1,1-dimethylethyl, Hydroperoxide, tert-butyl, Hydroperoxyde de butyle tertiaire [French], Perbutyl H, Slimicide, Slimicide DE-488, T-Butyl hydroperoxide, TBHP-70, Tertiary butyl hydroperoxide, Trigonox A-W70, t-Butylhydroperoxide, tert-Butyl hydrogen peroxide, tert-Butylhydroperoxide, [ChemIDplus] UN3109,



The increasing demand for Tertiary butyl hydroperoxide (TBHP) as a curing agent is one of the major trends being witnessed in the.
A curing agent is a substance that Tertiary butyl hydroperoxide (TBHP) is mainly used to harden a surface or a layer.
Tertiary butyl hydroperoxide (TBHP) is a colorless liquid with a pungent odor.


Tertiary butyl hydroperoxide (TBHP) is odorless, colorless liquid.
Tertiary butyl hydroperoxide (TBHP) is the organic compound with the formula (CH3)3COOH.
Tertiary butyl hydroperoxide (TBHP) is one of the most widely used hydroperoxides in a variety of oxidation processes, like the Halcon process.


Tertiary butyl hydroperoxide (TBHP) is normally supplied as a 69–70% aqueous solution.
Compared to hydrogen peroxide and organic peracids, Tertiary butyl hydroperoxide (TBHP) is less reactive and more soluble in organic solvents.
Overall, Tertiary butyl hydroperoxide (TBHP) is renowned for the convenient handling properties of its solutions.


Tertiary butyl hydroperoxide (TBHP)'s solutions in organic solvents are highly stable.
Tertiary butyl hydroperoxide (TBHP) is an organic peroxide widely used in a variety of oxidation processes.
Tertiary butyl hydroperoxide (TBHP) is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 100 000 to < 1 000 000 tonnes per annum.


Tertiary butyl hydroperoxide (TBHP) is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
Tertiary butyl hydroperoxide (TBHP) is widely used in a variety of oxidation processes.
Tertiary butyl hydroperoxide (TBHP) has a role as an antibacterial agent and an oxidising agent.


Tertiary butyl hydroperoxide (TBHP) is a watery odorless colorless liquid.
Tertiary butyl hydroperoxide (TBHP) floats and mixes slowly with water.
Tertiary butyl hydroperoxide (TBHP) is water soluble.



USES and APPLICATIONS of TERTIARY BUTYL HYDROPEROXIDE (TBHP):
Tertiary butyl hydroperoxide (TBHP) is used chemical Synthesis, Industrial Chemicals, Catalysts, Oxidizer, Polymers.
Tertiary butyl hydroperoxide (TBHP) is used as a chemical intermediate, a curing agent for polyesters, and a catalyst for polymerization.
Tertiary butyl hydroperoxide (TBHP) is also used for bleaching and deodorizing.


A polymerization initiator, Tertiary butyl hydroperoxide (TBHP) is used to produce specialty chemicals in closed systems.
Tertiary butyl hydroperoxide (TBHP), an organic peroxide, finds extensive utility in numerous oxidation processes.
Tertiary butyl hydroperoxide (TBHP), characterized by its tert-butyl alkyl group, serves as a versatile tool in diverse oxidation reactions.


With its dual role as an antibacterial agent and an oxidizing agent, Tertiary butyl hydroperoxide (TBHP) offers a broad range of applications.
Notably, Tertiary butyl hydroperoxide (TBHP) has been observed to play a significant role in peroxynitrite-dependent PC12 cell necrosis, a process associated with the peroxidation of membrane lipids and the induction of mitochondrial permeability transition.


In this context, Tertiary butyl hydroperoxide (TBHP) acts as a promoter, facilitating the development of the aforementioned cell necrosis through its involvement in oxidative processes.
This diverse range of functions highlights the multifaceted nature of Tertiary butyl hydroperoxide (TBHP) and its potential contributions to various biological and chemical processes.


Tertiary butyl hydroperoxide (TBHP) is an excellent curing agent, and it is applied on a polymeric surface to facilitate higher bonding of the molecular components of a material.
The stronger the molecular bonds, the higher the strength and hardness of the material.


Tertiary butyl hydroperoxide (TBHP) is highly used as a curing agent for thermoset resins, coatings, and specialty monomers, and these substances are effectively used in end-use industries such as automotive, aviation, and building and construction.
Tertiary butyl hydroperoxide (TBHP) is used in formulation or re-packing, at industrial sites and in manufacturing.


Release to the environment of Tertiary butyl hydroperoxide (TBHP) can occur from industrial use: formulation of mixtures.
Tertiary butyl hydroperoxide (TBHP) is used in the following products: polymers.
Tertiary butyl hydroperoxide (TBHP) is used in the following areas: formulation of mixtures and/or re-packaging.


Tertiary butyl hydroperoxide (TBHP) is used for the manufacture of: chemicals.
Release to the environment of Tertiary butyl hydroperoxide (TBHP) can occur from industrial use: as an intermediate step in further manufacturing of another substance (use of intermediates) and as processing aid.


Release to the environment of Tertiary butyl hydroperoxide (TBHP) can occur from industrial use: manufacturing of the substance.
Industrially, Tertiary butyl hydroperoxide (TBHP) is used to prepare propylene oxide.
In the Halcon process, molybdenum-based catalysts are used for this reaction:
(CH3)3COOH + CH2=CHCH3 → (CH3)3COH + CH2OCHCH3


The byproduct t-butanol can be dehydrated to isobutene and converted to MTBE.
On a much smaller scale, Tertiary butyl hydroperoxide (TBHP) is used to produce some fine chemicals by the Sharpless epoxidation.
Tertiary butyl hydroperoxide (TBHP) is an intermediate in the production of propylene oxide and t-butyl alcohol from isobutane and propylene.


Tertiary butyl hydroperoxide (TBHP) is primarily used as an initiator and finishing catalyst in the solution and emulsion polymerization methods for polystyrene and polyacrylates.
Other uses of Tertiary butyl hydroperoxide (TBHP) are for the polymerization of vinyl chloride and vinyl acetate and as an oxidation and sulfonation catalyst in bleaching and deodorizing operations.


Tertiary butyl hydroperoxide (TBHP) is a strong oxidant and reacts violently with combustible and reducing materials, and metallic and sulfur compounds.
Tertiary butyl hydroperoxide (TBHP) is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation.
Tertiary butyl hydroperoxide (TBHP) is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions.


Furthermore, Tertiary butyl hydroperoxide (TBHP) is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes.
Tertiary butyl hydroperoxide (TBHP) plays an important role for the introduction of peroxy groups in organic synthesis.



SYNTHESIS AND PRODUCTION OF TERTIARY BUTYL HYDROPEROXIDE (TBHP):
Many synthetic routes are available, e.g. by the auto-oxidation of isobutane.



CHEMICAL PROPERTIES OF TERTIARY BUTYL HYDROPEROXIDE (TBHP):
Tertiary butyl hydroperoxide (TBHP) is a water-white liquid commonly commercially available as a 70% solution in water; 80% solutions are also available.
Tertiary butyl hydroperoxide (TBHP) is used to initiate polymerization reactions and in organic syntheses to introduce peroxy groups into the molecule.

Tertiary butyl hydroperoxide (TBHP) vapor can burn in the absence of air and may be flammable at either elevated temperature or at reduced pressure.
Closed containers may generate internal pressure through the degradation of Tertiary butyl hydroperoxide (TBHP) to oxygen.
Tertiary butyl hydroperoxide (TBHP) is a highly reactive product.



PRODUCTION METHODS OF TERTIARY BUTYL HYDROPEROXIDE (TBHP):
Tertiary butyl hydroperoxide (TBHP) is produced by the liquid-phase reaction of isobutane and molecular oxygen or by mixing equimolar amounts of t-butyl alcohol and 30–50% hydrogen peroxide.

Tertiary butyl hydroperoxide (TBHP) can also be prepared from t-butyl alcohol and 30% hydrogen peroxide in the presence of sulfuric acid or by oxidation of tert-butylmagnesium chloride.
The manufacturing process of Tertiary butyl hydroperoxide (TBHP) is in a closed system.



MECHANISM OF ACTION OF TERTIARY BUTYL HYDROPEROXIDE (TBHP):
The general mechanism of transition metal-catalyzed oxidative Mannich reactions of N, N-dialkyl anilines with Tertiary butyl hydroperoxide (TBHP) as the oxidant consists of a rate-determining single electron transfer (SET) that is uniform from 4-methoxy- to 4-cyano-N, N-dimethylanilines.

The tert-butylperoxy radical is the major oxidant in the rate-determining SET step that is followed by competing backward SET and irreversible heterolytic cleavage of the carbon–hydrogen bond at the α-position to nitrogen.

A second SET completes the conversion of N, N-dimethylaniline to an iminium ion that is subsequently trapped by the nucleophilic solvent or the oxidant prior to the formation of the Mannich adduct.



PHYSICAL and CHEMICAL PROPERTIES of TERTIARY BUTYL HYDROPEROXIDE (TBHP):
CAS Number: 75-91-2
Molecular Weight: 90.12
Beilstein: 1098280
MDL number: MFCD00002130
PubChem Substance ID: 24869433
Physical state: Liquid
Color: No data available
Odor: No data available
Melting point/freezing point: No data available
Initial boiling point and boiling range: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Flash point: 43 °C - closed cup
Autoignition temperature: No data available
Decomposition temperature: No data available
pH: No data available
Viscosity: No data available

Water solubility: No data available
Partition coefficient: n-octanol/water: No data available
Vapor pressure: No data available
Density: 0.808 g/cm3
Relative density: No data available
Relative vapor density: No data available
Particle characteristics: No data available
Explosive properties: Not classified as explosive
Oxidizing properties: None
Other safety information: No data available
Physical Properties:
Boiling point: 37 °C (20 hPa)
Density: 0.94 g/cm3 (20 °C)
Flash point: 38 °C
Melting Point: -3 °C

Vapor pressure: 232 hPa (60 °C)
Refractive Index: 1.3870 (20 °C)
Solubility: 130 - 150 g/l
Chemical Properties:
Chemical formula: C4H10O2
Molar mass: 90.122 g·mol−1
Appearance: Colorless liquid
Density: 0.935 g/mL
Melting point: −3 °C (27 °F; 270 K)
Boiling point: 37 °C (99 °F; 310 K) at 2.0 kPa
Solubility in water: Miscible
log P: 1.23
Acidity (pKa): 12.69
Basicity (pKb): 1.31
Refractive index (nD): 1.3870

Std enthalpy of formation (ΔfH⦵298): −294±5 kJ/mol
Std enthalpy of combustion (ΔcH⦵298): 2.710±0.005 MJ/mol
Melting Point: -2.8°C
Color: Colorless
Density: 0.9400g/mL
Boiling Point: 37.0°C (15.0 mmHg)
Flash Point: 43°C
Packaging: Plastic Can
Linear Formula: (CH3)3COOH
Refractive Index: 1.3860 to 1.3880
Quantity: 10 kg
Beilstein: 01,IV,1616
Fieser: 01,88; 02,49; 03,37; 05,75; 06,81; 07,43; 08,62; 09,78; 10,64
Merck Index: 14,1570

Formula Weight: 90.12
Physical Form: Liquid
Chemical Name or Material: tert-Butyl hydroperoxide
Melting point: -2.8 °C
Boiling point: 37 °C (15 mmHg)
Density: 0.937 g/mL at 20 °C
Vapor pressure: 62 mmHg at 45 °C
Refractive index: n20/D 1.403
Flash point: 85 °F
Storage temp.: 2-8°C
pKa: pK1: 12.80 (25°C)
Form: Liquid
Color: Clear colorless
Water Solubility: Miscible
LogP: 1.230 (est)



FIRST AID MEASURES of TERTIARY BUTYL HYDROPEROXIDE (TBHP):
-Description of first-aid measures:
*General advice:
First aiders need to protect themselves.
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
Immediately call in physician.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
Call a physician immediately.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Immediately call in ophthalmologist.
Remove contact lenses.
*If swallowed:
After swallowing:
Make victim drink water (two glasses at most).
Call a physician immediately.
Do not attempt to neutralise.
-Indication of any immediate medical attention and special treatment needed:
No data available



ACCIDENTAL RELEASE MEASURES of TERTIARY BUTYL HYDROPEROXIDE (TBHP):
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up carefully with liquid-absorbent material.
Dispose of properly.
Clean up affected area.



FIRE FIGHTING MEASURES of TERTIARY BUTYL HYDROPEROXIDE (TBHP):
-Extinguishing media:
*Suitable extinguishing media:
Foam
Carbon dioxide (CO2)
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Remove container from danger zone and cool with water.
Prevent fire extinguishing water from contaminating surface water or the ground water system.



EXPOSURE CONTROLS/PERSONAL PROTECTION of TERTIARY BUTYL HYDROPEROXIDE (TBHP):
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Use equipment for eye protection.
Tightly fitting safety goggles
*Skin protection:
Handle with gloves.
Wash and dry hands.
Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0,4 mm
Break through time: 480 min
Splash contact:
Material: Nitrile rubber
Minimum layer thickness: 0,2 mm
Break through time: 60 min
*Body Protection:
Flame retardant antistatic protective clothing.
*Respiratory protection:
Recommended Filter type: Filter type ABEK
-Control of environmental exposure:
Do not let product enter drains.



HANDLING and STORAGE of TERTIARY BUTYL HYDROPEROXIDE (TBHP):
-Precautions for safe handling:
*Advice on safe handling:
Work under hood.
Take precautionary measures against static discharge.
*Hygiene measures:
Immediately change contaminated clothing.
Apply preventive skin protection.
Wash hands and face after working with substance.
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Keep locked up or in an area accessible only to qualified or authorized persons.
*Storage stability:
Recommended storage temperature:
2 - 8 °C



STABILITY and REACTIVITY of TERTIARY BUTYL HYDROPEROXIDE (TBHP):
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .
-Possibility of hazardous reactions:
No data available


TERTIARY DODECYL MERCAPTAN
Tertiary Dodecyl Mercaptan TDM (Tertiary Dodecyl Mercaptan) is commonly used in the manufacturing process of polymers based on butadiene and styrene (SB latex, SB rubber, ABS...) Chemical name : tert-dodecanethiol Common name : TDM Properties Density (20°C): 858 kg/m3 Viscosity (20 °C): 36 mPa.s (cP) Flash point (closed cup): 97 °C Vapour pressure (20°C): 0.03 mbar (hPa) Vapour pressure (50°C): 0.8 mbar (hPa) Refractive index (20°C): 1.461 Boiling point: 233°C Melting point < -30°C Decomposition temperature: 350°C SOLUBILITY Tertiary Dodecyl Mercaptan is not soluble in water, slightly soluble in light alcohols and soluble in styrene and most organic solvents. In the process of manufacturing latex such as styrene-butadiene, a chain transfer agent is required. The chain transfer agent assists in the polymerization to make products of the desired molecular distribution. Previously, chlorinated compounds such as carbon tetrachloride and chloroform have been used for this application, but because of their toxicity and negative environmental effects, it is no longer a practice to employ said compounds for the manufacturing of latex used for the carpet and paper industries. Instead, use of tertiary dodecyl mercaptan (TDM) is preferred for the applications described. As a result of the world demand for latex and the magnitude of the associated industries, Tertiary dodecyl mercaptan has become a chemical of industrial significance. From a manufacturing standpoint, Tertiary dodecyl mercaptan is a mixture of isomeric thiols produced from oligomers of propylene tetramer or sometimes, isobutylene trimer. Propylene tetramer is produced by oligomerization of propylene in the presence of a FriedelCrafts type catalyst such as sulfuric acid. Tertiary dodecyl mercaptan is produced by passing hydrogen sulfide and either propylene tetramer or isobutylene trimer over a catalyst such as boron trifluoride. Because of the fact that there are many permutations of the tetramer structure, and hence the location of the –C=C– bond, the thiol group can be located in many different positions, resulting in a product mixture of isomers with an average boiling point range around 230°C. Recently, there has also been some increased concerns regarding to the accumulation of Tertiary dodecyl mercaptan in the environment. The open literature contains little to no information on the analysis of Tertiary dodecyl mercaptan. This is partly due to the fact that the matrix can be quite complex. An example would be water soluble emulsion polymer, comprizing hundreds of components which can cause chromatographic interference. Also, alkyl mercaptans such as Tertiary dodecyl mercaptan are difficult to analyze due to reasons such as the alkyl chains are C8 to C15 in size and cover a wide range of boiling points, the polarity of the individual components in Tertiary dodecyl mercaptan varies with the degree of thiolation, the location of the R-SH moiety. In addition to the differences in polarity and boiling points of the Tertiary dodecyl mercaptan components, the product can also contain a fraction of relatively non-polar, non-thiolated tetramer. For the measurement of Tertiary dodecyl mercaptan, an internal method involves the use of headspace gas chromatography in combination with flame photometric detection (FPD) had been developed. The method, however, has its constraints, including competing vapour–liquid equilibrium of solutes in the sample and the lack of linear dynamic range of the FPD. As a result, a new chromatographic method is required for raw material identification of Tertiary dodecyl mercaptan, for trend analysis, and for the monitoring of residual material in the final products. The new chromatographic method was developed with three enablers: (i) Liquid–liquid extraction to remove Tertiary dodecyl mercaptan isomers from their respective matrices; (ii) Low thermal mass gas chromatography to deliver the flexibility of either speciation of individual sulfur compounds, or peak compression to combine individual sulfur compounds into one discreet peak with high temperature programming capability and to improves overall sample to sample throughput; (iii) Dual plasma sulfur chemiluminescence detector (DP-SCD) to offer the highest degree of selectivity for Tertiary dodecyl mercaptan isomers, equi-molar response and a respectable linear dynamic range. This report summarizes the method development and analytical results obtained. The total sulfur approach In the total sulfur approach, the separation power of the column is compressed by operating the column at an elevated temperature. The rationale of this approach is that because all the isomers of Tertiary dodecyl mercaptan are compressed into one discreet, Gaussian peak, in theory, the sensitivity of the method can be improved and since chromatographic separation is not required, shorter analytical time can be attained. The downside, however, is if there is any sulfur containing compounds in the sample retainable by the chromatographic column, it will also be measured as Tertiary dodecyl mercaptan. Method optimization involved selecting the appropriate operating temperature for the analytical column to obtain a symmetric peak for reliable quantitative work. Peak symmetry quality was compared between maintaining the column temperature isothermally versus a slight temperature program. Comparison of performance between the two approaches In terms of precision, as stated earlier for the speciated method, the distribution of individual isomers of Tertiary dodecyl mercaptan between 3.5 and 6.0 min was integrated, whereas for the total method, the discreet peak representing Tertiary dodecyl mercaptan was integrated. Standards containing 1000 ppm (v/v) of Tertiary dodecyl mercaptan in iso-octane were used for the evaluation. A relative standard deviation of 2.5% (n = 20) was obtained for the speciated method while a relative standard deviation of 3.9% (n = 10) was obtained for the total sulfur method. The results obtained were tabulated in Table I. In terms of linearity, over the range from 1 ppm to 1000 ppm (v/v) Tertiary dodecyl mercaptan, correlation coefficients R2 of 0.9994 and of 0.9995 were obtained for the speciated and the total sulfur method, respectively. The detection limit for Tertiary dodecyl mercaptan by the total sulfur method was found to be 0.5 ppm (v/v) Tertiary dodecyl mercaptan whereas 1.0 ppm (v/v) for the speciated method as shown in Figures 11 and 12. Table II shows a comparison of five iso-octane extract samples containing Tertiary dodecyl mercaptan. It was found the results obtained were comparable amongst the two methods; despite there is a trend that the Tertiary dodecyl mercaptan results obtained by the total sulfur method is consistently elevated as shown in Figure 13. Some plausible explanations for this bias include the samples might have a different distribution of isomers than Tertiary dodecyl mercaptan used for calibration, or more of the Tertiary dodecyl mercaptan is detected in the samples as isomers are thermally band compressed into a much shorter peak width than classical method. Nevertheless, the results obtained show that the concept of tracking for the presence of Tertiary dodecyl mercaptan by measuring its sulfur content and associated retention time range in the speciated method or by measuring its sulfur content alone can be employed for the material identification, trend monitoring, or the measurement of residual Tertiary dodecyl mercaptan in various matrices. If a high degree of accuracy is required, the results obtained by using said techniques must be compared to other assaying techniques. Conclusions A gas chromatographic technique has been successfully developed for the measurement of Tertiary dodecyl mercaptan based on its sulfur content for raw material identification, trend analysis, or for the measurement of un-reacted material in the final products. The method employs LTM-GC offering the flexibility either for speciation of individual sulfur compounds or delivering peak compression to combine individual sulfur compounds into one discreet peak without changing of hardware, and a DP-SCD to attain a high degree of sensitivity and selectivity. Using the technique described, a detection limit in the range of 0.5 ppm (v/v) Tertiary dodecyl mercaptan with less than 1 min analysis can be achieved. Response is linear over four orders of magnitude with a high degree of repeatability of less than 5%. Physicochemical Information Boiling point 233 °C (1013 hPa) Density 0.856 g/cm3 (20 °C) Flash point 98 °C Ignition temperature 350 °C Melting Point -45 °C Vapor pressure 1.33 hPa (25.5 °C) Solubility <0.1 g/l Evaluation Summary Tertiary Dodecyl Mercaptan (tert-dodecyl mercaptan, TDM) is a transitional ‘existing’ substance which was discussed by the former EU PBT Working Group on a number of o c c a si on s . As a result of these discussions the substance was included in Regulation (EC) No. 465/2008 of 28th May 2008, which required industry to conduct an enhanced biodegradation test and fish bioconcentration study and submit the results by November 2009. The data were provided in January 2013. Based on the available information, TDM does not meets the Annex XIII criteria for either a ‘persistent, bioaccumulative and toxic’ (PBT) or a ‘very persistent and very bioaccumulative’ (vPvB) substance in the environment. A recent paper by Comber and Thomas (2013) provided by the registrant suggests that the water solubility of Tertiary dodecyl mercaptan could be lower than given in the registration dossier. The Comber and Thomas (2013) paper refers to a water solubility for Tertiary dodecyl mercaptan of 0.00393 mg/l obtained in a slow-stir water solubility study. Details of the new water solubility test (Baltussen, 2013) have recently been provided in a robust study summary. The study was a GLP compliant OECD Guideline 105 study using the slow-stirring method. The substance tested had an analytical purity of 99.1%. The test was carried out by preparing triplicate samples in double distilled water at 19.9±0.4°C and stirring at 40 rpm. At various time points samples were taken, centrifuged and prepared for analysis, taking care to avoid volatilisation of the test substance (no further details of how this was achieved are given). The concentration of Tertiary dodecyl mercaptan was determined by a validated analytical method involving derivatisation followed by analysis using HPLC/MS/MS (this was presumably a similar method to that discussed in relation to the biodegradation and bioaccumulation data). The pH of the water was in the range 6.5 to 7.1 throughout the test. Samples were analysed at 24, 48, 72, 96, 120 and 144 hours. For the first three samples the concentration was found to increase slightly with time (0.00139 mg/l at 24 hours, 0.00174 mg/l at 48 hours and 0.00217 mg/l at 72 hours). For the latter three sampling times the concentration was found to be more stable, although the maximum difference in the concentration at the three sampling points was >15%. The concentrations measured were 0.00467 mg/l at 96 hours, 0.00415 mg/l at 120 hours and 0.00296 mg/l at 144 hours. The test report concluded that the variability in the results at these sampling points probably reflected the difficulties in accurately determining very low concentrations of Tertiary dodecyl mercaptan rather than a continuing increase in the amount of Tertiary dodecyl mercaptan dissolved (in fact the concentrations declined slightly with time during this phase). The water solubility was therefore determined to be 0.00393 mg/l based on the mean concentration measured between 96 hours and 144 hours. The robust study summary gives the study a reliability of 2 (reliable with restrictions) as the maximum difference between the measured concentrations at the last three sampling points was >15%. The eMS agrees with this reliability rating and also considers it likely that the variability seen in the measurements reflects the difficulties in measuring low concentrations of this substance rather than a continuing increase in the amount dissolved at the later sampling points. Therefore the actual water solubility of Tertiary dodecyl mercaptan can be taken to be around 0.00393 mg/l (3.93 µg/l) at 20°C. Comber and Thomas (2013) estimated a log Kow value for Tertiary dodecyl mercaptan of 7.43 using a validated QSAR based on this water solubility. A Robust Study Summary and details of the QSAR used have been made available to the eMS. The linear regression model was proprietary and was developed using confidential data sets (details of these were not given), but it was reported that the substance fell within the applicability domain of the QSAR. It should be noted, however, that the types of chemical used to train the model did not appear to specifically contain thiols (although it is not possible to be certain about this as the specific substances used were not given). The applicability of this method to thiols has since been demonstrated for a set of four thiols (primary and secondary), although the log Kow values of these were lower than for Tertiary dodecyl mercaptan (experimental log Kow values of the validation set were between 1.5 and 3.7) (personal communication to the evaluating Member State, 6th December 2013). A further measured water solubility value for Tertiary dodecyl mercaptan is reported in EA (2005). The water solubility was determined to be 0.25 mg/l at 20°C and the study used a nonguideline protocol (simple flask method) but was carried out according to GLP. This value was used in the EA (2005) assessment but only limited details are available (the registrants do not have access to the study) for this study and so the reasons for the discrepancy between this value and the value of 0.00393 mg/l given above are currently unknown2. The physico-chemical properties of Tertiary dodecyl mercaptan have also been reviewed by EA (2005) and the data presented there are generally consistent with those from the registration dossier but, apart from the water solubility, the main exception is the vapour pressure, which is given as 4 hPa (400 Pa) at 20oC in EA (2005) based on a non-GLP study conducted according to Method A4 of Directive 92/69/EEC. The test report was not available for review by EA (2005) and the registrants do not have access to the study, so the influence of volatile impurities in the test substance is not known. The value for the vapour pressure reported in EA (2005) is twenty times higher than the value reported in the registration dossier and the reasons for this discrepancy have not been investigated in detail for this evaluation. However, it is relevant to note that EA (2005) estimated a Henry’s law constant for Tertiary dodecyl mercaptan of around 3.24×105 Pa m3 /mole at 20oC based on the water solubility and vapour pressure (EA (2005) assumed a water solubility of 0.25 mg/l for Tertiary dodecyl mercaptan) and commented that this was higher than the Henry’s law constant estimated using the bond contribution method in EPIWIN of 5,900 Pa m3 /mole at 25°C. When the vapour pressure (20 Pa at 25 oC) and water solubility (0.21-0.28 mg/l at 25oC) given in the registration dossier are used to estimate the Henry’s law constant the value obtained is in the region of 14,490- 19,230 Pa m3 /mole at 25oC which is in closer agreement with the EPIWIN estimate than obtained using a vapour pressure of 400 Pa. When the more recent and lower water solubility value (0.00393 mg/l) is considered the Henry’s law constant can be estimated as around 1.03×106 Pa m3 /mole at 25°C using a vapour pressure of 20 Pa (and assuming the change in water solubility with temperature is minor between 20 and 25°C) or 2.06×10 7 Pa m3 /mole at 20°C using a vapour pressure of 400 Pa. The various estimates of Henry’s law constant, along with the equivalent dimensionless Henry’s law constants (Kaw) are summarised in Table 3. Clearly there is a wide range of values that can be estimated for Tertiary dodecyl mercaptan. The values all suggest that volatilisation from water to air will be an important process in the environmental distribution of Tertiary dodecyl mercaptan. The significance of the range of estimates in relation to longrange transport potential is considered in Section 3.3. Based on the currently available data the best estimate of the log Kaw is probably 2.62 based on the vapour pressure of 20 Pa at 25°C given in the registration dossier and the recent water solubility determination of 0.00393 mg/l at 20°C. Oxidation EA (2005) considered that, although abiotic degradation of thiols to disulfides or sulfonic acids by oxidation is reported in the literature, the significance of this process for Tertiary dodecyl mercaptan in the environment was unknown. The registration dossier gives the results of a preliminary oxidation test carried out using the OECD 111 method (reliability rating 2). This test was considered a supporting study in the registration dossier. The Tertiary dodecyl mercaptan tested was a commercial sample with a purity of 99.3%. The test was carried out using both algal culture medium (prepared in accordance with the OECD 201 test guideline) with a pH of 8 and also buffer solution with a pH of 7. Tertiary dodecyl mercaptan was added to the media at 10 mg/l and incubated for up to 150 days at 20°C either under aerated (aerobic) conditions or nonaerated (anaerobic) conditions. A co-solvent (acetonitrile) at 10% v/v was used to maintain the substance in solution. The primary degradation of Tertiary dodecyl mercaptan was followed by parent compound analysis. Tertiary dodecyl mercaptan was found to degrade slowly under the aerated conditions, with a half-life of approximately 150 days in both algal medium and pH 7 buffer. Under non-aerated conditions the half-life for Tertiary dodecyl mercaptan was found to be approximately 30 days in algal medium and 100 days in pH 7 buffer. Analyses were also carried out for di-tert-dodecyl disulphide, the anticipated oxidation product of Tertiary dodecyl mercaptan. This was detected at a concentration of 0.2-0.3 mg/l in the non-aerated algal medium experiment but was at or below the limit of quantification (~0.1 mg/l) in the other experimental systems. It was concluded that the levels of ditert-dodecyl disulphide found did not account fully for the level of degradation of Tertiary dodecyl mercaptan seen implying that degradation mechanisms other that oxidation may also be occurring. It was also concluded in the registration dossier that the 30 day half-life measured in the non-aerated algal medium was probably falsely short owing to poor agreement between replicates for the later samples and that overall this test shows that Tertiary dodecyl mercaptan can be degraded slowly in solution but the route/mechanism of degradation is uncertain. When considering this test, it should be noted that Tertiary dodecyl mercaptan is relatively volatile (vapour pressure 20 Pa at 25° C). The full test report of the study indicates that precautions were taken to avoid potential loss from volatilization (use of sealed vials and sampling via septa). Therefor it is unlikely that volatile loss would have contributed significantly to the removal of Tertiary dodecyl mercaptan seen. The other point worth noting is that, although the test was carried out using 10% v/v of acetonitrile as a cosolvent, the concentration of Tertiary dodecyl mercaptan used (10 mg/l) is well above the recently determined water solubility of 0.0039 mg/l. The solubility of Tertiary dodecyl mercaptan in an acetonitrile:water mixture is unknown but it is possible that not all of the Tertiary dodecyl mercaptan would have been in solution in this test. In conclusion, the results of this study suggest that oxidation of Tertiary dodecyl mercaptan in the environment is likely to be only a minor loss process. Screening tests A modified OECD 310 Test Guideline ready biodegradability test has been carried out with Tertiary dodecyl mercaptan (Davis et al., 2009). The test material used was a commercial sample with a purity of 99.9% and the test was carried out in accordance with GLP.The substance was added to the test system coated on silica gel (as an inert support) in order to maximise its availability to the microbial inoculum in accordance with the ISO 10634 (1995) guidance. Two loading rates were used in the study. A nominal loading rate of 20.5 µmoles Tertiary dodecyl mercaptan/g silica gel (4.15 mg Tertiary dodecyl mercaptan/g) was firstly prepared by adding the test substance directly to the silica gel in a sealed bottle under argon atmosphere and mixing for three days. A nominal loading of 2.05 µmoles Tertiary dodecyl mercaptan/g silica gel was then prepared by mixing 1.1 g of the treated silica gel with 10.3 g of unspiked silica gel followed by mixing for 1 day. The loading rates, and uniformity of the spiked samples were confirmed by analysis of triplicate samples immediately after preparation of the silica gel and after preparation of the test microcosms (the mean loading rates determined were 16.9 µmol/g and 1.70 µmol/g at the two loading rates, respectively). The inoculum used in the study was derived from activated sludge mixed liquor collected from a municipal waste water treatment plant treating predominantly domestic waste water (>90% from domestic sources). The mixed liquor suspended solids (MLSS) concentration of the activated sludge was 1,230 mg/l and appropriate volumes were added to mineral salts medium to give a nominal MLSS concentration in the test microcosm of either 30 mg/l or 4 mg/l4. The tests were carried out using a series of sealed 160 ml glass serum bottles containing 75 ml of mineral salts media inoculated with MLSS at either 4 or 30 mg/l and containing Tertiary dodecyl mercaptan (adsorbed onto silica gel) at a nominal concentration of either 2 µM (~0.4 mg/l) or 20 µM (~4 mg/l). The 2 µM concentration was around twice the estimated water solubility for Tertiary dodecyl mercaptan (given as 1.4 µM, which is equivalent to a water solubility of 0.28 mg/l (the estimated water solubility given in the registration dossier). As discussed in Section 1.5 a much lower water solubility of 0.0039 mg/l has recently become available and so the 2 µM treatment may have been as much as 100 times higher, and the 20 µM treatment as much as 1,000 times higher than the actual water solubility of Tertiary dodecyl mercaptan. The significance of the new water solubility on the bioavailability of Tertiary dodecyl mercaptan in this study is unclear but it is possible that the bioavailability may still have been limited even though the substance was adsorbed onto silica gel. Viability controls (containing 25 mg/l of aniline and MLSS), toxicity controls (containing MLSS and both aniline and Tertiary dodecyl mercaptan) and inoculum blanks (containing MLSS only) were also prepared. In addition abiotic controls (containing heat sterilized MLSS and Tertiary dodecyl mercaptan) were also prepared in order to assess abiotic loss of Tertiary dodecyl mercaptan. The tests were carried out at 20°C. The degradation was followed by monitoring the disappearance of Tertiary dodecyl mercaptan at various time periods (primary degradation). For this, replicate bottles (two or three per time point) were extracted with acetonitrile for 3 hours on a rotary shaker and the concentration of Tertiary dodecyl mercaptan determined. In addition, the formation of carbon dioxide (mineralization) was also determined at certain time points. The degradation of aniline was determined based on dissolved organic carbon measurements. The concentrations of Tertiary dodecyl mercaptan measured in the experiments using an initial Tertiary dodecyl mercaptan concentration of 20 µM are summarized in Table 5. The carbon dioxide measurements taken during the study indicated that little or no mineralization of Tertiary dodecyl mercaptan was occurring. About Tertiary dodecyl mercaptan Helpful information Tertiary dodecyl mercaptan is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 10 000 to < 100 000 per annum. Tertiary dodecyl mercaptan is used in formulation or re-packing, at industrial sites and in manufacturing. Consumer Uses ECHA has no public registered data indicating whether or in which chemical products the substance might be used. ECHA has no public registered data on the routes by which Tertiary dodecyl mercaptan is most likely to be released to the environment. Article service life ECHA has no public registered data on the routes by which Tertiary dodecyl mercaptan is most likely to be released to the environment. ECHA has no public registered data indicating whether or into which articles the substance might have been processed. Widespread uses by professional workers ECHA has no public registered data indicating whether or in which chemical products the substance might be used. ECHA has no public registered data on the types of manufacture using Tertiary dodecyl mercaptan. ECHA has no public registered data on the routes by which Tertiary dodecyl mercaptan is most likely to be released to the environment. Formulation or re-packing Tertiary dodecyl mercaptan is used in the following products: polymers and pH regulators and water treatment products. Tertiary dodecyl mercaptan has an industrial use resulting in manufacture of another substance (use of intermediates). Release to the environment of Tertiary dodecyl mercaptan can occur from industrial use: formulation of mixtures. Uses at industrial sites Tertiary dodecyl mercaptan is used in the following products: polymers and pH regulators and water treatment products. Tertiary dodecyl mercaptan has an industrial use resulting in manufacture of another substance (use of intermediates). Tertiary dodecyl mercaptan is used in the following areas: mining. Tertiary dodecyl mercaptan is used for the manufacture of: chemicals and rubber products. Release to the environment of Tertiary dodecyl mercaptan can occur from industrial use: as an intermediate step in further manufacturing of another substance (use of intermediates), as processing aid, in processing aids at industrial sites and as processing aid. Manufacture Release to the environment of Tertiary dodecyl mercaptan can occur from industrial use: manufacturing of the substance. Tertiary dodecyl mercaptan is used in lubricant intermediates to produce additives as well as final components to improve lubricant performance in base oils and metal working fluids Tertiary dodecyl mercaptan is a mixture of tertiary mercaptans, predominantly tertiary dodecyl mercaptan (thus the source for its acronym TDM). This product contains highly branched C12H25 alkyl mercaptan isomers, produced by the addition of hydrogen sulfide to propylene tetramer. It is used as a chemical intermediate to introduce bulky C12H25 alkyl-thio substituents into chemical substances. Its major use is as a chain transfer agent to control molecular weight of polymeric systems undergoing free-radical polymerization. Physical state : Liquid Color : Colorless Odor : Repulsive Flash point : 98 - 110 °C Oxidizing properties : no Autoignition temperature : 198 - 230 °C Thermal decomposition : 149 °C Molecular formula : C12H26S Molecular weight : 202,44 g/mol pH : Not applicable Melting point/range -16 °C Boiling point/boiling range : 233 °C Vapor pressure : 4,00 Paat 24 °C Relative density : 0,86 at 16 °C Water solubility : 0,00393 mg/l Method: OECD Test Guideline 105 Partition coefficient: noctanol/water: Pow: 7,43 at 20 °C Viscosity, dynamic : 2,6 cP at 20 °C Relative vapor density : 3 (Air = 1.0) Evaporation rate : < 1 Primary Chemistry: Sulfole® 120 Features & Benefits Sulfolane 120 (+b) Tertiary dodecyl mercaptan is a main component to produce metallic decoration (inks) for food packaging (porcelain, ceramics glass). Tertiary dodecyl mercaptan is also a lubricant additive used to improve lubricant performance in base oils and metal working fluids. Last but not least, it is a chain transfer agent in process where control of molecular weigh is critical from Polymer Modifiers in paint and coatings for emulsion polymerization, adhesives (pressure sensitive adh. for labeling) and surfactants & emulsifiers. Markets Automotive and transportation Polymer and rubber Chemical and plastics industry Polymer engineering Packaging and Paper Paper Paper and board Rigid packaging Specialty paper Paint, coatings and adhesives Acrylic resins Applications Chain transfer agent TDM (Tertiary Dodecyl Mercaptan) is commonly used in the manufacturing process of polymers based on butadiene and styrene (SB latex, SB rubber, ABS...) INDUSTRIAL USE of Tertiary Dodecyl Mercaptan Intermediaries Lubricants and Oil Additives Process regulators Automotive and Transportation Oil additive: to produce final components as well as final components to improve lubricant performance in fatty acids and metalworking fluids We supply a variety of chemicals used in lubricant intermediates. Polymers and rubber applications Normal (n-) dodecylmercaptan is used as reagents in the synthesis of antioxidants that minimize the unwanted effects of processes such as thickness balancing. dodecyl mercaptan, 1-dodecanethiol, lauryl mercaptan, NDDM, CAS # 112-55-0) are used. Consumer uses Plastic and rubber products not covered elsewhere Help on calculated properties New window Property name Property value Reference Molecular weight 202.4 g / mol calculated by PubChem 2.1 (PubChem release 2019.06.18) XLogP3-AA 4.8 calculated by XLogP3 3.0 (PubChem release 2019.06.18) Number of hydrogen bond donors 1 calculated by Cactvs 3.4.6.11 (PubChem release 2019.06.18) Number of hydrogen bond acceptors 1 calculated by Cactvs 3.4.6.11 (PubChem release 2019.06.18) Number of rotary links 3 calculated by Cactvs 3.4.6.11 (PubChem release 2019.06.18) Exact mass 202.175522 g / mol calculated by PubChem 2.1 (PubChem release 2019.06.18) Monoisotopic mass 202.175522 g / mol calculated by PubChem 2.1 (PubChem release 2019.06.18) Topological polar surface 1 Ų calculated by Cactvs 3.4.6.11 (PubChem release 2019.06.18) Number of heavy atoms 13 calculated by PubChem Formal load 0 calculated by PubChem Complexity 176 calculated by Cactvs 3.4.6.11 (PubChem version 2019.06.18) Number of isotopic atoms 0 calculated by PubChem Defined number of atomic stereocenters 0 calculated by PubChem Undefined atomic stereocenter number 0 calculated by PubChem Defined number of bond stereocenters 0 calculated by PubChem Number of undefined binding stereocentre 0 calculated by PubChem Number of covalently bound units 1 calculated by PubChem The compound is canonized Yes Building materials, flooring Materials for flooring (carpet, wood, vinyl flooring) or related to flooring such as wax or floor varnish General manufacturing information Processing sectors of the industry All other basic organic chemical manufacturing Manufacture of paints and coatings Plastic and resin manufacturing Synthetic rubber manufacturing Tertiary dodecyl mercaptan (tertiary dodecyl mercaptan) is commonly used as a chain transfer agent in the manufacturing process of styrene / butadiene latex for use in the carpet and paper industries. A technical gas chromatography has been successfully developed for the measurement of tertiary dodecyl mercaptan based on its sulfur content for material identification, trend analysis, or for monitoring unreacted residual material in finished products. The process uses low thermal mass gas chromatography (LTM-GC) and dual plasma sulfur chemiluminescence detector (DP-SCD) to achieve a high degree of sensitivity and selectivity. Using the described technique, a detection limit of between 0.5 ppm (v / v) tertiary dodecyl mercaptan and less than 1 minimum analysis time can be achieved. The response is linear over four orders of magnitude with a high degree of repeatability less than 5% RSD.
Tertiary Amines
SYNONYMS tertiaeres Amin;Aminyl radicalAmmoniac [French];Ammoniak [German];ammoniac CAS NO:8013-59-0
Tertiary butyl acetate (TBAc)
Acetic acid, tert-butyl ester; 1,1-Dimethyl ethyl acetate; acetic acid, 1,1-dimethylethyl ester; t-Butyl acetate; cas no: 540-88-5