4,4-Dithiodimorpholine molecule contains a total of 30 atom(s).
4,4-Dithiodimorpholine is a white or similar white crystal.
CAS Number: 103-34-4
EC Number: 203-103-0
MDL Number: MFCD00023319
Molecular Formula: C8H16N2O2S2
4,4'-DITHIODIMORPHOLINE, 103-34-4, Morpholine, 4,4'-dithiobis-, Sulfasan, 4,4-Dithiodimorpholine, Sulfasan R, Accel R, 4,4'-Dithiomorpholine, Morpholine disulfide, Morpholino disulfide, 4,4'-Dithiobismorpholine, Dimorpholine disulfide, Dimorpholino disulfide, Bismorpholino disulfide, Deovulc M, Sanfel R,
Dithiobismorpholine, Morpholinodisulfide, Vanax A, Disulfide, dimorpholino-, Usaf ek-t-6645, Usaf B-17, Dimorpholine N,N'-disulfide, N,N-Dithiodimorpholine, 4,4'-Dithiobis(morpholine), N,N'-Bismorpholine disulfide, N,N'-Dimorpholine Disulfide, Morpholine, 4,4'-dithiodi-, N,N'-Dithiodimorfolin, DITHIODIMORPHOLINE, 4-(morpholin-4-yldisulfanyl)morpholine, NSC 65239, Dithiobis(morpholine), N,N'-Dithiodimorpholine, DTXSID8026698, M786P489YF, NSC65239,
NSC-65239, Vulnoc, DTXCID706698, Di(morpholin-4-yl) disulphide, 4-(4-Morpholinyldisulfanyl)morpholine, CAS-103-34-4, Morpholine, N,N'-disulfide-,
CCRIS 8923, HSDB 5351, EINECS 203-103-0, 4,4/'-Dithiodimorpholine, BRN 0126214, UNII-M786P489YF, AI3-08625, Sulfazan R, 4-(morpholinodisulfanyl)morpholine, Dimorpholinodisulfide, Naugex SD-1, Akrochem accelerator R, Morpholine,4'-dithiodi-, 1,2-dimorpholinodisulfane, Morpholine,4'-dithiobis-, 4,4'-dithio-dimorpholine, N,N'-DimorpholineDisulfide, EC 203-103-0, Bis(4-morpholinyl)disulfide, Morpholine, N,N'-disulfide, N,N'-Dithiobis(morpholine), NCIOpen2_003134, 4-27-00-00613 (Beilstein Handbook Reference), 4,4'-Dimorpholine disulphide, SCHEMBL137538, CHEMBL582932, HLBZWYXLQJQBKU-UHFFFAOYSA-, MORPHOLINE N,N'-DISULFIDE, DITHIODIMORPHOLINE, 4,4'-, 4-morpholin-4-yldisulfanylmorpholine, Tox21_201775, Tox21_303110, BDBM50414924, MFCD00023319, AKOS015897388, WLN: T6N DOTJ ASS-AT6N DOTJ, 4,4'-DITHIODIMORPHOLINE [MI], 4,4'-DITHIODIMORPHOLINE [HSDB], 4-(4-Morpholinyldisulfanyl)morpholine #, NCGC00249116-01, NCGC00257082-01, NCGC00259324-01, AS-57709, CS-0196466, D0282, FT-0657982, NS00006501, E78171, Q27283591, InChI=1/C8H16N2O2S2/c1-5-11-6-2-9(1)13-14-10-3-7-12-8-4-10/h1-8H2, N,N'-Dimorpholine disulfide, N,N'-Dithiobis(morpholine), 4-(Morpholin-4-yldisulfanyl)morpholine, Morpholine, 4,4'-dithiobis-, Morpholine, 4,4'-dithiobis-, Accel R, Bismorpholino disulfide, Dimorpholine disulfide, Dimorpholino disulfide, Disulfide, dimorpholino-, Dithiobis(morpholine), Morpholine disulfide, Morpholine, 4,4'-dithiodi-, Morpholino disulfide, N,N'-Bismorpholine disulfide, N,N'-Dithiodimorpholine, Sulfasan, Sulfasan R, USAF EK-T-6645, USAF B-17, 4,4'-Dithiobis(morpholine), 4,4'-Dithiomorpholine, N,N'-Dithiodimorfolin, Sulfazan R, 4,4'-Dimorpholine disulphide, Akrochem accelerator R, Dimorpholine N,N'-disulfide, Morpholine, N,N'-disulfide, Naugex SD-1, Vanax A, Deovulc M, NSC 65239, Sanfel R, di(morpholin-4-yl) disulphide, N,N'-Dithiobismorpholine, N,N'-Dithiodimorpholine, Morpholine disulfide, Morpholinodisulfide, N,N'-Bismorpholine disulfide, 4,4'-DITHIOBIS(MORPHOLINE), 4,4'-Dithiomorpholine, Bismorpholino disulfide, Di(morpholin-4-yl) disulphide, Dimorpholine disulfide, Dimorpholino disulfide, Morpholine, 4,4'-dithiobis-, Accel R, Bismorpholino disulfide, Dimorpholine disulfide, Dimorpholino disulfide, Disulfide, dimorpholino-, Dithiobis(morpholine), Morpholine disulfide, Morpholine, 4,4'-dithiodi-, Morpholino disulfide, N,N'-Bismorpholine disulfide, N,N'-Dithiodimorpholine,
Sulfasan, Sulfasan R, USAF EK-T-6645, USAF B-17, 4,4'-Dithiobis(morpholine), 4,4'-Dithiomorpholine, N,N'-Dithiodimorfolin, Sulfazan R, 4,4'-Dimorpholine disulphide, Akrochem accelerator R, Dimorpholine N,N'-disulfide, Morpholine, N,N'-disulfide, Naugex SD-1, Vanax A, Deovulc M, NSC 65239, Sanfel R,
di(morpholin-4-yl) disulphide, N,N'-disulfide-Morpholine, DTDM, Dimorpholine N,N'-disulfide, Sulfasan R,, Morpholine, 4',4'-dithiodimorpholine, 4,4-dithiomorpholine, 4,4-dithiodimorpholine, morpholine disulfide, 4,4-dithiodimorpholine,(4,4-dimorpholine disulphide), 4,4'-dithio dimorpholine, 4,4'-dithiodimorpholine, 4,4'-dithiodimorpholinesulfasan(r)r, morpholinen,n'-disulfide, n,n'-dimorpholinedisulfide, n,n'-dithiobis(morpholine), vanaxa, vanaxafinegrind, vanaxarodform, 4,4'-dimorpholinedisulfide, 4,4'-dithiomorpholine, dtdm, dithiomorpholine, dimorpholinen,n'-disulfide, 4-(4-morpholinyldisulfanyl)morpholine, 4,4'-dithiobis(morpholine), 4,4'-dithiobis-morpholin, 4,4'-dithiobismorpholine, 4,4'-dithiobis-morpholine, 4,4'-dithiodi-morpholin, 4,4'-disulfanediyldimorpholine, 1,1'-[disulfanediylbis(carbonothioyloxy)]diethane, Rubber Accelerator DTDM, Rubber Vulcanizing Agent DTDM, Vulcanising Agent DTDM, 203-103-0, 4,4'-disulfanediyl-bis-morpholine, 4,4'-Disulfanediyldimorpholine, 4,4'-Dithiobis[morpholine], 4Mmorpholin-4-yldisulfanylmorpholine, accelr, deovulcm, DIMORPHOLINE DISULFIDE, Dimorpholine N,N'-disulfide, dimorpholinodisulfide, dithiodimorpholine, DTDM, EINECS 203-103-0, MFCD00023319, Morpholine N,N'-disulfide, Morpholine, 4,4'-dithiobis-, Morpholine, N,N'-disulfide, N,N'-DIMORPHOLINE DISULFIDE, N,N'-DITHIOBIS(MORPHOLINE), N,N'-dithio-bis-morpholine, sanfelr, SULFASAN(R) R, Sulfazan R, usafb-17, VANAX A, VANAX A FINE GRIND, VANAX A RODFORM, vulnoc,
SULFASAN(R) R, Morpholine N,N'-disulfide, N,N'-DIMORPHOLINE DISULFIDE, N,N'-DITHIOBIS(MORPHOLINE), VANAX A, VANAX A FINE GRIND, VANAX A RODFORM, 4Mmorpholin-4-yldisulfanylmorpholine, DTDM, 4,4'-d, accelr, vulnoc, VANAX A, sanfelr, Accel R, deovulcm, usafb-17, USAF B-17, SULFASAN(R) R, Morpholine N,N'-disulfide, N,N'-DIMORPHOLINE DISULFIDE, N,N'-DITHIOBIS(MORPHOLINE), VANAX A, VANAX A FINE GRIND, VANAX A RODFORM, 4Mmorpholin-4-yldisulfanylmorpholine
4,4'-Dithiobis(morpholine), 4,4'-Dithiomorpholine, Accel R, Bismorpholino disulfide, Deovulc M, Dimorpholine N,N'-disulfide, Dimorpholine disulfide, Dimorpholino disulfide, Disulfide, dimorpholino-, Dithiobismorpholine, Morpholine disulfide, Morpholine, 4,4'-dithiobis-, Morpholine, 4,4'-dithiodi-, Morpholine, N,N'-disulfide-, Morpholino disulfide, Morpholinodisulfide, N,N'-Bismorpholine disulfide, N,N-Dithiodimorpholine, Sanfel R, Sulfasan, Sulfasan R, Vanax A, Vulnoc, DTDM, Morpholine disulfide, 4,4'-Dithiodimorpholin, SULFASAN(R) R, Morpholine N,N'-disulfide, N,N'-DIMORPHOLINE DISULFIDE, N,N'-DITHIOBIS(MORPHOLINE), VANAX A, VANAX A FINE GRIND, VANAX A RODFORM, 4,4'-DITHIODIMORPHOLINE, Morpholine,4,4′-dithiobis-, Morpholine,4,4′-dithiodi-, 4,4′-Dithiobis[morpholine], 4,4′-Dithiodimorpholine, Morpholine disulfide, Sulfasan R, Sulfasan, N,N′-Dithiodimorpholine, N,N′-Bismorpholine disulfide, Bismorpholino disulfide, Accel R, Morpholinodisulfide, N,N′-Dimorpholinyl disulfide, Sanfel R, Vanax A, Bismorpholine disulfide, N,N′-Dithiobis[morpholine], Deovulc M, Di(4-morpholinyl) disulfide, Rhenocure M/G, Vulnoc R, Sulfasan DTDM, DTDM, Actor R, NSC 65239, Rhenocure M, Nocmaster R 80E, DTDM 80, Rhenogran DTDM 80, Sulphasan R, TT 106, 39393-19-6, 186983-49-3, 1081512-50-6, dimorpholinodisulfide, deovulcm, N,N-Dimorpholine Disulfide, MFCD00023319, 4,4-Dithiobis[morpholine], dithiodimorpholine, vulnoc, accelr, N,N-Dithiobis(morpholine), Sulfazan R, usafb-17, 4,4-Dithiodimorpholine, N,N-dithio-bis-morpholine, sanfelr, EINECS 203-103-0, Morpholine, 4,4-dithiobis-, 4,4-disulfanediyl-bis-morpholine, Dimorpholine N,N-disulfide, VANAX A, Morpholine, N,N-disulfide, DTDM, 4,4-Disulfanediyldimorpholine, dtdm, DTDM, vanaxa, VANAX A, vanaxarodform, SULFASAN(R) R, VANAX A RODFORM, vanaxafinegrind, dithiomorpholine, VANAX A FINE GRIND, 4,4-dithiomorpholine, morpholine disulfide, 4,4'-dithiomorpholine, 4,4-dithiodimorpholine, 4,4'-dithiodimorpholine, Rubber Accelerator DTDM, 4,4'-dithiodi-morpholin, morpholinen,n'-disulfide, 4,4'-dithiobismorpholine, 4,4'-dithio dimorpholine, 4,4'-dithiobis-morpholin, 4,4'-dithiobis-morpholine, Morpholine N,N'-disulfide, n,n'-dimorpholinedisulfide, 4,4'-dimorpholinedisulfide, dimorpholinen,n'-disulfide, n,n'-dithiobis(morpholine), 4,4'-dithiobis(morpholine), N,N'-DITHIOBIS(MORPHOLINE), N,N'-DIMORPHOLINE DISULFIDE, di(morpholin-4-yl) disulphide, 4,4'-disulfanediyldimorpholine, di(morpholin-4-yl) disulphide, 4,4'-dithiodimorpholinesulfasan(r)r, 4Mmorpholin-4-yldisulfanylmorpholine, 4-(4-morpholinyldisulfanyl)morpholine, 1,1'-[disulfanediylbis(carbonothioyloxy)]diethane, 4,4-dithiodimorpholine,(4,4-dimorpholine disulphide)
Morpholine,4,4'-dithiodi- (6CI,7CI,8CI), 4,4'-Dithiobis[morpholine], 4,4'-Dithiodimorpholine, Accel R, Actor R, Bismorpholine disulfide, Bismorpholino disulfide, DTDM, Deovulc M, Di(4-morpholinyl) disulfide, Morpholine disulfide, Morpholinodisulfide, N,N'-Bismorpholine disulfide, N,N'-Dimorpholinyl disulfide, N,N'-Dithiobis[morpholine], N,N'-Dithiodimorpholine, NSC 65239, Nocmaster R 80E, Rhenocure M, RhenocureM/G, Sanfel R, Sulfasan, Sulfasan DTDM, Sulfasan R, Vanax A, Vulnoc R, Rubber accelerator DTDM, 4',4'-dithiodimorpholine, 4,4-dithiomorpholine, 4,4-dithiodimorpholine, morpholine disulfide, 4,4-dithiodimorpholine,(4,4-dimorpholine disulphide), 4,4'-dithio dimorpholine, 4,4'-dithiodimorpholine, 4,4'-dithiodimorpholinesulfasan(r)r, morpholinen,n'-disulfide, n,n'-dimorpholinedisulfide, n,n'-dithiobis(morpholine), vanaxa, vanaxafinegrind, vanaxarodform, 4,4'-dimorpholinedisulfide, 4,4'-dithiomorpholine, dtdm, dithiomorpholine, dimorpholinen,n'-disulfide, 4-(4-morpholinyldisulfanyl)morpholine, 4,4'-dithiobis(morpholine), 4,4'-dithiobis-morpholin, 4,4'-dithiobismorpholine, 4,4'-dithiobis-morpholine, 4,4'-dithiodi-morpholin, 4,4'-disulfanediyldimorpholine, 1,1'-[disulfanediylbis(carbonothioyloxy)]diethane, Rubber Accelerator DTDM, Rubber Vulcanizing Agent DTDM, Vulcanising Agent DTDM,
4,4-Dithiodimorpholine is suitable for vulcanizing temperature between 140°C to 200°C.
4,4-Dithiodimorpholine has no blooming and pollution and is easy to disperse in sizing materials with good processability.
4,4-Dithiodimorpholine improves reducibility resistance of vulcanizing rubber.
4,4-Dithiodimorpholine exhibits excellent thermal and anti-oxidative performance to produce dynamic heat resistance in rubber products.
4,4-Dithiodimorpholine helps to reduce heat build-up property in NR and SBR.
Store 4,4-Dithiodimorpholine in a cool and dry place with good ventilation.
4,4-Dithiodimorpholine molecule contains a total of 30 atom(s).
There are 16 Hydrogen atom(s), 8 Carbon atom(s), 2 Nitrogen atom(s), 2 Oxygen atom(s), and 2 Sulfur atom(s).
A chemical formula of 4,4-Dithiodimorpholine can therefore be written as: C8H16N2O2S2
The chemical formula of 4,4-Dithiodimorpholine shown above is based on the molecular formula indicating the numbers of each type of atom in a molecule without structural information, which is different from the empirical formula which provides the numerical proportions of atoms of each type.
The chemical formula of 4,4-Dithiodimorpholine is the basis of stoichiometry in chemical equations, i.e., the calculation of relative quantities of reactants and products in chemical reactions.
The law of conservation of mass dictates that the quantity of each element given in the chemical formula of 4,4-Dithiodimorpholine does not change in a chemical reaction.
Thus, each side of the chemical equation must represent the same quantity of any particular element based on the chemical formula of 4,4-Dithiodimorpholine.
4,4-Dithiodimorpholine is the offering body of the sulphur.
4,4-Dithiodimorpholine will release a percentage of 27 active sulphur in the temperature of vulcanization.
4,4-Dithiodimorpholine is registered under the REACH Regulation and is manufactured in and/or imported to the European Economic Area, at ≥ 100 to < 1 000 tonnes per annum.
4,4-Dithiodimorpholine, synonymous with DTDM and Vulcanizing Agent DTDM, is a sulphur donor vulcanizing agent for efficient vulcanization and semi-efficient vulcanization cure systems.
4,4-Dithiodimorpholine is a white crystline powder or granule that is primarily used in the production of synthetic rubbers and adhesives.
4,4-Dithiodimorpholine is a vulcanizing agent and promoter of natural and synthetic rubber, it can release the sulphur in the vulcanizing temperature.
4,4-Dithiodimorpholine is a white or similar white crystal.
4,4-Dithiodimorpholine is an organic compound that has been used in a variety of scientific research applications.
4,4-Dithiodimorpholine will produce a high connecting effect to the rubber, part or whole replace the sulphur, so make the active sulphur gain an ideal physical machine function.
That makes up half effective structure rubber tesist not only fatigue but also oxidation.
According to 4,4-Dithiodimorpholine’s special chemical structure in the performance of vulcanized agent ,promoter, anti- oxidantand prevent coking comprehensive effect.
4,4-Dithiodimorpholine is non flammable.
4,4-Dithiodimorpholine, synonymous with DTDM and Vulcanizing Agent DTDM, is a sulphur donor vulcanizing agent for efficient vulcanization and semi-efficient vulcanization cure systems.
4,4-Dithiodimorpholine is a white crystline powder or granule that is primarily used in the production of synthetic rubbers and adhesives.
4,4-Dithiodimorpholine is a white, solid, crystalline compound with a molecular weight of 256.35 g/mol.
4,4-Dithiodimorpholine is insoluble in water, but soluble in polar organic solvents.
4,4-Dithiodimorpholine is a versatile reagent and has been used in a variety of organic and inorganic syntheses.
4,4-Dithiodimorpholine does not spray, does not pollute, and is easy to disperse in the rubber compound, and has good processing performance.
4,4-Dithiodimorpholine releases high-efficiency vulcanization rubber with high-efficiency vulcanization properties, which can significantly improve the resistance of vulcanizates.
4,4-Dithiodimorpholine can decompose morpholine free radicals with amine antioxidants in the rubber compound, which can make the vulcanized rubber have excellent heat and oxidation resistance.
4,4-Dithiodimorpholine has excellent thermal properties and is ideal for the manufacture of dynamic heat-resistant rubber products.
4,4-Dithiodimorpholine can reduce the heat-generating NR and SNR and is an ideal rubber vulcanizing agent.
With the increase of people's environmental protection concepts and health concerns, it has been found that the vulcanizing agents 4,4-Dithiodimorpholine and thiuram products will cleave at the vulcanization temperature to release secondary amino-based molecular fragments, which can be combined with the nitroso donor to produce carcinogens.
Nitrosamines, so the production and application of vulcanizing agents 4,4-Dithiodimorpholine and thiurams are subject to the limits and warnings of European and American countries and environmental regulations.
At present, the new vulcanizing agent DTDC (N, N-di(ε-caprolactam) disulfide) has attracted international attention due to the fact that it does not produce nitrosamines during vulcanization.
It is considered to be a vulcanizing agent 4,4-Dithiodimorpholine and disulfide or hexasulfurate.
The best alternative to M, replacing the vulcanizing agent 4,4-Dithiodimorpholine with the same amount, without changing the formulation and process of the compound.
4,4-Dithiodimorpholine is white or yellowish needle-like crystal.
A chemical formula of 4,4-Dithiodimorpholine can therefore be written as: C8H16N2O2S2.
4,4-Dithiodimorpholine is white or light yellow crystal (or powder).
4,4-Dithiodimorpholine is white or yellowish needle-like crystal.
4,4-Dithiodimorpholine is a white crystalline or powder.
Specific gravity of 4,4-Dithiodimorpholine is 1.28-1.32.
4,4-Dithiodimorpholine has no poison.
4,4-Dithiodimorpholine is soluble in benzene, alcohol and acetone.
4,4-Dithiodimorpholine is insoluble in water.
The vulcanizing agent 4,4-Dithiodimorpholine can adapt to the vulcanization temperature of 140 °C-200 °C, and the scorch safety is good.
After reaching the normal vulcanization temperature, the vulcanization rate is accelerated, and the vulcanization property is ideal.
4,4-Dithiodimorpholine has excellent thermal properties and is ideal for the manufacture of dynamic heat-resistant rubber products.
USES and APPLICATIONS of 4,4-DITHIODIMORPHOLINE:
4,4-Dithiodimorpholine is used in formulation or re-packing and at industrial sites.
4,4-Dithiodimorpholine is used in the following products: polymers.
Release to the environment of 4,4-Dithiodimorpholine can occur from industrial use: formulation of mixtures and formulation in materials.
4,4-Dithiodimorpholine is used for the manufacture of: rubber products.
4,4-Dithiodimorpholine is used sulphur donor vulcanizing agent for efficient vulcanization and semi-efficient vulcanization cure system; provide heat/reversion/aging resistance in NR and synthetic rubbers; non-blooming; excellent storage safety.
4,4-Dithiodimorpholine can be used to improve the anti-retrogradation and anti-thermal aging properties of sulfur vulcanized elastomer.
4,4-Dithiodimorpholine can be used as vulcanizing agent and accelerator for natural rubber and synthetic rubber.
The rubber feed of this product does not spray frost, pollution, discoloration and easy dispersion.
The vulcanizates obtained when used in effective and half-effect vulcanization systems have good heat resistance and aging resistance.
Active sulfur can be released at vulcanization temperature, the effective sulfur content is 27%, the operation is safe, the vulcanization speed is slow when used alone, and the use of thiazole, thiuram and dithiocarbamate can increase the vulcanization speed.
4,4-Dithiodimorpholine is especially suitable for butyl rubber.
4,4-Dithiodimorpholine is produced in the manufacture of tires, butyl inner tubes, adhesive tapes and heat-resistant rubber products.
4,4-Dithiodimorpholine is also used as an asphalt stabilizer for vertical highways.
4,4-Dithiodimorpholine is suitable for natural rubber and synthetic rubber, with the characteristics of heat resistance, fatigue resistance, reduction resistance, no frost spraying, and scorch prevention.
4,4-Dithiodimorpholine can be used in the butyl rubber to produce tyre, butyl inner tube of tire, rubber belt and anti-heat rubber products, it also can be used as pitch stabilizer in the expressway.
4,4-Dithiodimorpholine is widely used in articles resistant to reversion based on NR such as tyre carcasses & ageing resistant articles based on SBR, NBR and EPDM
4,4-Dithiodimorpholine can be used as vulcanizing agent and accelerator of natural rubber and synthetic rubber.
In cross linking reaction, 4,4-Dithiodimorpholine mainly forms mono-sulfur bond.
Release to the environment of 4,4-Dithiodimorpholine can occur from industrial use: as processing aid.
Application of 4,4-Dithiodimorpholine: Sulphur donor vulcanizing agent for efficient vulcanization and semi-efficient vulcanization cure system; provide heat/reversion/aging resistance in NR and synthetic rubbers; non-blooming; excellent storage safety.
4,4-Dithiodimorpholine acts as a vulcanizing agent.
Recommended of 4,4-Dithiodimorpholine to be used in rubber.
So many rubber products manufacturers including domestic and overseas pay attention to 4,4-Dithiodimorpholine.
Generally, 4,4-Dithiodimorpholine is used in combination, or sulfenamide or thiazole accelerator is used to adjust the scorch period and vulcanization rate.
4,4-Dithiodimorpholine can be used as a vulcanizing agent and accelerator for natural rubber and synthetic rubber.
4,4-Dithiodimorpholine is mainly used as vulcanization agent and accelerator for natural rubber and artificial rubber.
Under vulcanizing temperature, 4,4-Dithiodimorpholine can decompose active sulfur, whose content is 27%.
4,4-Dithiodimorpholine is primarily used in the synthesis of organosulfur compounds and has also been used in the synthesis of other organic and inorganic compounds such as nitriles, amides, and heterocycles.
The vulcanized rubber has good heat resistance and aging resistance when used in effective and semi-effective vulcanization systems.
At the sulfurization temperature can release the active sulfur, effective sulfur content is 27%, safe operation, when 4,4-Dithiodimorpholine is used alone the sulfurization speed is slow, and thiazole class, thiuram class and dithiocarbamate can be used to increase the sulfurization speed.
4,4-Dithiodimorpholine is especially suitable for butyl rubber, mainly used in the manufacture of tire, butyl inner tube, rubber belt and heat resistant rubber products, also used in highway asphalt stabilizer.
4,4-Dithiodimorpholine does not spray frost, does not pollute, does not change color, easy to disperse.
4,4-Dithiodimorpholine is used suitable for natural rubber and synthetic rubber, with heat resistance, fatigue resistance, anti-reduction, no frost, anti-scorch characteristics.
4,4-Dithiodimorpholine is produced in the manufacture of tires, butyl inner tubes, adhesive tapes and heat-resistant rubber products.
APPLICATION AND CHARACTERISTICS OF 4,4-DITHIODIMORPHOLINE:
4,4-Dithiodimorpholine is mainly used as vulcanized agent and accelerator for natural rubber and artificial rubber.
Under vulcanizing temperature, 4,4-Dithiodimorpholine can decompose active sulfur, whose content is 27%.
In cross linking reaction, 4,4-Dithiodimorpholine mainly forms monosulphur bond. Its usual use level is 0.5-2 orders.
4,4-Dithiodimorpholine, which has the characteristic of processing safely, is usually used together with such accelerators as thiazoles, thiuram, dithiocarbamates etc.
FEATURES OF 4,4-DITHIODIMORPHOLINE:
4,4-Dithiodimorpholine is the offering body of the sulphur.
4,4-Dithiodimorpholine will release a percentage of 27 active sulphur in the temperature of vulcanization.
4,4-Dithiodimorpholine will produce a high connecting effect to the rubber, part or whole replace the sulphur, so make the active sulphur gain an ideal physical machine function.
That makes up half effective structure rubber tesist not only fatigue but also oxidation.
According to 4,4-Dithiodimorpholine’s special chemical structure in the performance of vulcanized agent ,promoter, anti- oxidantand prevent coking comprehensive effect.
So many rubber products manufacturers including domestic and overseas pay attention to 4,4-Dithiodimorpholine.
Vulcanization temperature, in addition to release active sulphur, so that make the rubber produce a high connecting function, morphlinyl, which has the second amine structure feature.
This kind of free radical can not only resist heat and oxygen, but also delay coking time, so that speed up vulcanization.
So, 4,4-Dithiodimorpholinehas a performance of vulcanized agent ,promoter, anti- oxidantand prevent coking comprehensive effect.
CHARACTER OF 4,4-DITHIODIMORPHOLINE:
4,4-Dithiodimorpholine is a white needle-like crystal.
Relative density 1.32-1.38.
4,4-Dithiodimorpholine is soluble in benzene, carbon tetrachloride, slightly soluble in acetone, gasoline, insoluble in ethanol, ether, insoluble in water.
4,4-Dithiodimorpholine is decomposition in the presence of an inorganic acid or base.
4,4-Dithiodimorpholine is stable storage at room temperature. 4,4-Dithiodimorpholine is non-toxic, fishy.
WHAT IS 4,4-DITHIODIMORPHOLINE AND WHERE IS 4,4-DITHIODIMORPHOLINE FOUND?
4,4-Dithiodimorpholine is used as an accelerator and vulcanizing agent used in rubber products.
4,4-Dithiodimorpholine is also used to protect metals against corrosion and tarnish by acid fumes as well as in toiletry and cosmetic products, hair conditioners, deodorant products and hair dyes.
4,4-Dithiodimorpholine is also found in pharmaceuticals for local anesthetics and antibiotics.
Further research may identify additional product or industrial usages of 4,4-Dithiodimorpholine.
MARKET OVERVIEW OF AND REPORT COVERAGE OF 4,4-DITHIODIMORPHOLINE:
4,4-Dithiodimorpholine is a chemical compound used as a crosslinking agent in the rubber industry.
4,4-Dithiodimorpholine is primarily used in the production of rubber products to improve their mechanical properties, such as hardness, flexibility, and abrasion resistance.
4,4-Dithiodimorpholine is widely used in the manufacturing of rubber tires, seals, gaskets, conveyor belts, and other rubber products.
The future outlook of the 4,4-Dithiodimorpholine market is promising.
The increasing demand for rubber products across various industries such as automotive, construction, and electronics is driving the growth of this market.
The rising focus on improving the performance and durability of rubber products to meet the stringent quality standards is further boosting the demand for 4,4-Dithiodimorpholine.
Moreover, the growing automotive industry, particularly in emerging economies, is expected to fuel the demand for rubber tires, which, in turn, will drive the demand for 4,4-Dithiodimorpholine.
Additionally, the increasing environmental concerns and regulations regarding the disposal of rubber waste are encouraging manufacturers to seek sustainable and eco-friendly rubber products, further driving the market growth.
The current outlook of the 4,4-Dithiodimorpholine market is positive, with steady growth observed in recent years.
The market is characterized by the presence of several key players who are actively engaged in research and development activities to enhance product performance and expand their market share.
Manufacturers are also focusing on strategic partnerships, collaborations, and acquisitions to strengthen their market position and gain a competitive edge.
Overall, the 4,4-Dithiodimorpholine market is expected to witness significant growth in the coming years.
With increased demand for high-quality and durable rubber products, coupled with technological advancements in the manufacturing process, the market is projected to grow at a CAGR of % during the forecasted period.
PRODUCTION METHOD OF 4,4-DITHIODIMORPHOLINE:
add morpholine, solvent gasoline (or benzene and toluene) and a small amount of water to the reaction kettle.
After stirring evenly, add sulfur monochloride, gasoline and sodium hydroxide solution dropwise into the kettle at the same time, control the temperature below 10 ℃, and add the sodium hydroxide solution slightly before a carbon chloride dropwise.
After dropping, add a certain amount of water and continue stirring for 30min.
The reactants are then pumped out, and the filtrate is separated from the water phase of gasoline and recovered.
The filter cake is added to the centrifuge and washed with water to be neutral.
After removing the water, 4,4-Dithiodimorpholine is dried to obtain the finished product.
SOURCES/USES OF 4,4-DITHIODIMORPHOLINE:
4,4-Dithiodimorpholine is used as a stain protector for rubber, a vulcanizer (sulfur donor) and accelerator for natural and synthetic rubbers, a fungicide, and a curing agent for poly(fluoroalkoxyphosphazenes).
PURIFICATION METHODS OF 4,4-DITHIODIMORPHOLINE:
Crystallise 4,4-Dithiodimorpholine from hot aqueous dimethylformamide or EtOH.
4,4-Dithiodimorpholine is a fungicide.
CHARACTERISTICS AND APPLICATION OF 4,4-DITHIODIMORPHOLINE:
4,4-Dithiodimorpholine is mainly used as vulcanized agent and accelerator for natural rubber and artificial rubber.
Under vulcanizing temperature, 4,4-Dithiodimorpholine can decompose active sulfur, whose content is 27%.
In cross linking reaction, 4,4-Dithiodimorpholine mainly forms monosulphur bond.
4,4-Dithiodimorpholines usual use level is 0.5-2 orders.
4,4-Dithiodimorpholine, which has the characteristic of processing safely, is usually used together with such accelerators as thiazoles, thiuram, dithiocarbamates etc.
SCIENTIFIC RESEARCH APPLICATIONS OF 4,4-DITHIODIMORPHOLINE:
Chemical Synthesis and Organic Chemistry: 4,4-Dithiodimorpholine's used in the synthesis of thiiranes, contributing to the study of organic chemical reactions.
Toxicology: Research has shown that 4,4-Dithiodimorpholine exhibits significant embryotoxicity, making it a critical subject in studies related to chemical toxicity and environmental safety.
Medical Applications: 4,4-Dithiodimorpholine has potential as a lead compound in treating neoplastic lesions of the cervix by acting on the oncoprotein E6 of human papillomavirus-16.
Antiviral Research: Studies have compared 4,4-Dithiodimorpholine's effects with other compounds in treating HPV-related lesions, contributing to the development of antiviral therapies.
Material Science and Engineering: 4,4-Dithiodimorpholine's effects on the ageing properties of SBS-modified asphalts have been studied, indicating its role in improving the durability of road materials.
Rubber Chemistry: Research has been conducted on 4,4-Dithiodimorpholine'effects on the mechanical properties of EPDM vulcanizate, an important aspect in the field of polymer science and rubber technology.
PHYSICAL and CHEMICAL PROPERTIES of 4,4-DITHIODIMORPHOLINE:
Molecular Weight: 236.4 g/mol
XLogP3-AA: 0.6
Hydrogen Bond Donor Count: 0
Hydrogen Bond Acceptor Count: 6
Rotatable Bond Count: 3
Exact Mass: 236.06532010 g/mol
Monoisotopic Mass: 236.06532010 g/mol
Topological Polar Surface Area: 75.5Ų
Heavy Atom Count: 14
Formal Charge: 0
Complexity: 143
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes
CAS: 103-34-4
Formula: C8H16N2O2S2
Molecular weight: 236,35 g/mol
Melting point: 124-125°C
Boiling point: 371.7±52.0 °C(Predicted)
Density: 1.32~1.38g/cm3
vapor pressure: 0.004Pa at 25℃
refractive index: 1.6300 (estimate)
storage temp.: Refrigerator
form: powder to crystaline
pka: 0.78±0.20(Predicted)
color: White to Almost white
Specific Gravity: 1.36
Water Solubility: 215mg/L at 20.2℃
Merck: 14,3372
InChIKey: HLBZWYXLQJQBKU-UHFFFAOYSA-N
LogP: 2.67 at 22℃
Indirect Additives used in Food Contact Substances: 4,4'-DITHIODIMORPHOLINE
FDA 21 CFR: 175.105; 177.2600
CAS DataBase Reference: 103-34-4(CAS DataBase Reference)
EWG's Food Scores: 1
FDA UNII: M786P489YF
NIST Chemistry Reference: Morpholine disulfide(103-34-4)
EPA Substance Registry System: Morpholine, 4,4'-dithiobis- (103-34-4)
Melting point : 124-125°C
Boiling point : 371.7±52.0 °C(Predicted)
density : 1.32~1.38g/cm3
vapor pressure: 0.004Pa at 25℃
refractive index :1.6300 (estimate)
storage temp. : Refrigerator
form : powder to crystaline
pka: 0.78±0.20(Predicted)
color: White to Almost white
Specific Gravity: 1.36
Water Solubility: 215mg/L at 20.2℃
Merck: 14,3372
InChIKey: HLBZWYXLQJQBKU-UHFFFAOYSA-N
LogP: 2.67 at 22℃
CAS DataBase Reference: 103-34-4(CAS DataBase Reference)
NIST Chemistry Reference: Morpholine disulfide(103-34-4)
EPA Substance Registry System: Morpholine, 4,4'-dithiobis- (103-34-4)
Physical state: powder
Color: white
Odor: No data available
Melting point/freezing point:
Melting point/range: 125,0 °C - OECD Test Guideline 102
Initial boiling point and boiling range: No data available
Flammability (solid, gas): No data available
Upper/lower flammability or explosive limits: No data available
Flash point: No data available
Autoignition temperature: No data available
Decomposition temperature: No data available
pH: No data available
Viscosity
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Water solubility: 0,215 g/l at 20,2 °C
Partition coefficient:
n-octanol/water:
log Pow: 2,67 at 22 °C
Vapor pressure: 0,00004 hPa at 25 °C
Density: 0,4525 g/cm3 at 20 °C
Relative density: No data available
Relative vapor density: No data available
Particle characteristics: No data available
Explosive properties: No data available
Oxidizing properties: none
Other safety information: No data available
Molecular Formula / Molecular Weight: C8H16N2O2S2 = 236.35
Physical State (20 deg.C): Solid
Storage Temperature: 0-10°C
Condition to Avoid: Heat Sensitive
CAS RN 103-34-4
Reaxys Registry Number: 126214
PubChem Substance ID: 87566980
SDBS (AIST Spectral DB): 10257
Merck Index (14): 3372
MDL Number: MFCD00023319
CAS: 103-34-4
Color: White-Yellow
MDL Number: MFCD00023319
Synonym: N,N′C-Dimorpholine Disulfide, N,N′C-Dithiobis(morpholine)
SMILES: C1COCCN1SSN2CCOCC2
Molecular Weight (g/mol): 236.348
Formula Weight: 236.35
Physical Form: Crystalline Powder
Melting Point: 125°C
Molecular Formula: C8H16N2O2S2
InChI Key: HLBZWYXLQJQBKU-UHFFFAOYSA-N
IUPAC Name: 4-(morpholin-4-yldisulfanyl)morpholine
PubChem CID: 7648
Percent Purity: ≥98.0% (HPLC,N)
Chemical Name or Material: 4,4′-Dithiodimorpholine
CAS No.: 103-34-4
Molecular Formula: C8H16N2O2S2
InChIKeys: InChIKey=HLBZWYXLQJQBKU-UHFFFAOYSA-N
Molecular Weight: 236.35500
Exact Mass: 236.35
EC Number: 203-103-0
UNII: M786P489YF
NSC Number: 65239
DSSTox ID: DTXSID8026698
Color/Form: CRYSTALS|GRAY TO TAN POWDER
Categories: Antioxidants
PSA: 75.54000
XLogP3: 0.73800
Appearance: DryPowder; DryPowder, PelletsLargeCrystals; PelletsLargeCrystals
Density: 1.36 g/cm3 @ Temp: 25 °C
Melting Point: 125 °C
Boiling Point: 371.7ºC at 760 mmHg
Flash Point: 154ºC
Refractive Index: 1.6300 (estimate)
Storage Conditions: Refrigerator
Density: 1.36
Appearance: White Crystal powder
Melting Point: 120 degC min
Ash: 0.30% max
Particle Size: Max- 1.0(63um), 0.50(um)
Oil: 0; 1.0~2.0
Loss on Drying: 0.30% max
Specific gravity: 1.28~1.32
Molecular weight: 236.38
Melting point : 124-125°C
Boiling point : 371.7±52.0 °C(Predicted)
density: 1.32~1.38g/cm3
vapor pressure : 0.004Pa at 25℃
refractive index: 1.6300 (estimate)
storage temp.: Refrigerator
pka: 0.78±0.20(Predicted)
form: powder to crystaline
color: White to Almost white
Specific Gravity: 1.36
Water Solubility: 215mg/L at 20.2℃
Merck: 14,3372
InChIKey: HLBZWYXLQJQBKU-UHFFFAOYSA-N
LogP: 2.67 at 22℃
Molecular Weight:236.35500
Exact Mass:236.35
EC Number:203-103-0
UNII:M786P489YF
NSC Number:65239
DSSTox ID:DTXSID8026698
Color/Form:CRYSTALS|GRAY TO TAN POWDER
PSA:75.54000
XLogP3:0.73800
Appearance:DryPowder; DryPowder, PelletsLargeCrystals; PelletsLargeCrystals
Density:1.36 g/cm3 @ Temp: 25 °C
Melting Point:125 °C
Boiling Point:371.7ºC at 760 mmHg
Flash Point:154ºC
Refractive Index:1.6300 (estimate)
Storage Conditions: Refrigerator
Melting Point: 124-125°C
Boiling Point: 371.7±52.0 °C at 760 mmHg
Flash Point: 178.6±30.7 °C
Molecular Formula: C8H16N2O2S2
Molecular Weight: 236.355
Density: 1.3±0.1 g/cm3
CAS: 103-34-4
EINECS: 203-103-0
InChI: InChI=1/2C4H9NO.2S/c2*1-3-6-4-2-5-1;;/h2*5H,1-4H2;;/q;;2*-2
InChIKey: HLBZWYXLQJQBKU-UHFFFAOYSA-N
Molecular Formula: C8H16N2O2S2
Molar Mass: 236.35
Density: 1.32~1.38g/cm3
Melting Point: 124-125°C
Boling Point: 371.7±52.0 °C(Predicted)
Water Solubility: 215mg/L at 20.2℃
Vapor Presure: 0.004Pa at 25℃
Appearance: White powder
Specific Gravity: 1.36
Color: White to Almost white
Merck: 14,3372
pKa: 0.78±0.20(Predicted)
Storage Condition: Refrigerator
Refractive Index: 1.6300 (estimate)
MDL: MFCD00023319
Physical and Chemical Properties: White needle-like crystals.
Fish Odor.
FIRST AID MEASURES of 4,4-DITHIODIMORPHOLINE:
-Description of first-aid measures:
*General advice:
Show this material safety data sheet to the doctor in attendance.
*If inhaled:
After inhalation:
Fresh air.
*In case of skin contact:
Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
Consult a physician.
*In case of eye contact:
After eye contact:
Rinse out with plenty of water.
Remove contact lenses.
*If swallowed:
After swallowing:
Immediately make victim drink water (two glasses at most).
Consult a physician.
-Indication of any immediate medical attention and special treatment needed:
No data available
ACCIDENTAL RELEASE MEASURES of 4,4-DITHIODIMORPHOLINE:
-Personal precautions, protective equipment and emergency procedures:
*Advice for non-emergency personnel:
Ensure adequate ventilation.
-Environmental precautions:
Do not let product enter drains.
-Methods and materials for containment and cleaning up:
Cover drains.
Collect, bind, and pump off spills.
Observe possible material restrictions.
Take up dry.
Dispose of properly.
Clean up affected area.
FIRE FIGHTING MEASURES of 4,4-DITHIODIMORPHOLINE:
-Extinguishing media:
*Suitable extinguishing media:
Water
Foam
Carbon dioxide (CO2)
Dry powder
*Unsuitable extinguishing media:
For this substance/mixture no limitations of extinguishing agents are given.
-Further information:
Suppress (knock down) gases/vapors/mists with a water spray jet.
Prevent fire extinguishing water from contaminating surface water or the ground water system.
EXPOSURE CONTROLS/PERSONAL PROTECTION of 4,4-DITHIODIMORPHOLINE:
-Control parameters:
--Ingredients with workplace control parameters:
-Exposure controls:
--Personal protective equipment:
*Eye/face protection:
Safety glasses
*Skin protection:
Full contact:
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Splash contact:
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
*Body Protection:
protective clothing
*Respiratory protection:
Recommended Filter type: Filter type P2
-Control of environmental exposure:
Do not let product enter drains.
HANDLING and STORAGE of 4,4-DITHIODIMORPHOLINE:
-Conditions for safe storage, including any incompatibilities:
*Storage conditions:
Tightly closed.
Dry.
STABILITY and REACTIVITY of 4,4-DITHIODIMORPHOLINE:
-Chemical stability:
The product is chemically stable under standard ambient conditions (room temperature) .
-Conditions to avoid:
no information available
-Incompatible materials:
No data available