Tert-Butyl hydrogen peroxide
CAS Number: 75-91-2
EC Number: 200-915-7
Molecular Formula: C₄H₁₀O₂
Molecular Weight: 90.12
APPLICATIONS
Tert-Butyl hydrogen peroxide (TBHP)'s production and use as a chemical intermediate may result in its release to the environment through various waste streams(SRC).
Based on a classification scheme, an estimated Koc value of 86(SRC), determined from a structure estimation method, indicates that Tert-Butyl hydrogen peroxide (TBHP) is expected to have high mobility in soil(SRC).
However, hydroperoxides react with a variety of compounds and are reduced readily to the corresponding alcohols.
They are decomposed readily bymultivalent metal ions, are photo- and thermally sensitive and undergo initial oxygen-oxygen bond homolysis, and are attacked readily by free radicals, undergoing induced and self-induced decomposition.
Chemical degradation is expected tobe the dominant fate process in soil(SRC).
The pKa of Tert-Butyl hydrogen peroxide (TBHP) is 12.80, indicating that this compound will exist in the unionized form in the environment.
Volatilization of Tert-Butyl hydrogen peroxide (TBHP) from moist soil surfacesis expected to be an important fate process(SRC) given an estimated Henry's Law constant of 1.6X10-5 atm-cu m/mole(SRC), using a fragment constant estimation method.
Tert-Butyl hydrogen peroxide (TBHP) is expected to volatilize from dry soil surfaces(SRC) based upon a vapour pressure of 5.46 mm Hg at 25 °C.
Utilizing the Japanese MITI test, 0% of the Theoretical BOD was reached in 4 weeks indicating that biodegradation is not an important environmental fate process in soil(SRC).
Tert-Butyl hydrogen peroxide (tBuOOH) is the organic compound with the formula (CH3)3COOH.
Tert-Butyl hydrogen peroxide is a hydroperoxide, in fact one of the most widely used in a variety of oxidation processes, for example the Halcon process.
Furthermore, Tert-Butyl hydrogen peroxide is normally supplied as a 69–70% aqueous solution.
Tert-Butyl hydrogen peroxide (TBHP) provides a readily available and convenient source of active oxygen suitable for diverseoxidation technologies.
Producers of initiators use T-Hydro solution to synthesize many perester, dialkyl peroxide and perketal derivatives.
Tert-Butyl hydrogen peroxide itself serves as a free radical initiator for polymerization, copolymerizations, graftpolymerizations and curing of polymers.
Moreover, Tert-Butyl hydrogen peroxide (TBHP) offers advantages of versatility, regioselectivity, stereoselectivity, chemoselectivity and reactivity control with catalyst choice, mild reaction conditions and bulk availability.
Tert-Butyl hydrogen peroxide (TBHP) finds use in preparing speciality chemicals required by fine chemical and performance chemical industries such as pharmaceuticals and agrochemicals.
Besides, Tert-Butyl hydrogen peroxide (TBHP) can selectively oxidize hydrocarbons, olefins and alcohols.
Asymmetric epoxidation and kinetic resolution with Tert-Butyl hydrogen peroxide (TBHP) can provide access to complex chiral intermediates.
Tert-Butyl hydrogen peroxide is used as an initiator for radical polymerization and in various oxidation process such as Sharpless epoxidation.
Tert-Butyl hydrogen peroxide is involved in the osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions.
Furthermore, Tert-Butyl hydrogen peroxide is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes.
Tert-Butyl hydrogen peroxide plays an important role in the introduction of peroxy groups in organic synthesis.
In addition, Tert-Butyl hydrogen peroxide is used as an oxidant in the Halcon process for the production of propylene oxide.
The standard commercial product (80%, stabilized with water and phosphoric acid) is suitable for curing polyester resins and for the emulsion polymerization of styrene -butadiene rubbers.
Compared to hydrogen peroxide and organic peracids, Tert-Butyl hydrogen peroxide is less reactive, more soluble in organic solvents.
Overall, tert-Butyl hydrogen peroxide is renowned for the convenient handling properties of its solutions.
tert-Butyl hydrogen peroxides solutions in organic solvents are highly stable.
(TBHP) is a clear, colorless, stable and aqueous solution usually available in concentration of approximately 70 wt% TBHP and 30 wt% water.
More to that, tert-Butyl hydrogen peroxide belongs to the alkyl hydroperoxide chemical family.
tert-Butyl hydrogen peroxide is a highly reactive product, with three types of significant physical hazards: flammability, thermal, and decomposition due to contamination.
Applications of tert-Butyl hydrogen peroxide:
Industrially, tert-Butyl hydrogen peroxide is used to prepare propylene oxide.
In the Halcon process, molybdenum-based catalysts are used for this reaction:
(CH3)3COOH + CH2=CHCH3 → (CH3)3COH + CH2OCHCH3
Tert-Butyl hydrogen peroxide is catalyst in polymerization reactions.
Further to that, Tert-Butyl hydrogen peroxide is used to introduce peroxy group into organic molecules, in radical substitution reactions.
Use Areas of Tert-Butyl hydrogen peroxide:
General adhesives and binding agents for a variety of uses
Relating to agricultural, including the raising and farming of animals and growing of crops
Products used to care for apparel (e.g., she polish, products to repair footwear or leather, waterproofing sprays, etc.)
The building or construction process for buildings or boats (includes activities such as plumbing and electrical work, bricklaying, etc)
Materials used in the building process, such as flooring, insulation, caulk, tile, wood, glass, etc.
Flooring materials (carpets, wood, vinyl flooring), or related to flooring such as wax or polish for floors
Wall construction materials, or wall coverings
Catalyst
Drug product, or related to the manufacturing of drugs, veterinary, animal, or pet.
pharmaceutical
Products related to computers or the manufacturing of computers
Products related to the activity of fishing
Includes antifoaming agents, coagulating agents, dispersion agents, emulsifiers, flotation agents, foaming agents, viscosity
adjusters, etc
Includes food packaging, paper plates, cutlery, small appliances such as roasters, etc.; does not include facilities thatmanufacture food
Forestry
The activity of hunting
Related to all forms of cleaning/washing, including cleaning products used in the home, laundry detergents, soaps, de-greasers, spot removers, etc; modifiers included when specific information is known, such as dry cleaning, laundry, soap,window/floor, etc
Materials used in the building process, such as flooring, insulation, caulk, tile, wood, glass, etc.
Wood used as a building material, wood preservatives
The manufacturing of chemicals, or laboratory chemicals.
Related to manufacturing for export.
Furniture, or the manufacturing of furniture
Manufacturing of or related to machinery, for production of cement or food, air/spacecraft machinery, electrical machinery,etc
Related to metals - manufacturing of metals, casting of metals, production of metals, surface treatment of metals, etc
Crude oil, crude petroleum, refined oil products, fuel oils, drilling oils
Various types of paint for various uses, modifiers included when more information is known
Plastic products, industry for plastics, manufacturing of plastics, plastic additives (modifiers included when known)
Raw materials used in a variety of products and industries (e.g. in cosmetics, chemical manufacturing, production of metals,etc); modifiers included when known to indicate what the raw materials are used for.
Rubber products (e.g. tires) and their manufacture
Various types of paint for various uses.
Modifier included when source indicates the product is water-based
Related to the manufacturing of pulp or paper products, or paper products in general
Substances used for preventing, destroying or mitigating pests
Additive for products to promote hardening, used in paints and varnishes, plastics, etc.
Accelerators, activators, oxidation agents, reducing agents, etc
General antioxidants, application indicated if known
Oxidizing/reducing agents
Related to fracking, natural gas, industrial gases
Crude oil, crude petroleum, refined oil products, fuel oils, drilling oils
Surface treatments for metals, hardening agents, corrosion inhibitors, polishing agents, rust inhibitors, water repellants, etc(surfaces to be applied to often not indicated in source description)
Chairs and seats
Tert-Butyl hydrogen peroxide is an important commercial chemical.
Additionally, Tert-Butyl hydrogen peroxide is used in many chemical manufacturing processes and is used in bleaching and deodorizing.
The general population is not likely to be exposed to Tert-Butyl hydrogen peroxide.
If Tert-Butyl hydrogen peroxide is released to the environment, it will be broken down in air.
Tert-Butyl hydrogen peroxide is expected to be broken down by sunlight.
Furthermore, Tert-Butyl hydrogen peroxide will not move into air from moist soil and water surfaces.
Tert-Butyl hydrogen peroxide is unstable and breaks down rapidly to oxygen.
Application Areas of Tert-Butyl hydrogen peroxide:
Industrially, Tert-Butyl hydrogen peroxide is used as a radical polymerization initiator.
For example, its reaction with propene yields propylene oxide and the byproduct t-butanol which can dehydrate to isobutene and convert to MTBE.
Synthesis and production of Tert-Butyl hydrogen peroxide:
Many synthetic routes are available, including:
The reaction of hydrogen peroxide with isobutylene or tert-butyl alcohol in the presence of sulfuric acid
Auto-oxidation of isobutane with oxygen
Tert-Butyl hydrogen peroxide (TBHP) is primarily used in the chemical industry.
TMoreover, ert-Butyl hydrogen peroxide is used as starting material (or intermediate) and as a reactive ingredient (catalyst, initiator or curing agent).
Applications of tert-Butyl hydrogen peroxide are:
The epoxidation of propylene to propylene oxide (intermediate)
Free radical initiator for polymerisations, copolymerisations, graft polymerisations and curing of polymers (plastic industry)
Free radical initiator to polymerise unsaturated monomers, usually to high polymers
Tert-Butyl hydrogen peroxide is mainly used by manufacturers of synthetic lattices or water borne dispersions.
Besides, Tert-Butyl hydrogen peroxide is also used as a component of catalysts systems for unsaturated polyester resins.
Spesific uses of Tert-Butyl hydrogen peroxide:
The synthesis of other organic peroxy molecules (as a precursor of initiators) such as perester, persulphate, dialkyl peroxide and perketal derivatives;
The preparation of speciality chemicals required by fine chemical and performance chemical industries, such as pharmaceuticals and agrochemicals (fungicide).
Tert-Butyl hydrogen peroxide can be dehydrated to isobutene and convert to MTBE.
On a much smaller scale, tert-Butyl hydrogen peroxide is used to produce some fine chemicals by the Sharpless epoxidation.
The use as an ingredient of hardeners for plastics
Hardeners for plastics are also used in the plastic industry
Tert-Butyl hydrogen peroxide is used as a chemical intermediate, a curing agent for polyesters, and a catalyst for polymerization; also used for bleaching and deodorizing.
In addition, Tert-Butyl hydrogen peroxide is a polymerization initiator used to produce specialty chemicals in closed systems.
Tert-Butyl hydrogen peroxide Solution is used for the emulsion polymerization of Styrene, Acrylates and Methacrylates and thecuring of polyester resins.
Suitable to be used as active peroxide in high-pressure polymerization or as an initiator in oxygen combination of Ethylene.
Common applications of Tert-Butyl hydrogen peroxide are acrylate, vinyl acetate, styrene-butadiene production, curing of styrene -polyester resins, oxidizing agent for hydrocarbons.
Recommended storage temperature of Tert-Butyl hydrogen peroxide is between 0 °C and +30 °C.
Tert-Butyl hydrogen peroxide (TBHP)39’s the production and use as a chemical intermediate may result in its release to the environment through various waste streams.
If released to air, a vapour pressure of 5.46 mm Hg at 25 C indicates Tert-Butyl hydrogen peroxide will exist solely as a vapour in the ambient atmosphere.
Vapour-phase Tert-Butyl hydrogen peroxide (TBHP) will be degraded in the atmosphere by reaction with photochemically produced hydroxyl radicals; the half-life for this reaction in air is estimated to be 5 days.
Tert-Butyl hydrogen peroxide (TBHP) will directly photolyze with breakage of the peroxidebond.
If released to soil, Tert-Butyl hydrogen peroxide (TBHP) is expected to have high mobility based upon an estimated Koc of86.
Volatilization from moist soil surfaces may be an important fate process based upon an estimated Henry 39’s Lawconstant of 1.6X10-5 atm-cu m/mole.
The pKa of Tert-Butyl hydrogen peroxide (TBHP) is 12.8, indicating that this compound willexist in the un-ionized form in the environment.
Tert-Butyl hydrogen peroxide (TBHP) may volatilize from dry soil surfaces basedupon its vapour pressure.
Utilizing the Japanese MITI test, 0% of the Theoretical BOD was reached in 4 weeks, indicating that biodegradation is not an important environmental fate process in soil or water.
Tert-Butyl hydrogen peroxide is expected to react rapidly with organic matter in soil and water and be decomposed rapidly by metal ions, which will attenuate all transport processes.
Hydroperoxides would be converted to the corresponding alcohols.
If released into water, Tert-Butyl hydrogen peroxide (TBHP) is not expected to adsorb to suspended solids and sediment based upon the estimated Koc.
However, hydroperoxides react with a variety of compounds and are reduced readily to the corresponding alcohols.
Anestimated BCF of 3 suggests the potential for bioconcentration in aquatic organisms is low.
Occupational exposure to Tert-Butyl hydrogen peroxide (TBHP) may occur through inhalation and dermal contact with this compound at workplaces where Tert-Butyl hydrogen peroxide (TBHP) is produced or used.
The general public is not likely to be exposed to Tert-Butyl hydrogen peroxide.
Industrially, Tert-Butyl hydrogen peroxide is used to prepare propylene oxide.
In the Halcon process, molybdenum-based catalysts are used for this reaction:
(CH3)3COOH + CH2=CHCH3 → (CH3)3COH + CH2OCHCH3
The byproduct t-butanol, which can be dehydrated to isobutene and converted to MTBE.
On a much smaller scale, Tert-Butyl hydrogen peroxide is used to produce some fine chemicals by the Sharpless epoxidation.
Tert-Butyl hydrogen peroxide is an intermediate in the production of propylene oxide and t-butyl alcohol from isobutane and propylene.
More to that, Tert-Butyl hydrogen peroxide is primarily used as an initiator and finishing catalyst in the solution and emulsion polymerization methods for polystyrene and polyacrylates.
Other uses of Tert-Butyl hydrogen peroxide are for the polymerization of vinyl chloride and vinyl acetate and as an oxidation and sulfonation catalyst in bleaching and deodorizing operations.
Tert-Butyl hydrogen peroxide is a strong oxidant and reacts violently with combustible and reducing materials, and metallic and sulfur compounds.
Tert-Butyl hydrogen peroxide is catalyst in polymerization reactions.
Further to that, Tert-Butyl hydrogen peroxide is used to introduce peroxy group into organic molecules, in radical substitution reactions.
Tert-Butyl hydrogen peroxide is used for polymerization, oxidation, sulfonation catalyst, bleaching, deodorizing.
Tert-Butyl hydrogen peroxide is used as an oxidant in the Halcon process for the production of propylene oxide.
The standard commercial product (80%, stabilized with water and phosphoric acid) is suitable for curing polyester resins and for the emulsion polymerization of styrene-butadiene rubbers.
Industry Uses of Tert-Butyl hydrogen peroxide:
Fillers
Fuels and fuel additives
Intermediates
Paint additives and coating additives not described by other categories
Plasticizers
Plating agents and surface treating agents
Process regulators
Processing aids, not otherwise listed
Consumer Uses
Electrical and electronic products
Fuels and related products
Paints and coatings
Plastic and rubber products not covered elsewhere
Water treatment products
Tert-Butyl hydrogen peroxide is used to initiate polymerization reactions and in organic syntheses to introduce peroxy groups into the molecule.
Additionally, Tert-Butyl hydrogen peroxide is catalyst in polymerization reactions.
Tert-Butyl hydrogen peroxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation.
Furthermore, Tert-Butyl hydrogen peroxide is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions.
Furthermore, tert-Butyl hydrogen peroxide is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes.
tert-Butyl hydrogen peroxide plays an important role for the introduction of peroxy groups in organic synthesis.
DESCRIPTION
Tert-Butyl hydrogen peroxide is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
Moreover, Tert-Butyl hydrogen peroxide is widely used in a variety of oxidation processes.
Production Methods:
Tert-Butyl hydrogen peroxide is produced by the liquid-phase reaction of isobutane and molecular oxygenor by mixing equimolar amounts of t-butyl alcohol and 30–50% hydrogen peroxide.
Besides, Tert-Butyl hydrogen peroxide can also be prepared from t-butyl alcohol and 30% hydrogen peroxide in the presence of sulfuric acid or by oxidation of tert-butylmagnesium chloride. The manufacturing process of Tert-Butyl hydrogen peroxide is in a closed system.
Tert-Butyl hydrogen peroxide (tBuOOH) is the organic compound with the formula (CH3)3COOH.
In addition, Tert-Butyl hydrogen peroxide is one of the most widely used hydroperoxides in a variety of oxidation processes, for example the Halcon process.
Tert-Butyl hydrogen peroxide is normally supplied as a 69–70% aqueous solution.
Compared to hydrogen peroxide and organic peracids, Tert-Butyl hydrogen peroxide is less reactive and more soluble in organic solvents.
Overall, Tert-Butyl hydrogen peroxide is renowned for the convenient handling properties of its solutions.
Its solutions in organic solvents are highly stable.
Tert-Butyl hydrogen peroxide is an alkyl hydroperoxide in which the alkyl group is tert-butyl.
More to that, Tert-Butyl hydrogen peroxide is widely used in a variety of oxidation processes.
Tert-Butyl hydrogen peroxide has a role as an antibacterial agent and an oxidising agent.
Tert-Butyl hydrogen peroxide is a natural product found in Apium graveolens.
Further to that, Tert-Butyl hydrogen peroxide is a watery odorless colorless liquid.
Tert-Butyl hydrogen peroxide floats on and dissolves slowly in water.
Additionally, Tert-Butyl hydrogen peroxide is an organic peroxide widely used in a variety of oxidation processes.
Chemical Properties of tert-Butyl hydrogen peroxide:
Tert-Butyl hydrogen peroxide (TBHP) is a water-white liquid commonly commercially available as a 70% solution in water; 80% solutions are also available.
Furthermore, Tert-Butyl hydrogen peroxide is used to initiate polymerization reactions and in organic syntheses to introduce peroxy groups into the molecule.
Tert-Butyl hydrogen peroxide vapor can burn in the absence of air and may be flammable at either elevated temperature or at reduced pressure.
Fine mist/spray may be combustible at temperatures below the normal flash point.
When evaporated, the residual liquid will concentrate tert-Butyl hydrogen peroxide content and may reach an explosive concentration (＞90%).
Closed containers may generate internal pressure through the degradation of tert-Butyl hydrogen peroxide to oxygen .
Tert-Butyl hydrogen peroxide is a highly reactive product.
The three types of significant physical hazards are flammability, thermal, and decomposition due to contamination.
To minimize these hazards, avoid exposure to heat, fire, or any condition that will concentrate the liquid material.
Store Tert-Butyl hydrogen peroxide away from heat, sparks, open flames, foreign contaminants, combustibles, and reducing agents.
PROPERTIES
Molecular Weight: 90.12
XLogP3-AA: 0.6
Hydrogen Bond Donor Count: 1
Hydrogen Bond Acceptor Count: 2
Rotatable Bond Count: 1
Exact Mass: 90.068079557
Monoisotopic Mass: 90.068079557
Topological Polar Surface Area: 29.5 Ų
Heavy Atom Count: 6
Formal Charge: 0
Complexity: 35.3
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes
FIRST AID
Eyes:
First check the victim for contact lenses and remove if present.
Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center.
Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician.
IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Skin:
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing.
Gently wash all affected skin areas thoroughly with soap and water.
IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop.
IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.
Inhalation:
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air.
If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital.
Provide proper respiratory protection to rescuers entering an unknown atmosphere.
Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing.
Ingestion:
DO NOT INDUCE VOMITING.
Corrosive chemicals will destroy the membranes of the mouth, throat, and esophagus and volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting.
Thus, the risk of increasing the medical problems by inducing vomiting of a volatile corrosive chemical is very high.
If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center.
IMMEDIATELY transport the victim to a hospital.
If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body.
DO NOT INDUCE VOMITING.
IMMEDIATELY transport the victim to a hospital.
HANDLING AND STORAGE
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
Keep combustibles (wood, paper, oil, etc.) away from spilled material.
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Keep substance wet using water spray.
Stop leak if you can do it without risk.
Small Spill:
Pick up with inert, damp, non-combustible material using clean, non-sparking tools and place into loosely covered plastic containers for later disposal.
Large Spill:
Wet down with water and dike for later disposal.
Prevent entry into waterways, sewers, basements or confined areas.
DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.
Store in original container.
Keep container tightly closed in a dry and well-ventilated place.
Containers which are opened must be carefully resealed and kept upright to prevent leakage.
Recommended storage temperature 2 - 8 °C
SYNONYMS
2-hydroperoxy-2-methylpropane
2-methylpropane-2-peroxol
Hydroperoxide, 1,1-Dimethylethyl
t-Butyl hydroperoxide
Tert-Butyl hydrogen peroxide
Tert-Butyl hydrogen peroxide
Tert-Butyl hydrogen peroxide
Tert-Butyl hydrogen peroxide
Tert-Butyl hydrogen peroxide (upper limit: 72% w/w; typical concentration: 70% w/w)
Tert-Butyl hydrogen peroxide;75-91-2;TBHP;T-Butyl;hydroperoxide;tert-Butylhydroperoxide;Perbutyl H;t-
Butylhydroperoxide;2-Hydroperoxy-2-methylpropane;Cadox TBH;1,1-Dimethylethyl hydroperoxide;Hydroperoxide, 1,1-
dimethylethyl;tert-Butyl hydrogen peroxide;Terc. butylhydroperoxid;Hydroperoxyde de butyle tertiaire;Hydroperoxide, tertbutyl;
Slimicide;DE-488;Tertiary butyl hydroperoxide;Trigonox a-75;Trigonox A-W70;TBHP-70;NSC 672;Tertiary-butyl
hydroperoxide;1,1-Dimethylethylhydroperoxide;tert-Butyl-hydroperoxide;Dimethylethyl hydroperoxide;T-Hydro;tBuOOH;t-
BuOOH;UNII-955VYL842B;Tert-Butyl hydrogen peroxide solution;CHEBI:64090;955VYL842B;Tert-Butyl hydrogen peroxide (70%
Solution in Water);MFCD00002130;Tert-Butyl hydrogen peroxide, 70% solution in water;Caswell No. 130BB;Trigonox A-75
[Czech];terc.Butylhydroperoxid [Czech];CCRIS 5892;HSDB 837;terc.Butylhydroperoxid;terc. Butylhydroperoxid [Czech];tert
Butylhydroperoxide;EINECS 200-915-7;DE-488;BRN 1098280;Hydroperoxyde de butyle tertiaire [French];AI3-
50541;Kayabutyl H;tert-BuOOH;Hydroperoxide, 1,1-dimethylethyl-;tBOOH;Perbutyl H 69;Perbutyl H 69T;Perbutyl H80;Luperox TBH 70X;t-butyl-hydroperoxide;terbutyl hydroperoxide;tert-butyhydroperoxide;tert-C4H9OOH;Trigonox A-W
70;t-butyl hydrogenperoxide;t-butyl-hydrogenperoxide;tert.-butylhydroperoxide;tert.butyl
hydroperoxide;tertiarybutylhydroperoxide;tertbutylhydrogen peroxide;t-butyl hydrogen peroxide;tert.-butyl
hydroperoxide;ACMC-1BM3U;DSSTox_CID_4693;tert-butylhydrogen peroxide;EC 200-915-
7;DSSTox_RID_78866;DSSTox_GSID_31209;tertiary butyl hydro peroxide;Hydroperoxide,1-dimethylethyl;Trigonox A-80
(Salt/Mix);UN 2093 (Salt/Mix);UN 2094 (Salt/Mix);USP -800 (Salt/Mix);CHEMBL348399;NSC672;DTXSID9024693;tert-Butyl
hydroperoxide (8CI);Tert-Butyl hydrogen peroxide, >90% with water [Forbidden];WLN: QOX1&1&1;tert-Butyl-hydroperoxide
solution;NSC-672;2-Methyl-prop-2-yl-hydroperoxide;ZINC8585869;CC(C)([OH+][O-])C;Tox21_200838;ANW-43954;Aztec tbutyl
Hydroperoxide-70, Aq;Tert-Butyl hydrogen peroxide solution, CP;AKOS000121070;2-$l^{1}-oxidanyloxy-2-
methylpropane;NCGC00090725-01;NCGC00090725-02;NCGC00090725-03;NCGC00258392-01;Hydroperoxide, 1,1-
dimethylethyl (9CI);Tert-Butyl hydrogen peroxide (70% in Water);Tert-Butyl hydrogen peroxide, >90% with water;B3153;FT-
0657109;Q286326;J-509597;Tert-Butyl hydrogen peroxide solution, ~5.5 M in decane;F1905-8242;Tert-Butyl hydrogen peroxide
solution (TBHP), 70% in H2O;Tert-Butyl hydrogen peroxide solution, 5.0-6.0 M in decane;Tert-Butyl hydrogen peroxide solution, 5.0-6.0
M in nonane;Luperox(R) TBH70X, Tert-Butyl hydrogen peroxide solution, 70 wt. % in H2O;Tert-Butyl hydrogen peroxide solution, ~80%
in di-tert-butyl peroxide/water 3:2;Tert-Butyl hydrogen peroxide solution, packed in FEP bottles, ~5.5 M in decane (over molecular
sieve 4??);Tert-Butyl hydrogen peroxide solution, packed in FEP bottles, ~5.5 M in nonane (over molecular sieve 4 ??)
Tert-Butyl hydrogen peroxide
75-91-2
TBHP
T-Butyl hydroperoxide
tert-Butylhydroperoxide
2-Hydroperoxy-2-methylpropane
Perbutyl H
t-Butylhydroperoxide
1,1-Dimethylethyl hydroperoxide
Cadox TBH
Hydroperoxide, 1,1-dimethylethyl
tert-Butyl hydrogen peroxide
Terc. butylhydroperoxid
Hydroperoxyde de butyle tertiaire
Hydroperoxide, tert-butyl
Slimicide DE-488
Tertiary butyl hydroperoxide
Trigonox a-75
Trigonox A-W70
TBHP-70
1,1-Dimethylethylhydroperoxide
NSC 672
t-BuOOH
Tertiary-butyl hydroperoxide
tert-Butyl-hydroperoxide
Dimethylethyl hydroperoide
T-Hydro
Perbutyl H 69T
Luperox TBH 70X
Trigonox A-W 70
Tert-Butyl hydrogen peroxide solution
CHEBI:64090
NSC-672
955VYL842B
Tert-Butyl hydrogen peroxide (70% Solution in Water)
Caswell No. 130BB
Trigonox A-75 [Czech]
tBOOH
terc.Butylhydroperoxid [Czech]
CCRIS 5892
HSDB 837
terc.Butylhydroperoxid
terc. Butylhydroperoxid [Czech]
tert Butylhydroperoxide
EINECS 200-915-7
DE 488
DE-488
BRN 1098280
Hydroperoxyde de butyle tertiaire [French]
UNII-955VYL842B
AI3-50541
Kayabutyl H
tBuOOH
tert-BuOOH
Hydroperoxide, 1,1-dimethylethyl-
Perbutyl H 69
Perbutyl H 80
t-butyl-hydroperoxide
terbutyl hydroperoxide
tert-butyhydroperoxide
tert-C4H9OOH
t-butyl hydrogenperoxide
t-butyl-hydrogenperoxide
tert.-butylhydroperoxide
tert.butyl hydroperoxide
tertiarybutylhydroperoxide
tertbutylhydrogen peroxide
t-butyl hydrogen peroxide
tert.-butyl hydroperoxide
KAYABUTYL H 70
DSSTox_CID_4693
tert-butylhydrogen peroxide
EC 200-915-7
DSSTox_RID_78866
DSSTox_GSID_31209
tertiary butyl hydro peroxide
Hydroperoxide,1-dimethylethyl
Trigonox A-80 (Salt/Mix)
UN 2093 (Salt/Mix)
UN 2094 (Salt/Mix)
USP -800 (Salt/Mix)
CHEMBL348399
NSC672
DTXSID9024693
Tert-Butyl hydrogen peroxide (8CI)
Tert-Butyl hydrogen peroxide, >90% with water [Forbidden]
WLN: QOX1&1&1
tert-Butyl-hydroperoxide solution
2-Methyl-prop-2-yl-hydroperoxide
ZINC8585869
Tox21_200838
Aztec t-butyl Hydroperoxide-70, Aq
MFCD00002130
Tert-Butyl hydrogen peroxide [II]
Tert-Butyl hydrogen peroxide [MI]
Tert-Butyl hydrogen peroxide solution, CP
AKOS000121070
Tert-Butyl hydrogen peroxide [HSDB]
NCGC00090725-01
NCGC00090725-02
NCGC00090725-03
NCGC00258392-01
Tert-Butyl hydrogen peroxide aqueous solution
Hydroperoxide,1,1-dimethylethyl (9CI)
Tert-Butyl hydrogen peroxide (70% in Water)
Tert-Butyl hydrogen peroxide, >90% with water
B3153
FT-0657109
Tert-Butyl hydrogen peroxide, 70% solution in water
Q286326
J-509597
Tert-Butyl hydrogen peroxide solution, ~5.5 M in decane
F1905-8242
Tert-Butyl hydrogen peroxide solution (TBHP), 70% in H2O
Tert-Butyl hydrogen peroxide solution, 5.0-6.0 M in decane
Tert-Butyl hydrogen peroxide solution, 5.0-6.0 M in nonane
Luperox(R) TBH70X, Tert-Butyl hydrogen peroxide solution, 70 wt. % in H2O
Tert-Butyl hydrogen peroxide solution, ~80% in di-tert-butyl peroxide/water 3:2
Tert-Butyl hydrogen peroxide solution, packed in FEP bottles, ~5.5 M in decane (over molecular sieve 4??)
Tert-Butyl hydrogen peroxide solution, packed in FEP bottles, ~5.5 M in nonane (over molecular sieve
